CN107955680A - A kind of import cutter special environment protection antirust oil and preparation method thereof - Google Patents
A kind of import cutter special environment protection antirust oil and preparation method thereof Download PDFInfo
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- CN107955680A CN107955680A CN201711265824.1A CN201711265824A CN107955680A CN 107955680 A CN107955680 A CN 107955680A CN 201711265824 A CN201711265824 A CN 201711265824A CN 107955680 A CN107955680 A CN 107955680A
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- monoamine
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/041—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving a condensation reaction
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/065—Organic compounds derived from inorganic acids or metal salts derived from Ti or Zr
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/48—Slushing oils
Abstract
The present invention provides a kind of import cutter special environment protection antirust oil, and the preparing raw material of the antirust oil includes：Antirust agent, base oil, corrosion inhibiter, antioxidant, antirust agent adjuvant；Possess excellent rustless property and antirust cycle.
Description
Technical field
The present invention relates to a kind of environment-friendly antirust oil, and in particular to a kind of import cutter special environment protection antirust oil and its preparation side
Method.
Background technology
Antirust oil reservoir can protect tool surface, and not so tool surface is easier to wear.Cutter also can at the same time
In use, by the flushing of various surfactants, therefore existing antirust oil effect is general, the antirust cycle compared with
It is short, it is impossible to carry out the antirust of longer term.
For example, if metal surface is attached with chloride or water, antirust oil is difficult to fully play its effect.Processing
Early period process Metalworking fluid in used the material of the extreme pressure additive containing chlorine system in the case of, fill in order to obtain
The rustless property divided, it is necessary to remove the chloride as the occurrence factor that gets rusty in advance.Therefore it is being known as specified in JIS K2246
The fingerprint of NP-0 remove often chloride is washed in shape antirust oil, remove after reuse antirust oil.Meanwhile to being attached to moisture
Metal implement antirust treatment, it is necessary to first except water-based excellent finish is washed and removes moisture, to be then coated with antirust oil.
But due to reasons such as productivity and costs, can not often implement " removing moisture ", " coating antirust oil " this two procedures, because
This people seeks the finish that processing can be made unified.But actual conditions are, only by with except water-based finish
Then rust-preventing characteristic is inadequate for reason, and omits water removal process and be coated with antirust oil again less than sufficient rustless property.
Meanwhile existing antirust oil substantially adds one or more rust-inhibiting additives (again in petroleum-type solvent
Claim oil-soluble inhibitor) form, the rust-inhibiting additive of rust-inhibiting additive generally use nitrites or organic, it exists such as
Lower defect：1st, the rust-inhibiting additive of nitrites is poisonous, easily pollutes environment, and its metal surface adhesion property compared with
Difference, the oil film of formation is relatively thin, and stability is poor；2nd, the antirust oil using organic matter as main rust-inhibiting additive can not solve micro- life
Thing etching problem.Therefore the synthesis rustless property of existing antirust oil is poor, it is difficult to ensures the working performance and service life of cutter.
For the above situation, the present invention relates to a kind of import cutter special environment protection antirust oil and preparation method thereof.
The content of the invention
The present invention provides a kind of import cutter special environment protection antirust oil, it is characterised in that the preparing raw material of the antirust oil
Comprising：
Antirust agent, base oil, corrosion inhibiter, antioxidant, antirust agent adjuvant.
As one embodiment of the present invention, in parts by weight, the preparing raw material of the antirust oil includes：
As one embodiment of the present invention, in parts by weight, the preparing raw material of the antirust oil includes：
As one embodiment of the present invention, the base oil be selected from vegetable and animals oils, mineral oil, hydrogenated oil, solvent naphtha,
At least one of transformer oil or artificial oil.
As one embodiment of the present invention, the preparing raw material of the antirust agent is：Methyltrimethoxysilane, metatitanic acid
Four butyl esters and dimethyl diethoxysilane.
As one embodiment of the present invention, the preparation method of the antirust agent is as follows：By methyltrimethoxysilane
It is added to dimethyl diethoxysilane in reactor, after hydrolysis, adds solution of tetrabutyl titanate, antirust is obtained after reaction
Agent.
As one embodiment of the present invention, the corrosion inhibiter is organic inhibitor.
As one embodiment of the present invention, the antirust agent adjuvant is selected from alcamines material.
