CN107151543A - It is a kind of for the adhesive on floor and preparation method thereof - Google Patents
It is a kind of for the adhesive on floor and preparation method thereof Download PDFInfo
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- CN107151543A CN107151543A CN201710467920.8A CN201710467920A CN107151543A CN 107151543 A CN107151543 A CN 107151543A CN 201710467920 A CN201710467920 A CN 201710467920A CN 107151543 A CN107151543 A CN 107151543A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/5026—Amines cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/66—Mercaptans
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of for the adhesive on floor and preparation method thereof, it is related to field of adhesive technology, includes the raw material of following part meter：80 ~ 90 parts of 85 ~ 95 parts of reactive resin, 55 ~ 57 parts of wax phase change microballoon, 45 ~ 50 parts of cornstarch, 40 ~ 42 parts of polyvinyl alcohol, 25 ~ 35 parts of nano titanium oxide, 20 ~ 25 parts of nano aluminium oxide, 18 ~ 20 parts of gelling agent, 15 ~ 17 parts of filler, 10 ~ 15 parts of cyclacet, 10 ~ 13 parts of ethyl laurate, 5 ~ 10 parts of acid solution, 15 ~ 20 parts of auxiliary agent and deionized water.The present invention has stronger bonding strength, curing rate fast, easy construction and safety and environmental protection.
Description
Technical field
The present invention relates to field of adhesive technology, and in particular to a kind of for the adhesive on floor and preparation method thereof.
Background technology
Adhesive, also known as adhesive, are to obtain bonding force by adhesive is produced on a solid surface, by of the same race or difference
Plant the material that material is securely attached together.At present, the application of adhesive has been impregnated into the every field of national economy,
Under many occasions, adhesive effectively can couple instead of welding, riveting, be spirally connected with other machinery, be that each production front simplifies work
Skill, the energy is saved, cost is reduced, increases economic efficiency there is provided effective way.With developing rapidly for science and technology, to gluing
The performance and adhesive technology of agent propose higher and higher requirement.The sorting technique of adhesive is a lot, can be divided into by application process
Heat curing-type, heat molten type, room temperature curing type, pressure sensitive etc.；It is divided into structural type, non-configuration or special gelatin by application；Connect form
Water-soluble, emulsion type, solvent-borne type and various solid-state versions etc. can be divided into.
Adhesive plays vital effect in laying floor, and the quality of adhesive directly influences laying quality.
At present, the existing floor glue of in the market has the following disadvantages：The adhesive configured can assembly time it is short, easily solidification scrap, shadow
Ring efficiency of construction；At room temperature, it is required that overlong time is fully cured；Viscosity is bigger than normal, and mobility is poor, and construction has certain difficulty,
And the feature of environmental protection is not enough.
The content of the invention
It is strong with stronger bonding it is an object of the invention to provide a kind of for the adhesive on floor and preparation method thereof
Degree, curing rate are fast, easy construction and safety and environmental protection.
The invention provides following technical scheme：A kind of adhesive for floor, includes the raw material of following part meter：It is living
85 ~ 95 parts of resin of property, 55 ~ 57 parts of wax phase change microballoon, 45 ~ 50 parts of cornstarch, 40 ~ 42 parts of polyvinyl alcohol, nanometer titanium dioxide
25 ~ 35 parts of titanium, 20 ~ 25 parts of nano aluminium oxide, 18 ~ 20 parts of gelling agent, 15 ~ 17 parts of filler, 10 ~ 15 parts of cyclacet,
80 ~ 90 parts of 10 ~ 13 parts of ethyl laurate, 5 ~ 10 parts of acid solution, 15 ~ 20 parts of auxiliary agent and deionized water；
The auxiliary agent includes the raw material that following part is counted：5 ~ 7 parts of thixotropic agent, 4 ~ 5 parts of preservative, 2 ~ 3 parts of toughener, curing agent 1 ~ 2
Part, except 0.2 ~ 0.8 part of 0.2 ~ 1.2 part of aldehyde auxiliary agent and colouring agent.
