CN107936867A - A kind of woodwork additive with air cleaning - Google Patents

A kind of woodwork additive with air cleaning Download PDF

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Publication number
CN107936867A
CN107936867A CN201711146809.5A CN201711146809A CN107936867A CN 107936867 A CN107936867 A CN 107936867A CN 201711146809 A CN201711146809 A CN 201711146809A CN 107936867 A CN107936867 A CN 107936867A
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CN
China
Prior art keywords
parts
organic acid
woodwork
additive
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711146809.5A
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Chinese (zh)
Inventor
李壮源
张琼
柯少佳
林益曾
颜敏
黄琼涛
杨如娥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shantou City Of New Mstar Technology Ltd
Yihua Life Polytron Technologies Inc
Original Assignee
Shantou City Of New Mstar Technology Ltd
Yihua Life Polytron Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shantou City Of New Mstar Technology Ltd, Yihua Life Polytron Technologies Inc filed Critical Shantou City Of New Mstar Technology Ltd
Priority to CN201711146809.5A priority Critical patent/CN107936867A/en
Publication of CN107936867A publication Critical patent/CN107936867A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives

Abstract

The present invention is a kind of woodwork additive with air cleaning, which includes 2 imidazolidinones, erucyl amide, organic acid, interfacial agent and nanometer silicon chip;Its preparation method includes:(1)2 imidazolidinones, erucyl amide are uniformly mixed with organic acid;(2)Activating agent is added in blender, adds organic acid soln, is uniformly mixed;(3)Add powdered TiO2Nanotube;(4)Add nanometer silicon chip, stirring to the liquid that homogeneous transparent is presented.Advantage:1st, short time absorption is adsorbed, decomposes the oxious components such as the formaldehyde being hazardous to the human body in air, VOC, reaches purification air, antibacterial and mouldproof, the effect of taste removal deodorization, realizes air cleaning function;2nd, the physical behavior of glue-line or coating will not be changed.Woodwork adhesive is made an addition to, does not influence angle and performance and glue-line color;Woodwork coating is made an addition to, the heat resistance of paint film, abrasion performance are good, there is the effect for preventing light checking.

