CN101654602A - Method for preparing hydrated adhesive - Google Patents
Method for preparing hydrated adhesive Download PDFInfo
- Publication number
- CN101654602A CN101654602A CN200910013568A CN200910013568A CN101654602A CN 101654602 A CN101654602 A CN 101654602A CN 200910013568 A CN200910013568 A CN 200910013568A CN 200910013568 A CN200910013568 A CN 200910013568A CN 101654602 A CN101654602 A CN 101654602A
- Authority
- CN
- China
- Prior art keywords
- glue
- water
- soluble
- sodium
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Paper (AREA)
Abstract
The invention provides a method for preparing hydrated adhesive, which solves the problems of disposable usage, difficultly-controlled pasting position, difficult removal and the like in the traditional tackifier fundamentally. The technical key points of the invention are as follows: the hydrated adhesive is prepared by mixedly stirring the following raw materials by weight percent at normal temperature and pressure: 10%-35% of sodium alga acid (C6H7O8Na), 5%-30% of competed hydrate, 20%-50% of water-soluble adhesive and 5%-65% of water. The hydrated adhesive in the invention has the advantages of controllable viscosity, stable physicochemical property, environment protection, capability of repeated use, no residual and the like, and is suitable for caking of solid materials such as various paper, plastic and the like.
Description
Technical field
The present invention relates to the compound method of a kind of non-setting adhesive glue face and aqueous binders, particularly a kind of preparation method who is applicable to solid material agglutinating hydrated adhesives such as any papery, plastics.
Background technology
The main raw of tradition tackiness agent is natural (synthesizing) rubber and vinylformic acid, file an application in the Britain and the U.S. May 30 nineteen twenty-eight, De Lu has developed a kind of tamanori very light, that a pressure is promptly closed, invent scotch tape again through improving afterwards, promptly on tape surface, scribbled one deck tackiness agent.Tackiness agent the earliest comes from animal and plant, and 19th-century, rubber are the major ingredient of tackiness agent, and the modern times are the various polymkeric substance of widespread use then.Tackiness agent can cling thing, is that this bond can stick together molecule firmly owing to the intermolecular formation bond of molecule and the desire attachment of itself.And the composition of tackiness agent according to different labels, different sorts, comprises various polymkeric substance.Under the situation that person skilled is is constantly researched and developed and people require to improve constantly, BOPP (Biaxially oriented polypropylene film (BOPP)) adhesive tape arises at the historic moment as a kind of special adhesive carrier, and becomes indispensable articles for use in enterprise, company, the personal lifestyle.Country has only an industry standard " QB/T 2422-1998 joint sealing BOPP pressure-sensitive adhesive tape " to the adhesive tape industry perfect standard of none also.Generally, our adhesive tape used in everyday is to apply glue after making its surface irregularity after the high-voltage corona on the basis of the former film of BOPP, after be divided into rouleau through itemize.Adhesive tape glue is CALCIUM ACRYLATE glue, claims pressure sensitive adhesive again, and main component is a tincture fat.Tincture fat is the movable material of a kind of polymer, and the height of temperature has certain influence to molecule activity, the viscous force of remote effect adhesive tape.In addition, the content of tincture fat directly has influence on the service condition of adhesive tape in the glue.The initial bonding strength of normal tape is between 〉=No. 13 (steel ball number), and the thickness of this adhesive tape glue is generally 22 microns, conformance with standard thickness.This traditional tackiness agent is easy to use, but mostly is disposable use, in use often slips up, and paste position is difficult to control.Be subjected to work-ing life influence, can't continue after the untapped tackiness agent drying to use, and the tackiness agent after using externally paper material still be bonded at solid surface after damaging, be difficult to remove.
Application number is the sizing agent compound method that 89100519.6 Chinese patent has been introduced a kind of non-setting adhesive, is made by polystyrene, organic solvent, softening agent and auxiliary material.This glue is suitable for being used for paper one class article (as trade mark, label) are sticked on object surfaces such as glass, metal, wall.Because of this invention utilizes the depleted porous plastics as raw material, therefore not only with low cost, and eliminated public hazards.In addition, this glue is effective, can reuse acidproof, alkaline-resisting, anti-freezing.By regulating the weight percent of its preparing materials, can change the wet speed degree of doing of non-setting adhesive.Though this invention is reusable, but its glue face is a permanent adhesive, the degree of cleaning of glue face are subjected to very big challenge, foreign material such as dust easily are bonded at the normal use that has influenced non-setting adhesive on the glue face greatly, non-setting adhesive removes the preservation in following time and is not easy, and the glue face also weakens greatly along with the increase viscosity of access times.