Preferably, the raw material of following part meter is included：90 parts of reactive resin, 56 parts of wax phase change microballoon, cornstarch 47.5
Part, 41 parts of polyvinyl alcohol, 30 parts of nano titanium oxide, 22.5 parts of nano aluminium oxide, 19 parts of gelling agent, 16 parts of filler, acetic acid three
85 parts of 12.5 parts of cyclodecene ester, 11.5 parts of ethyl laurate, 7.5 parts of acid solution, 17.5 parts of auxiliary agent and deionized water；
The auxiliary agent includes the raw material that following part is counted：6 parts of thixotropic agent, 4.5 parts of preservative, 2.5 parts of toughener, 1.5 parts of curing agent,
Except 0.5 part of 0.7 part of aldehyde auxiliary agent and colouring agent.
Preferably, the reactive resin is bisphenol F epoxy resin, aliphatic glycidyl ether epoxy resin, glycidol
The one or more of ester type epoxy resin and many phenolic tetraglycidel ether epoxy resins.
Preferably, the wax phase change microballoon is made up of the paraffin and Opacifying polymers shell enclosed, the paraffin envelope
Loaded in polymer shell.
Preferably, the Opacifying polymers shell is hollow polymer spheroid, and the hollow polymer spheroid is propylene
The polymer of acid esters and styrene composition.
Preferably, the gelling agent is one kind in sodium chloride, potassium chloride, calcium chloride, calcium sulfate, sodium sulphate and sodium carbonate
Or it is several, the filler is precipitated calcium carbonate or flyash.
Preferably, the thixotropic agent is in aerosil, bentonite, modified hydrogenated castor oil and polyamide wax powder
One or more, the preservative is the one or more in chitosan, sodium benzoate, Tea Polyphenols and Tebuconazole.
Preferably, the toughener is polyurethane resin or acrylated polyurethane resin, and the coupling agent is that silane is even
Join agent, the curing agent is modified polysulfide alcohol or modified aliphatic cyclic amine, and the aldehyde auxiliary agent that removes is ethylene urea, citric acid and three ethanol
One or more in amine, the colouring agent is any of titanium dioxide, carbon black, red titanium oxide, iron oxide yellow and barba hispanica.
Preferably, the acid solution is oxalic acid solution or ethanedioic acid solution, and the acid solution mass concentration is 15 ~ 20%.
The present invention provides a kind of preparation method of adhesive for floor, comprises the following steps：
（1）, nano titanium oxide, nano aluminium oxide and cornstarch are weighed according to proportioning, be well mixed, obtain powders A, it is standby
With；
（2）, weigh reactive resin, wax phase change microballoon, polyvinyl alcohol and gelling agent according to proportioning, add into deionized water,
1 ~ 2h is stirred under 300 ~ 500r/min speed conditions, slurry B is obtained, it is standby；
（3）, by step（1）Obtained powders A and surplus stock is added to step（3）In obtained slurry B, in 600 ~ 700r/
30 ~ 40min is stirred under min speed conditions, the adhesive for floor is obtained.
