CN101230306B - Method for preparing cutting fluid - Google Patents
Method for preparing cutting fluid Download PDFInfo
- Publication number
- CN101230306B CN101230306B CN2007100101638A CN200710010163A CN101230306B CN 101230306 B CN101230306 B CN 101230306B CN 2007100101638 A CN2007100101638 A CN 2007100101638A CN 200710010163 A CN200710010163 A CN 200710010163A CN 101230306 B CN101230306 B CN 101230306B
- Authority
- CN
- China
- Prior art keywords
- acid ester
- boric acid
- water
- cutting fluid
- esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention provides a cutting fluid preparing method, which belongs to an antirust water-base cutting fluid, and is mainly used for cooling, lubricating, cleaning and rust preventing in the machine parts processing field. The invention aims at providing a preparing method for a cutting fluid which has high antirust property, stable performance and long service period. The invention adopts the following technical scheme: 1, preparing water-soluble boric acid ester and water-soluble molybdic acid ester, in a closed reaction kettle, under the condition of 90-180 DEG C, reacting diethanolamine, boric acid and alcohol to prepare molybdic acid ester; 2, the cutting fluid including the components by weight percentage: 8-10% of boric acid ester, 6-10% of antirust, 2-4% of molybdic acid ester, 1-3% of foam suppressor, 0.5-2% of oleic acid, 10-18% of emulsifier, 5-8% of triethanolamine, 2-3% of osmotic agent, 2-4% of benzoate, and the balance water.
Description
Technical field:
The present invention belongs to a kind of anti-rust water-based cutting fluid, is mainly used in the cooling of mechanical component manufacture field, lubricated, cleaning and antirust.
Background technology:
At present, the cutting fluid of mechanical processing industry use has machining oil and emulsion two classes.Machining oil can produce a large amount of oil smoke in high-temperature machining is produced, both contaminate environment influenced safety in production again; And machining oil needs stoste cutting, production cost height; Be that rustless property is poor again, even part get final product corrosion after 1～2 hour.Emulsion is a kind of mixed aqueous solution, and the animal and plant grease that contains in the emulsion is very easily rotten, poor stability; Breakdown of emulsion in use easily takes place, and not only life cycle is short, and the waste liquid environmental pollution is serious.
Summary of the invention:
The present invention is exactly at the problems referred to above, provides a kind of rust-preventing characteristic good, stable performance, the preparation method of the cutting fluid that life cycle is long.
The present invention adopts following technical scheme:
1, preparation water-soluble boron acid esters, water-soluble molybdates esters:
In closed reactor, under 90～180 ℃ of conditions, diethanolamine, boric acid, alcohol reaction make boric acid ester;
In closed reactor, under 90～180 ℃ of conditions, diethanolamine, amine molybdate, elaidin reaction make molybdates esters;
2, the composition of cutting fluid and weight percentage thereof are:
Boric acid ester 8～10 rust-preventive agent 6～10
Molybdates esters 2～4 defoamers 1～3
Oleic acid 0.5～2 emulsifying agent 10～18
Trolamine 5～8 permeate agents 2～3
Benzoate 2～4 water surplus
Described rust-preventive agent comprises phytic acid or higher fatty acid.
Described emulsifying agent comprises nonionic surface active agent OP or AEO.
Described alcohol is methyl alcohol, ethanol or butanols.
Beneficial effect of the present invention:
Contain water-soluble boron acid esters and water-soluble molybdates esters in the cutting fluid of the present invention, they can provide good oilness and extreme pressure property for cutting fluid.Process pyroreaction parts such as dispersive oleic acid, trolamine, benzoate, permeate agent, rust-preventive agent, defoamer are converted into soluble ester in the water, another part is under the effect of emulsifying agent, be dispersed in uniformly in the water with the colloidal solid state, can guarantee that cutting fluid has good penetration, preservative property and rust-preventing characteristic.Cutting fluid of the present invention is never degenerated at normal temperatures, but life-time service.
Embodiment:
Embodiment:
1, the preparation of boric acid ester and molybdates esters: in closed reaction kettle, control reaction temperature is 90～180 ℃, makes water-soluble boron acid esters and water-soluble molybdates esters respectively, and the needed raw material of boric acid ester and molybdates esters is as follows:
Preparation needed raw material of boric acid ester and weight percentage thereof are:
Diethanolamine 45
Boric acid 25
Butanols 30
The yield of boric acid ester is 85%.
