CN107892854A - Formula of leather color inhibition synthesis resin and preparation method thereof - Google Patents
Formula of leather color inhibition synthesis resin and preparation method thereof Download PDFInfo
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- CN107892854A CN107892854A CN201711319279.XA CN201711319279A CN107892854A CN 107892854 A CN107892854 A CN 107892854A CN 201711319279 A CN201711319279 A CN 201711319279A CN 107892854 A CN107892854 A CN 107892854A
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- parts
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- color inhibition
- leather
- synthesis resin
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
A kind of formula of leather color inhibition synthesis resin, it is related to the resistance to yellow formula of leather, the component of the formula is color inhibition acrylic emulsion, paraffin wax emulsions, filler, thickener, hollow polymer spheroid, PH conditioning agents, defoamer, preservative and water；The parts by weight of the formula each component are 200 400 parts of 200 300 parts of color inhibition acrylic emulsion, 100 200 parts of paraffin wax emulsions, 80 160 parts of filler, 10 30 parts of thickener, 50 100 parts of hollow polymer spheroid, 10 30 parts of PH conditioning agents, 10 30 parts of defoamer, 50 100 parts of preservative and water.Glossiness, polish retention, non-plastic, the resistance to bent rich property of leather can additionally be increased, make the leather hand feeling after processing comfortable；And without the organic solvents such as APES class compound, safety and environmental protection in the formula.
Description
Technical field：
The present invention relates to the resistance to yellow formula of leather, and in particular to a kind of formula of leather color inhibition synthesis resin and its preparation side
Method.
Background technology：
Color inhibition synthesis resin is can directly to add the product that pigment paste is covered with paint, lacquer, colour wash, etc., and the pulp layer allocated instead of skin factory worker can
To save factory work intensity, operating efficiency is improved.Current most of synthesis resin is all unable to color inhibition, limits making for factory
With in order to solve the above-mentioned technical problem, spy proposes a kind of new technical scheme.
The content of the invention：
In place of overcoming above-mentioned the shortcomings of the prior art, and provide a kind of leather color inhibition
Formula of synthesis resin and preparation method thereof.
The technical solution adopted by the present invention is：A kind of formula of leather color inhibition synthesis resin, the component of the formula is resistance to
Xanthochromia acrylic emulsion, paraffin wax emulsions, filler, thickener, hollow polymer spheroid, PH conditioning agents, defoamer, preservative and
Water；The parts by weight of the formula each component are color inhibition acrylic emulsion 200-300 parts, paraffin wax emulsions 100-200 parts, filler
80-160 parts, thickener 10-30 parts, hollow polymer spheroid 50-100 parts, PH conditioning agent 10-30 parts, defoamer 10-30 parts,
Preservative 50-100 parts and water 200-400 parts.
The parts by weight of the formula each component be color inhibition acrylic emulsion 250-260 parts, paraffin wax emulsions 150-160 parts,
Filler 100-130 parts, thickener 15-20 parts, hollow polymer spheroid 70-80 parts, PH conditioning agent 20-26 parts, defoamer 15-20
Part, preservative 6-8 parts and water 250-300 parts.
Described color inhibition acrylic emulsion is by ethyl acrylate, acrylic acid, lauryl sodium sulfate and activated zinc oxide
Composition；The parts by weight of the color inhibition acrylic emulsion each component are ethyl acrylate 50-100 parts, acrylic acid 20-50 parts, ten
Sodium dialkyl sulfate 3-5 parts and activated zinc oxide 5-7 parts.
Described filler is made up of kaolin and cellulose；The filler each component parts by weight are kaolin 200-250 parts
And cellulose 10-20 parts.
Described thickener is alkali swollen thickener.
Described preservative is made up of water lily fibrin, streptococcus lactis and Tea Polyphenols；The weight of the preservative each component
It is water lily fibrin 1-3 parts, streptococcus lactis 2-5 parts and Tea Polyphenols 1-6 parts to measure number.
Described described defoamer is the fatty acid ester compounded thing of higher alcohols or polyoxyethylene polyoxy propyl alcohol amidogen ether.
This method comprises the following steps：
Step 1: by water, acrylic emulsion, polyaminoester emulsion, liquid wax emulsion, filler, pH value conditioning agent and preservative
It is separately added into order in reactor, side adds, while stirring, mixing speed is 600~1600r/min；
Step 2: thickener is added slowly thereto, mixing liquid is set gradually slowly to thicken, to reach preferable denseness
(4# Ford cups 50~120 seconds)；
Step 3: the mixed system after thickening is filtered, detection, the synthesis resin of water-based color inhibition is obtained；
This method reaction condition is lower 5 DEG C~35 DEG C of normal temperature condition.
