CN107880813A - A kind of preparation method of quick-drying honeycomb cardboard adhesive - Google Patents

A kind of preparation method of quick-drying honeycomb cardboard adhesive Download PDF

Info

Publication number
CN107880813A
CN107880813A CN201711187701.0A CN201711187701A CN107880813A CN 107880813 A CN107880813 A CN 107880813A CN 201711187701 A CN201711187701 A CN 201711187701A CN 107880813 A CN107880813 A CN 107880813A
Authority
CN
China
Prior art keywords
quick
minutes
preparation
honeycomb cardboard
drying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711187701.0A
Other languages
Chinese (zh)
Inventor
史闵新
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Fuzhong Plastic Co Ltd
Original Assignee
Suzhou Fuzhong Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Fuzhong Plastic Co Ltd filed Critical Suzhou Fuzhong Plastic Co Ltd
Priority to CN201711187701.0A priority Critical patent/CN107880813A/en
Publication of CN107880813A publication Critical patent/CN107880813A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J105/00—Adhesives based on polysaccharides or on their derivatives, not provided for in groups C09J101/00 or C09J103/00
    • C09J105/16—Cyclodextrin; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention provides a kind of preparation method of quick-drying honeycomb cardboard adhesive, comprise the following steps：（1）Beta cyclodextrin, pullulan and distilled water are mixed, 70 80 DEG C is heated to and stirs 5 10 minutes；（2）Room temperature is down to, Sodium Polyacrylate, konjac oligosaccharides, hydrogenated rosin glyceride and absolute ethyl alcohol is added, is stirred 25 minutes under the 700r/min of rotating speed 500；（3）Add potassium sorbate, AESA, sorbitol anhydride monopalmitate, filler, oxalic acid and glycerine, ultrasonic shear 5 10 minutes；（4）Vacuum outgas removes bubble and produced.The preparation method of the quick-drying honeycomb cardboard adhesive of the present invention, prepared adhesive have very high gumminess, and peel strength is high, while rate of drying is fast, and drying time is short.

