CN106867425A - A kind of seamless reusable new Year scroll glue of konjaku glucomannan and preparation method thereof - Google Patents
A kind of seamless reusable new Year scroll glue of konjaku glucomannan and preparation method thereof Download PDFInfo
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- CN106867425A CN106867425A CN201710115502.2A CN201710115502A CN106867425A CN 106867425 A CN106867425 A CN 106867425A CN 201710115502 A CN201710115502 A CN 201710115502A CN 106867425 A CN106867425 A CN 106867425A
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- konjaku glucomannan
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- colloid
- new year
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J105/00—Adhesives based on polysaccharides or on their derivatives, not provided for in groups C09J101/00 or C09J103/00
- C09J105/02—Dextran; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J105/00—Adhesives based on polysaccharides or on their derivatives, not provided for in groups C09J101/00 or C09J103/00
- C09J105/04—Alginic acid; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Jellies, Jams, And Syrups (AREA)
Abstract
The present invention relates to seamless reusable new Year scroll glue of a kind of konjaku glucomannan and preparation method thereof.A kind of preparation method of the seamless reusable new Year scroll glue of konjaku glucomannan, including it is the preparation of sodium alginate colloid, the preparation of konjaku glucomannan colloid, the preparation of composite colloid, vacuum outgas, filling.The present invention is with konjaku glucomannan, sodium alginate as main material, konjaku glucomannan, sodium alginate are the extremely low natural polysaccharides of two kinds of costs, its viscosity can change with the change of pH value after the two compounds crosslinking under conditions of special, based on this principle, viscosity is developed to can control, glue is easily removed, and recyclable recycling the seamless reusable new Year scroll glue of konjaku glucomannan.The present invention has the advantages that preparation process is simple, with low cost, permanent tack, clears up simplicity, recoverable, free from environmental pollution.In average family life, using extremely convenient.
Description
Technical field is the present invention relates to a kind of glue and preparation method thereof, and in particular to a kind of konjaku glucomannan is seamless
Reusable new Year scroll glue and preparation method thereof.
Background technology
Patch new Year scroll are the excellent traditional customs of China, same day New Year's Eve, and every household all can be on door, the work such as wall or automobile
New Year scroll are pasted on tool, is an extremely celebrating and significant thing.But while being accompanied by celebrating, exist because of patch new Year scroll
The variety of problems of initiation, such as timber paint are scraped, and luxury car outward appearance is destroyed, and because the removal of old new Year scroll is clean etc., bring a variety of
Problem in terms of folk custom, these reasons come from the adhesive tape or glue used by patch new Year scroll after all.At present, patch new Year scroll are usually used
Common glue or one side adhesive tape, glue are adhered on door or can tightly be adsorbed in body surface after being solidified on wall and is difficult to clear up,
And old new Year scroll will not also be taken off completely；During new New year scrolls pasting, adhesive tape has viscous insecure again, easily comes off etc. and to lack
Point.New Year scroll are usually to change once for 1 year, and tape-stripping new Year scroll are insecure, need to regularly replace glue using tape-stripping new Year scroll
Band, it is unsightly also extremely not convenient.Common glue, adhesive tape etc. are all disposable products, not reproducible to use, and cause to waste, its
In plastic or other material can also cause environmental problem.
The patent " back side glue-lines of new Year scroll " of Application No. 201310259600.5（Shen:2013.06.16）, invention
A kind of back side by new Year scroll applies last layer viscose glue water, and being then made of the method for covered rearing with plastic film directly to paste in wall
On new Year scroll, only need to the plastic sheeting at the back side to take off when using, it is possible to be adhered directly on wall, not only facilitate but also firmly, than
Adhesive tape is attractive in appearance.But, one layer of glue-line is covered at the new Year scroll back side, paste difficulty greatly, new Year scroll patch out-of-flatness is easily caused, paste askew
After be difficult to tear re-posted the problems such as.And be difficult to tear completely when removing, wall easy to stick, it is difficult to clear up, and gluing area is big, cost
Height, causes to waste.
A kind of patent " new Year scroll " of Application No. 201520172506.0（The applying date：2015.03.25）, disclose one kind
Main glue-line is coated on the edge of paper layer reverse side, then one layer of new Year scroll of release film layer covered after main glue-line, using it is simple,
It is easy to operate, and paste smooth, firm, raw material is saved, but, currently the majority rural area new Year scroll non-printing system for hand-written new Year scroll
Product, the method for attached glue is difficult to promote after new Year scroll are printed, cannot also solve after new Year scroll are torn it is gluing be difficult to tear on the wall ask
Topic.