Summary of the invention
The objective of the invention is in order to provide a kind of chemical physical property stable, the preparation method of repeatedly used hydrated adhesive, fundamentally solving the disposable use of traditional tackiness agent, paste position is difficult to control, removes problem such as difficulty, compare with existing reusable tackiness agent, have sticking face degree of cleaning height, preserve easily, reuse the still more strongly adherent advantage of maintenance.
Technical scheme of the present invention is: the preparation method of this hydrated adhesive, its technical essential is: mixed together at normal temperatures and pressures by following raw materials by weight percent: the competition hydrate of the sodium alginate of 10%-35% (C6H7O8Na) n, 5%-30%, the water-soluble glue of 20%-50%, the water of 5%-65%.
Described competition hydrate is sugar, starch or the salt that contains univalent cation, and described sugar is monose or disaccharides or polysaccharide, and described salt is sylvite or sodium salt.
Described water-soluble glue is white glue with vinyl or xanthan gum or gum rosin or polysaccharide viscose glue or water-soluble polysaccharide or Herba Cistanches polyose or water-soluble dry powder glue or caouttchouc or water soluble elastic waterproof polyvinyl chloride glue or grouting leak-stopping glue or saliva glue or gum arabic or peach gum.
Described sodium salt is sodium-chlor or sodium sulfate or SODIUMNITRATE or sodium hydroxide or yellow soda ash, and described sylvite is Repone K or vitriolate of tartar or saltpetre or potassium hydroxide or salt of wormwood.
Advantage of the present invention and positive technique effect are: compound method of the present invention is simple, selects meticulously only to need after the preparation raw material to mix by weight percentage at normal temperatures and pressures to stir, and waits for that mixture mixes can use fully.The present invention and traditional tackiness agent not to be both the characteristics that just produce viscosity when meeting water with sodium alginate serve as to prepare at all.Sodium alginate has another name called sodium alginate, seaweed gel, algin, alginate, is by the natural polysaccharide carbohydrate that extracts in the sea-tangle.It is widely used in products such as food, medicine, weaving, printing and dyeing, papermaking, daily-use chemical industry, as uses such as thickening material, emulsifying agent, stablizer, tackiness agent, sizing agents.The sodium alginate water-swellable is transparent jelly, and rate of expansion is bigger.Be characterized in soluble in water, and meet the water toughness.In addition, can reduce the water and the property of sodium alginate, slow down the sodium alginate hydration rate as the competition hydrate of constitutive material.And water-soluble glue has the chemical physical property of consolidating after the binding agent film forming, improves binding agent viscosity, reduces the effect of sodium alginate water-swellable rate.Water brings out the viscosity of sodium alginate as solvent of the present invention.More than after 4 kinds of raw materials mix, under the integrated bond of water-soluble glue, sodium alginate in conjunction with firmly, and has good viscosity in the competition hydrate.Make after glue face and the drying, sodium alginate is evenly distributed on the glue face, can produce good adhesive effect with water, under the effect of competition hydrate, the rate of expansion of sodium alginate and hydration rate is effectively reduced, and is unlikely to produce the situation of glue face collapse.
Hydrated adhesive among the present invention is a kind of novel binders, can be used for the manufacturing of non-setting adhesive, is formed by multiple compound, it is slightly soluble in water, meeting water generates viscosity, itself is solid, becomes the thickness jelly to can be used for purposes such as stickup, multiviscosisty, emulsification after the interpolation suitable quantity of water.Its advantage is: (1) viscosity free adjustment in controlled range; (2) material physical chemistry stable in properties own and environmental protection; (3) paste the back water and dab and can remove, body surface noresidue or residual few, and can remove fully with clear water; (4) the present invention is reusable, after the removing glue is dried, and get wet again when using and can produce viscosity immediately next time; When (5) use was of the present invention, glue was met water generates viscosity, and the surface is very lubricated, can be at the random slide control paste position of solid surface; (6) reaction such as, allergy non-stimulated to human body; (7) conveniently preserve and use, adhere to foreign matter such as dust as the glue face and can clean removing gently, can continue to use with clear water.