As one embodiment of the present invention, the alcamines material is selected from single alkanol of the alcohol of carbon number 1~16
Monoamine, the dialkanol monoamine of alcohol of carbon number 1~7, three alkanol monoamines of alcohol with 3 carbon numbers 1~5, with 1
The monoalkyl dialkanol monoamine of the alcohol of the alkyl of carbon number 2~4 and 2 carbon numbers 2~5, have 2 carbon numbers 2~4
Alkyl and 1 carbon number 2~5 alcohol dialkyl group list alkanol monoamine, there is the alcohol of cyclohexyl and 1 carbon number 2 or 3
Monocyclic hexyl list alkanol monoamine, have in the monocyclic hexyl dialkanol monoamine of alcohol of cyclohexyl and 2 carbon numbers 2 or 3
It is a kind of.
As one embodiment of the present invention, the alcamines material is selected from single alkanol of the alcohol of carbon number 1~16
Monoamine, the dialkanol monoamine of alcohol of carbon number 1~7, three alkanol monoamines of alcohol with 3 carbon numbers 1~5, with 1
The monoalkyl dialkanol monoamine of the alcohol of the alkyl of carbon number 2~4 and 2 carbon numbers 2~5, have 2 carbon numbers 2~4
Alkyl and 1 carbon number 2~5 alcohol dialkyl group list alkanol monoamine, there is the alcohol of cyclohexyl and 1 carbon number 2 or 3
Monocyclic hexyl list alkanol monoamine in one kind.
Embodiment
Participate in the election of the detailed description of the invention below for being preferable to carry out method and including embodiment this hair can be more easily understood
Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with fields of the present invention
The normally understood identical implication of technical staff.When there is a conflict, the definition in this specification shall prevail.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ",
" having ", " containing " or its any other deformation, it is intended that cover including for non-exclusionism.For example, the combination comprising listed elements
Thing, step, method, product or device are not necessarily limited to those key elements, but can include not expressly listed other key elements or
Such a composition, step, method, product or the intrinsic key element of device.
Conjunction " Consists of " excludes any key element do not pointed out, step or component.If be used in claim, this
Phrase will make claim be closed, it is not included the material in addition to the material of those descriptions, but relative normal
Except rule impurity.When being rather than immediately following in the clause that phrase " Consists of " appears in claim main body after theme,
It is only limited to the key element described in the clause；Other key elements are not excluded outside the claim as a whole.
Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit
During the Range Representation that choosing value limits, this, which is appreciated that, specifically discloses by any range limit or preferred value and any scope
All scopes that any pairing of lower limit or preferred value is formed, regardless of whether the scope separately discloses.For example, when open
During scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to
5 ", " 1 to 3 and 5 " etc..When number range is described herein, unless otherwise stated, otherwise the scope is intended to include its end
Value and all integers and fraction within the range.
Singulative includes plural number and object is discussed, unless the context clearly dictates otherwise." optional " or it is " any
It is a kind of " refer to that the item that describes thereafter or event may or may not occur, and the description include situation that event occurs and
The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, represents specific the present invention is not limited to this
Quantity, further includes the modified part of the acceptable change without cause related basic function close to the quantity.Phase
Answer, modify a numerical value with " about ", " about " etc., mean that the invention is not restricted to the exact numerical.It is approximate in some examples
Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, scope limits can be with
Combine and/or exchange, these scopes include all subranges contained therebetween if not stated otherwise.
In addition, indefinite article " one kind " before key element of the present invention or component and "one" quantitative requirement to key element or component
(i.e. occurrence number) unrestriction.Therefore "one" or " one kind " should be read as including one or at least one, and odd number
The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.
One aspect of the present invention provides a kind of import cutter special environment protection antirust oil, and the preparing raw material of the antirust oil includes：
Antirust agent, base oil, corrosion inhibiter, antioxidant, antirust agent adjuvant.
Antirust agent
Metal processing piece is during production and processing and transport, it is easy to gets rusty, this is just needed using antirust oil in gold
Metal surface forms thin film, prevents the chemicals of corrosion of metal.So-called rust is due to that oxygen and water act on metal surface generation
The mixture of oxide and hydroxide, iron rust are red, and patina is green, and the rust of aluminum and zinc claims white rust.Machinery exists
It is difficult not contacted with the oxygen in air, moisture or other Korrosionsmediums in operation and storage, these materials will in metal surface
Generation electrochemical corrosion and get rusty, to prevent corrosion from above material must be prevented to be contacted with metal.