Beneficial effects of the present invention are：This formula has preferably embossing constancy, and film forming is soft, and covering is strong.This
Glossiness, polish retention, non-plastic, the resistance to bent rich property of leather can also be increased outside, make the leather hand feeling after processing comfortable；And
And without the organic solvents such as APES class compound, safety and environmental protection in the formula；The preparation method letter of the formula
Single practical, consersion unit is not required to particularly customized, common mixer and the production of dispersion impeller can, and this method is prepared
Leather finishing agent there is better stability, preparation method process stabilizing, be adapted to industrialized production.In addition, this method is prepared into
The properties of product arrived are very outstanding, and use range is wide, reduce the probability using factory's compounding mistake, removed from office especially suitable for white,
Color inhibition quality problems not up to standard and caused are avoided, can lift original Leather Properties, Leather Factory's also right and wrong when in use
It is often convenient, it is simple to operate, it is cheap, factory's benefit can be lifted.
Embodiment：
The present invention is further described in conjunction with specific embodiments：
Embodiment one：
A kind of formula of leather color inhibition synthesis resin, the parts by weight of the formula each component are color inhibition acrylic emulsion
200 parts, 100 parts of paraffin wax emulsions, 80 parts of filler, 10 parts of thickener, 50 parts of hollow polymer spheroid, 10 parts of PH conditioning agents, defoaming
200 parts of 10 parts of agent, 50 parts of preservative and water.The parts by weight of the color inhibition acrylic emulsion each component are ethyl acrylate 50
Part, 20 parts of acrylic acid, 3 parts of lauryl sodium sulfate and 5 parts of activated zinc oxide.The filler each component parts by weight are kaolin
200 parts and 10 parts of cellulose.Described thickener is alkali swollen thickener.The parts by weight of the preservative each component are that water lily is fine
1 part of 1 part of fibrillarin, 2 parts of streptococcus lactis and Tea Polyphenols.Described described defoamer be the fatty acid ester compounded thing of higher alcohols or
Polyoxyethylene polyoxy propyl alcohol amidogen ether.
Embodiment two：
A kind of formula of leather color inhibition synthesis resin, the parts by weight of the formula each component are color inhibition acrylic emulsion
150 parts, 150 parts of paraffin wax emulsions, 100 parts of filler, 20 parts of thickener, 90 parts of hollow polymer spheroid, 20 parts of PH conditioning agents, defoaming
300 parts of 20 parts of agent, 70 parts of preservative and water.The parts by weight of the color inhibition acrylic emulsion each component are ethyl acrylate 75
Part, 30 parts of acrylic acid, 4 parts of lauryl sodium sulfate and 6 parts of activated zinc oxide.The filler each component parts by weight are kaolin
220 parts and 15 parts of cellulose.Described thickener is alkali swollen thickener.The parts by weight of the preservative each component are that water lily is fine
5 parts of 2 parts of fibrillarin, 3 parts of streptococcus lactis and Tea Polyphenols.Described described defoamer be the fatty acid ester compounded thing of higher alcohols or
Polyoxyethylene polyoxy propyl alcohol amidogen ether.
Embodiment three：
A kind of formula of leather color inhibition synthesis resin, the parts by weight of the formula each component are color inhibition acrylic emulsion
300 parts, 200 parts of paraffin wax emulsions, 160 parts of filler, 30 parts of thickener, 100 parts of hollow polymer spheroid, 30 parts of PH conditioning agents, disappear
400 parts of 30 parts of infusion, 100 parts of preservative and water.The parts by weight of the color inhibition acrylic emulsion each component are ethyl acrylate
7 parts of 100 parts, 50 parts of acrylic acid, 5 parts of lauryl sodium sulfate and activated zinc oxide.The filler each component parts by weight are kaolinite
Native 250 parts and 20 parts of cellulose.Described thickener is alkali swollen thickener.The parts by weight of the preservative each component are water lily
6 parts of 3 parts of fibrin, 5 parts of streptococcus lactis and Tea Polyphenols.Described described defoamer is the fatty acid ester compounded thing of higher alcohols
Or polyoxyethylene polyoxy propyl alcohol amidogen ether.
Three above embodiment is prepared using following preparation method：
This method comprises the following steps：
Step 1: by water, acrylic emulsion, polyaminoester emulsion, liquid wax emulsion, filler, defoamer and preservative by suitable
Sequence is separately added into reactor, and side adds, while stirring, mixing speed is 600~1600r/min；
Step 2: thickener is added slowly thereto, mixing liquid is set gradually slowly to thicken, to reach preferable denseness
(4# Ford cups 50~120 seconds)；
Step 3: the mixed system after thickening is filtered, detection, the synthesis resin of water-based color inhibition is obtained.