Embodiment
The applicant in the long-term practice process through to the comparison of traditional tackiness agent and constantly research, form a kind of have excellent adhering, practicality, stable physics-chem characteristic and the hydrated adhesive of environmental protection repeatedly through a large amount of experiment modulation, the preparation method of this hydrated adhesive specifically is to be mixed together at normal temperatures and pressures by following raw materials by weight percent: the competition hydrate of the sodium alginate of 10%-35% (C6H7O8Na) n, 5%-30%, the water-soluble glue of 20%-50%, 5% ~ 65% water.Wherein competing hydrate is sugar, starch or the salt that contains univalent cation etc., and sugar can be selected monose or disaccharides or polysaccharide etc., and salt can be selected sylvite or sodium salt etc.Sodium salt can be selected sodium-chlor or sodium sulfate or SODIUMNITRATE or sodium hydroxide or yellow soda ash etc.Sylvite can be selected Repone K or vitriolate of tartar or saltpetre or potassium hydroxide or salt of wormwood etc.And water-soluble glue is white glue with vinyl or the water-soluble tackiness agent classes of energy such as xanthan gum or gum rosin or polysaccharide viscose glue or water-soluble polysaccharide or Herba Cistanches polyose or water-soluble dry powder glue or caouttchouc or water soluble elastic waterproof polyvinyl chloride glue or grouting leak-stopping glue or saliva glue or gum arabic or peach gum.
Specific embodiment 1
Weight part is respectively 10 parts of sodium alginates (C6H7O8Na) n, 5 parts of competition hydrate-sodium-chlor, 20 parts of water-soluble glue-white glue with vinyl, 65 parts of water evenly mix at normal temperatures and pressures, then can be sprayed on and obtain the glue face on the self-adhesive paper.Because solutes content is low, what obtain that the glue face can make behind complete drying is ultra-thin, and the glue face is firm, and viscosity is relatively low, removes following time and is pasted solid surface and be difficult for residually, is applicable to the non-setting adhesive manufacturing of some special requirement.
Specific embodiment 2
Weight part is respectively 20 parts of sodium alginates (C6H7O8Na) n, 8 parts of competition hydrate-sodium-chlor, 35 parts of water-soluble glue-white glue with vinyl, 37 parts of water evenly mix at normal temperatures and pressures, then can be sprayed on and obtain the glue face on the self-adhesive paper.Binding agent is made after glue face and the complete drying, is fit to the production and the manufacturing of common non-setting adhesive, and chance water viscosity is higher, glue face oilness height.
Specific embodiment 3
Weight part is respectively 35 parts of sodium alginates (C6H7O8Na) n, 10 parts of competition hydrate-sodium-chlor, 50 parts of water-soluble glue-white glue with vinyl, 5 parts of water evenly mix at normal temperatures and pressures, are sprayed on and obtain the glue face on the self-adhesive paper.This binding agent viscosity is very high, and rate of expansion is also higher, is not suitable for making non-setting adhesive, can be used as special gelatin and uses.
Specific embodiment 4
Weight part is respectively 20 parts of sodium alginates (C6H7O8Na) n, 20 portions of competition hydrate-sugar, 35 parts of water-soluble glue-xanthan gum, 25 parts of water evenly mix at normal temperatures and pressures, its viscosity is prescription maximum in the hydrated adhesive, have quite high binding property, the pliability of glue face, slickness are very desirable, long perfomance life.
Can in raw material, choose suitable competition hydrate in the above example wantonly and mix, in scope that chemical physics changes does not take place mutually raw material itself, not carry out proportioning, its proportioning effect basically identical with water-soluble glue.Material choice of the present invention is very extensive, and buys easily on market, and cost is lower, so the not only concrete practical value of the present invention also has considerable economic worth.
Claims (4)
1, a kind of preparation method of hydrated adhesive is characterized in that: mixed together at normal temperatures and pressures by following raw materials by weight percent: the competition hydrate of the sodium alginate of 10%-35% (C6H7O8Na) n, 5%-30%, the water-soluble glue of 20%-50%, the water of 5%-65%.
2, the preparation method of a kind of hydrated adhesive according to claim 1 is characterized in that: described competition hydrate is sugar, starch or the salt that contains univalent cation, and described sugar is monose or disaccharides or polysaccharide, and described salt is sylvite or sodium salt.