Antirust agent is a kind of synthesis bleeding agent of super grade high efficiency, it can be strongly penetrated into iron rust, erosion, greasy dirt so as to light
Loose ground disposes screw, the rusty stain on snail and erosion, has infiltration derusting, loosens lubrication, resists burn into protection metal etc.
Performance.And can be formed on parts surface and store one layer of lubricating film, moisture can be suppressed and many other chemical analysis cause
Corrosion.
Antirust agent is a kind of surfactant that liquid can be made quickly and evenly to penetrate into certain solid interior, is being printed and dyed
There is extensive purposes in industry.Shu Bo profit bleeding agents are made into using active permeation auxiliary agent, lubricant and rust remover etc., have pine
The multi-functional such as rust, anti-corrosion, moisture-proof, cleaning, lubrication, protection, penetrating power is strong, easy to use, to metal, woodenware, facing etc.
Material is corrosion-free, and has defencive function.
As one embodiment of the present invention, the preparing raw material of the antirust agent includes：Methyltrimethoxysilane, titanium
Sour four butyl esters and dimethyl diethoxysilane.
As one embodiment of the present invention, the preparation method of the antirust agent is as follows：
6.8g methyltrimethoxysilane and 11.1g dimethyl diethoxysilanes are added in reactor, added
5.4g water, adds the hydrolysis of second acid as catalyst, adds the mixed liquor of 8.5g butyl titanates and 5g n-butanols, heats up and flowing back
Under the conditions of react 3h, obtain antirust agent solution, removed under reduced pressure solution, obtains antirust agent.
Base oil
Base oil mainly divides mineral base oil, synthetic base oil and plant oil base oil three classes.Mineral base oil application
Extensively, dosage is very big (about more than 90%), but some application scenarios must then use synthetic base oil and plant oil base oil tune
The product matched somebody with somebody, Esters oil is as the high-end use of lubricating oil.
Dormant oils base oil is refined by crude oil and formed.The main production process of lube base oil has：Atmospheric and vacuum distillation, solvent take off
Pitch, solvent refining, solvent dewaxing, carclazyte or hydrofining.Nineteen ninety-five has revised the existing lube base oil in China
Standard, mainly have modified sorting technique, and add the low solidifying and special base oil standard of two class of deep refining.Mineral type lubricating oil
Production, it is most important that select optimal crude oil
The chemical composition of mineral base oil includes higher boiling, high-molecular weight hydrocarbon and non-hydrocarbons mixture.It forms general
For alkane (straight chain, side chain, highly branched chain), cycloalkane (monocyclic, bicyclic, polycyclic), aromatic hydrocarbons (mononuclear aromatics, polycyclic aromatic hydrocarbon), cycloalkanes
Base aromatic hydrocarbons and the non-hydrocarbons such as oxygen-containing, nitrogenous, organic compounds containing sulfur and colloid, asphalitine.
Synthetic lubricant fluid refers to that, by the base oil by being chemically synthesized, synthetic base oil has many types, common
Have：Synthesize hydrocarbon, synthetic ester, polyethers, silicone oil, fluorine-containing oil, phosphate.Synthetic lubricant fluid is better than the thermal oxidation stability of mineral oil,
The advantages that heat decomposition temperature is high, and resistance to low temperature is good.
Vegetable oil is just becoming increasingly popular, it has the characteristics that mineral oil and most of artificial oils institute are incomparable, is exactly
Can be biodegradable and rapidly reduce environmental pollution.Since reduction is all being sought to ring by industrial enterprise all in the world today
The measure of border pollution, and this " natural " lubricating oil is just possessing this feature, although vegetable oil is of high cost, the increased expense of institute
It is enough to offset using environmental improvement expense caused by other mineral oil, synthetic lubricant fluid.
Vegetable oil advantage is that the low greasy property of toxicity and extreme pressure property are better than synthesis based lubricating oil.But vegetable oil is few because of yield
And compare mineral oil.
As one embodiment of the present invention, the base oil be selected from vegetable and animals oils, mineral oil, hydrogenated oil, solvent naphtha,
At least one of transformer oil or artificial oil.