Using effect is tested：
This research is examined the effect of the formula of leather color inhibition synthesis resin and preparation method thereof by 100 enterprises
Examine, test event standards of grading are：Very satisfied 5 points, 4 points are satisfied with, general 3 points, is unsatisfied with 2 points, very dissatisfied 1 point.Its
In common group be common leather color inhibition synthesis resin formula；
| Test event | Embodiment one | Embodiment two | Embodiment three | Common group |
| The glossiness of leather | 4.8 | 4.9 | 4.7 | 3.0 |
| Polish retention | 4.8 | 4.9 | 5.0 | 1.0 |
| Non-plastic | 4.7 | 4.9 | 4.8 | 3.0 |
| Resistance to bent rich property | 4.7 | 4.9 | 4.6 | 3.2 |
| The feature of environmental protection | 4.9 | 4.9 | 4.9 | 2.0 |
| It is embossed constancy | 4.7 | 4.9 | 4.8 | 3.0 |
| Film flexibility | 4.7 | 4.9 | 4.6 | 3.2 |
| Covering | 4.9 | 4.9 | 4.9 | 2.0 |
In summary, the present invention its not only can effectively solve the glossiness of leather, polish retention, non-plastic and resistance to
The problem of bent rich property, and it is more healthy by human body with certain environmental-protecting performance.This formula has preferably embossing constancy, and
Film forming is soft, and covering is strong.Glossiness, polish retention, non-plastic, the resistance to bent rich property of leather can additionally be increased, make place
Leather hand feeling after reason is comfortable；And without the organic solvents such as APES class compound, safety collar in the formula
Protect；The preparation method of the formula is simple and practical, and consersion unit is not required to particularly customized, common mixer and the life of dispersion impeller can
Production, and the leather finishing agent that this method is prepared has better stability, preparation method process stabilizing, is adapted to industrial metaplasia
Production.In addition, the properties of product that this method is prepared are very outstanding, use range is wide, reduces using the several of factory's compounding mistake
Rate, removed from office especially suitable for white, avoid color inhibition quality problems not up to standard and caused, original Leather Properties can be lifted,
Leather Factory be also when in use it is very convenient, it is simple to operate, it is cheap, factory's benefit can be lifted.
For those skilled in the art, it is various corresponding can be made according to above technical scheme and design for other
Change and deformation, and all these change and deformation should all belong within the protection domain of the claims in the present invention.
Claims (9)
- A kind of 1. formula of leather color inhibition synthesis resin, it is characterised in that：The component of the formula be color inhibition acrylic emulsion, Paraffin wax emulsions, filler, thickener, hollow polymer spheroid, PH conditioning agents, defoamer, preservative and water；The formula each component Parts by weight are color inhibition acrylic emulsion 200-300 parts, paraffin wax emulsions 100-200 parts, filler 80-160 parts, thickener 10- 30 parts, hollow polymer spheroid 50-100 parts, PH conditioning agent 10-30 parts, defoamer 10-30 parts, preservative 50-100 parts and water 200-400 parts.
- 2. the formula of leather color inhibition synthesis resin according to claim 1, it is characterised in that：The weight of the formula each component Amount number is color inhibition acrylic emulsion 250-260 parts, paraffin wax emulsions 150-160 parts, filler 100-130 parts, thickener 15-20 Part, hollow polymer spheroid 70-80 parts, PH conditioning agent 20-26 parts, defoamer 15-20 parts, preservative 6-8 parts and water 250-300 Part.
- 3. the formula of leather color inhibition synthesis resin according to claim 1, it is characterised in that：Described color inhibition propylene Yogurt liquid is made up of ethyl acrylate, acrylic acid, lauryl sodium sulfate and activated zinc oxide；The color inhibition acrylic emulsion is each The parts by weight of component are ethyl acrylate 50-100 parts, acrylic acid 20-50 parts, lauryl sodium sulfate 3-5 parts and active oxygen Change zinc 5-7 parts.
- 4. the formula of leather color inhibition synthesis resin according to claim 1, it is characterised in that：Described filler is by kaolinite Soil and cellulose composition；The filler each component parts by weight are kaolin 200-250 parts and cellulose 10-20 parts.
- 5. the formula of leather color inhibition synthesis resin according to claim 1, it is characterised in that：Described thickener is alkali Swollen thickener.
- 6. the formula of leather color inhibition synthesis resin according to claim 1, it is characterised in that：Described preservative is by sleeping Lotus fibrin, streptococcus lactis and Tea Polyphenols composition；The parts by weight of the preservative each component are water lily fibrin 1-3 Part, streptococcus lactis 2-5 parts and Tea Polyphenols 1-6 parts.
- 7. the formula of leather color inhibition synthesis resin according to claim 1, it is characterised in that：Described described defoaming Agent is the fatty acid ester compounded thing of higher alcohols or polyoxyethylene polyoxy propyl alcohol amidogen ether.
