CN107897202A - A kind of Pesticidal combination and application thereof - Google Patents
A kind of Pesticidal combination and application thereof Download PDFInfo
- Publication number
- CN107897202A CN107897202A CN201711426135.4A CN201711426135A CN107897202A CN 107897202 A CN107897202 A CN 107897202A CN 201711426135 A CN201711426135 A CN 201711426135A CN 107897202 A CN107897202 A CN 107897202A
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- Prior art keywords
- indoxacarb
- biphenthrin
- pesticidal combination
- agent
- plant
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
Abstract
A kind of Pesticidal combination of the present invention and application thereof is related to one kind and includes Biphenthrin（Bifenthrin）And indoxacarb（Indoxacarb）Pesticidal combination as active component.The Pesticidal combination is used to preventing or controlling the animal pest run into agricultural, animal health, forest, garden and Relexing device, the protection of Stored Product and health field.A kind of Pesticidal combination, active ingredient are made of Biphenthrin and indoxacarb, and wherein the weight ratio of Biphenthrin and indoxacarb is 1:100 to 100:1.The Biphenthrin and indoxacarb account for 0.5% to 100% of the composition by weight altogether.
Description
The application is Application No. 201410835491.1, and the applying date is on December 30th, 2014, entitled " a kind of
The divisional application of Pesticidal combination and application thereof ".
Technical field
The present invention relates to a kind of Pesticidal combination, active ingredient is made of Biphenthrin and indoxacarb.The present invention is also
It is related to the purposes of Biphenthrin and indoxacarb joint for preventing or controlling pest, and the method for prevention or control pest.
Background technology
Chemical prevention is agriculturally or public health prevents and an important means for control pest.However, currently make
Medicament is still not satisfied enough to the effect of some pests；Also, since long-time uses insecticide, many pests have generated
To the resistance of common insecticide.And carry out prevention and control using conventional dose and just becoming increasingly difficult.Therefore, there is an urgent need to develop go out use
In the new method and medicine that control these pests.In addition, currently for requirement of the insecticide on environment and economic aspect also not
It is disconnected to improve, such as action spectrum, toxicity, selectivity, rate of application, pesticide residue and favourable preparation ability etc..In addition, also as
The problem of resistance may be produced for known activity compound, develop it is new at least in some or some aspects relative to existing medicine
The advantageous newtype drug of thing just into it is current in the urgent need to address the problem of.
Biphenthrin（Bifenthrin）, it is chemical entitled：(1R, S)-cis-(Z) -2,2- dimethyl -3- (2- chloro- 3,3,
The fluoro- 1- acrylic of 3- tri-) cyclopropane-carboxylic acid -2- methyl -3- phenyl benzyl esters, structural formula is：
Biphenthrin
Biphenthrin（Bifenthrin）It is the pyrethroid insecticides of Fu Meishi companies of U.S. exploitation, by suppressing insect
The conduction at neural axon position is worked, and is had to insect and is walked quickly and kept away, knocks down, tagging and stomach poison function.Insecticidal spectrum is wide, activity compared with
Height, drug effect is rapid, resistance of rainwater washing against after sprinkling, has to lepidopterous larvae, Homoptera, Orthoptera, Semiptera and mite class preferably
Preventive effect.Suitable for crops such as tealeaves, cotton, fruit tree, vegetables.But long-time service, pest are also easy to produce resistance.
Indoxacarb（Indoxacarb）, it is chemical entitled：7- chloro- 2,3,4a, 5- tetrahydrochysene -2- [methoxycarbonyls（4- fluoroforms
Phenyl）Carbamoyl] indeno [1,2-e] [1,3,4-] oxadiazines -4a- carboxylate methyl esters, structural formula is：
Indoxacarb（Indoxacarb）It is a kind of insecticide of du pont company's development and production, has and tag and stomach poison function,
It is all effective to each instar larvae.Medicament is entered in insect bodies by contact and feeding, by blocking the sodium in insect nerve cell
Ion channel, makes nerve cell loss function；Interior insect stops feeding when 0-4 is small, is benumbed immediately, the coordination ability of insect
It can decline, cause larva to be fallen from crop, interior death when generally 24-60 is small after medicine.Indoxacarb insecticidal mechanism is unique, with it
Cross resistance is not present by insecticide in he；It is less toxic while non-to beneficial insects such as the non-target organisms in environment to mammal, domestic animal
Chang Anquan, remains low in crop, can harvest within the 2nd day after medication, especially the crop such as greengrocery, tealeaves to repeatedly harvesting
Class is very suitable for.Suitable for prevention tealeaves, apple, pears, peach, apricot, wild cabbage, flower coconut palm class, cabbage mustard, tomato, capsicum, cucumber, Xiao Hu
Tea lesser leafhopper, tea geometrid, leaf rollers, carpocapsa pononella, sweet tea on the crops such as melon, eggplant, lettuce, cotton, potato, grape
Dish noctuid, diamondback moth, cabbage caterpillar, prodenia litura, lopper worm, bollworm, oriental tobacco budworm, spark, colorado potato bug etc..
Biphenthrin, the activity of indoxacarb individual compounds are good；However, make in low rate of application or for single pest
Used time, they were not that can meet the high request that insecticide, acaricide or nematicide must are fulfilled for.
It is to need to reduce dosage rate and the reduction of active ingredient in the typical demand that field of pest control occurs
Or unfavorable environment or toxicological effects are avoided, while still allow for the control of insect of effect.Another demand is can to combine to hit
Activity and lasting period, i.e., with reference to snap action and long-acting.
It is to repeat using another difficulty of insecticide and uniquely uses single Pesticidal compound in many cases
Cause to produce the reactive compound quick selection that is natural or adapting to drug-fast pest.Therefore, it is necessary to help to prevent
Or overcome drug-fast pest control agent.
The content of the invention
The purpose of the present invention is to solve above-mentioned technical problem, there is provided a kind of Pesticidal combination, said composition pass through
Biphenthrin and indoxacarb are combined so that obtained composition has gain effect in prevention effect, and expands
Insecticidal spectrum, improves the snap action and long-acting to control of insect, has delayed drug-fast generation.
It is at least one in described problem it is an object of the present invention to provide solving, dosage rate is such as reduced, improves and lives
Property spectrum, with reference to knock down activity and lasting period, delaying drug resistance.
Therefore, it is an object of the present invention to provide a kind of Pesticidal combination, active ingredient is by Biphenthrin and indoxacarb
Composition.
A kind of Pesticidal combination of the present invention is to take following technical scheme to realize：
A kind of Pesticidal combination, active ingredient are made of Biphenthrin and indoxacarb, the weight of the Biphenthrin and indoxacarb
Than for 1:100 to 100:1.
A kind of Pesticidal combination, active ingredient are made of Biphenthrin and indoxacarb, wherein Biphenthrin and indoxacarb
Weight ratio is 1:50 to 50:1, preferably 1:20 to 20:1, more preferably 1:10 to 10:1.
A kind of Pesticidal combination, active ingredient Biphenthrin account for 0.5% of the composition by weight altogether with indoxacarb
To 100%, preferably 1% to 80%, more preferably 5%-60%.
A kind of Pesticidal combination of the present invention, also comprising carrier and/or surfactant.
A kind of Pesticidal combination of the present invention, formulation are：Suspending agent, microcapsules, missible oil, suspending agent, water dispersible granules, can
Wet powder, suspension emulsion, aqueous emulsion, suspension seed-coating agent, granule, bait grain.
Present invention also offers the purposes that a kind of Pesticidal combination by the present invention is used to preventing or controlling agricultural pests.
It is used to prevent present invention also offers a kind of Pesticidal combination by the present invention or controls invasion and attack plant or plant numerous
Grow the purposes of the agricultural pests of material.
The plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
The agricultural pests for bollworm, small heart-eating peach worm, oriental fruit months, tetranychus viennensis, mandarin orange macula lutea stinkbug, eating attraction,
Vegetable aphid, cabbage caterpillar, diamondback moth, red spider, Caloptiliatheivora, Trialeurodes vaporariorum Westwood, tea geometrid, Euproctis pseudoconspersa, leafhopper, beet armyworm, dark greyish green
Worm, prodenia litura, lopper worm, oriental tobacco budworm, carpocapsa pononella, spark, beetle.