Vegetable oil is the compound being bound up by unrighted acid and glycerine, is distributed widely in nature, be from
The grease obtained in the fruit of plant, seed, plumule.Such as peanut oil, soya-bean oil, linseed oil, castor oil, rape seed oil.Vegetable oil
Main component be straight chain higher fatty acids and the ester of glycerine generation, aliphatic acid also contains in addition to palmitic acid, stearic acid and oleic acid
A variety of unsaturated acids, such as erucic acid, eleostearic acid, castor oil acid.Vegetable oil mainly contains the ore deposits such as vitamin E, K, calcium, iron, phosphorus, potassium
Material, aliphatic acid etc..Aliphatic acid in vegetable oil can make skin moisturizing glossy.
White oil, alias paraffin oil, white oil, mineral oil.Chemical constitution：This product is the mixed of the refining liquid hydrocarbon obtained by oil
The cycloalkane and alkane mixture of compound, predominantly saturation, crude oil add through normal pressure and vacuum fractionation, solvent extraction and dewaxing
Hydrogen is refined and obtained.
Hydrogenated base oil be by hydrogenation technique (hydrotreating, be hydrocracked, hydroisomerization, hydrofinishing, catalysis it is de-
Wax), change base oil chemical composition.
Solvent naphtha can be divided into three classes：Low boiling point solvent oil, such as 6# solvent for extraction, boiling range is 60-90 DEG C；Medium-boiling solvent
Oil, such as rubber solvent naphtha, boiling range are 80-120 DEG C；High boiling point solvent oil, such as paint naphtha, boiling range are 140-200 DEG C, ink
Solvent naphtha does up to 300 DEG C.Under normal circumstances, 60~90 DEG C be known as solvent for extraction, i.e., it has often been said that 6# solvents
Oil；80~120 DEG C be known as rubber solvent naphtha, i.e., it has often been said that 120# solvent naphthas；140~200 DEG C are known as paint naphtha, i.e.,
200# solvent naphthas.In addition, also 406# printing oil solvents, Stoddard solvent etc..Sometimes, each enterprise of the cutting of boiling range also has
Institute is different.For example, 6# solvent naphthas, the boiling range scope of some producers is 60~75 DEG C, usually we term it narrow 6# solvent naphthas, with
Show difference.According to produce reality, the boiling range of 120# solvent naphthas is often controlled between 90~120 DEG C.
Transformer oil：It is a kind of fraction products of oil, its main component is alkane, naphthene series's saturated hydrocarbons, aromatic series
The compounds such as unsaturated hydrocarbons.The side's of being commonly called as canopy oil, light yellow clear liquid, relative density 0.895.Solidification point<-45℃.
Artificial oil, is obtained by the method for chemical synthesis or refining processing, its complex process, refining is with high costs,
Possess the incomparable advantage of mineral oil.
As a kind of preferred embodiment of the present invention, the base oil is the mixture of mineral oil and artificial oil, and the ore deposit
The weight ratio of thing oil and artificial oil is 1：3.
The artificial oil is bought from Ai Gehao lumber's industry Materials Co., Ltd of Shenzhen, brand kluberh, model
KLUBER ERSYNTH GH 6-80。
The mineral oil purchase auspicious fine oil product Co., Ltd, model U.S. SONNEBORN mineral oil from Dongguan City
Kaydol。
Corrosion inhibiter
By appropriate concentration and in the form of be present in environment (medium) when, can prevent or slow down the chemicals of material corrosion
Matter or compound, therefore corrosion inhibiter is referred to as corrosion inhibitor.Its dosage very little (0.1%~1%), but effect is shown
Write.The method of this protection metal claims corrosion inhibiter to protect.Corrosion inhibiter is used for neutral medium (boiler feed water, recirculated cooling water), acid
Property medium (hydrochloric acid to descale, the acid dip solution of plating piece derusting before plating) and gas medium (vapour phase inhibitor).
Corrosion inhibiter can be divided into inorganic inhibitor, organic inhibitor, polymerization species corrosion inhibiter.
Inorganic inhibitor mainly includes chromate, nitrite, silicate, molybdate, tungstates, Quadrafos, zinc salt
Deng.