Description

A kind of woodwork additive with air cleaning
Technical field
The present invention relates to a kind of woodwork additive with air cleaning, belong to woodwork additive technology Field.
Background technology
Show according to the research to external indoor air pollutants component in the late six decades, volatile organic compounds (VOC)It is one of major pollutants in room air, and the species of interior VOC uses day with various novel chemical substances Benefit increases.Indoor VOC species is various, and contacting these low concentration multicomponent pollutants for a long time will be to the skin of people, breathing System and cardiovascular system cause great damage, may produce the stimulation of nose larynx, headache, dizziness, lethargic sleep, distraction, an evil The malaise symptoms such as the heart, uncomfortable in chest.The World Health Organization(WHO)Research show, be chronically exposed to containing formaldehyde, benzene is contour endangers VOC In the air of component, it may result in and produce the malignant diseases such as cancer, leukaemia.
In China, with deepening continuously for urbanization process in recent years, a large amount of newly constructed houses, the construction area to come into operation Increasingly increase, the demand of indoor decorating and building materials furniture also increasingly improves, but manufactures these finishing construction materials and family Adhesive used in tool and coating, include harmful VOC such as formaldehyde, benzene homologues by producing.Interior VOC pollution conditions in recent years Still it can not be ignored, especially formaldehyde and the exceeded phenomenon of TVOC contents is still more universal.Therefore, how household woodwork into Indoor air purification is realized at product end, i.e., the gaseous pollutant in air is converted into constraint by modes such as absorption and sorption, reactions State is degraded into harmless material, is that one of the present invention requires emphasis.
The content of the invention
The present invention proposes a kind of woodwork additive with air cleaning, it is desirable to provide one kind can the short time The formaldehyde composition that is hazardous to the human body in adsorption-decomposition function space is simultaneously converted into bound state or is degraded into the additive of harmless material And preparation method thereof.
Technical scheme:
A kind of woodwork additive with air cleaning, including 2- imidazolidinones, erucyl amide, organic acid, interface Activating agent, nanometer silicon chip and TiO2Nanotube, wherein 2- imidazolidinones, erucyl amide, organic acid, interfacial agent, nano-silicon Piece and TiO2The parts by weight of nanotube are followed successively by 8~30 parts, 5~15 parts, 10~60 parts, 3~15 parts, 0.1~3 part and 0.1 ~5 parts.
Its preparation method, comprises the following steps:
(1)2- imidazolidinones, erucyl amide are mixed with organic acid, 20min is stirred to complete with 800~1500r/min rotating speeds It is dissolved as organic acid soln, the parts by weight that wherein 2- imidazolidinones, erucyl amide and organic acid mix are respectively 8~30 parts, 5~ 15 parts, 10~60 parts;
(2)Interfacial agent is added in blender, interfacial agent is formed with the rotating speed stirring 15min of more than 1500r/min Mixed liquor, interfacial agent parts by weight account for 3 ~ 15 parts;
(3)By step(1)In organic acid soln be slowly added into step(2)In interfacial agent mixed liquor in, with The rotating speed stirring 30min of more than 1500r/min, is uniformly mixed;
(4)Add powdered TiO2Nanotube, 20min, TiO are stirred with the rotating speed of 2000~3000r/min2Nanotube Parts by weight are 0.1~5 part;
(5)Mixing speed is reduced to 800~1000r/min, is slowly added into a nanometer silicon chip, the parts by weight of nanometer silicon chip are 0.1 ~3 parts, it is kept stirring the liquid until homogeneous transparent is presented;
(6)Filtered with 80 mesh gauzes, after removing granule foreign, sealed packaging becomes additive finished product.
Beneficial effects of the present invention:
1st, the short time is adsorbed, decomposes the oxious components such as the formaldehyde being hazardous to the human body in air, VOC, reaches purification air, antibacterial Mould proof, taste removal deodorization effect, realizes air cleaning function;
2nd, the physical behavior of glue-line or coating will not be changed.Woodwork adhesive is made an addition to, does not influence glue performance and glue-line face Color;Woodwork coating is made an addition to, the heat resistance of paint film, abrasion performance are good, there is the effect for preventing light checking.
Embodiment
A kind of woodwork additive with air cleaning, including 2- imidazolidinones, erucyl amide, organic acid, Interfacial agent, nanometer silicon chip and TiO2Nanotube, wherein 2- imidazolidinones, erucyl amide, organic acid, interfacial agent, receive Rice silicon chip and TiO2The parts by weight of nanotube be followed successively by 8~30 parts, 5~15 parts, 10~60 parts, 3~15 parts, 0.1~3 part and 0.1~5 part.
The organic acid is one kind of acrylic acid, formic acid, acetic acid, benzoic acid, ethanedioic acid, salicylic acid, lactic acid.
The interfacial agent is polyoxyethylene sorbitol acid anhydride laurate, sodium sulfate of polyethenoxy ether of fatty alcohol and double The mixing of sebacate, one of which interfacial agent parts by weight be 1 ~ 5 part, by polyoxyethylene sorbitol acid anhydride laurate, The order of sodium sulfate of polyethenoxy ether of fatty alcohol and bis sebacate sequentially adds blender and stirs evenly.
The additive prepare rear 3 finished it is small when interior use, when small more than 3 should before use with 800~ 1000r/min speed stirs evenly.
