CN107892638A - A kind of gas producing medicinal - Google Patents

A kind of gas producing medicinal Download PDF

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Publication number
CN107892638A
CN107892638A CN201710308215.3A CN201710308215A CN107892638A CN 107892638 A CN107892638 A CN 107892638A CN 201710308215 A CN201710308215 A CN 201710308215A CN 107892638 A CN107892638 A CN 107892638A
Authority
CN
China
Prior art keywords
gas
producing medicinal
azodicarbonamide
gas producing
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710308215.3A
Other languages
Chinese (zh)
Inventor
鲁锐华
石俊涛
郭春亮
向进
邓康清
黄昌龙
李颖
杨玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Institute of Aerospace Chemical Technology
Original Assignee
Hubei Institute of Aerospace Chemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Institute of Aerospace Chemical Technology filed Critical Hubei Institute of Aerospace Chemical Technology
Priority to CN201710308215.3A priority Critical patent/CN107892638A/en
Publication of CN107892638A publication Critical patent/CN107892638A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06DMEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
    • C06D5/00Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
    • C06D5/06Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B29/00Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
    • C06B29/02Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal

Abstract

The present invention relates to a kind of gas producing medicinal, the gas producing medicinal includes potassium hyperchlorate and azodicarbonamide.Its mass percent component:Potassium hyperchlorate:40%~60%;Azodicarbonamide:40%~60%.Gas producing medicinal of the present invention has the characteristics that gas production is big, combustion temperature is low, gas componant is clean;It is cheap and raw material are easy to obtain, production process safety.The method have the benefit that:(1)Gas production is big:More than 600L/kg(Standard state).(2)Safety and stability:Sensitivity is low.(3)Cost is low:Azodicarbonamide source is wide, cheap.(4)Combustion gas is cleaned:Main component is H2、CO2、N2、H2O etc..It can be widely applied to civilian and military domain.

Description

A kind of gas producing medicinal
Technical field
The present invention relates to a kind of gas producing medicinal, more particularly to a kind of gas production is big, combustion temperature is low, safe and reliable, inexpensive, combustion The gas producing medicinal of gas cleaning.
Background technology
Gas-forming agent is mainly by fuel agent, oxidant and additive composition.Additive generally comprises catalyst, bonding Agent, cooling agent, burning ratemodifier etc., can be by gas generator, and rapid burning discharges a large amount of gases, for externally doing work or filling Gas buffers.Gas-forming agent is widely used in military and civil area.The former is such as the rail control engine energy, landing cushion gasbag Source of the gas etc.;The latter such as civil aviaton meets an urgent need slide source of the gas, Mae West source of the gas, unmanned plane buffering landing air bag, underwater salvage air bag Deng.
At present, gas-forming agent is broadly divided into nitrine class and non-nitrine class gas-forming agent.In nitrine class gas-forming agent Azide is fuel agent, wherein Alkali-Metal Na NO3The most used, oxidant typically uses metal oxide Fe2O3、MnO2 Deng.Composition of Sodium Azide Gas Generant tool ignition temperature is low(About 1500K), a large amount of nontoxic nitrogen, burning speed are produced after burning Spend the advantage such as relatively fast and free from the influence of the external environment.But azide is easily production after toxic articles, with oxidant reaction Raw stimulating component, residue is not easy to filter after burning;The danger such as blast during use be present.Therefore function admirable is developed, Safe and reliable non-nitrine class gas-forming agent is imperative.
The content of the invention
In view of the shortcomings of the prior art, object of the present invention is to provide gas production is big, combustion temperature is low, safe and reliable, low Cost, the gas producing medicinal of combustion gas cleaning.
Technical scheme includes potassium hyperchlorate and azodicarbonamide, its mass percent component:
Potassium hyperchlorate:40%~60%
Azodicarbonamide:40%~60%.
Preferred mass percentage component of the present invention:
Potassium hyperchlorate:43%~47%
Azodicarbonamide:53%~57%.
Potassium hyperchlorate of the present invention is oxidant, and granularity is no more than 150um.
Azodicarbonamide of the present invention is reducing agent, and granularity is no more than 20um.
Compared with prior art, gas producing medicinal of the present invention has the characteristics that gas production is big, combustion temperature is low, gas componant is clean; It is cheap and raw material are easy to obtain, production process safety, it can be widely applied to civilian and military domain.The present invention's has Benefit has the technical effect that:
(1)Gas production is big:More than 600L/kg(Standard state).
(2)Safety and stability:Sensitivity is low.
(3)Cost is low:Azodicarbonamide source is wide, cheap.
(4)Combustion gas is cleaned:Main component is H2、CO2、N2、H2O etc..
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art's it will be clearly understood that the reality Apply example to be only to aid in understanding the present invention, be not construed as the concrete restriction to the present invention.
Embodiment 1
Precise 40g potassium hyperchlorates and 60g azodicarbonamides, are uniformly sufficiently mixed, are loaded with closed container afterwards.Using most Freedom in minor affairs energy method calculates thermodynamic parameter of the present embodiment under 5MPa environmental pressures:The combustion temperature of this formula is 1916 K, is got angry Measure as 746L/kg.Product component is shown in Table 1.
The product component of table 1
Embodiment 2
Precise 45g potassium hyperchlorates and 55g azodicarbonamides, are uniformly sufficiently mixed, are loaded with closed container afterwards.Using most Freedom in minor affairs energy method calculates parameter of this formula under 5MPa environmental pressures:The combustion temperature of this formula is 2150K, gas forming amount 706L/ kg.Product component is shown in Table 2.
The product component of table 2
Embodiment 3
Precise 50g potassium hyperchlorates and 50g azodicarbonamides, are uniformly sufficiently mixed, are loaded with closed container afterwards.Using most Freedom in minor affairs energy method calculates parameter of this formula under 5MPa environmental pressures:The combustion temperature of this formula is 2429K, gas forming amount 659L/ kg.Product component is shown in Table 3.
The product component of table 3
Embodiment 4
Precise 55g potassium hyperchlorates and 45g azodicarbonamides, are uniformly sufficiently mixed, are loaded with closed container afterwards.Using most Freedom in minor affairs energy method calculates parameter of this formula under 5MPa environmental pressures:The combustion temperature of this formula is 2559 K, gas forming amount 620 L/kg.Gas componant is shown in Table 4.
The product component of table 4
Embodiment 5
Precise 60g potassium hyperchlorates and 40g azodicarbonamides, are uniformly sufficiently mixed, are loaded with closed container afterwards.Using most Freedom in minor affairs energy method calculates parameter of this formula under 5MPa environmental pressures:The combustion temperature of this formula is 2374 K, gas forming amount 598L/ Kg, gas componant are shown in Table 5.
The product component of table 5
The above embodiments are merely illustrative of the technical solutions of the present invention and unrestricted, institute within the spirit and principles of the invention All any modification, equivalent and improvement done etc., it all should cover in the protection claimed range of the present invention.