On the other hand, present invention also offers a kind of method prevented or control agricultural pests, by the desinsection group of the present invention
Compound acts on target agricultural pests and/or its environment.
A kind of method for protecting plant to be attacked to prevent agricultural pests, including make the Pesticidal combination of the present invention and target useful
Plant, target agricultural pests and/or its environment, the propagating materials contact of target useful plant.
A kind of to protect method attack to prevent agricultural pests of plant including separated, sequentially or simultaneously Biphenthrin and indenes worm
Prestige.
A kind of method prevented or control agricultural pests, wherein Biphenthrin and indoxacarb is individually formulated composition
Form.
A kind of method for protecting vegetable seeds, it include making seed prior to seeding and/or vernalization afterwards with a effective amount of
The Pesticidal combination contact of invention.
The Pesticidal combination of the present invention is used for the purposes for handling seed.
On the other hand, present invention also offers a kind of Pesticidal combination, for preventing or controlling sanitary insect pest
Purposes.The sanitary insect pest is red fire ant, termite, mosquito, fly.
Applied present invention also offers a kind of method prevented or control sanitary insect pest, including by the Pesticidal combination of the present invention
With to target sanitary insect pest and/or its environment.
The present invention by both compound benefit have it is following some：
A, it is obvious to pest synergistic effect, the dosage of two compositions can be reduced；
B, both are mixed, solve the problems, such as to pest lasting period and quick-acting, so as to reduce times for spraying, reduce manually into
This；
C, the generation of resistance has been delayed：Both mechanisms of action and the mode of action are entirely different, have after combination tag, stomach toxicity etc.
Effect, so that pest is more easy to be killed, so as to delay the generation of resistance.
Embodiment
The present invention unexpected has found：Biphenthrin is combined to the adduction that can not only bring for insecticidal spectrum with indoxacarb
Property improve, and more importantly, it can be achieved that amazing synergistic effect.
Term " synergistic effect " used herein refers to activating agent combination of the present invention or the insecticidal effect of composition is more than respectively
The sum of activating agent effect, in other words, its effect is superadditivity.In addition, referring also to effect defined in Tammes methods
“Isoboles, a graphic representation of synergism in pesticides", Netherlands
Journal of Plant Pathology, 70(1964), pages 73-80。
A kind of Pesticidal combination, active ingredient are made of Biphenthrin and indoxacarb, the Biphenthrin and indoxacarb
Weight ratio is 1:100 to 100:1.
A kind of Pesticidal combination, active ingredient are made of Biphenthrin and indoxacarb, wherein Biphenthrin and indoxacarb
Weight ratio is 1:50 to 50:1, preferably 1:20 to 20:1, more preferably 1:10 to 10:1.
The total amount of active compound component can make choice according to material elements in Pesticidal combination of the present invention, to realize
Desired effect, the factor is such as formulation, object to be administered, application process.Biphenthrin and indoxacarb account for institute altogether
State 0.5% to 100% of composition by weight, preferably 1% to 80%, more preferably 5%-60%.
The Pesticidal combination of the present invention is also optionally including agronomically acceptable surfactant and/or extender.
According to the present invention, term " filler ", which refers to, can be combined with reactive compound or combines to make it easier for being administered to
Object（Such as plant, crop or careless class）Natural or synthetic organic or inorganic compound.Therefore, the filler is preferably
It is inert, at least it should be agronomically acceptable.The filler can be solid or liquid.
Suitable solid carrier is：For example, the natural rock such as calcite, marble, float stone, the Hai Pao that crush and be classified
Stone, dolomite, and inorganic and organic dust synthesis particle, and organic substance such as paper, sawdust, coconut husk, corncob
With the particle of tobacco stem；
Suitable liquid-carrier is, for example, water, polarity and nonpolar organic chemistry liquid, such as aromatic hydrocarbons and non-aromatic hydro carbons（Such as
Paraffin, alkylbenzene, alkylnaphthalene, chlorobenzene）, alcohol and polyalcohol（If appropriate, its can also be substitution, etherificate and/or esterification
's）, ketone（Such as acetone, cyclohexanone）, esters（Including fat and oil）With polyethers, unsubstituted and substituted amine, amide-type, interior
Amide-type（Such as N- alkyl pyrrolidones）With lactone, sulfone class and sulfoxide type（Such as dimethyl sulfoxide (DMSO)）.
If liquid-carrier used is water, such as organic solvent also can be used as cosolvent.Suitable liquid is molten
Agent mainly has：Aromatic hydrocarbons such as dimethylbenzene, toluene or alkylnaphthalene；Chlorinated aromatic hydrocarbons and chlorinated aliphatic hydrocarbon, such as chlorobenzene, vinyl chloride or dichloromethane
Alkane；Aliphatic hydrocarbon, such as hexamethylene or paraffin such as petroleum distillate；Mineral and vegetable oil；Alcohol such as butanol or ethylene glycol, and their ether
And ester；Ketone such as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) or cyclohexanone；Intensive polar solvent such as dimethyl sulfoxide (DMSO).
To make the emulsification of active ingredient compound, scattered, solubilized and/or wetting to use surfactant example
Fatty alcohol polyoxyethylene ether, polyoxyethylene alkylaryl ether, polyoxyethylene higher fatty acid esters, polyoxyethylene alcohol can such as be enumerated
Or the branch shape copolymerization of the phosphate of phenol, the fatty acid ester of polyalcohol, naphthalene sulfonic acid polymer, lignosulfonates, macromolecule comb shape
Thing, butyl naphthalene sulfonate, alkylaryl sulfonates, sodium alkylsulfosuccinates, grease, fatty alcohol and ethylene oxide condensate,
Polyacrylate, the protein hydrolysate of alkyltaurate.Suitable oligosaccharide thing or polymer, such as based on single second
Alkene monomer, acrylic acid, polyoxyethylene and/or polyoxypropylene or its with for example（It is polynary）Alcohol or（It is polynary）The combination of amine.
To disperse active ingredient compound, stabilizing, adhering to, such as xanthans, aluminium-magnesium silicate, gelatin, shallow lake can be used
Powder, methyl cellulose, polyvinyl alcohol, polyvinyl acetate and natural phospholipid（Such as cephalin and lecithin）And synthetic phospholipid,
The adjuvants such as bentonite, sodium lignin sulfonate.
The wherein optional spent glycol of antifreezing agent, propane diols, glycerine, sorbierite.Deflocculant as suspension product
The adjuvant such as naphthalene sulfonic acid polymer, polymeric phosphate can be used.Organic silicon defoamer can be used as defoamer.For
The mobility of solid product is improved, the adjuvant such as paraffin, stearate, alkylphosphonate can be used.
The colouring agent that can be used, such as inorganic pigment, such as iron oxide, titanium oxide and Prussian blue；And organic pigment/
Dyestuff：Alizarin dyes, azo dyes and metallized phthalocyanine dye；And trace element, such as molysite, manganese salt, boron salt, mantoquita, cobalt
Salt, molybdenum salt and zinc salt.
Optionally, can also include other annexing ingredients, for example, protecting colloid, adhesive, thickener, thixotropic agent, bleeding agent,
Stabilizer, screening agent.
The Pesticidal combination of the present invention can be used directly, be made using dosage form or as type of service prepared therefrom
With, such as aerosol, suspending agent, microcapsulated granule, granula subtilis, flowable concentrate, ready to use solution agent, pulvis, missible oil, water and milk
Agent, oil emu, big granula, fine granule, oil dispersed pulvis, the miscible mobility concentrate of oil, oily miscible liquids, foaming agent, paste,
Suspending concentrate, suspension emulsion, solubility concentrate, soluble powder, granule, water-soluble granular and/or tablet, water soluble powder
Agent, wettable powder, the natural or synthetic material through reactive compound dipping, the microcapsules in polymeric material and moisture dissipate
Property particle.
In preferred embodiments, the agrochemical composition for missible oil, suspending agent, seed coat agent, water dispersible granules,
Wettable powder, suspension emulsion, smoke agent, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, ultra low volume liquids, bait grain.