Description

A kind of preparation method of quick-drying honeycomb cardboard adhesive
Technical field
The present invention relates to a kind of preparation method of quick-drying honeycomb cardboard adhesive.
Background technology
Honeycomb cardboard is exactly the structure for copying honeycomb, using paper as base material, is produced with the equipment of the electromechanical one of modernization A kind of cellular new material, have it is light, intensity is high, good rigidity, and have good buffering, vibration isolation, insulation, it is heat-insulated, The performances such as sound insulation, production cost is low, and applicability is wide, is widely used in packaging, accumulating, construction industry, car and boat manufacturing industry and furniture etc., Timber, clay brick, foamed plastic etc. can be replaced, the felling to reducing forest, preserves the ecological environment and is significant.Influence For honeycomb cardboard quality in addition to cardboard quality itself, the adhesive used is also a key factor.The flower bulb used for many years Alkali is adhesive, although operating procedure is simple, meets wet deliquescence, binding speed is slow.With the continuous development of scientific technology, honeycomb The jointing material of cardboard also in continuous renewal and improves, and is extended the sodium silicate used unsuitable fast package always Need.Therefore, research and develop the adhesive that viscosity is high, binding speed is fast has for adapting to the reach of science, the competition in market Important meaning.
The content of the invention
Technical problems to be solved：It is an object of the invention to provide a kind of preparation method of quick-drying honeycomb cardboard adhesive, Prepared adhesive has very high gumminess, and peel strength is high, while rate of drying is fast, and drying time is short.
Technical scheme：A kind of preparation method of quick-drying honeycomb cardboard adhesive, comprises the following steps：
（1）Beta-schardinger dextrin 5-10g, pullulan 2-5g and distilled water 50-80ml are mixed, are heated to 70-80 DEG C of stirring 5-10 Minute；
（2）It is down to room temperature, adds Sodium Polyacrylate 5-10g, konjac oligosaccharides 1-3g, hydrogenated rosin glyceride 2-5ml and anhydrous Ethanol 5-10ml, 2-5 minutes are stirred under rotating speed 500-700r/min；
（3）Add potassium sorbate 0.5-1g, AESA 1-3g, sorbitol anhydride monopalmitate 1-2g, Filler 1-3g, oxalic acid 0.8-1g and glycerine 5-8ml, ultrasonic shear 5-10 minutes；
（4）Vacuum outgas removes bubble and produced.
It is further preferred that the filler is one or both of precipitated calcium carbonate and talcum powder.
It is further preferred that the molecular weight of the konjac oligosaccharides is 80 ~ 1,500,000.
It is further preferred that step（1）In be heated to 75 DEG C, mixing time is 7-9 minutes.
It is further preferred that step（2）Middle rotating speed is 550-650r/min, and mixing time is 3-4 minutes.
It is further preferred that step（3）The middle ultrasonic shear time is 7-9 minutes.
Beneficial effect：A kind of preparation method of quick-drying honeycomb cardboard adhesive of the present invention, prepared adhesive have Very high gumminess, viscosity reach as high as 22.7mPas, initial bonding strength 95%, and peel strength is most 15.60 by forceN/ 25mm, together When rate of drying it is fast, drying time is short, most drying time be 101 minutes.
Embodiment
Embodiment 1
A kind of preparation method of quick-drying honeycomb cardboard adhesive, comprises the following steps：
（1）Beta-schardinger dextrin 5g, pullulan 2g and distilled water 50ml are mixed, 70 DEG C is heated to and stirs 5 minutes；
（2）Room temperature is down to, adds Sodium Polyacrylate 5g, konjac oligosaccharides 1g, hydrogenated rosin glyceride 2ml and absolute ethyl alcohol 5ml, stirred 2 minutes under rotating speed 500r/min；
（3）Add potassium sorbate 0.5g, AESA 1g, sorbitol anhydride monopalmitate 1g, lightweight carbon Sour calcium 1g, oxalic acid 0.8g and glycerine 5ml, ultrasonic shear 5 minutes；
（4）Vacuum outgas removes bubble and produced.
Embodiment 2
A kind of preparation method of quick-drying honeycomb cardboard adhesive, comprises the following steps：
（1）Beta-schardinger dextrin 6g, pullulan 3g and distilled water 60ml are mixed, 75 DEG C is heated to and stirs 6 minutes；
（2）Room temperature is down to, adds Sodium Polyacrylate 6g, konjac oligosaccharides 2g, hydrogenated rosin glyceride 3ml and absolute ethyl alcohol 6ml, stirred 3 minutes under rotating speed 550r/min；
（3）Add potassium sorbate 0.6g, AESA 1.5g, sorbitol anhydride monopalmitate 1.5g, light Talcum powder 1.5g, oxalic acid 0.85g and glycerine 6ml, ultrasonic shear 6 minutes；
（4）Vacuum outgas removes bubble and produced.
Embodiment 3
A kind of preparation method of quick-drying honeycomb cardboard adhesive, comprises the following steps：
（1）Beta-schardinger dextrin 7.5g, pullulan 3.5g and distilled water 65ml are mixed, 75 DEG C is heated to and stirs 7 minutes；
（2）Room temperature is down to, adds Sodium Polyacrylate 7.5g, konjac oligosaccharides 2g, hydrogenated rosin glyceride 3.5ml and anhydrous second Alcohol 7.5ml, stirred 3 minutes under rotating speed 600r/min；
（3）Add potassium sorbate 0.75g, AESA 2g, sorbitol anhydride monopalmitate 1.5g, light Matter calcium carbonate 1g, talcum powder 1g, oxalic acid 0.9g and glycerine 6.5ml, ultrasonic shear 7 minutes；
（4）Vacuum outgas removes bubble and produced.
Embodiment 4
A kind of preparation method of quick-drying honeycomb cardboard adhesive, comprises the following steps：
（1）Beta-schardinger dextrin 9g, pullulan 4g and distilled water 70ml are mixed, 75 DEG C is heated to and stirs 9 minutes；
（2）Room temperature is down to, adds Sodium Polyacrylate 9g, konjac oligosaccharides 2.5g, hydrogenated rosin glyceride 4ml and absolute ethyl alcohol 9ml, stirred 4 minutes under rotating speed 650r/min；
（3）Add potassium sorbate 0.9g, AESA 2.5g, sorbitol anhydride monopalmitate 1.5g, light Matter calcium carbonate 2.5g, oxalic acid 0.95g and glycerine 7ml, ultrasonic shear 9 minutes；
（4）Vacuum outgas removes bubble and produced.
Embodiment 5
A kind of preparation method of quick-drying honeycomb cardboard adhesive, comprises the following steps：
（1）Beta-schardinger dextrin 10g, pullulan 5g and distilled water 80ml are mixed, 80 DEG C is heated to and stirs 10 minutes；
（2）Room temperature is down to, adds Sodium Polyacrylate 10g, konjac oligosaccharides 3g, hydrogenated rosin glyceride 5ml and absolute ethyl alcohol 10ml, stirred 5 minutes under rotating speed 700r/min；
（3）Add potassium sorbate 1g, AESA 3g, sorbitol anhydride monopalmitate 2g, talcum powder 3g, oxalic acid 1g and glycerine 8ml, ultrasonic shear 10 minutes；
（4）Vacuum outgas removes bubble and produced.
Comparative example 1
A kind of preparation method of quick-drying honeycomb cardboard adhesive, comprises the following steps：
（1）Beta-schardinger dextrin 5g and distilled water 50ml is mixed, 70 DEG C is heated to and stirs 5 minutes；
（2）Room temperature is down to, Sodium Polyacrylate 5g, hydrogenated rosin glyceride 2ml and absolute ethyl alcohol 5ml are added, in rotating speed 500r/ Stirred 2 minutes under min；
（3）Add potassium sorbate 0.5g, AESA 1g, sorbitol anhydride monopalmitate 1g, lightweight carbon Sour calcium 1g, oxalic acid 0.8g and glycerine 5ml, ultrasonic shear 5 minutes；
（4）Vacuum outgas removes bubble and produced.
Comparative example 2
A kind of preparation method of quick-drying honeycomb cardboard adhesive, comprises the following steps：
（1）Beta-schardinger dextrin 5g, pullulan 2g and distilled water 50ml are mixed, 70 DEG C is heated to and stirs 5 minutes；
（2）Room temperature is down to, adds Sodium Polyacrylate 5g, konjac oligosaccharides 1g, hydrogenated rosin glyceride 2ml and absolute ethyl alcohol 5ml, stirred 2 minutes under rotating speed 500r/min；
（3）Add potassium sorbate 0.5g, precipitated calcium carbonate 1g, oxalic acid 0.8g and glycerine 5ml, ultrasonic shear 5 minutes；
（4）Vacuum outgas removes bubble and produced.
Viscosity is measured with reference to national standard GB/T14074-2006 standards.
The measure of initial bonding strength is measured using national standard GB-T2794 standards.
Peel strength is measured using GB/T 7122-1996 standards, and disbonded test is carried out with liquid crystal electron testing machine.
The embodiment of invention adhesives and the partial properties index of comparative example see the table below, it will be seen that of the invention With very high gumminess, viscosity reaches as high as 22.7mPas, initial bonding strength 95%, and peel strength is most 15.60 by forceN/ 25mm, while rate of drying is fast, drying time is short, and most drying time is 101 minutes.
The partial properties index of the combined corrugated board adhesive of table 1
Viscosity（mPa·s） Initial bonding strength（%） Peel strength（N/25mm） Drying time（min）
Embodiment 1 22.4 95 15.37 105
Embodiment 2 22.6 95 15.43 103
Embodiment 3 22.7 95 15.54 101
Embodiment 4 22.7 95 15.60 101
Embodiment 5 22.5 95 15.55 103
Comparative example 1 20.7 93 13.19 107
Comparative example 2 21.2 93 13.67 105