Beneficial effects of the present invention：Fast, easy construction and safety and environmental protection, tool with stronger bonding strength, curing rate
Body is as follows：
（1）, the present invention addition wax phase change microballoon, the leakage problem brought when paraffin can be prevented to be converted into liquid by solid, also
Due to the paraffin of encapsulation being isolated with other matrixes, the chemical property of paraffin is effectively protected, and the phase change microsphere also has
Flexible excellent, light weight, chemicals-resistant, low-permeable, good mechanical strength, when ambient temperature is raised, solid paraffin is inhaled
Heat is received, is undergone phase transition after heat absorption enough, solid paraffin is converted into atoleine；After ambient temperature is reduced, atoleine is released
Thermal discharge, undergoes phase transition, atoleine is converted into solid, and this heat absorption and heat release function can make paraffin phase after release enough
The temperature on change microsphere surface keeps relative constancy within a certain period of time so that adhesive of the invention also has heat-insulating property；
（2）, the present invention in add a certain amount of nano titanium oxide and nano aluminium oxide, its special molecular structure can with it is each
Raw material is closely fitted to together, and the space filled up between each raw material so that adhesive uniformly continuous and densification；Separately
Also there is antibacterial bacteriostatic outside and the performances such as taste is mould proof of dispelling, can make adhesive that there is antibacterial and mouldproof effect；
（3）, the present invention in addition polyurethane resin or acrylated polyurethane resin be toughener, such toughener containing live
Property group, curing reaction can be participated in, will not be separated out after solidification, assign invention adhesive toughness while to solidfied material
Hardness influence is smaller；
（4）, be used as compatibility between primary raw material, with thermosetting composite floor board high using reactive resin in the present invention so that glue
Cohesive force is strong between stick and thermosetting composite floor board, is not susceptible to degumming cracking；
（5）, in the present invention addition remove aldehyde auxiliary agent, can significantly reduce the free formaldehyde content in adhesive, improve environmental-protecting performance；Add
Reinforce agent so that adhesive curing rate is fast, and the adhesive after solidification has higher adhesion strength to mat surface.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
A kind of adhesive for floor, includes the raw material of following part meter：85 parts of reactive resin, 55 parts of wax phase change microballoon, jade
45 parts of rice starch, 40 parts of polyvinyl alcohol, 25 parts of nano titanium oxide, 20 parts of nano aluminium oxide, 18 parts of gelling agent, 15 parts of filler,
80 parts of 10 parts of cyclacet, 10 parts of ethyl laurate, 5 parts of acid solution, 15 parts of auxiliary agent and deionized water；
The auxiliary agent includes the raw material that following part is counted：5 parts of thixotropic agent, 4 parts of preservative, 2 parts of toughener, 1 part of curing agent, help except aldehyde
0.2 part of 0.2 part of agent and colouring agent.
Wherein, the reactive resin is bisphenol F epoxy resin.
Wherein, the wax phase change microballoon is made up of the paraffin and Opacifying polymers shell enclosed, the paraffin encapsulation
In in polymer shell.
Wherein, the Opacifying polymers shell is hollow polymer spheroid, and the hollow polymer spheroid is acrylic acid
The polymer of ester and styrene composition.
Wherein, the gelling agent is sodium chloride, and the filler is precipitated calcium carbonate.
Wherein, the thixotropic agent is aerosil, and the preservative is chitosan.
Wherein, the toughener is polyurethane resin, and the coupling agent is silane coupler, and the curing agent is modified poly-
Mercaptan, described except aldehyde auxiliary agent is ethylene urea, the colouring agent is titanium dioxide.
Wherein, the acid solution is oxalic acid solution, and the acid solution mass concentration is 15%.
A kind of preparation method of the adhesive for floor is provided in the present embodiment, comprised the following steps：
（1）, nano titanium oxide, nano aluminium oxide and cornstarch are weighed according to proportioning, be well mixed, obtain powders A, it is standby
With；
（2）, weigh reactive resin, wax phase change microballoon, polyvinyl alcohol and gelling agent according to proportioning, add into deionized water,
1h is stirred under 300r/min speed conditions, slurry B is obtained, it is standby；
（3）, by step（1）Obtained powders A and surplus stock is added to step（3）In obtained slurry B, turn in 600r/min
30min is stirred under the conditions of speed, the adhesive for floor is obtained.
Embodiment 2
A kind of adhesive for floor, includes the raw material of following part meter：95 parts of reactive resin, 57 parts of wax phase change microballoon, jade
50 parts of rice starch, 42 parts of polyvinyl alcohol, 35 parts of nano titanium oxide, 25 parts of nano aluminium oxide, 20 parts of gelling agent, 17 parts of filler,
90 parts of 15 parts of cyclacet, 13 parts of ethyl laurate, 10 parts of acid solution, 20 parts of auxiliary agent and deionized water；
The auxiliary agent includes the raw material that following part is counted：7 parts of thixotropic agent, 5 parts of preservative, 3 parts of toughener, 2 parts of curing agent, help except aldehyde
0.8 part of 1.2 parts of agent and colouring agent.