The preparation of the present invention can be mixed the reactive compound to prepare by known way with conventional additives.
For example conventional extender of the conventional additives and solvent or diluent, emulsifying agent, dispersant, and/or adhesive or fixation
Agent, wetting agent, waterproofing agent, if it is desired, can also include drier and colouring agent, stabilizer, pigment, defoamer, preservative, increasing
Thick dose, water and other processing aids.
These compositions not only include can be by suitable equipment as sprayed or dusting equipment is immediately suitable for pending
Object, and be additionally included in and be applied to the concentration commercial composition that object needs to be diluted before.
The Pesticidal combination of the present invention can be made to apply in the form of the composition of its active compound component
Preparation, can also be applied in the form of the combination of the commercial preparation of its suitable dosage.It can also be administered in combination with other activating agents,
Other agents such as insecticide, attractant, bactericidal agent, bactericide, acaricide, nematicide, fungicide, life
Long conditioning agent, herbicide, safener, fertilizer or semiochemical etc..
It is used to prevent present invention also offers a kind of Pesticidal combination by the present invention or controls agricultural pests, sanitary insect pest
Purposes.
It is used to prevent present invention also offers a kind of Pesticidal combination by the present invention or controls invasion and attack plant or plant numerous
Grow the purposes of the agricultural pests of material.
Present invention also offers the purposes that a kind of Pesticidal combination by the present invention is used to preventing or controlling sanitary insect pest.
The Pesticidal combination of the present invention is suitable for prevention in agricultural, gardening, animal husbandry, forestry, garden and Relexing device, storage
Animal pest is run into the protection of Tibetan product and health field, particularly insect, arthropod, parasitic worm, nematode and software
Animal.The Pesticidal combination of the present invention shows the tolerance good to plant, to the hypotoxicity of warm blooded species and good at the same time
Environmental compatibility.It is active to normal sensitive and resistance kind, it is active to all or special stage of development.Above-mentioned evil
Worm includes：
From Isopoda, such as damp worm（Oniscus aselluse）, pillworm（Armadillidium vulgare）, and spot
Pillworm（Porcellio scaber）.
From Diplopoda, such as Blaniuus guttulatus.
From chilopoda, for example, centipede（Geophilus carpophagus）With common house centipede dragonfly（Scutigera spp.）.
From Symphyla, such as clean symphilid（Scutigerella immaculate）.
From Thysanoptera, such as silverfiss（Lepisma saccharina）.
From Collembola, such as Onychiurus arcticus（Onychiurus armatus）.
From Orthoptera, such as house cricket found in a kitchen（Acheta domesticus）, Gryllotalpa spp（Gryllotalpa spp.）, heat
Band migratory locusts（Locusta migratoria migratorioides）, long volume bears locust category（Melanoplus spp.）, and desert
Locust（Schistocerca gregaria）.
From Blattaria, such as oriental cockroach（Blatta orientalis）, American cockroach（ Periplaneta
Americana）, leucophaea maderae（Leucophaea maderae）, Groton bug（Blattella germanica）.
From Dermaptera, such as European earwig（Forficula auricularia）.
From Isoptera, such as Reticulitermes.
From Anoplura, such as body louse（Pediculus humanus corporis）, blind pediculus, and long volume Pediculus, poultry louse
Belong to, Damalinia.
From Thysanoptera, such as greenhouse Hercinothrips spp（Hercinothrips femoralis）, cotton thrips（Thrips
tabaci）, Thrips palmi and Frankliniella accidentalis.
From Heteroptera, such as Eurygasterspp category, middle red cotton bug（ Dysdercus intermedius）, beet plan lace bug（
Piesma quadrata）, the smelly stinkbug in temperate zone（ Cimex lectularius）, red abdomen hunts stinkbug（ Rhodnius prolixus）
And Triatoma.
From Homoptera, such as wild cabbage aleyrodid（ Aleurodes brassicae）, Bemisia tabaci（Bemisia
tabaci）, Trialeurodes vaporariorum Westwood（ Trialeurodes vaporariorum）, cotten aphid（ Aphis gossypii）, brevicoryne brassicae
（ Brevicoryne brassicae）, the hidden knurl volume aphid of tea deer（ Cryptomyzus ribis）, black bean aphid（Brevicoryne
brassicae）, apple aphid（Aphispomi）, apple aphid（ Eriosoma lanigerum）, mealy plum aphid
（Hyalopterus arundinis）, grape phylloxera（Phylloxera vastatrix）, Pemphigus, grain aphid
(Macrosiphum avenae), knurl volume Aphis, hops knurl volume aphid (Phorodo), rice green leafhopper (Nephotettix
Cincticeps), brown apricot scale (Lecanium
Corni), olive helmet (Saissetia oleae), rice small brown rice planthopper (Laodelphaxstriatellus), brown back rice plant hopper
(Nilaparvata lugens), California red scale (Aonidiel1a aurantii), oleander circle a red-spotted lizard (Aspidiotus
Hederae), mealybug category and Psylla spp.
From Lepidoptera, such as pink bollworm (Pectinophora gossypiella), loose looper (Bupalus
Piniarius), winter geometrid moth (Chemimatobia brumata), Lithoclletis blancardela, cherry ermine moth
（Hyponomeuta padella）, diamondback moth (Plutella xylostella), tent caterpillar (Malacosoma
Neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrix
Thurberiella), tangerine leaf miner (Phyllocnis tiscitrella), Agrotis, cutworm category, brown Noctua,
Earias insulana (Eariasinsulana), Noctua, lopper worm (Mamestra brassicae), small noctuid
(Panolis flammea), Noctua, cabbage looper (Trichoplusiani), carpocapsa pononella (Carpocapsa
Pomonella), Pier, snout moth's larva category（Pyraustlla), bag casemaking clothes moth (Tineola bisselliella), etting moth
(Tinea Pellionella), brown oecophorid (Hofmannophila pseudospretella), yellow tail leaf roller
(Cacoecia podana), choristoneura fumigerana (Choristoneura fumiferana), grape stay moth-eaten moth (Clysia
Ambiguella), tea yellow leaf curl moth (Homona magnanima), the green leaf roller of oak (Tortrix viridana), rolls up snout moth's larva
Belong to, Oulema oryzae (Oulema oryzae).
From coleoptera, such as furniture death watch beetle (Anobium punctatum), lesser grain borer (Rhizopertha
Dominica), Bruchidius obtectus, bean weevil (Acanthoscelides obtectus), house longhorn beetle
(Hylotrupes bajulus), alder purple flea beetle (Agelastica alni), colorado potato bug
(Leptinotarsadecemlineata), horseradish ape is chrysomelid (Phaedon cochleariae), chrysomelid category, and rape is blue to jump
First (Psylliodes chrysocephala), mexican bean ladybird (Epi1achna varivestis), hidden wing first category, saw
Chest ostomatid (Oryzaephilus surinamensis), weevil category, Sitophilus, vine black ear is as (Otiorrhynchus
Sulcatus), banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil
(Ceuthorrhynchusassimilis), alfalfa weevil (Hypera postica), khapra beetle category, spot khapra beetle category, circle skin
Moth belongs to, and hair is moth-eaten to be belonged to, and powder is moth-eaten to be belonged to, pollen beetle (Meligethes aeneus), spider
First category, golden yellow ptinid (Niptus hololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium are yellow
Meal beetle (Tenebrio molitor), click beetle category, acupuncture needle Eimeria, angle cockchafer (Melolontha melolontha), June are golden
Tortoise (Amphimallon solstitialis), brown New Zealand's rib wing gill cockchafer (Costelytra
) and Lissorhoptrusoryzophilus (Lissorhoptrus oryzophilus) zealandica.
From Hymenoptera, such as Neodiprion spp category, tenthredinidae, field ant category, MonomoriumMayr (Monomorium pharaonis)
With Vespa
From Diptera, such as Aedes, spot Anopheles, Culex, drosophila yellow gorilla (Drosophila melanogaster)
, Musca, male servant's fly category, calliphora erythrocephala (Calliphoraerythrocephala), lucilia sericata category, Carysomyia, cuterbrid category,
Gasterophilus, Hippobosca, chela fly category, nose fly category, Hypoderma, Pituophis, Tannia belong to, march fly category（ Bibio hortulanus
）, Sweden's straw rope (Oscinella frit), wheat fly category, beet fly (Pegomyiahyoscyami), Mediterranean
Trypetid (Ceratitis capitata), dacus oleae (Dacusoleae) and European daddy-longlegs (Tipula paludosa)
, Hylemyia, and Hippelates.