The content of the invention it is an object of the invention to provide a kind of seamless reusable new Year scroll glue of konjaku glucomannan and its
Preparation method, the present invention is with konjaku glucomannan, sodium alginate both natural polysaccharides as primary raw material is prepared from.This hair
It is bright to solve New year scrolls pasting loosely the drawbacks of broken traditional new Year scroll glue, it is difficult to remove after patch, Chen Bengao, glue can not be again
Use again, after patch effect unsightly the problems such as.
A kind of preparation method of the seamless reusable new Year scroll glue of konjaku glucomannan of the invention, it is characterised in that system
Standby step is as follows：
（1）The preparation of sodium alginate colloid：Under 50~60 DEG C of condition of water bath heating, mass parts are taken for 98~100 parts of distilled water
It is placed in mixer, adds 1~1.3 part of sodium alginate, 0.1~0.2 part of calcium chloride, 300r/min to stir 40~60min, obtain
It is standby to sodium alginate colloid；
（2）The preparation of konjaku glucomannan colloid：1~1.3 part of konjaku glucomannan is taken, in 98~100 parts of distilled water, 50
Under~60 DEG C of condition of water bath heating, 400~500r/min stirs 30~40min, obtains konjaku glucomannan colloid, standby；
（3）The preparation of composite colloid：By step（1）Sodium alginate colloid, the konjaku glucomannan colloid obtained by step (2),
It is placed in thermostat water bath, 2~3h is stirred with 500r/min under the conditions of 50~60 DEG C, obtains composite colloid；
（4）It is vacuum outgas, filling：By step（3）Composite colloid be placed in 60 DEG C of vacuum drying chamber be de-gassed treatment 5~
10min, it is then filling, the seamless reusable new Year scroll glue of konjaku glucomannan is obtained.
The present invention has advantages below：The present invention with konjaku glucomannan, sodium alginate as main material, konjak portuguese gansu polyose
Sugar, sodium alginate are the extremely low natural polysaccharides of two kinds of costs, and the two compounds after crosslinking its viscosity under conditions of special can be with
The change of pH value and change, based on this principle, develop viscosity can control, glue is easily removed, and recyclable recycling evil spirit
The seamless reusable new Year scroll glue of taro Glucomannan.Konjaku glucomannan is stable in properties, is not susceptible to change, as adhesive
Can be with Reusability, it is to avoid waste, cannot be corrected after patch mistake or patch are askew when solving the problems, such as patch new Year scroll.When clearing up old new Year scroll,
A small amount of vinegar only need to be picked with cleaning cloth, you can eliminated, reach seamless effect.Konjaku glucomannan of the invention is seamless
The safety and reliability of reusable new Year scroll glue complies fully with relative national standards requirement, compared with commercially available common glue
Compared with there is preparation process is simple, with low cost, permanent tack, cleaning simplicity, recoverable, free from environmental pollution.General
In logical family life, using extremely convenient.
The seamless reusable new Year scroll glue of konjaku glucomannan of the invention is with commercially available office cement ratio compared with as a result such as table
Shown in 1.
The seamless reusable new Year scroll glue of the konjaku glucomannan of table 1 with it is commercially available office glue comparing
Specific embodiment
In order to fully disclose seamless reusable new Year scroll glue of konjaku glucomannan of the invention and preparation method thereof, tie below
Embodiment is closed to be illustrated.
A kind of preparation method of the seamless reusable new Year scroll glue of embodiment 1, konjaku glucomannan, including following step
Suddenly：
（1）The preparation of sodium alginate colloid：Under 55 DEG C of condition of water bath heating, mass parts are taken for 99 parts of distilled water are placed in mixer
In, 1.2 parts of sodium alginate, 0.15 part of calcium chloride is added, 300r/min stirring 50min obtain sodium alginate colloid, standby；
（2）The preparation of konjaku glucomannan colloid：1.2 parts of konjaku glucomannan is taken, in 99 parts of distilled water, is added in 55 DEG C of water-baths
Under heat condition, 450r/min stirs 35min, obtains konjaku glucomannan colloid, standby；
（3）The preparation of composite colloid：By step（1）Sodium alginate colloid, the konjaku glucomannan colloid obtained by step (2),
It is placed in thermostat water bath, 2h is stirred with 500r/min under the conditions of 55 DEG C, obtains composite colloid；
（4）It is vacuum outgas, filling：By step（3）Composite colloid be placed in treatment be de-gassed in 60 DEG C of vacuum drying chamber
8min, it is then filling, the seamless reusable new Year scroll glue of konjaku glucomannan is obtained.