Preparation needed raw material of molybdates esters and weight percentage thereof are:
Diethanolamine 45
Amine molybdate 15
Oleic acid 50
The yield of molybdates esters is 100%.
2, be raw material with boric acid ester, molybdates esters, add oleic acid, trolamine, benzoate, rust-preventive agent, defoamer, permeate agent, emulsifying agent and water again and become water-base cutting fluid that its each weight percentages of components is through heated polymerizable:
Boric acid ester 10
Molybdates esters 4
Oleic acid 2
Trolamine 5
Benzoate 3
Rust-preventive agent 6
Defoamer 1.5
Permeate agent 3
Emulsifying agent 15
Water surplus
Above-mentioned cutting fluid is mixed with 95% the aqueous solution, is used for the permanent magnet material slicing machine and used 40 days, nontoxic, harmless, have no irritating odor, consume diluent 40kg.Discharging is never degenerated, do not had to cutting fluid in the use, only needs regularly to replenish the needs that cutting fluid can satisfy machining accuracy.To compare cost low with the oil base cutting fluid, is a kind of ideal machining oil substitute products.
Claims (2)
1. the preparation method of a cutting fluid is characterized in that adopting following steps:
(1), prepare water-soluble boron acid esters, water-soluble molybdates esters:
In closed reactor, under 90～180 ℃ of conditions, diethanolamine, boric acid, alcohol reaction make boric acid ester;
In closed reactor, under 90～180 ℃ of conditions, diethanolamine, amine molybdate, elaidin reaction make molybdates esters;
(2), the composition of cutting fluid and weight percentage thereof are:
Boric acid ester 8～10 rust-preventive agent 6～10
Molybdates esters 2～4 defoamers 1～3
Oleic acid 0.5～2 emulsifying agent 10～18
Trolamine 5～8 permeate agents 2～3
Benzoate 2～4 water surplus.
2. the preparation method of a kind of cutting fluid according to claim 1 is characterized in that adopting following steps:
(1), the preparation of boric acid ester and molybdates esters: in closed reaction kettle, control reaction temperature is 90～180 ℃, makes water-soluble boron acid esters and water-soluble molybdates esters respectively, and the needed raw material of boric acid ester and molybdates esters is as follows:
Preparation needed raw material of boric acid ester and weight percentage thereof are:
Diethanolamine 45
Boric acid 25
Butanols 30
The yield of boric acid ester is 85%;
Preparation needed raw material of molybdates esters and weight percentage thereof are:
Diethanolamine 45
Amine molybdate 15
Oleic acid 50
The yield of molybdates esters is 100%;
(2), be raw material with boric acid ester, molybdates esters, add oleic acid, trolamine, benzoate, rust-preventive agent, defoamer, permeate agent, emulsifying agent and water again and become water-base cutting fluid through heated polymerizable, its each weight percentages of components is:
Boric acid ester 10
Molybdates esters 4
Oleic acid 2
Trolamine 5
Benzoate 3
Rust-preventive agent 6
Defoamer 1.5
Permeate agent 3
Emulsifying agent 15
Water surplus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100101638A CN101230306B (en) | 2007-01-24 | 2007-01-24 | Method for preparing cutting fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100101638A CN101230306B (en) | 2007-01-24 | 2007-01-24 | Method for preparing cutting fluid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101230306A CN101230306A (en) | 2008-07-30 |
| CN101230306B true CN101230306B (en) | 2011-05-25 |
Family
ID=39897128
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100101638A Expired - Fee Related CN101230306B (en) | 2007-01-24 | 2007-01-24 | Method for preparing cutting fluid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101230306B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101519622B (en) * | 2009-03-20 | 2012-07-18 | 天津市澳路浦润滑油有限公司 | Water-based response type multifunctional metal machining liquid and preparation method thereof |
| CN101613634B (en) * | 2009-07-28 | 2012-06-06 | 武汉玻尔科技有限公司 | High-property water-based emulsion cutting fluid composite |
| CN101812366A (en) * | 2010-04-30 | 2010-08-25 | 北京卡尔化工研究所 | Reactive type water-based metal grinding fluid and preparation method thereof |