Organic inhibitor mainly includes phosphonic acids (salt), phosphine carboxylic acid, coloured glaze base benzothiazole, benzotriazole, lignosulfonate etc.
Some heterocyclic compounds containing oxynitrides.
Polymerization species corrosion inhibiter mainly includes the producing high-molecular of some oligomer such as polyethylene kind, POCA, poly-aspartate
Learn thing.
As one embodiment of the present invention, the corrosion inhibiter is organic inhibitor.
As one embodiment of the present invention, the corrosion inhibiter is selected from 17 alkenyl imidazoles woods alkenyl succinates, amine
Ethyl imidazol(e) hyamine, KORANTIN SH octadecylammonium salt, benzotriazole, the one of which in methyl benzotriazazole or
More than one combination.
Antioxidant
Antioxidant is a kind of chemical substance, in the presence of it is only a small amount of in polymeric system, so that it may delay or suppresses to gather
The progress of compound oxidizing process, so as to prevent the aging of polymer and extend its service life, is otherwise known as " antioxidant ".
As one embodiment of the present invention, the antioxidant is selected from phenol system or amine system antioxidant.
Phenol system antioxidant：Phenol system has the function that capture peroxylradicals stops oxidation reaction, phenol and mistake in theory
When oxyradical reacts, become stable phenol free radical.
As one embodiment of the present invention, the phenol system antioxidant is selected from acetophenone, 2,2 '-diethoxy acetyl
Benzene, to dimethylated phenyl methyl ketone, to the acetophenone class such as tert-butyl group acetophenone, benzophenone, 2- chlorobenzophenones, p, p '-bis- diformazans
Aminobenzophenone, 3,3 ', 4,4 '-four (tert-butyl-peroxy carbonyl) benzophenone, 4,4 '-lignocaine benzophenone etc. two
The benzoin ethers such as Benzophenone class, benzoin methylether, benzoin iso-propylether, benzoin butyl ether, 2- methyl isophthalic acids-(4- (methyl mercapto)
Phenyl) -2- lists foline, acetone -1,1,2- benzyl -2- dimethylaminos -1- (the mono- foline phenyl of 4-)-butanone -1, double (2,4,6- tri-
Methyl benzoyl) the glycine class such as alpha-aminoalkyl benzophenone class, N-phenylglycine such as phenyl-phosphine-oxide, 2,4- trichlorines
The triazines such as methyl-(4 '-methoxyl-styrene) -6- triazines, 2,4- trichloromethyls-(4 '-methoxyl-styrene) -6- triazines
One or more in class.
As one embodiment of the present invention, the amine system antioxidant is N- (2H-1,2,4- triazole -5- bases) salicyloyl
Amine.
Antirust agent adjuvant
The adsorption capacity of antirust agent and base material, cambial compactness influence its rustless property.
For this phenomenon, the present invention provides a kind of antirust agent adjuvant, and the antirust agent adjuvant is alcohol amine polymer,
The preparing raw material of the alcohol amine polymer includes：Diethanol amine, epoxychloropropane and sodium hydroxide.
As one embodiment of the present invention, the preparation method of the alcohol amine polymer is as follows：
(1) in the reactor, the diethanol amine of 2 molar parts and the epoxychloropropane of 1 molar part are added, is stirred at room temperature
After reacting 30min, the reaction generation chloro- 2- propyl alcohol of 1- dihydroxy amino -3-；
(2) by the reaction system of step (1) after reaction, the addition sodium hydroxide of 0.5 molar part, continues to stir at room temperature
After mixing 30min, N, N- dihydroxy ethyl amino -1,2- propylene oxide are obtained；
(3) N for obtaining step (2), N- dihydroxy ethyl amino -1,2- propylene oxide carry out epoxy addition polymerisation,
Alcohol amine polymer can be prepared；The ring-opening polymerization condition is as follows：Reacted in autoclave, nitrogen is used before reaction
Air-blowing sweeps reaction kettle 2 times, and 130 degree of reaction temperature, gauge pressure 0.25MPa, potassium hydroxide is catalyst.
As one embodiment of the present invention, the antirust agent adjuvant is selected from alcamines material.