From Siphonaptera, such as Xenopsyllacheopis (Xenopsylla cheopis) and angle leaf sage mouse.
From Arachnoidea, such as scorpion (Scorpio maurus), black widow (Latrodectus mactans)
, Acarus siro (Acarus siro), hidden category, blunt port category, Dermanyssus gallinae (Dermanyssys gallinae), tea deer goitre mite
(Eriophyesribis), citrus rust mite (Phyllocoptruta oleivora), Boophilus, carrapato category, Amblyomma, glass eye
Tick category, Isodesspp, Acarus tritici category, ginger mite category, Sarcoptesspp, the compacted category of line, Bryobia praetiosa (Bryobia praetiosa), red spider
Belong to, the compacted category of red autumnal leaves, sharp tenthredinidae, short whisker Acarapis
Parasitic plant nematode includes such as Pratylenchus, Radopholus similis Throne (Radopholus similis), raising grass blade
Nematode (Ditylenchus dipsaci), Tylenchulus Semipenetrans (Tylenchulus semipenetrans), Heterodera,
Ball Heterodera, Meloidogyne, Aphelenchoides, minute hand Turbatrix, Xiphinema, and burr Turbatrix, remote spring dragonfly category.
The Pesticidal combination of the present invention specifically includes following pest especially suitable for preventing " biting " pest, these pests：
From Lepidoptera, such as pink bollworm (Pectinophora gossypiella), loose looper (Bupalus
Piniarius), winter geometrid moth (Cheimatobia brumata), Lithocolletis blancardel1a, cherry ermine moth
(Hyponomeuta padella), diamondback moth (Plutella xylostella), tent caterpillar (Malacosoma
Neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrix
Thurberlella), tangerine leaf miner (Phyllocnistiscitrella), Agrotis, cutworm category, brown Noctua,
Egyptian complete just brill (Eariasinsulana), Noctua, lopper worm (Mamestra brassicae), small noctuid
(Panolisflammea), Noctua, powder pattern moth (Trichoplusiani), carpocapsa pononella (Carpocapsa
Pomonella), Pier, snout moth's larva category, Pyrausta nubilalis, Anagasta kuehniella (Ephestia
Kuehniella), rheum officinale snout moth's larva (Gal1eriamellonella), bag casemaking clothes moth (Tineola bisselliella), etting moth
(Tineapellionella), brown oecophorid (Hofmannophila pseudospretella), yellow tail leaf roller
(Cacoecia podana), Capua reticulana, choristoneura fumigerana (Choristoneura fumiferana),
Grape stays moth-eaten moth (Clysia ambiguella), tea yellow leaf curl moth (Homona magnanima), the green leaf roller of oak
(Tortrix viridana), rolls up snout moth's larva category, Oulema oryzae (Oulema oryzae).
From coleoptera, such as furniture death watch beetle (Anobium punctatum), lesser grain borer (Rhizopertha
Dominica), Bruchidius obtectus, bean weevil (Acanthoscelides obtectus), house longhorn beetle
(Hylotrupes bajulus), alder purple flea beetle (Agelastica alni), colorado potato bug (Leptinotarsa
Decemlineata), horseradish ape is chrysomelid (Phaedon cochleariae), chrysomelid category, rape orchid flea beetle (Psylliodes
Chrysocephala), mexican bean ladybird (Epilachnavarivestis), hidden wing first category, saws chest ostomatid
(Oryzaephilus surinamensis), weevil category, Sitophilus, vine black ear beak (Otiorrhynchus sulcatus)
When, banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil (Ceuthorrhynchus assimilis)
, alfalfa weevil (Hypera postica), khapra beetle category, spot khapra beetle category, Anthrenus, hair is moth-eaten to be belonged to, and powder is moth-eaten to be belonged to, rape liquid distilled from honeysuckle flowers or lotus leaves
Tail first (Meligethes aeneus), spider
First category, golden yellow ptinid (Niptus hololeucus), wheat ptinid (Gibbium psylloides), Tribolium are yellow
Meal beetle (Tenebrio molitor), click beetle category, acupuncture needle Eimeria, angle cockchafer (Melolontha melolontha), June
Chafer (Amphimallon solstitialis), brown New Zealand's rib wing gill cockchafer, angle cockchafer (Costelytra
) and Lissorhoptrusoryzophilus (Lissorhoptrus oryzophilus) zealandica.
A kind of Pesticidal combination containing Biphenthrin and indoxacarb of the present invention especially suitable for preventing " sucking " pest, these
Pest specifically includes following pest：
From Homoptera, such as wild cabbage aleyrodid (Aleurodes brassicae), Bemisia tabaci (Bemisia tabaci), temperature
Room trialeurodes vaporariorum (Trialeurodes vaporariorum), cotten aphid (Aphis gossypii), brevicoryne brassicae (Brevicoryne
Brassicae), the hidden knurl volume aphid of tea deer (Cryptomyzus ribis), black bean aphid (Aphis fabae), apple aphid
(Aphispomi), apple aphid (Eriosoma lanigerum), mealy plum aphid (Hyalopterusarundinis), Portugal
Grape radicola (Phylloxera vastatrix), goitre cotten aphid category, grain aphid (Macrosiphum avenae), knurl volume aphid
Belong to, hops knurl volume aphid (Phorodonhumuli), grain Rhopalosiphum spp (Rhopalosiphum padi), leafhopper category
（Cicadellidae）, rice green leafhopper (Nephotettix cincticeps), brown apricot scale (Lecaniumcorni), oily olive
Olive helmet (Saissetia oleae), rice small brown rice planthopper (Laodel phaxstriatellus), brown back rice plant hopper (Nilaparvata
Lugens), California red scale (Aonidiella aurantii), oleander circle a red-spotted lizard (Aspidiotus hederae), mealybug category
And Psylla spp.
Preferably, Pesticidal combination of the invention is suitable for prevention bollworm, small heart-eating peach worm, oriental fruit months, leaves of Hawthorn
Mite, mandarin orange macula lutea stinkbug, eating attraction, vegetable aphid, cabbage caterpillar, diamondback moth, red spider, Caloptiliatheivora, Trialeurodes vaporariorum Westwood, tea geometrid, Euproctis pseudoconspersa,
The agricultural pests such as leafhopper, beet armyworm, cabbage caterpillar, prodenia litura, lopper worm, oriental tobacco budworm, carpocapsa pononella, spark, beetle.
Preferably, Pesticidal combination of the invention is suitable for the sanitary insect pests such as prevention termite, red fire ant, mosquito, fly.
On the other hand, present invention also offers a kind of prevention or control agricultural pests, the method for sanitary insect pest, by the present invention
Pesticidal combination act on target agricultural pests, sanitary insect pest and/or its environment.
The present invention also provides a kind of method for protecting plant to be attacked to prevent agricultural pests, sanitary insect pest, including make the present invention
Pesticidal combination contacted with target useful plant, target pest and/or its environment, the propagating materials of target useful plant.
The implication of plant herein is interpreted as all plants and plant population.Plant is can be by conventional breeding and excellent
Choosing method can pass through biotechnology and genetic engineering method or the plant that can be obtained by the combination of these methods.The plant
Including genetically modified plants, also include that (plant breeders'rights) protection can be weighed by plant breeder or be not protected by it
Plant variety.