Its preparation method, comprises the following steps:
(1)2- imidazolidinones, erucyl amide are mixed with organic acid, 20min is stirred to complete with 800~1500r/min rotating speeds It is dissolved as organic acid soln, the parts by weight that wherein 2- imidazolidinones, erucyl amide and organic acid mix are respectively 8~30 parts, 5~ 15 parts, 10~60 parts;
(2)Interfacial agent is added in blender, interfacial agent is formed with the rotating speed stirring 15min of more than 1500r/min Mixed liquor, interfacial agent parts by weight account for 3 ~ 15 parts;
(3)By step(1)In organic acid soln be slowly added into step(2)In interfacial agent mixed liquor in, with The rotating speed stirring 30min of more than 1500r/min, is uniformly mixed;
(4)Add powdered TiO2Nanotube, 20min, TiO are stirred with the rotating speed of 2000~3000r/min2Nanotube Parts by weight are 0.1~5 part;
(5)Mixing speed is reduced to 800~1000r/min, adds nanometer silicon chip, the parts by weight of nanometer silicon chip are 0.1~3 Part, it is kept stirring the liquid until homogeneous transparent is presented;
(6)Filtered with 80 mesh gauzes, after removing granule foreign, sealed packaging becomes additive finished product.
Embodiment 1
2- imidazolidinones, erucyl amide are mixed to be contained in the first tank diameter with organic acid and make preliminary mixing, treats that its is complete After moistening and dissolve entirely, the first mixed liquor is modulated into;By polyoxyethylene sorbitol acid anhydride laurate(Nonionic penetrant), fat Fat alcohol polyethenoxy ether sodium sulfate(Negative ion type interfacial agents), bis sebacate(Heat-resistant agent)Three kinds of interfacial agents sequentially add It is stirred in second tank diameter, it is to be mixed in after even phase, it is modulated into the second mixed liquor;Persistently stirred in foregoing second mixed liquor Mix in running, foregoing first mixed liquor is slowly added into the second mixed liquor and continues stir about 30 minutes, make first to mix After conjunction liquid is uniformly mixed with the second mixed liquor;Add TiO2Nanotube, adds nanometer silicon chip after being sufficiently stirred, formed uniform Transparency liquid.After the completion of mixed uniformly additive is prepared, removal impurity need to be filtered, then again sealed packaging become additive into Product.
Embodiment 2
(1)2- imidazolidinones, erucyl amide are mixed with organic acid, with 800r/min rotating speeds stir 20min to be completely dissolved for Organic acid soln, the parts by weight that wherein 2- imidazolidinones, erucyl amide and organic acid mix are respectively 8 parts, 15 parts, 60 parts;
(2)Three kinds of activating agents are added in blender, interfacial agent is formed with the rotating speed stirring 15min of more than 1500r/min Mixed liquor, interfacial agent parts by weight account for 3 parts;
(3)By step(1)The organic acid soln is slowly added into step(2)In the interfacial agent mixed liquor, with The rotating speed stirring 30min of more than 1500r/min, makes to be uniformly mixed;
(4)Add powdered TiO2Nanotube, 20min, TiO are stirred with the rotating speed of 2000r/min2The parts by weight of nanotube Number is 5 parts;
(5)Mixing speed is reduced to 1000r/min, adds nanometer silicon chip, nano-silicon sheet weight number is 1 part, equal until presenting Even transparent liquid;
(6)Filtered with 80 mesh gauzes, after removing granule foreign, sealed packaging becomes additive finished product.
Embodiment 3
(1)2- imidazolidinones, erucyl amide are mixed with organic acid, 20min is stirred to being completely dissolved with 1500r/min rotating speeds For organic acid soln, the parts by weight that wherein 2- imidazolidinones, erucyl amide and organic acid mix are respectively 30 parts, 5 parts, 10 parts;
(2)Interfacial agent is added in blender, interfacial agent mixing is formed with the rotating speed stirring 15min of 1500r/min Liquid, interfacial agent parts by weight account for 15 parts;
(3)By step(1)The organic acid soln is slowly added into step(2)In the interfacial agent mixed liquor, with The rotating speed stirring 30min of more than 1500r/min, makes to be uniformly mixed;
(4)Add powdered TiO2Nanotube, 20min, TiO are stirred with the rotating speed of 3000r/min2The parts by weight of nanotube Number is 0.1 part;
(5)Mixing speed is reduced to 800r/min, adds nanometer silicon chip, nano-silicon sheet weight number is 0.2 part, until presenting The liquid of homogeneous transparent;
(6)Filtered with 80 mesh gauzes, after removing granule foreign, sealed packaging becomes additive finished product.
Embodiment 4
(1)2- imidazolidinones, erucyl amide are mixed with organic acid, 20min is stirred to being completely dissolved with 1000r/min rotating speeds For organic acid soln, the parts by weight that wherein 2- imidazolidinones, erucyl amide and organic acid mix are respectively 26 parts, 10 parts, 50 parts;
(2)Interfacial agent is added in blender, interfacial agent mixing is formed with the rotating speed stirring 15min of 1500r/min Liquid, interfacial agent parts by weight account for 10 parts;
(3)By step(1)The organic acid soln is slowly added into step(2)In the interfacial agent mixed liquor, with The rotating speed stirring 30min of more than 1500r/min, makes to be uniformly mixed;
(4)Add powdered TiO2Nanotube, 20min, TiO are stirred with the rotating speed of 2500r/min2The parts by weight of nanotube Number is 3 parts;
(5)Mixing speed is reduced to 900r/min, adds nanometer silicon chip, nano-silicon sheet weight number is 1 part, equal until presenting Even transparent liquid;
(6)Filtered with 80 mesh gauzes, after removing granule foreign, sealed packaging becomes additive finished product.