Claims (6)

1. a kind of preparation method of quick-drying honeycomb cardboard adhesive, it is characterised in that comprise the following steps：
（1）Beta-schardinger dextrin 5-10g, pullulan 2-5g and distilled water 50-80ml are mixed, are heated to 70-80 DEG C of stirring 5-10 Minute；
（2）It is down to room temperature, adds Sodium Polyacrylate 5-10g, konjac oligosaccharides 1-3g, hydrogenated rosin glyceride 2-5ml and anhydrous Ethanol 5-10ml, 2-5 minutes are stirred under rotating speed 500-700r/min；
（3）Add potassium sorbate 0.5-1g, AESA 1-3g, sorbitol anhydride monopalmitate 1-2g, Filler 1-3g, oxalic acid 0.8-1g and glycerine 5-8ml, ultrasonic shear 5-10 minutes；
（4）Vacuum outgas removes bubble and produced.
A kind of 2. preparation method of quick-drying honeycomb cardboard adhesive according to claim 1, it is characterised in that：The filler For one or both of precipitated calcium carbonate and talcum powder.
A kind of 3. preparation method of quick-drying honeycomb cardboard adhesive according to claim 1, it is characterised in that：The konjaku The molecular weight of oligosaccharide is 80 ~ 1,500,000.
A kind of 4. preparation method of quick-drying honeycomb cardboard adhesive according to claim 1, it is characterised in that：The step （1）In be heated to 75 DEG C, mixing time is 7-9 minutes.
A kind of 5. preparation method of quick-drying honeycomb cardboard adhesive according to claim 1, it is characterised in that：The step （2）Middle rotating speed is 550-650r/min, and mixing time is 3-4 minutes.
A kind of 6. preparation method of quick-drying honeycomb cardboard adhesive according to claim 1, it is characterised in that：The step （3）The middle ultrasonic shear time is 7-9 minutes.
CN201711187701.0A 2017-11-24 2017-11-24 A kind of preparation method of quick-drying honeycomb cardboard adhesive Pending CN107880813A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711187701.0A CN107880813A (en) 2017-11-24 2017-11-24 A kind of preparation method of quick-drying honeycomb cardboard adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711187701.0A CN107880813A (en) 2017-11-24 2017-11-24 A kind of preparation method of quick-drying honeycomb cardboard adhesive