It can be used for what the present invention protected, and include according to the present invention using the useful plant of Pesticidal combination：Cereal
Plant such as wheat, oat, barley, triticale and rye, and corn, jowar He Li, rice；Beet, such as sugar beet or feed
Beet；Fruit, such as apple class fruit, drupe, tree nut or soft water fruit, such as apple, pears, plum, peach, banana, almond, core
Peach, American pistachios, cherry or berry, such as strawberry or blackberry, blueberry；Legume such as Kidney bean, pea or soybean；Oily crop, such as rape, mustard
Dish, olive, sunflower, castor-oil plant, cocoa chocolate tree or peanut；Cucurbitaceous plant, such as pumpkin, cucurbita pepo, cucumber or muskmelon；Fiber is planted
Thing, such as cotton, flax, hemp or jute；Citrus fruit, such as orange, lemon, grape fruit or orange；Vegetables such as spinach, lettuce
Lettuce, asparagus, cabbage, carrot, onion, tomato, hot red pepper, potato or bell pepper；Lauraceae, such as avocado, Chinese cassia tree or camphor；With
And tobacco, nut, coffee, eggplant, sugarcane, tea tree, pepper, grapevine, hops, Plantaginaceae, lactiferous plant, lawn, grass
Level ground, fodder grasses, and ornamental plant, such as Petunia, heartsease and balsamine；And shrub, broad leaf tree and aithullium,
Such as coniferous tree.
Directly carried out or with conventional treatment method by acting on it with processing of the Pesticidal combination of the present invention to plant
Environment, habitat or storage areas and carry out, the conventional treatment method is for example impregnated, poured, being sprayed, atomizing, is broadcasted sowing, is sprayed
Powder, mist formation, broadcast sowing, foam, coating, being coated with, the mode such as trickle irrigation is applied to the blade of plant（Foliage applying）, administration can be adjusted
Frequency and dosage, adapt it to the degree encroached on by the agricultural pests.
The Pesticidal combination of the present invention is also suitable for propagating materials such as seed, fruit, stem tuber or the kernel of protection plant
Or plant cutting is from the infringement of harmful organism particularly insect and acarid.Can be before administration with the compositions-treated breeding material
Material, such as dress seed prior to seeding.Also by soaking kernel in fluid composition or kernel can be coated with solid composite, by work
Property component is applied in benevolence（Coating）.When propagating materials is applied to for example seed is broadcast in ditch in seeding process, also may be used
Said composition is applied to application site.These processing methods to plant propagation material and the plant propagation material being processed as
All it is further subject matter of the present invention.
Term " plant propagation material " is interpreted as referring to all plant parts for having fertility, such as seed, Yi Jizhi
Physical property material such as cuttage bar or stem tuber（Such as potato）.Therefore, plant part used herein includes plant propagation
Material.It is mentioned that such as seed（In the narrow sense）, root, fruit, stem tuber, bulb, rhizome and plant part.Treat from soil
The germination plant and effective plant suppressed after germination or after emergence is also what be can be mentioned that.Young plant can pass through before transplantation
Dipping carries out whole or Local treatment to be protected.
Plant part and the plant organ then grown are by any of the plant propagation material such as plant of seed generation
Part.Plant part, plant organ and plant can also be benefited to be planted by the way that composition is applied to plant propagation material protection
Thing is from plant disease.Certain plants part and some plant organs then grown can also regard plant propagation material as, its
Itself can be applied with composition（Or processing）；So as to the plant produced by processed plant part and processed plant organ
Thing, other plant part and other plant organs can also benefit from by by composition be applied to certain plants part and
Certain plants Organoprotective plant is from insect pest of the plant.
In order to handle plant propagation material particularly seed, can also be impregnated in succession by using the liquid preparation of each active ingredient
Stem tuber or grain, or coated by using the wet or dry preparation combined, so that active ingredient is administered on seed（Coating）.
The Pesticidal combination of the present invention is applied to seed with itself or suitable formulation.It is preferred that seed is in stable state
It is lower processed, so that processing does not cause any infringement.Processing to seed usually can be between harvesting and sowing it is any
Time carries out.It has to be noticed that being applied to the amount of the present composition of seed and/or other additions usually during seed treatment
The amount selected as of agent does not interfere with the germination of seed or will not damage gained plant.
A kind of method for protecting seed, it includes making seed prior to seeding and/or the vernalization sheet with cooperative effective quantity afterwards
The Pesticidal combination contact of invention.
The invention further relates to a kind of seed for the Pesticidal combination processing for applying the present invention.
The Pesticidal combination of the present invention can be applied to environment, habitat or the storage areas of plant growth.Plant growth
Environment, habitat are the supporters for referring to make crops take root, grow, such as：Soil, water etc., specific raw material can make
With such as sand, float stone, vermiculite, diatomite, agar-agar, gelling material, polymer substance, asbestos, sawdust, bark.It is preferred that soil
Earth.
The method of medicament is applied into soil, such as liquid preparation is diluted in water or do not diluted and is directly applied to plant
The methods of in the root of body or the rice seedling bed of seedling, side granule being disseminated in the root of plant or the rice seedling bed of seedling
Method has the method that pulvis, water dispersible granules etc. are sprayed in soil prior to seeding and are integrally mixed with soil, before sowing or plants
It will be sprayed on before kind plant after pulvis, water-dispersible grain dilution agent in implantation hole, seed furrow, carrying out method of sowing etc..
The present invention method additionally provide by separate, sequentially or simultaneously in a manner of the reactive compound is administered in combination.This hair
It is common and favourable that bright composition or activating agent combination are usually applied with following dosage：
- for leaf portion processing：0.1-10000 g/ha, preferably 5-1000g/ha, more preferably 10-50g/ha；For impregnating or dripping
For note is applied, the dosage even can also reduce, particularly when applying inert base such as asbestos or perlite；
- for seed treatment：2-200 g/100kg seeds, preferably 3-150g/100kg seeds；
- for soil treatment：0.1-10000g/ha, preferably 1-5000g/ha.
Above-mentioned dosage is only general exemplary dose, and those skilled in the art can be according to actual conditions when reality is applied
And needs, adjust rate of application especially in accordance with the property and insect pest situation of pending plant or crop.
On the other hand, processing of the invention can also produce following super additive effect：Improve plant growth, improve to high temperature
Or low temperature tolerance, improve to arid or to the tolerance of water or soil salt content, improve Flowering quality, make harvesting simpler
Just, accelerate ripe, raising harvesting yield, improve the quality of harvested products and/or improve its nutritive value, improve harvested products
Bin stability and/or its processing performance.
Moreover, it has been discovered that the Pesticidal combination of the present invention has effective insecticidal action to the pest for destroying industrial materials.
As example and it is preferably provided that following insect, but not limited to this:
Coleoptera such as North America house longhorn beetle (Hyloptrupes bajulus), green tiger longicorn (Chlorophorus pilosis),
Furniture death watch beetle, report dead material death watch beetle (during Xestobiumrufovillosu, class wing death watch beetle (Ptilinus pecticornis),
Dendrobium pertinex, loose bud branch death watch beetle (Ernobius mol1is), loose product death watch beetle (Priobiumcarpini)
, Lyctus brunneus Stephens (Lyctus brunneus), powder moth (Lyctus africanus), southern powder moth (Lyctus
Planicollis), quercitron is moth-eaten (Lyctus linearis), powder moth (Lyctus pubescens), and chest powder is moth-eaten
(Trogoxylon aequale), minthea rugicollis (M i n t h e s r u g i c o l l i s), material bark beetle category,
Wood strip bark beetle category, coffee is black long moth-eaten (Apa temonachus), Bostrychus capucins, and brown different long wing is moth-eaten
(Heterobostrychusbrunneus), spine length is moth-eaten belongs to, and bamboo pole powder length is moth-eaten (Dinoderus minutus).
Dermaptera, such as blue black wood wasp (Sirex juvencus), the big wood wasp of dragon spruce (Urocerusgigas), Thailand add
Big wood wasp (Urocerus gigas taignus), big wood wasp (Urocerus augur).
Termite, such as kalotermitid (Kalotermes flavicollis), numb head heap sand termite (Cryptotermes
Brevis), the different termite of Indian-Pakistani structural wood (Heterotermes indicola), American-European reticulitermes flavipe (Reticulitermes
Flavipes), reticulitermes flavipe (Reticulitermes santonensis), reticulitermes flavipe (Reticuli
Termeslucifugus), Mastotermes darwiniensis (Mastotermes darwiniensis), Nevada Gu termite
(Zootermopsis nevadensis), TaiWan, China formosanes (Coptotermesformosanus).