A kind of preparation method of the seamless reusable new Year scroll glue of embodiment 2, konjaku glucomannan, including following step
Suddenly：
（1）The preparation of sodium alginate colloid：Weigh the sodium alginate that mass parts are 1 part, 0.1 part of calcium chloride, 98 parts of distilled water,
Under 50 DEG C of condition of water bath heating, distilled water is placed in mixer, opens mixer to 300r/min, add the marine alga for weighing
Sour sodium and calcium chloride, sodium alginate colloid is obtained after stirring 40min, standby；
（2）The preparation of konjaku glucomannan colloid：Take 1 part of konjaku glucomannan, 98 parts of distilled water.In 50 DEG C of condition of water bath heating
Under, distilled water is placed in mixer, mixer is opened to 400r/min, the konjaku glucomannan of weighing is slowly added into, stir
Konjaku glucomannan colloid is obtained after 30min, it is standby；
（3）The preparation of composite colloid：By step（1）, the colloid obtained by step (2) be placed in thermostat water bath, in 50 DEG C of conditions
Under with 500r/min stir 2h, obtain composite colloid；
（4）Vacuum outgas：By step（3）Composite colloid be placed in 60 DEG C of vacuum drying chamber be de-gassed treatment 5min；
（5）It is quantitative canned：By step（4）Compound adhesive after vacuum outgas add carry out in Full-automatic quantitative bottle placer it is filling, often
Bottle glue content is 50 ± 2mL, is sealed；
（6）Detection, packaging：By step（5）The seamless reusable new Year scroll glue of konjaku glucomannan it is labelled, check be
It is no to have the problems such as gas leakage, balsam bottle breakage, as packaging, finished product.
A kind of preparation method of the seamless reusable new Year scroll glue of embodiment 3, konjaku glucomannan
1）The preparation of sodium alginate colloid：Weigh the sodium alginate that mass parts are 1.3 parts, 0.2 part of calcium chloride, 100 parts of distilled water.
Under 60 DEG C of condition of water bath heating, distilled water is placed in mixer, opens mixer to 300r/min, add the marine alga for weighing
Sour sodium and calcium chloride, sodium alginate colloid is obtained after stirring 60min, standby；
（2）The preparation of konjaku glucomannan colloid：Take 1.3 parts of konjaku glucomannan, 100 parts of distilled water.In 60 DEG C of heating water baths
Under the conditions of, distilled water is placed in mixer, mixer is opened to 400r/min, the konjaku glucomannan of weighing is slowly added into,
Konjaku glucomannan colloid is obtained after stirring 40min, it is standby；
（3）The preparation of composite colloid：By step（1）, the colloid obtained by step (2) be placed in thermostat water bath, in 60 DEG C of conditions
Under with 500r/min stir 3h, obtain composite colloid；
（4）It is vacuum outgas, filling：By step（3）Composite colloid be placed in treatment be de-gassed in 60 DEG C of vacuum drying chamber
10min, it is then filling, the seamless reusable new Year scroll glue of konjaku glucomannan is obtained.
The foregoing is only presently preferred embodiments of the present invention, all impartial changes done according to scope of the present invention patent with
Modification, should all belong to covering scope of the invention.
Claims (4)
1. the preparation method of the seamless reusable new Year scroll glue of a kind of konjaku glucomannan, it is characterised in that preparation process is such as
Under：
（1）The preparation of sodium alginate colloid：Under 50~60 DEG C of condition of water bath heating, mass parts are taken for 98~100 parts of distilled water
It is placed in mixer, adds 1~1.3 part of sodium alginate, 0.1~0.2 part of calcium chloride, 300r/min to stir 40~60min, obtain
It is standby to sodium alginate colloid；
（2）The preparation of konjaku glucomannan colloid：1~1.3 part of konjaku glucomannan is taken, in 98~100 parts of distilled water, 50
Under~60 DEG C of condition of water bath heating, 400~500r/min stirs 30~40min, obtains konjaku glucomannan colloid, standby；
（3）The preparation of composite colloid：By step（1）Sodium alginate colloid, the konjaku glucomannan colloid obtained by step (2),
It is placed in thermostat water bath, 2~3h is stirred with 500r/min under the conditions of 50~60 DEG C, obtains composite colloid；
（4）Vacuum outgas：By step（3）Composite colloid be placed in 60 DEG C of vacuum drying chamber be de-gassed treatment 5~
10min, it is then filling, the seamless reusable new Year scroll glue of konjaku glucomannan is obtained.