3, the preparation method of a kind of hydrated adhesive according to claim 1 is characterized in that: described water-soluble glue is white glue with vinyl or xanthan gum or gum rosin or polysaccharide viscose glue or water-soluble polysaccharide or Herba Cistanches polyose or water-soluble dry powder glue or caouttchouc or water soluble elastic waterproof polyvinyl chloride glue or grouting leak-stopping glue or saliva glue or gum arabic or peach gum.
4, the preparation method of a kind of hydrated adhesive according to claim 2 is characterized in that: described sodium salt is sodium-chlor or sodium sulfate or SODIUMNITRATE or sodium hydroxide or yellow soda ash, and described sylvite is Repone K or vitriolate of tartar or saltpetre or potassium hydroxide or salt of wormwood.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910013568A CN101654602A (en) | 2009-09-01 | 2009-09-01 | Method for preparing hydrated adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910013568A CN101654602A (en) | 2009-09-01 | 2009-09-01 | Method for preparing hydrated adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101654602A true CN101654602A (en) | 2010-02-24 |
Family
ID=41709063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910013568A Pending CN101654602A (en) | 2009-09-01 | 2009-09-01 | Method for preparing hydrated adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101654602A (en) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589370A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Application of non-toxic and odourless laminating adhesive |
| CN103589371A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Laminating adhesive containing arabic gum |
| CN103589373A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Laminating adhesive with sodium polyacrylate |
| CN103589368A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Application of laminating adhesive with sodium polyacrylate |
| CN103589372A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Laminating adhesive |
| CN103589369A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Application of laminating adhesive containing arabic gum |
| CN103602282A (en) * | 2013-11-18 | 2014-02-26 | 太仓港亨得蕾实业有限公司 | Application of complex film adhesive |
| CN103602283A (en) * | 2013-11-18 | 2014-02-26 | 太仓港亨得蕾实业有限公司 | Non-toxic smellless complex film adhesive |
| CN104204125A (en) * | 2011-11-28 | 2014-12-10 | 赵波新 | Method and apparatus for adhesive bonding in an aqueous medium |
| CN104877591A (en) * | 2015-05-08 | 2015-09-02 | 南通启秀门窗有限公司 | Metal door |
| CN104946164A (en) * | 2015-05-08 | 2015-09-30 | 南通启秀门窗有限公司 | Metal window |
| CN106317279A (en) * | 2016-08-25 | 2017-01-11 | 董晓 | Method for preparing weather-proof tough white emulsion |
| CN106867425A (en) * | 2017-03-01 | 2017-06-20 | 福建农林大学 | A kind of seamless reusable new Year scroll glue of konjaku glucomannan and preparation method thereof |
| CN107784923A (en) * | 2017-11-02 | 2018-03-09 | 广东天元实业集团股份有限公司 | Label and preparation method thereof |
| CN108797161A (en) * | 2017-05-03 | 2018-11-13 | 海安润德服装有限公司 | A kind of natural printing thickening agent |
| CN109385227A (en) * | 2018-09-17 | 2019-02-26 | 陈茂河 | A kind of water opens up glue of bootstrapping, glue film and its preparation method and application |
| CN109852279A (en) * | 2018-12-27 | 2019-06-07 | 绍兴明基新材料有限公司 | Vegetable and fruit binding plant base adhesive tape and preparation method thereof |
| CN110172106A (en) * | 2019-06-11 | 2019-08-27 | 深圳保时健生物工程有限公司 | A kind of peach gum polysaccharide iron and its application |
| CN110827661A (en) * | 2019-11-16 | 2020-02-21 | 湖北劲佳包装有限公司 | Fragile label |
| CN110982446A (en) * | 2019-12-18 | 2020-04-10 | 江门新时代胶粘科技有限公司 | Water-soluble adhesive tape and preparation method and application thereof |
| CN114507482A (en) * | 2021-12-31 | 2022-05-17 | 苏州工业园区莱博特瑞新材料科技有限公司 | Label for automobile bumper and production process thereof |
-
2009
- 2009-09-01 CN CN200910013568A patent/CN101654602A/en active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104204125B (en) * | 2011-11-28 | 2019-02-19 | 赵波新 | The method and apparatus combined in an aqueous medium for adhesive |