As one embodiment of the present invention, the alcamines material is selected from single alkanol of the alcohol of carbon number 1~16
Monoamine, the dialkanol monoamine of alcohol of carbon number 1~7, three alkanol monoamines of alcohol with 3 carbon numbers 1~5, with 1
The monoalkyl dialkanol monoamine of the alcohol of the alkyl of carbon number 2~4 and 2 carbon numbers 2~5, have 2 carbon numbers 2~4
Alkyl and 1 carbon number 2~5 alcohol dialkyl group list alkanol monoamine, there is the alcohol of cyclohexyl and 1 carbon number 2 or 3
Monocyclic hexyl list alkanol monoamine, have in the monocyclic hexyl dialkanol monoamine of alcohol of cyclohexyl and 2 carbon numbers 2 or 3
It is a kind of.
The second aspect of the present invention provides the preparation method of the import cutter special environment protection antirust oil, the preparation method
The step of it is as follows：
1st, rust and corrosion and a small amount of base oil stir half an hour at 60 DEG C and obtain mixture A；
2nd, remaining preparing raw material and a small amount of base oil are mixed to prepare mixture B；
3rd, mixture A, mixture B, and remaining base oil are persistently stirred, is uniformly mixed, obtains product.
Embodiment 1：Present embodiment provides a kind of import cutter special environment protection antirust oil, and the preparation of the antirust oil is former
Material includes：Antirust agent, base oil, corrosion inhibiter, antioxidant, antirust agent adjuvant.
The import cutter special environment protection antirust oil of embodiment 2. as tdescribed in embodiment 1, it is in parts by weight, described anti-
The preparing raw material of rust oil includes：
The import cutter special environment protection antirust oil of embodiment 3. as tdescribed in embodiment 1, it is in parts by weight, described anti-
The preparing raw material of rust oil includes：
The import cutter special environment protection antirust oil of embodiment 4. as tdescribed in embodiment 1, the base oil are selected from dynamic plant
At least one of thing oil, mineral oil, hydrogenated oil, solvent naphtha, transformer oil or artificial oil.
The import cutter special environment protection antirust oil of embodiment 5. as tdescribed in embodiment 1, the preparation of the antirust agent are former
Material includes：Methyltrimethoxysilane, butyl titanate and dimethyl diethoxysilane.
The import cutter special environment protection antirust oil of embodiment 6. as tdescribed in embodiment 1, the preparation side of the antirust agent
Method is as follows：Methyltrimethoxysilane and dimethyl diethoxysilane are added in reactor, after hydrolysis, add metatitanic acid four
Butyl acetate solution, obtains antirust agent solution, removed under reduced pressure solution, obtains antirust agent after reaction.
The import cutter special environment protection antirust oil of embodiment 7. as tdescribed in embodiment 1, the corrosion inhibiter are organic slow
Lose agent.
The import cutter special environment protection antirust oil of embodiment 8. as tdescribed in embodiment 1, the antirust agent adjuvant choosing
From alcamines material.
Import cutter special environment protection antirust oil of the embodiment 9. as described in embodiment 8, the alcamines material are selected from
Single alkanol monoamine of the alcohol of carbon number 1~16, the alcohol of carbon number 1~7 dialkanol monoamine, have 3 carbon numbers 1~
The monoalkyl dioxane of the alcohol of three alkanol monoamines of 5 alcohol, the alkyl with 1 carbon number 2~4 and 2 carbon numbers 2~5
The dialkyl group list alkanol monoamine of the alcohol of alcohol monoamine, the alkyl with 2 carbon numbers 2~4 and 1 carbon number 2~5, with
The monocyclic hexyl list alkanol monoamine of the alcohol of cyclohexyl and 1 carbon number 2 or 3, have cyclohexyl and 2 carbon numbers 2 or 3
One kind in the monocyclic hexyl dialkanol monoamine of alcohol.
Import cutter special environment protection antirust oil of the embodiment 10. as described in embodiment 8, the alcamines material are selected from
Single alkanol monoamine of the alcohol of carbon number 1~16, the alcohol of carbon number 1~7 dialkanol monoamine, have 3 carbon numbers 1~
The monoalkyl dioxane of the alcohol of three alkanol monoamines of 5 alcohol, the alkyl with 1 carbon number 2~4 and 2 carbon numbers 2~5
The dialkyl group list alkanol monoamine of the alcohol of alcohol monoamine, the alkyl with 2 carbon numbers 2~4 and 1 carbon number 2~5, with
One kind in the monocyclic hexyl list alkanol monoamine of the alcohol of cyclohexyl and 1 carbon number 2 or 3.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following embodiments are only used
In the invention will be further described, it is impossible to be interpreted as limiting the scope of the invention, professional and technical personnel in the field
Some the nonessential modifications and adaptations made according to the content of the invention described above, still fall within protection scope of the present invention.