2. the preparation method of the seamless reusable new Year scroll glue of a kind of konjaku glucomannan according to claim 1, its
It is characterised by the preparation of the sodium alginate colloid：Under 55 DEG C of condition of water bath heating, mass parts are taken for 99 parts of distilled water are placed in
In mixer, 1.2 parts of sodium alginate, 0.15 part of calcium chloride, 300r/min stirring 50min is added to obtain sodium alginate colloid.
3. the preparation method of the seamless reusable new Year scroll glue of a kind of konjaku glucomannan according to claim 1, its
It is characterised by the preparation of the konjaku glucomannan colloid：1.2 parts of konjaku glucomannan is taken, in 99 parts of distilled water, at 55 DEG C
Under condition of water bath heating, 450r/min stirs 35min, obtains konjaku glucomannan colloid.
4. the seamless reusable new Year scroll glue of konjaku glucomannan that prepared by the either method as described in claim 1-3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710115502.2A CN106867425B (en) | 2017-03-01 | 2017-03-01 | A kind of seamless reusable new Year scroll glue of konjaku glucomannan and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710115502.2A CN106867425B (en) | 2017-03-01 | 2017-03-01 | A kind of seamless reusable new Year scroll glue of konjaku glucomannan and preparation method thereof |
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| CN106867425A true CN106867425A (en) | 2017-06-20 |
| CN106867425B CN106867425B (en) | 2018-09-18 |
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| CN201710115502.2A Expired - Fee Related CN106867425B (en) | 2017-03-01 | 2017-03-01 | A kind of seamless reusable new Year scroll glue of konjaku glucomannan and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880813A (en) * | 2017-11-24 | 2018-04-06 | 苏州甫众塑胶有限公司 | A kind of preparation method of quick-drying honeycomb cardboard adhesive |
| CN109439275A (en) * | 2018-09-03 | 2019-03-08 | 捷成实业（深圳）有限公司 | A kind of environmental protection fruit juice gel and preparation method thereof |
| CN115624179A (en) * | 2022-10-18 | 2023-01-20 | 陕西科技大学 | Acid-resistant ROS-scavenging microgel, preparation method thereof and application thereof in carrier |
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| CN101284974A (en) * | 2008-05-30 | 2008-10-15 | 福建农林大学 | Konjak polysaccharide adhesive |
| CN101654602A (en) * | 2009-09-01 | 2010-02-24 | 梁跃飞 | Method for preparing hydrated adhesive |
| CN105885725A (en) * | 2016-04-18 | 2016-08-24 | 文登蓝岛建筑工程有限公司 | Preparation method of konjac starch glue for wallpaper |
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2017
- 2017-03-01 CN CN201710115502.2A patent/CN106867425B/en not_active Expired - Fee Related
Patent Citations (3)
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| CN101284974A (en) * | 2008-05-30 | 2008-10-15 | 福建农林大学 | Konjak polysaccharide adhesive |
| CN101654602A (en) * | 2009-09-01 | 2010-02-24 | 梁跃飞 | Method for preparing hydrated adhesive |
| CN105885725A (en) * | 2016-04-18 | 2016-08-24 | 文登蓝岛建筑工程有限公司 | Preparation method of konjac starch glue for wallpaper |
Non-Patent Citations (1)
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880813A (en) * | 2017-11-24 | 2018-04-06 | 苏州甫众塑胶有限公司 | A kind of preparation method of quick-drying honeycomb cardboard adhesive |
| CN109439275A (en) * | 2018-09-03 | 2019-03-08 | 捷成实业（深圳）有限公司 | A kind of environmental protection fruit juice gel and preparation method thereof |
| CN115624179A (en) * | 2022-10-18 | 2023-01-20 | 陕西科技大学 | Acid-resistant ROS-scavenging microgel, preparation method thereof and application thereof in carrier |
| CN115624179B (en) * | 2022-10-18 | 2023-10-27 | 陕西科技大学 | Acid-resistant and ROS-scavenging microgel, preparation and application in carrier |
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| CN106867425B (en) | 2018-09-18 |
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