| CN102268318B (en) * | 2010-06-01 | 2013-07-31 | 中国石油化工股份有限公司 | Water base cutting fluid composition and preparation method thereof |
| CN101914411B (en) * | 2010-08-24 | 2013-01-09 | 安庆市中天石油化工有限公司 | Anti-rust cutting fluid and preparation method thereof |
| CN102352278A (en) * | 2011-06-22 | 2012-02-15 | 江西金葵能源科技有限公司 | Special cutting fluid for diamond wire |
| CN102311864B (en) * | 2011-08-05 | 2013-04-03 | 安庆市中天石油化工有限公司 | Cutting fluid special for NC machine tools |
| CN102876439A (en) * | 2012-09-11 | 2013-01-16 | 启东新加源化工有限公司 | Cutting fluid |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3719598A (en) * | 1970-10-23 | 1973-03-06 | Master Chemical Corp | Aqueous cutting fluid which protects ferrous metals against corrosion |
| CN1139151A (en) * | 1994-06-22 | 1997-01-01 | 唐山工程技术学院 | Prepn of efficient antirusting water-base cutting fluid |
| CN1088100C (en) * | 1999-09-29 | 2002-07-24 | 中国石油化工集团公司 | Water-series wax-base lubricant and its preparing process |
| CN1546622A (en) * | 2003-12-16 | 2004-11-17 | 东风汽车有限公司 | long-acting universal processing liquid |
-
2007
- 2007-01-24 CN CN2007100101638A patent/CN101230306B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3719598A (en) * | 1970-10-23 | 1973-03-06 | Master Chemical Corp | Aqueous cutting fluid which protects ferrous metals against corrosion |
| CN1139151A (en) * | 1994-06-22 | 1997-01-01 | 唐山工程技术学院 | Prepn of efficient antirusting water-base cutting fluid |
| CN1088100C (en) * | 1999-09-29 | 2002-07-24 | 中国石油化工集团公司 | Water-series wax-base lubricant and its preparing process |
| CN1546622A (en) * | 2003-12-16 | 2004-11-17 | 东风汽车有限公司 | long-acting universal processing liquid |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101230306A (en) | 2008-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101230306B (en) | Method for preparing cutting fluid | |
| CN102719306B (en) | Green microemulsion metal cutting fluid and preparation method thereof | |
| CN102102312B (en) | Water-based zinc stearate dispersion liquid and preparation method thereof | |
| CN103361151B (en) | Lubricant composite, preparation method thereof and trace lubricant made of same | |
| CN105001964A (en) | Microemulsified cutting fluid | |
| CN100482772C (en) | Cutting liquor composition | |
| CN104450130A (en) | Metal cutting liquid and preparation method thereof | |
| CN102205390A (en) | Environmentally-friendly casting mold-releasing agent and preparation method thereof | |
| CN104593126A (en) | Rustproof lubricant and preparation method thereof | |
| CN104479833A (en) | High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof | |
| CN104830491A (en) | Antirust lubricant and preparation method thereof | |
| CN102010782A (en) | Flame-resistant hydraulic fluid composition and preparation method thereof | |
| CN108865382A (en) | A kind of stainless steel plant base water-soluble flush pressure oil and preparation method thereof | |
| CN100482773C (en) | Cutting liquor composition for metal processing | |
| CN107418673A (en) | A kind of cutting fluid of novel emulsion system based on polyisobutenyl succinic anhydride and its preparation method and application | |
| CN105670758A (en) | High-lubricity and ecological safety water-based cutting fluid and preparation method thereof | |
| CN104357201A (en) | Microemulsified cutting fluid applicable to magnesium alloy material machining and preparation method thereof | |
| CN102746932A (en) | Preparation method of environment-friendly water-based metal cutting fluid | |
| CN105062646A (en) | Rolling oil for rolling thin plate | |
| CN104312710A (en) | Fully synthesized magnesium alloy cutting fluid and preparation method thereof | |
| CN104109568B (en) | Biodiesel is for the preparation of the application of environment-friendly metal working fluid | |
| CN101629121B (en) | Novel lubricating grease and preparation method thereof | |
| CN106811280A (en) | A kind of cutting fluid and preparation method thereof | |
| CN109777564A (en) | A kind of slushing compound and preparation method thereof | |
| CN113736544B (en) | Environment-friendly water-soluble stainless steel sheet stamping oil and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110525 Termination date: 20140124 |