In addition, if without other explanations, it is raw materials used to be all commercially available.
Embodiment 1：The present embodiment provides a kind of import cutter special environment protection antirust oil, in parts by weight, the antirust
The preparing raw material of oil includes：
Antirust agent：The preparing raw material of the antirust agent includes：Methyltrimethoxysilane, butyl titanate and dimethyl two
Ethoxysilane；The preparation method of the antirust agent is as follows：
6.8g methyltrimethoxysilane and 11.1g dimethyl diethoxysilanes are added in reactor, added
5.4g water, adds the hydrolysis of second acid as catalyst, adds the mixed liquor of 8.5g butyl titanates and 5g n-butanols, heats up and flowing back
Under the conditions of react 3h, obtain antirust agent solution, removed under reduced pressure solution, obtains antirust agent.
Base oil：The base oil is the mixture of mineral oil and artificial oil, and the weight of the mineral oil and artificial oil
Than for 1：3.
The artificial oil is bought from Ai Gehao lumber's industry Materials Co., Ltd of Shenzhen, brand kluberh, model
KLUBER ERSYNTH GH 6-80。
The mineral oil purchase auspicious fine oil product Co., Ltd, model U.S. SONNEBORN mineral oil from Dongguan City
Kaydol。
Corrosion inhibiter：The corrosion inhibiter is amine ethyl imidazol(e) hyamine.
Antioxidant：The antioxidant is N- (2H-1,2,4- triazole -5- bases) salicylamide.
Antirust agent adjuvant：The antirust agent adjuvant is alcohol amine polymer, the preparing raw material bag of the alcohol amine polymer
Contain：Diethanol amine, epoxychloropropane and sodium hydroxide.
As one embodiment of the present invention, the preparation method of the alcohol amine polymer is as follows：
(1) in the reactor, the diethanol amine of 2 molar parts and the epoxychloropropane of 1 molar part are added, is stirred at room temperature
After reacting 30min, the reaction generation chloro- 2- propyl alcohol of 1- dihydroxy amino -3-；
(2) by the reaction system of step (1) after reaction, the addition sodium hydroxide of 0.5 molar part, continues to stir at room temperature
After mixing 30min, N, N- dihydroxy ethyl amino -1,2- propylene oxide are obtained；
(3) N for obtaining step (2), N- dihydroxy ethyl amino -1,2- propylene oxide carry out epoxy addition polymerisation,
Alcohol amine polymer can be prepared；The ring-opening polymerization condition is as follows：Reacted in autoclave, nitrogen is used before reaction
Air-blowing sweeps reaction kettle 2 times, and 130 degree of reaction temperature, gauge pressure 0.25MPa, potassium hydroxide is catalyst.
The step of preparation method of the environment-friendly antirust oil, is as follows：
1st, rust and corrosion and a small amount of base oil stir half an hour at 60 DEG C and obtain mixture A；
2nd, remaining preparing raw material and a small amount of base oil are mixed to prepare mixture B；
3rd, mixture A, mixture B, and remaining base oil are persistently stirred, is uniformly mixed, obtains product.
Embodiment 2：Difference lies in the preparing raw material of the antirust oil includes with embodiment 1：
Embodiment 3：Difference lies in the preparing raw material of the antirust oil includes with embodiment 1：
Embodiment 4：Difference lies in, antirust agent purchase from Nanjing Sai Xiang Environmental Protection Technology Co., Ltd with embodiment 1,
Brand is to match Xiang, code name SX918.
Embodiment 5：Difference lies in the weight ratio that, the base oil is mineral oil and artificial oil it is 1 with embodiment 1：1
Mixture.
Embodiment 6：Difference lies in the base oil is mineral oil with embodiment 1.
Embodiment 7：Difference lies in the base oil is artificial oil with embodiment 1.
Embodiment 8：Difference lies in the antirust agent adjuvant is diethanol amine with embodiment 1.