Claims (4)

1. a kind of gas producing medicinal, it is characterised in that including following masses percentage component:
Potassium hyperchlorate:40%~60%
Azodicarbonamide:40%~60%.
2. a kind of gas producing medicinal according to claim 1, it is characterised in that including following masses percentage component:
Potassium hyperchlorate:43%~47%
Azodicarbonamide:53%~57%.
A kind of 3. gas producing medicinal according to claim 1, it is characterised in that:The potassium hyperchlorate is oxidant, and granularity is not More than 150um.
A kind of 4. gas producing medicinal according to claim 1, it is characterised in that:The azodicarbonamide is reducing agent, grain Degree is no more than 20um.
CN201710308215.3A 2017-05-04 2017-05-04 A kind of gas producing medicinal Pending CN107892638A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710308215.3A CN107892638A (en) 2017-05-04 2017-05-04 A kind of gas producing medicinal

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710308215.3A CN107892638A (en) 2017-05-04 2017-05-04 A kind of gas producing medicinal

Publications (1)

Publication Number Publication Date
CN107892638A true CN107892638A (en) 2018-04-10

Family

ID=61803080

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710308215.3A Pending CN107892638A (en) 2017-05-04 2017-05-04 A kind of gas producing medicinal

Country Status (1)

Country Link
CN (1) CN107892638A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1125933A (en) * 1994-02-15 1996-07-03 日本工机株式会社 Gas generator composition, process for producing tablet therefrom, and transportation method
CN1266416A (en) * 1998-04-30 2000-09-13 大赛璐化学工业株式会社 Enhancer composition for inflator
CN1272102A (en) * 1998-04-20 2000-11-01 大赛璐化学工业株式会社 Method of reducing NOx
CN101432245A (en) * 2006-05-02 2009-05-13 日本化药株式会社 Gas generant composition for gas actuator for activating safety device and gas generator for gas actuator using the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1125933A (en) * 1994-02-15 1996-07-03 日本工机株式会社 Gas generator composition, process for producing tablet therefrom, and transportation method
CN1272102A (en) * 1998-04-20 2000-11-01 大赛璐化学工业株式会社 Method of reducing NOx
CN1266416A (en) * 1998-04-30 2000-09-13 大赛璐化学工业株式会社 Enhancer composition for inflator
CN101432245A (en) * 2006-05-02 2009-05-13 日本化药株式会社 Gas generant composition for gas actuator for activating safety device and gas generator for gas actuator using the same

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Application publication date: 20180410