Publications (1)

Publication Number Publication Date
CN107880813A true CN107880813A (en) 2018-04-06

Family

ID=61774997

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711187701.0A Pending CN107880813A (en) 2017-11-24 2017-11-24 A kind of preparation method of quick-drying honeycomb cardboard adhesive

Country Status (1)

Country Link
CN (1) CN107880813A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10212899A1 (en) * 2002-03-23 2003-10-02 Tesa Ag Production of polyacrylate adhesive material for use on adhesive tape involves emulsion or dispersion polymerisation of acrylate monomers in presence of a cyclodextrin, preferably methylated beta-cyclodextrin
CN103074007A (en) * 2012-12-27 2013-05-01 上海交通大学 Water-based adhesive used in silicon anode of lithium ion battery and preparation method of silicon anode
JP2017036394A (en) * 2015-08-10 2017-02-16 リンテック株式会社 Adhesive composition, adhesive, adhesive sheet and display body
CN106867425A (en) * 2017-03-01 2017-06-20 福建农林大学 A kind of seamless reusable new Year scroll glue of konjaku glucomannan and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10212899A1 (en) * 2002-03-23 2003-10-02 Tesa Ag Production of polyacrylate adhesive material for use on adhesive tape involves emulsion or dispersion polymerisation of acrylate monomers in presence of a cyclodextrin, preferably methylated beta-cyclodextrin
CN103074007A (en) * 2012-12-27 2013-05-01 上海交通大学 Water-based adhesive used in silicon anode of lithium ion battery and preparation method of silicon anode
JP2017036394A (en) * 2015-08-10 2017-02-16 リンテック株式会社 Adhesive composition, adhesive, adhesive sheet and display body
CN106867425A (en) * 2017-03-01 2017-06-20 福建农林大学 A kind of seamless reusable new Year scroll glue of konjaku glucomannan and preparation method thereof

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
张玉龙等: "《淀粉胶黏剂》", 30 June 2003, 化学工业出版社 *
方亮等: "《全国高等医药院校药学类第四轮规划教材 药剂学 第3版》", 31 March 2016, 中国医药科技出版社 *
李津明主编: "《现代制药技术》", 30 April 2005, 中国医药科技出版社 *
郑水林等编著: "《非金属矿加工技术与设备》", 30 June 1998, 中国建材工业出版社 *

Similar Documents

Publication Publication Date Title
CN100482761C (en) Single-component room-temperature fast sulfidization dealcoholization type sealing rubber with silicone structure and preparing method thereof
CN101864259B (en) SIS (Styrene-Isoprene-Styrene) hot melt adhesive for car light adhesion and preparation method thereof
CN102199409B (en) Composite paper board binding agent and preparation method thereof
CN104962219A (en) Water-based zero-formaldehyde adhesive for plywoods
CN107841261A (en) A kind of environment-protective adhesive
CN101020806A (en) Fast drying paper product adhesive with high strength and low cost and its prepn
CN107033801A (en) A kind of fire-retardant heat-sensitive variable colour adhesive tape
CN102993988A (en) Adhesive with strong adhering property
CN107880813A (en) A kind of preparation method of quick-drying honeycomb cardboard adhesive
CN105255388A (en) Glue
CN103102827A (en) Starch binder
CN103666323A (en) Paperboard adhesive with high water resistance
CN106753065A (en) A kind of quickstick MR adhesive and its preparation method for corrugated board temperature production
CN106245432B (en) A kind of environment-friendly type corrugated board starch enhancer and the preparation method and application thereof
US20100032092A1 (en) Zeolite starch adhesive for corrugated cardboards and method for making the same
CN104893208A (en) Full-degradable plastic film with good freezing resistance and toughness and production method thereof
CN107805484A (en) A kind of preparation method of wood materials starch adhesive
CN107828356A (en) A kind of wood furniture starch adhesive
CN101979452B (en) Method for preparing waterproof adhesive for corrugated paper production
CN104263280A (en) Adhesive for binding paper products and preparation method thereof
CN113831861A (en) Environment-friendly sealing adhesive and preparation method thereof
CN106590527A (en) Multifunctional environmentally friendly adhesive and preparation method thereof
CN102796468A (en) High-elastic-modulus and high-waterproof composite resin bonding agent
CN103694932B (en) Modified soybean-based emulsion adhesive and preparation method thereof
CN108059923A (en) A kind of modified silicone insulating glass sealant and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180406