Wherein, the reactive resin is aliphatic glycidyl ether epoxy resin.
Wherein, the wax phase change microballoon is made up of the paraffin and Opacifying polymers shell enclosed, the paraffin encapsulation
In in polymer shell.
Wherein, the Opacifying polymers shell is hollow polymer spheroid, and the hollow polymer spheroid is acrylic acid
The polymer of ester and styrene composition.
Wherein, the gelling agent is potassium chloride, and the filler is flyash.
Wherein, the thixotropic agent is bentonite, and the preservative is sodium benzoate.
Wherein, the toughener is acrylated polyurethane resin, and the coupling agent is silane coupler, and the curing agent is
Modified aliphatic cyclic amine, described except aldehyde auxiliary agent is triethanolamine, the colouring agent is that titanium oxide is red.
Wherein, the acid solution is ethanedioic acid solution, and the acid solution mass concentration is 20%.
A kind of preparation method of the adhesive for floor is provided in the present embodiment, comprised the following steps：
（1）, nano titanium oxide, nano aluminium oxide and cornstarch are weighed according to proportioning, be well mixed, obtain powders A, it is standby
With；
（2）, weigh reactive resin, wax phase change microballoon, polyvinyl alcohol and gelling agent according to proportioning, add into deionized water,
2h is stirred under 500r/min speed conditions, slurry B is obtained, it is standby；
（3）, by step（1）Obtained powders A and surplus stock is added to step（3）In obtained slurry B, turn in 700r/min
40min is stirred under the conditions of speed, the adhesive for floor is obtained.
Embodiment 3
A kind of adhesive for floor, includes the raw material of following part meter：90 parts of reactive resin, 56 parts of wax phase change microballoon, jade
47.5 parts of rice starch, 41 parts of polyvinyl alcohol, 30 parts of nano titanium oxide, 22.5 parts of nano aluminium oxide, 19 parts of gelling agent, filler 16
Part, 12.5 parts of cyclacet, 11.5 parts of ethyl laurate, 7.5 parts of acid solution, 17.5 parts of auxiliary agent and deionized water 85
Part；
The auxiliary agent includes the raw material that following part is counted：6 parts of thixotropic agent, 4.5 parts of preservative, 2.5 parts of toughener, 1.5 parts of curing agent,
Except 0.5 part of 0.7 part of aldehyde auxiliary agent and colouring agent.
Wherein, the reactive resin is glycidyl ester type epoxy resin.
Wherein, the wax phase change microballoon is made up of the paraffin and Opacifying polymers shell enclosed, the paraffin encapsulation
In in polymer shell.
Wherein, the Opacifying polymers shell is hollow polymer spheroid, and the hollow polymer spheroid is acrylic acid
The polymer of ester and styrene composition.
Wherein, the gelling agent is calcium sulfate, and the filler is flyash.
Wherein, the thixotropic agent is modified hydrogenated castor oil, and the preservative is Tea Polyphenols.
Wherein, the toughener is acrylated polyurethane resin, and the coupling agent is silane coupler, and the curing agent is
Modified polysulfide alcohol, described except aldehyde auxiliary agent is ethylene urea, the colouring agent is iron oxide yellow.
Wherein, the acid solution is oxalic acid solution, and the acid solution mass concentration is 17%.
A kind of preparation method of the adhesive for floor is provided in the present embodiment, comprised the following steps：
（1）, nano titanium oxide, nano aluminium oxide and cornstarch are weighed according to proportioning, be well mixed, obtain powders A, it is standby
With；
（2）, weigh reactive resin, wax phase change microballoon, polyvinyl alcohol and gelling agent according to proportioning, add into deionized water,
1.5h is stirred under 400r/min speed conditions, slurry B is obtained, it is standby；
（3）, by step（1）Obtained powders A and surplus stock is added to step（3）In obtained slurry B, turn in 650r/min
35min is stirred under the conditions of speed, the adhesive for floor is obtained.