Embodiment 9：Difference lies in the preparing raw material of the antirust oil does not include antirust adjuvant with embodiment 1.
Test：
1st, 1 is tested：
The cutter covers knife for the silver-colored hawk of Guangdong Inwin Industry Group Co., Ltd.
Above example is only used for the method detailed for illustrating the present invention, the invention is not limited in above-mentioned method detailed, i.e.,
Do not mean that the present invention has to rely on above-mentioned method detailed and could implement.Person of ordinary skill in the field is it will be clearly understood that right
Any improvement of the present invention, addition, the selection of concrete mode of equivalence replacement and auxiliary element to each raw material of product of the present invention
Deng all falling within protection scope of the present invention and the open scope.
Claims (10)
1. a kind of import cutter special environment protection antirust oil, it is characterised in that the preparing raw material of the antirust oil includes：
Antirust agent, base oil, corrosion inhibiter, antioxidant, antirust agent adjuvant.
2. import cutter special environment protection antirust oil as claimed in claim 1, it is characterised in that in parts by weight, described anti-
The preparing raw material of rust oil includes：
3. import cutter special environment protection antirust oil as claimed in claim 1, it is characterised in that in parts by weight, described anti-
The preparing raw material of rust oil includes：
4. import cutter special environment protection antirust oil as claimed in claim 1, it is characterised in that the base oil is selected from animals and plants
At least one of oil, mineral oil, hydrogenated oil, solvent naphtha, transformer oil or artificial oil.
5. import cutter special environment protection antirust oil as claimed in claim 1, it is characterised in that the preparing raw material of the antirust agent
Comprising：Methyltrimethoxysilane, butyl titanate and dimethyl diethoxysilane.
6. import cutter special environment protection antirust oil as claimed in claim 1, it is characterised in that the preparation method of the antirust agent
It is as follows：Methyltrimethoxysilane and dimethyl diethoxysilane are added in reactor, after hydrolysis, add four fourth of metatitanic acid
Ester solution, obtains antirust agent solution, removed under reduced pressure solution, obtains antirust agent after reaction.
7. import cutter special environment protection antirust oil as claimed in claim 1, it is characterised in that the corrosion inhibiter is organic inhibition
Agent.
8. import cutter special environment protection antirust oil as claimed in claim 1, it is characterised in that the antirust agent adjuvant is selected from
Alcamines material.
9. import cutter special environment protection antirust oil as claimed in claim 8, it is characterised in that the alcamines material is selected from carbon
Single alkanol monoamine of the alcohol of atomicity 1~16, the alcohol of carbon number 1~7 dialkanol monoamine, there are 3 carbon numbers 1~5
Alcohol three alkanol monoamines, there is the monoalkyl dialkanol of the alkyl of 1 carbon number 2~4 and the alcohol of 2 carbon numbers 2~5
The dialkyl group list alkanol monoamine of the alcohol of monoamine, the alkyl with 2 carbon numbers 2~4 and 1 carbon number 2~5, with ring
The monocyclic hexyl list alkanol monoamine of the alcohol of hexyl and 1 carbon number 2 or 3, the alcohol with cyclohexyl and 2 carbon numbers 2 or 3
Monocyclic hexyl dialkanol monoamine in one kind.
10. import cutter special environment protection antirust oil as claimed in claim 8, it is characterised in that the alcamines material is selected from
Single alkanol monoamine of the alcohol of carbon number 1~16, the alcohol of carbon number 1~7 dialkanol monoamine, have 3 carbon numbers 1~
The monoalkyl dioxane of the alcohol of three alkanol monoamines of 5 alcohol, the alkyl with 1 carbon number 2~4 and 2 carbon numbers 2~5
The dialkyl group list alkanol monoamine of the alcohol of alcohol monoamine, the alkyl with 2 carbon numbers 2~4 and 1 carbon number 2~5, with
One kind in the monocyclic hexyl list alkanol monoamine of the alcohol of cyclohexyl and 1 carbon number 2 or 3.
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| CN108822940A (en) * | 2018-07-26 | 2018-11-16 | 郑州市欧普士科技有限公司 | A kind of long-life viscosity oil film rust preventive oil and preparation method thereof |
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| CN107955680B (en) | 2020-07-14 |
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