Claims (5)

  1. A kind of 1. woodwork additive with air cleaning, it is characterized in that including 2- imidazolidinones, erucyl amide, having Machine acid, interfacial agent, nanometer silicon chip and TiO2Nanotube, wherein 2- imidazolidinones, erucyl amide, organic acid, interfacial activity Agent, nanometer silicon chip and TiO2The parts by weight of nanotube be followed successively by 8~30 parts, 5~15 parts, 10~60 parts, 3~15 parts, 0.1~ 3 parts and 0.1~5 part.
  2. A kind of 2. woodwork additive with air cleaning according to claim 1, it is characterised in that:It is described Organic acid be acrylic acid, formic acid, acetic acid, benzoic acid, ethanedioic acid, salicylic acid, lactic acid one kind.
  3. A kind of 3. woodwork additive with air cleaning according to claim 1, it is characterised in that:It is described Interfacial agent be polyoxyethylene sorbitol acid anhydride laurate, sodium sulfate of polyethenoxy ether of fatty alcohol and bis sebacate it is mixed Close, wherein the parts by weight of every kind of interfacial agent are 1 ~ 5 part, by polyoxyethylene sorbitol acid anhydride laurate, fatty alcohol polyoxy The order of ethene ether sodium sulfate and bis sebacate sequentially adds blender and stirs evenly.
  4. A kind of 4. woodwork additive with air cleaning according to claim 1, it is characterised in that:It is described Additive prepare finish rear 3 it is small when interior use, when small more than 3 should before use with 800~1000r/min speed stir Uniformly.
  5. 5. a kind of preparation method of the woodwork additive with air cleaning as claimed in claim 1, its feature It is to comprise the following steps:
    (1)2- imidazolidinones, erucyl amide are mixed with organic acid, 20min is stirred to complete with 800~1500r/min rotating speeds It is dissolved as organic acid soln, the parts by weight that wherein 2- imidazolidinones, erucyl amide and organic acid mix are respectively 8~30 parts, 5~ 15 parts, 10~60 parts;
    (2)Interfacial agent is added in blender, interfacial agent is formed with the rotating speed stirring 15min of more than 1500r/min Mixed liquor, interfacial agent parts by weight account for 3 ~ 15 parts;
    (3)By step(1)In organic acid soln be slowly added into step(2)In interfacial agent mixed liquor in, with The rotating speed stirring 30min of more than 1500r/min, is uniformly mixed;
    (4)Add powdered TiO2Nanotube, 20min, TiO are stirred with the rotating speed of 2000~3000r/min2The weight of nanotube It is 0.1~5 part to measure number;
    (5)Mixing speed is reduced to 800~1000r/min, is slowly added into a nanometer silicon chip, the parts by weight of nanometer silicon chip are 0.1 ~3 parts, it is kept stirring the liquid until homogeneous transparent is presented;
    (6)Filtered with 80 mesh gauzes, after removing granule foreign, sealed packaging becomes additive finished product.
CN201711146809.5A 2017-11-17 2017-11-17 A kind of woodwork additive with air cleaning Pending CN107936867A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Publications (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113088216A (en) * 2021-05-06 2021-07-09 中山市森林家新材料科技有限公司 Formaldehyde removal additive composition and preparation method thereof
CN113980615A (en) * 2021-12-28 2022-01-28 中山市森林家新材料科技有限公司 Functional composition for melamine adhesive layer and manufacturing method thereof
CN115039793A (en) * 2022-07-05 2022-09-13 汕头市优森活新材料科技有限公司 Indoor efficient antibacterial smell-cleaning agent and preparation method and application thereof

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CN107151543A (en) * 2017-06-20 2017-09-12 合肥市淑芹美装饰工程有限公司 It is a kind of for the adhesive on floor and preparation method thereof

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CN105802414A (en) * 2016-04-15 2016-07-27 刘云 Preparation method of formaldehyde adsorption water-based environmental protection coating
CN106349797A (en) * 2016-06-12 2017-01-25 北京化工大学 Ethylene urea composite nano-material for capturing formaldehyde and preparation method
CN106988158A (en) * 2017-05-03 2017-07-28 刘艳丽 A kind of indoor air purification paster
CN107151543A (en) * 2017-06-20 2017-09-12 合肥市淑芹美装饰工程有限公司 It is a kind of for the adhesive on floor and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113088216A (en) * 2021-05-06 2021-07-09 中山市森林家新材料科技有限公司 Formaldehyde removal additive composition and preparation method thereof
CN113980615A (en) * 2021-12-28 2022-01-28 中山市森林家新材料科技有限公司 Functional composition for melamine adhesive layer and manufacturing method thereof
CN115039793A (en) * 2022-07-05 2022-09-13 汕头市优森活新材料科技有限公司 Indoor efficient antibacterial smell-cleaning agent and preparation method and application thereof

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Application publication date: 20180420