The present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, its according to
The technical scheme described in foregoing embodiments can so be modified, or which part technical characteristic is equally replaced
Change.Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., should be included in the present invention
Protection domain within.
Claims (10)
1. a kind of adhesive for floor, it is characterised in that the raw material counted including following part：85 ~ 95 parts of reactive resin, paraffin
It is 55 ~ 57 parts of phase change microsphere, 45 ~ 50 parts of cornstarch, 40 ~ 42 parts of polyvinyl alcohol, 25 ~ 35 parts of nano titanium oxide, nano oxidized
20 ~ 25 parts of aluminium, 18 ~ 20 parts of gelling agent, 15 ~ 17 parts of filler, 10 ~ 15 parts of cyclacet, 10 ~ 13 parts of ethyl laurate,
80 ~ 90 parts of 5 ~ 10 parts of acid solution, 15 ~ 20 parts of auxiliary agent and deionized water；
The auxiliary agent includes the raw material that following part is counted：5 ~ 7 parts of thixotropic agent, 4 ~ 5 parts of preservative, 2 ~ 3 parts of toughener, curing agent 1 ~ 2
Part, except 0.2 ~ 0.8 part of 0.2 ~ 1.2 part of aldehyde auxiliary agent and colouring agent.
2. the adhesive according to claim 1 for floor, it is characterised in that the raw material counted including following part：Activity
90 parts of resin, 56 parts of wax phase change microballoon, 47.5 parts of cornstarch, 41 parts of polyvinyl alcohol, 30 parts of nano titanium oxide, nano oxygen
Change 22.5 parts of aluminium, 19 parts of gelling agent, 16 parts of filler, 12.5 parts of cyclacet, 11.5 parts of ethyl laurate, acid solution
85 parts of 7.5 parts, 17.5 parts of auxiliary agent and deionized water；
The auxiliary agent includes the raw material that following part is counted：6 parts of thixotropic agent, 4.5 parts of preservative, 2.5 parts of toughener, 1.5 parts of curing agent,
Except 0.5 part of 0.7 part of aldehyde auxiliary agent and colouring agent.
3. the adhesive according to claim 1 for floor, it is characterised in that the reactive resin is Bisphenol F epoxy
Resin, aliphatic glycidyl ether epoxy resin, glycidyl ester type epoxy resin and many phenolic tetraglycidel ether epoxy resins
One or more.
4. the adhesive according to claim 1 for floor, it is characterised in that the wax phase change microballoon is by enclosing
Paraffin and Opacifying polymers shell composition, the paraffin are packaged in polymer shell.
5. the adhesive according to claim 4 for floor, it is characterised in that the Opacifying polymers shell is sky
Heart polymer spheres, the hollow polymer spheroid is the polymer that acrylate and styrene are constituted.
6. the adhesive according to claim 1 for floor, it is characterised in that the gelling agent is sodium chloride, chlorination
One or more in potassium, calcium chloride, calcium sulfate, sodium sulphate and sodium carbonate, the filler is precipitated calcium carbonate or flyash.
7. the adhesive according to claim 1 for floor, it is characterised in that the thixotropic agent is gas phase titanium dioxide
One or more in silicon, bentonite, modified hydrogenated castor oil and polyamide wax powder, the preservative is chitosan, benzoic acid
One or more in sodium, Tea Polyphenols and Tebuconazole.
8. the adhesive according to claim 1 for floor, it is characterised in that the toughener be polyurethane resin or
Person's acrylated polyurethane resin, the coupling agent is silane coupler, and the curing agent is modified polysulfide alcohol or modified alicyclic ring
Amine, described is the one or more in ethylene urea, citric acid and triethanolamine except aldehyde auxiliary agent, and the colouring agent is titanium dioxide, charcoal
Black, titanium oxide is red, any of iron oxide yellow and barba hispanica.
9. the adhesive according to claim 1 for floor, it is characterised in that the acid solution is oxalic acid solution or second
Diacid solution, the acid solution mass concentration is 15 ~ 20%.