Thread tail mesh, such as TaiWan, China silverfish (Lepisma saccharina)
Industrial materials herein are understood to mean that non-living material such as preferred polymers, adhesive, glue, paper and plate, skin
Leather, timber, timber-work and coating.The particularly preferred timber of material and woodworking article of insect infestations to be protected it from.
Can with Pesticidal combination of the present invention or the mixture containing said composition protection timber and woodworking article should manage
Solve to represent for example：
Construction timber, wooden frame, railroad tie, bridge member, breakwater, wooden vehicles, box, pallet, container, telephone wire
Bar, timber partition, wooden window and door, glued board, wound card, joinery, or it is thin commonly used in building construction or building
The timber-work of carpenter.
Pesticidal combination can as former state, with concentrate or conventional formulation such as pulvis, granule, solution, suspending agent, emulsion or paste
The form of agent uses.
Above-mentioned preparation can be prepared in a way known, such as by by reactive compound and at least one solvent or dilute
When releasing agent, emulsifying agent, dispersant and/or adhesive or fixative, waterproofing agent, drier when needing and UV stabilizer and needing
Colouring agent and pigment and other processing aids mixing.
It is 0.0001-95wt% that Pesticidal combination or concentrate for protecting timber and timber-work, which contain concentration, especially
It is the reactive compound of the invention of 0.01-60wt%.
The dosage of composition or concentrate depends on the kind and quantity and medium of insect.In all cases optimal
Dosage can be determined by dispenser campaign, but according to the materials'use 0.0001-20wt%, preferably 0.001- to be protected
The reactive compound of 10wt% is generally sufficient.
The Pesticidal combination of the present invention is also applied for the animal pest of prevention enclosure space, particularly insect, spider and mite
Worm, the enclosure space such as house, factory floor, office, cabin etc..They are available for preventing this in domestic insecticide products
A little pests, they are to sensitive and resistance kind and active to all stages of development.These pests include:
Scorpionida, such as pincers exhaust (Buthus occitanus).
Acarina, for example, adobe tick, stick up edge sharp-edged tick, Bryobia, Dermanyssus gallinae, family food sweet tea mite, tampan tick,
Brown dog tick, trombiculid (Trombicula alfreddugesi), Neutrombicula autumnalis, dermatophagoides pteronyssinus, powder
Dust mite
Araneida, such as cockle spider section, Yuan Zhu sections
Opiliones, such as intend scorpion class (Pseudoscorpiones chelifer), Pseudoscorpiones
cheiridium, Opiliones phalangium。
Isopoda, such as damp worm, pillworm
Sufficient mesh again, such as tool zebra land, mountain cricket Eimeria
Lip foot mesh, for example, Scolopendra.
Zygentoma mesh, such as comb silverfish category, TaiWan, China silverfish, Lepismodes inquilinus.
Blattaria, such as oriental cockroach, Groton bug, Blatella (Bl a t t el1a asahinai), leucophaea maderae, angle
Abdomen Lian categories, wood Lian categories, Australian cockroach, American cockroach, Periplanetabrunnea, Peroplaneta fluligginosa, long hair blattaria.
Saltatoria, such as family Shuai.
Dermaptera, such as European earwig.
Isoptera, such as kalotermitid category, Reticulitermes.
Worm mesh, such as Lepinatus belongs to, powder asthma Eimeria
Coleoptera, such as Anthrenus, fur is moth-eaten to be belonged to, khapra beetle category, long head lesser grain borer, hidden instep cuckoo Eimeria, Ptinus, lesser grain borer, paddy
As, rice weevil, sitophilus zea-mais, Stegobium paniceum.
Diptera, such as Aedes aegypti, aedes albopictus, Aedes taeniorhynchus, Anopheles, calliphora erythrocephala,
Great number sarcophagid, Culex quinquefasciatus, sharp and rounded sounds storehouse grave, Culex tarsalis, stay fly category, Fannia canicularis, housefly, Bai Ling categories, sarcophagid
(Sarcophaga carnaria), Simulium, male servant chela fly, daddy-longlegs (Tipula paludosa).
Lepidoptera, such as lesser wax-moth, galleria mellonella waxmoth, India Gu phycitid, rain moth, bag rain moth, Tineolabisselliella
Siphonaptera, such as dog comb head lices, Ctenocephalides felis felis, humanlice, chigo, Xanthopsyllacheopis
Hymenoptera, such as hunchbacked ant is blazoned, bright hair ant, black wool ant, Lasius umbratus, MonomoriumMayr, Paravespula
Belong to, Pavement Ant.
Anoplura, such as head louse, body louse, crab louse.
Heteroptera, such as cimex hemipterus, bed bug, phodnius prolixus, invades and harasses vertebra and hunts stinkbug.
The Pesticidal combination of the present invention can be used as aerosol, no pressure spray product such as pump spraying and atomizer spray, oneself
Dynamic mist formation system, aerosol producer, foam, gel, evaporator product, the liquid with evaporating plate made of cellulose or polymer
Evacuator body device, gel and film evaporator, propeller driving evaporator, do not consume energy or passive type vapo(u)rization system, catch baby worm paper, catch
Moth bag and insect-catching glue, draw agent or pulvis, in the bait formulation of sprinkling or bait formulation position as.
Example of formulations
Embodiment 1：+ 10% indoxacarb suspending agent of 2% Biphenthrin
Biphenthrin 2%
Indoxacarb 10%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
The each components such as active component, dispersant, wetting agent and water are uniformly mixed according to the ratio of formula, it is ground and/or high
+ 10% indoxacarb suspending agent of 2% Biphenthrin is obtained after speed shearing.
+ 4% indoxacarb wettable powder of 2 20% Biphenthrin of embodiment
Biphenthrin 20%
Indoxacarb 4%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Active ingredient, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, that is, obtained
+ 4% indoxacarb wettable powder of 20% Biphenthrin.
+ 20% indoxacarb aqueous emulsion of 3 0.2% Biphenthrin of embodiment
Biphenthrin 0.2%
Indoxacarb 20%
1-methyl-2-pyrrolidinone 15%
Calcium dodecyl benzene sulfonate 5%
Ethoxylated castor oil 5%
Water complements to 100%
Active compound, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed to prepare water phase；
Under high velocity agitation, it is oil phase is mixed with water ,+20% indoxacarb aqueous emulsion of 0.2% Biphenthrin is made.
+ 1.5% indoxacarb water dispersible granule of 4 3.5% Biphenthrin of embodiment
Biphenthrin 3.5%
Indoxacarb 1.5%
Sodium lignin sulfonate 4%
Lauryl sodium sulfate 5%
White Carbon black 10%
Kaolin complements to 100%
Active ingredient, dispersant, wetting agent, disintegrant and filler are uniformly mixed in the ratio of formula, by air-flow crushing into
Wettable powder, adds a certain amount of water mixing extruding and makes material.+ 1.5% indenes worm of 3.5% Biphenthrin is obtained after dry sieve
Prestige water dispersible granules.
+ 0.2% indoxacarb suspending agent of 5 20% Biphenthrin of embodiment
Biphenthrin 20%
Indoxacarb 0.2%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
The each components such as active ingredient, dispersant, wetting agent and water are uniformly mixed in the ratio of formula, ground and/or high speed
+ 0.2% indoxacarb suspending agent of 20% Biphenthrin is obtained after shearing.
+ 2.5% indoxacarb suspending agent of 6 7.5% Biphenthrin of embodiment
Biphenthrin 7.5%
Indoxacarb 2.5%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
The each components such as active ingredient, dispersant, wetting agent and water are uniformly mixed in the ratio of formula, ground and/or high speed
+ 2.5% indoxacarb suspending agent of 7.5% Biphenthrin is obtained after shearing.
+ 10% indoxacarb wettable powder of 7 1% Biphenthrin of embodiment
Biphenthrin 1%
Indoxacarb 10%
Lauryl sodium sulfate 10%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
+ 1% indoxacarb suspending agent of 8 50% Biphenthrin of embodiment
Biphenthrin 50%
Indoxacarb 1%
Fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through being sanded, is prepared into suspending agent.