- A kind of 8. preparation method of the formula of leather color inhibition synthesis resin, it is characterised in that：This method comprises the following steps：Step 1: by water, acrylic emulsion, polyaminoester emulsion, liquid wax emulsion, filler, pH value conditioning agent and preservative by suitable Sequence is separately added into reactor, and side adds, while stirring, mixing speed is 600~1600r/min；Step 2: thickener is added slowly thereto, mixing liquid is set gradually slowly to thicken, to reach preferable denseness (4# good fortune Special cup 50~120 seconds)；Step 3: the mixed system after thickening is filtered, detection, the synthesis resin of water-based color inhibition is obtained；
- 9. the preparation method of the formula of leather color inhibition synthesis resin according to claim 8, it is characterised in that：This method Reaction condition is lower 5 DEG C~35 DEG C of normal temperature condition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711319279.XA CN107892854A (en) | 2017-12-12 | 2017-12-12 | Formula of leather color inhibition synthesis resin and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711319279.XA CN107892854A (en) | 2017-12-12 | 2017-12-12 | Formula of leather color inhibition synthesis resin and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107892854A true CN107892854A (en) | 2018-04-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711319279.XA Pending CN107892854A (en) | 2017-12-12 | 2017-12-12 | Formula of leather color inhibition synthesis resin and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110066565A (en) * | 2019-05-24 | 2019-07-30 | 齐鲁工业大学 | A kind of high-adhesiveness leather finishing agent of color inhibition and preparation method thereof |
| CN111318433A (en) * | 2020-03-02 | 2020-06-23 | 明新旭腾新材料股份有限公司 | Manufacturing method of leather with 3D (three-dimensional) effect |
| CN112724831A (en) * | 2021-04-01 | 2021-04-30 | 佛山市昭景环保科技有限公司 | Water-based treating agent for printing burst-style synthetic leather and preparation method thereof |
| CN114250019A (en) * | 2021-12-30 | 2022-03-29 | 盛瑞(常州)特种材料有限公司 | Leather surface modifier, composition for forming same and application |
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| CN101434763A (en) * | 2008-12-09 | 2009-05-20 | 朗盛（无锡）化工有限公司 | Yellow stain resistant blowing promoter for coating leather |
| CN101824260A (en) * | 2009-03-04 | 2010-09-08 | 中国皮革和制鞋工业研究院 | Synthesis resin for leather and preparation method thereof |
| CN102746780A (en) * | 2012-07-11 | 2012-10-24 | 山东天庆科技发展有限公司 | Aqueous comprehensive resin and preparation method of aqueous comprehensive resin |
| CN104419774A (en) * | 2013-08-28 | 2015-03-18 | 青岛医防消毒专业技术中心 | Leather moisture-proof agent containing water lily phenolphthalein |
| CN104513870A (en) * | 2013-09-27 | 2015-04-15 | 青岛畅绿生物研究所 | Leather antiseptic containing water lily fibrin |
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Patent Citations (5)
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|---|---|---|---|---|
| CN101434763A (en) * | 2008-12-09 | 2009-05-20 | 朗盛（无锡）化工有限公司 | Yellow stain resistant blowing promoter for coating leather |
| CN101824260A (en) * | 2009-03-04 | 2010-09-08 | 中国皮革和制鞋工业研究院 | Synthesis resin for leather and preparation method thereof |
| CN102746780A (en) * | 2012-07-11 | 2012-10-24 | 山东天庆科技发展有限公司 | Aqueous comprehensive resin and preparation method of aqueous comprehensive resin |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110066565A (en) * | 2019-05-24 | 2019-07-30 | 齐鲁工业大学 | A kind of high-adhesiveness leather finishing agent of color inhibition and preparation method thereof |
| CN110066565B (en) * | 2019-05-24 | 2021-08-13 | 齐鲁工业大学 | Yellowing-resistant high-adhesion leather finishing agent and preparation method thereof |
| CN111318433A (en) * | 2020-03-02 | 2020-06-23 | 明新旭腾新材料股份有限公司 | Manufacturing method of leather with 3D (three-dimensional) effect |
| CN112724831A (en) * | 2021-04-01 | 2021-04-30 | 佛山市昭景环保科技有限公司 | Water-based treating agent for printing burst-style synthetic leather and preparation method thereof |
| CN112724831B (en) * | 2021-04-01 | 2021-07-27 | 佛山市昭景环保科技有限公司 | Water-based treating agent for printing burst-style synthetic leather and preparation method thereof |
| CN114250019A (en) * | 2021-12-30 | 2022-03-29 | 盛瑞(常州)特种材料有限公司 | Leather surface modifier, composition for forming same and application |
| CN114250019B (en) * | 2021-12-30 | 2023-01-17 | 盛瑞(常州)特种材料有限公司 | Leather surface modifier, composition for forming same and application |
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Application publication date: 20180410 |