10. a kind of preparation method of adhesive for floor according to any one of claim 1 ~ 9, it is characterised in that
Comprise the following steps：
（1）, nano titanium oxide, nano aluminium oxide and cornstarch are weighed according to proportioning, be well mixed, obtain powders A, it is standby
With；
（2）, weigh reactive resin, wax phase change microballoon, polyvinyl alcohol and gelling agent according to proportioning, add into deionized water,
1 ~ 2h is stirred under 300 ~ 500r/min speed conditions, slurry B is obtained, it is standby；
（3）, by step（1）Obtained powders A and surplus stock is added to step（3）In obtained slurry B, in 600 ~ 700r/
30 ~ 40min is stirred under min speed conditions, the adhesive for floor is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710467920.8A CN107151543A (en) | 2017-06-20 | 2017-06-20 | It is a kind of for the adhesive on floor and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710467920.8A CN107151543A (en) | 2017-06-20 | 2017-06-20 | It is a kind of for the adhesive on floor and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107151543A true CN107151543A (en) | 2017-09-12 |
Family
ID=59795386
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710467920.8A Withdrawn CN107151543A (en) | 2017-06-20 | 2017-06-20 | It is a kind of for the adhesive on floor and preparation method thereof |
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| CN (1) | CN107151543A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107815292A (en) * | 2017-11-22 | 2018-03-20 | 苏州市宽道模具机械有限公司 | A kind of wax-based binder based on nano material doping and preparation method thereof |
| CN107936867A (en) * | 2017-11-17 | 2018-04-20 | 宜华生活科技股份有限公司 | A kind of woodwork additive with air cleaning |
| CN108454209A (en) * | 2018-03-05 | 2018-08-28 | 徐新学 | A kind of environmentally friendly heating floor improving indoor air quality |
| CN108972824A (en) * | 2018-08-23 | 2018-12-11 | 安徽美林凯迪木业有限公司 | A kind of high-strength environmentally friendly door |
| CN110281322A (en) * | 2019-05-23 | 2019-09-27 | 肥西县创玺建材科技有限公司 | A kind of preparation method keeping the temperature high-strength plywood |
| CN112521573A (en) * | 2020-11-25 | 2021-03-19 | 山东益丰生化环保股份有限公司 | Modified polythiol and metal anticorrosion UV (ultraviolet) coating using same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289623A (en) * | 2013-05-24 | 2013-09-11 | 苏州富通高新材料科技股份有限公司 | Bi-component adhesive for wood floor |
-
2017
- 2017-06-20 CN CN201710467920.8A patent/CN107151543A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289623A (en) * | 2013-05-24 | 2013-09-11 | 苏州富通高新材料科技股份有限公司 | Bi-component adhesive for wood floor |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107936867A (en) * | 2017-11-17 | 2018-04-20 | 宜华生活科技股份有限公司 | A kind of woodwork additive with air cleaning |
| CN107815292A (en) * | 2017-11-22 | 2018-03-20 | 苏州市宽道模具机械有限公司 | A kind of wax-based binder based on nano material doping and preparation method thereof |
| CN108454209A (en) * | 2018-03-05 | 2018-08-28 | 徐新学 | A kind of environmentally friendly heating floor improving indoor air quality |
| CN108972824A (en) * | 2018-08-23 | 2018-12-11 | 安徽美林凯迪木业有限公司 | A kind of high-strength environmentally friendly door |
| CN110281322A (en) * | 2019-05-23 | 2019-09-27 | 肥西县创玺建材科技有限公司 | A kind of preparation method keeping the temperature high-strength plywood |
| CN112521573A (en) * | 2020-11-25 | 2021-03-19 | 山东益丰生化环保股份有限公司 | Modified polythiol and metal anticorrosion UV (ultraviolet) coating using same |
| CN112521573B (en) * | 2020-11-25 | 2021-07-30 | 山东益丰生化环保股份有限公司 | Modified polythiol and metal anticorrosion UV (ultraviolet) coating using same |
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Application publication date: 20170912 |