+ 20% indoxacarb aqueous emulsion of 9 30% Biphenthrin of embodiment
Oil phase：
Biphenthrin 30%
Indoxacarb 20%
Methyl oleate 38%
Polystyrene 3.7%
Water phase：
Xanthans 0.07%
The sodium salt 1% of naphthalene sulfonic acids-formaldehyde condensation products of sulfonation
Fungicide 0.2%
Water complements to 100%
Biphenthrin and indoxacarb are dissolved in methyl oleate, polystyrene is added and obtains oil phase；According to the component in formula
It is uniformly mixed and obtains water phase；Oil phase addition water is mutually obtained into aqueous emulsion under agitation.
+ 1% indoxacarb wettable powder of 10 20% Biphenthrin of embodiment
Biphenthrin 20%
Indoxacarb 1%
Sodium lignin sulfonate 4%
NaLS 2%
The silicic acid 1% of high degree of dispersion
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
+ 20% indoxacarb coated granule of 11 1% Biphenthrin of embodiment
Biphenthrin 1%
Indoxacarb 20%
Polyethylene glycol 3%
The silicic acid 1% of high degree of dispersion
Calcium carbonate complements to 100%
In a mixer, by levigate active ingredient even spread to the carrier soaked by polyethylene glycol.It can obtain in this way
Obtain dust-free coated granules agent.
+ 20% indoxacarb wettable powder of 12 60% Biphenthrin of embodiment
Biphenthrin 60%
Indoxacarb 20%
Lauryl sodium sulfate 3%
Sodium lignin sulfonate 3%
White carbon 5%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
+ 40% indoxacarb of 13 20% Biphenthrin of embodiment extrudes granule
Biphenthrin 20%
Indoxacarb 40%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 2%
Kaolin complements to 100%
Active component is mixed and ground with auxiliary agent, mixture is soaked with water.The mixture is extruded, is then done in the air stream
It is dry.
+ 50% indoxacarb suspending agent of 14 1% Biphenthrin of embodiment
Biphenthrin 1%
Indoxacarb 50%
Fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through being sanded, is prepared into suspending agent.
+ 20% indoxacarb microcapsule suspension-suspendinagent agent of 15 10% Biphenthrin of embodiment
ATLOX TM4913 4%
Citric acid 0.05%
Catalyst 0.1%
Water 13%
Biphenthrin 10%
PAPI 1.35%
Methyl oleate 5%
ATLOX TM491316%
Dispersant LFH 0.3%
Defoamer 0.16%
Urea 8.4%
Indoxacarb 20%
Water complements to 100%
By PAPI, the oil phase addition that indoxacarb and methyl oleate are formed contains ATLOX TMIn 4913 aqueous solution, emulsion is formed.
Then heat and keep the temperature 50oWhen addition catalyst reaction 2 is small under C.The microcapsules of indoxacarb is obtained after cooling.
ATLOX TM4913, dispersant LFH, defoamer, urea, Biphenthrin and water mix in proportion, and through sand
Mill, is prepared into suspending agent.
The microcapsules of obtained indoxacarb is added in the aqueous suspension agent of Biphenthrin, be uniformly mixing to obtain 10% biphenyl chrysanthemum
The indoxacarb microcapsule suspension suspending agent of ester+20%.
+ 15% indoxacarb suspended emulsion of 16 5% Biphenthrin of embodiment
Biphenthrin 5%
Indoxacarb 15%
SOLVESSO TM20030%
Ethoxylated castor oil 4%
Fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Biphenthrin is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added, obtains the missible oil of Biphenthrin；Will
Indoxacarb, fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium, above-mentioned each component mix in proportion, and through being sanded,
It is prepared into suspending agent.
Oil phase containing Biphenthrin is added in the suspending agent containing indoxacarb, obtains suspended emulsion.
+ 10% indoxacarb missible oil of 17 10% Biphenthrin of embodiment
Biphenthrin 10%
Indoxacarb 10%
Ethoxylated castor oil 5%
Calcium dodecyl benzene sulfonate 3%
SOLVESSO TM100 complement to 100%
Above-mentioned each component is mixed, stirring is to obtaining transparent homogeneous phase.
+ 0.01% indoxacarb bait grain of 18 1% Biphenthrin of embodiment
Biphenyl polyester 1%
Indoxacarb 0.01%
Bait 60%
Cornstarch complements to 100%
Through air-flow crushing into wettable powder after said components are uniformly mixed, add a certain amount of water mixing extruding and make material and obtain
Obtain bait grain.
+ 0.05% indoxacarb bait grain of 19 0.05% Biphenthrin of embodiment
Biphenyl polyester 0.05%
Indoxacarb 0.05%
Bait 80%
Cornstarch complements to 100%
Through air-flow crushing into wettable powder after said components are uniformly mixed, add a certain amount of water mixing extruding and make material and obtain
Obtain bait grain.
+ 5% indoxacarb suspension seed-coating agent of 20 5% Biphenthrin of embodiment
Biphenthrin 5%
Indoxacarb 5%
Fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
PVP-K30 1%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through being sanded, is prepared into suspension seed-coating agent.
+ 50% indoxacarb of 21 50% Biphenthrin of embodiment
Biphenthrin 50%
Indoxacarb 50%
Biphenthrin and indoxacarb are proportionally uniformly mixed.
Biological test example
A kind of good desinsection of Pesticidal combination of the present invention and the effect of mite killing worm are found in the following example.Although individually
Reactive compound shortcoming is shown in its effect, but composition exhibits more than the effect of the simple adduction of each effect.When
When the effect of active compound combinations exceedes the summation of the effect when each reactive compound is administered alone, there are killing for collaboration
Worm and acaricidal action.The predictive role of the particular combination of two kinds of reactive compounds can be used so-called " Colby formula " (referring to
S.R. Colby, "Calculating Synergistic and Antagonistic Responses of Herbicide
Combinations ", Weeds 1967,15,20-22) it is calculated as below:If
X is when the use of dosage being mg/ha or kill rate during reactive compound A that concentration is mppm, is expressed as accounting for untreated
The percentage of control,
Y is when the use of dosage being ng/ha or kill rate during reactive compound B that concentration is nppm, is expressed as accounting for untreated
The percentage of control,
E be when the use of dosage being m and n g/ha or kill rate during reactive compound A and B that concentration is m and n ppm,
It is expressed as accounting for the percentage of untreated control,
So
If actual desinsection lethality exceedes calculated value, the lethal effect of composition is super adduction, that is, there is collaboration and make
With.In this case, the kill rate actually observed must be over the expection kill rate value (E) calculated using above-mentioned formula
Value.
Test example 1
Tea lesser leafhopper is tested
7 parts by weight dimethylformamide of solvent
2 parts by weight alkaryl polyglycol ether of emulsifying agent
To manufacture the appropriate formulation of reactive compound, 1 Parts by weight Active compound is mixed with the solvent and emulsifying agent of the amount,
Concentrate is diluted to required concentration with water.
It is carried out by being impregnated into by the tealeaves of tea lesser leafhopper severe infections in the active agent preparations for wish concentration
Processing.
After the desired time, death rate % is measured.100% represents that all tea lesser leafhoppers have been killed；0% indicate without
Tea lesser leafhopper is killed.The death rate of measure is calculated using " Colby formula ".
Show in this test, such as compared with reactive compound is administered alone, Pesticidal combination of the invention display association
With the activity of synergy.
Table 1
It was found that *=discovery activity
The * of calculating=be applicable in the activity that Colby formula calculate
Test example 2
Bollworm is tested
7 parts by weight dimethylformamide of solvent
2 parts by weight alkaryl polyglycol ether of emulsifying agent
To manufacture the appropriate formulation of reactive compound, 1 Parts by weight Active compound is mixed with the solvent and emulsifying agent of the amount,
Concentrate is diluted to required concentration with water.
It is handled by being impregnated into by the cotton leaf of bollworm severe infections in the active agent preparations for wish concentration.
After the desired time, death rate % is measured.100% represents that all bollworms have been killed；0% indicates no cotton boll
Worm is killed.The death rate of measure is calculated using " Colby formula ".
Show in this test, such as compared with reactive compound is administered alone, Pesticidal combination of the invention display association
With the activity of synergy.
Table 2
It was found that *=discovery activity
The * of calculating=be applicable in the activity that Colby formula calculate
Test example 3
Red spider is tested
7 parts by weight dimethylformamide of solvent
2 parts by weight alkaryl polyglycol ether of emulsifying agent
To manufacture the appropriate formulation of reactive compound, 1 Parts by weight Active compound is mixed with the solvent and emulsifying agent of the amount,
Concentrate is diluted to required concentration with water.
It is carried out by being impregnated into by the citrus leaf of red spider severe infections in the active agent preparations for wish concentration
Processing.
After the desired time, death rate % is measured.100% represents that all red spiders have been killed；0% indicates without red spider
Spider is killed.The death rate use of measure " Colby formula " are calculated.
Show in this test, such as compared with reactive compound is administered alone, Pesticidal combination of the invention display association
With the activity of synergy.
Table 3
It was found that *=discovery activity
The * of calculating=be applicable in the activity that Colby formula calculate
Test example 4
Trialeurodes vaporariorum is tested
7 parts by weight dimethylformamide of solvent
2 parts by weight alkaryl polyglycol ether of emulsifying agent
To manufacture the appropriate formulation of reactive compound, 1 Parts by weight Active compound is mixed with the solvent and emulsifying agent of the amount,
Concentrate is diluted to required concentration with water.
It will be impregnated into by the tomato leaf of trialeurodes vaporariorum severe infections in the active agent preparations for wish concentration at it
Reason.
After the desired time, death rate % is measured.100% represents that all trialeurodes vaporariorums have been killed；0% indicates no white powder
Lice is killed.The death rate use of measure " Colby formula " are calculated.
Show in this test, such as compared with reactive compound is administered alone, Pesticidal combination of the invention display association
With the activity of synergy.
Table 4
It was found that *=discovery activity
The * of calculating=be applicable in the activity that Colby formula calculate
Test example 5
Diamondback moth is tested
7 parts by weight dimethylformamide of solvent
2 parts by weight alkaryl polyglycol ether of emulsifying agent
To manufacture the appropriate formulation of reactive compound, 1 Parts by weight Active compound is mixed with the solvent and emulsifying agent of the amount,
Concentrate is diluted to required concentration with water.
It will be impregnated into by the cabbage leaves of diamondback moth severe infections in the active agent preparations for wish concentration at it
Reason.
After the desired time, death rate % is measured.100% represents that all diamondback moths have been killed；0% indicates no pickles
Moth is killed.The death rate use of measure " Colby formula " are calculated.
Show in this test, such as compared with reactive compound is administered alone, Pesticidal combination of the invention display association
With the activity of synergy.
Table 5
It was found that *=discovery activity
The * of calculating=be applicable in the activity that Colby formula calculate
Test example 6
Fly is tested
7 parts by weight dimethylformamide of solvent
2 parts by weight alkaryl polyglycol ether of emulsifying agent
To manufacture the appropriate formulation of reactive compound, 1 Parts by weight Active compound is mixed with the solvent and emulsifying agent of the amount,
Concentrate is diluted to required concentration with water.
A certain amount of fly worm is placed in the space of each closing.With wishing the reactive compound of concentration at it
Reason.
After the desired time, death rate % is measured.100% represents that all flies have been killed；0% indicates that no fly is killed.
The death rate use of measure " Colby formula " are calculated.
Show in this test, such as compared with reactive compound is administered alone, Pesticidal combination of the invention display association
With the activity of synergy.
Table 6
It was found that *=discovery activity
The * of calculating=be applicable in the activity that Colby formula calculate
Test example 7
Termite is tested
7 parts by weight dimethylformamide of solvent
2 parts by weight alkaryl polyglycol ether of emulsifying agent
To manufacture the appropriate formulation of reactive compound, 1 Parts by weight Active compound is mixed with the solvent and emulsifying agent of the amount,
Concentrate is diluted to required concentration with water.
It will be handled into the active agent preparations for wish concentration by the timber pickling of termite Eroded.
After the desired time, death rate % is measured.100% represents that all termites have been killed；0% indicates no termite quilt
Kill.The death rate use of measure " Colby formula " are calculated.
Show in this test, such as compared with reactive compound is administered alone, Pesticidal combination of the invention display association
With the activity of synergy.
Table 7
It was found that *=discovery activity
The * of calculating=be applicable in the activity that Colby formula calculate.
Claims (12)
1. a kind of Pesticidal combination is used for the purposes for preventing or controlling sanitary insect pest, the Pesticidal combination, its active ingredient bag
Containing Biphenthrin and indoxacarb, the weight ratio of the Biphenthrin and indoxacarb is 1:100 to 100:1.
2. purposes according to claim 1, the sanitary insect pest is termite, fly.
3. purposes according to claim 1, it is characterised in that：The weight ratio of the Biphenthrin and indoxacarb is 1:50 arrive
50:1。
4. purposes according to claim 1, it is characterised in that：The weight ratio of the Biphenthrin and indoxacarb is 1:20 arrive
20:1。
5. purposes according to claim 1, it is characterised in that：The weight ratio of the Biphenthrin and indoxacarb is 1:10 arrive
10:1。
6. purposes according to claim 1, it is characterised in that：The weight ratio of the Biphenthrin and indoxacarb is 1:5 arrive
5:1。
7. purposes according to claim 1, it is characterised in that：The Biphenthrin and indoxacarb account for the desinsection group altogether
Compound by weight 0.5% to 100%.
8. purposes according to claim 1, it is characterised in that：The Biphenthrin and indoxacarb account for the desinsection group altogether
Compound by weight 1% to 80%.
9. purposes according to claim 1, it is characterised in that：The Biphenthrin and indoxacarb account for the desinsection group altogether
Compound by weight 5% to 60%.
10. purposes according to claim 1, it is characterised in that：The Pesticidal combination is also lived comprising carrier and/or surface
Property agent.
11. purposes according to claim 1, it is characterised in that：The Pesticidal combination, its formulation are：Suspending agent, micro-capsule
Agent, missible oil, suspending agent, water dispersible granules, wettable powder, suspension emulsion, aqueous emulsion, suspension seed-coating agent, granule, bait grain.
12. purposes according to claim 1, target sanitary insect pest is applied to by the Pesticidal combination described in claim 1
And/or its environment.
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| CN108294052A (en) * | 2018-02-12 | 2018-07-20 | 平南县兴民龙藤茶业专业合作社 | A kind of Synergistic insecticidal composition of prevention tea geometrid |
| TW202200008A (en) * | 2020-03-17 | 2022-01-01 | 美商富曼西公司 | Processes for preparing suspension concentrate formulations comprising pesticidal mixtures |
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| CN102986719A (en) * | 2012-12-28 | 2013-03-27 | 江苏龙灯化学有限公司 | Insecticide composition containing bifenthrin and pyriproxyfen and applications thereof |
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| GB0118137D0 (en) * | 2001-07-25 | 2001-09-19 | Syngenta Ltd | Insecticidal mixture |
| CN101243798A (en) * | 2008-01-11 | 2008-08-20 | 湖南万家丰科技有限公司 | Insecticidal composition containing indoxacarb |
| RU2013158642A (en) * | 2011-06-08 | 2015-07-20 | Интервет Интернэшнл Б.В. | PARASITICID COMBINATION INCLUDING INDOXACARB AND DELTAMETRIN |
| CN102349529A (en) * | 2011-07-28 | 2012-02-15 | 尹小根 | Insecticidal composition containing indoxacarb and etofenprox |
| CN102696665A (en) * | 2012-05-15 | 2012-10-03 | 镇江市苏盾植保专业合作联社 | Insecticide combination containing indoxacarb |
| CN103053600B (en) * | 2012-12-29 | 2014-12-31 | 广东中迅农科股份有限公司 | Insecticidal composition of indoxacarb and efficient cyfluthrin |
| CN104705337A (en) * | 2013-12-11 | 2015-06-17 | 清远市顾地丰生物科技有限公司 | Pesticide |
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| M N R ATTIQUE ET AL.: "Could resistance to insecticides in Plutella xylostella (Lep., Plutellidae) be overcome by insecticide mixtures?", 《J.APPL.ENTOMOL.》 * |
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