| CN104204125A (en) * | 2011-11-28 | 2014-12-10 | 赵波新 | Method and apparatus for adhesive bonding in an aqueous medium |
| CN103602282A (en) * | 2013-11-18 | 2014-02-26 | 太仓港亨得蕾实业有限公司 | Application of complex film adhesive |
| CN103589368A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Application of laminating adhesive with sodium polyacrylate |
| CN103589372A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Laminating adhesive |
| CN103589369A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Application of laminating adhesive containing arabic gum |
| CN103589373A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Laminating adhesive with sodium polyacrylate |
| CN103602283A (en) * | 2013-11-18 | 2014-02-26 | 太仓港亨得蕾实业有限公司 | Non-toxic smellless complex film adhesive |
| CN103589371A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Laminating adhesive containing arabic gum |
| CN103589370A (en) * | 2013-11-18 | 2014-02-19 | 太仓港亨得蕾实业有限公司 | Application of non-toxic and odourless laminating adhesive |
| CN104877591A (en) * | 2015-05-08 | 2015-09-02 | 南通启秀门窗有限公司 | Metal door |
| CN104946164A (en) * | 2015-05-08 | 2015-09-30 | 南通启秀门窗有限公司 | Metal window |
| CN106317279A (en) * | 2016-08-25 | 2017-01-11 | 董晓 | Method for preparing weather-proof tough white emulsion |
| CN106317279B (en) * | 2016-08-25 | 2019-02-19 | 常州威斯双联科技有限公司 | A kind of preparation method of weather-proof toughness white glue with vinyl |
| CN106867425A (en) * | 2017-03-01 | 2017-06-20 | 福建农林大学 | A kind of seamless reusable new Year scroll glue of konjaku glucomannan and preparation method thereof |
| CN108797161A (en) * | 2017-05-03 | 2018-11-13 | 海安润德服装有限公司 | A kind of natural printing thickening agent |
| CN107784923A (en) * | 2017-11-02 | 2018-03-09 | 广东天元实业集团股份有限公司 | Label and preparation method thereof |
| CN109385227A (en) * | 2018-09-17 | 2019-02-26 | 陈茂河 | A kind of water opens up glue of bootstrapping, glue film and its preparation method and application |
| CN109852279A (en) * | 2018-12-27 | 2019-06-07 | 绍兴明基新材料有限公司 | Vegetable and fruit binding plant base adhesive tape and preparation method thereof |
| CN109852279B (en) * | 2018-12-27 | 2021-06-01 | 绍兴明基新材料有限公司 | Vegetable and fruit binding plant base adhesive tape and preparation method thereof |
| CN110172106A (en) * | 2019-06-11 | 2019-08-27 | 深圳保时健生物工程有限公司 | A kind of peach gum polysaccharide iron and its application |
| CN110827661A (en) * | 2019-11-16 | 2020-02-21 | 湖北劲佳包装有限公司 | Fragile label |
| CN110982446A (en) * | 2019-12-18 | 2020-04-10 | 江门新时代胶粘科技有限公司 | Water-soluble adhesive tape and preparation method and application thereof |
| CN114507482A (en) * | 2021-12-31 | 2022-05-17 | 苏州工业园区莱博特瑞新材料科技有限公司 | Label for automobile bumper and production process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101654602A (en) | Method for preparing hydrated adhesive | |
| WO2009074006A1 (en) | An adhesive, preparation and use thereof | |
| RU2011112988A (en) | REMINERALIZATION OF TEETH | |
| CN101418196A (en) | Pressure sensitive viscous composite using rice flour as raw material and use thereof | |
| CN104861892A (en) | Oxidized starch adhesive and preparation method thereof | |
| CN101899272B (en) | Solid gum and preparation method thereof | |
| CN105440972A (en) | Nano-compound biomass waterborne adhesive | |
| CN102618191A (en) | High-polymer instant-dissolving environment-friendly binder powder | |
| TWI262210B (en) | Pressure sensitive adhesives | |
| JP2008137970A (en) | Pressure-sensitive adhesive gel sheet for living body and sheet-like cosmetic using the same | |
| CN104263275A (en) | Environment-friendly self-adhesive label material | |
| CN101787237B (en) | Powder emulsion paint for interior wall | |
| CN106634599A (en) | Environment-friendly paint and preparation method thereof | |
| CN104629647A (en) | Environment-friendly starch adhesive | |
| CN109456707A (en) | A kind of adhesive for corrugated board bonding | |
| CN1667075A (en) | Process for preparing environmental protection bone glue adhesive | |
| CN102559094B (en) | Cold sealing adhesive for food and medicines | |
| CN105153795A (en) | Nanometer antibacterial water-based ink and preparation method thereof | |
| JP2002541285A (en) | Use of polyamino acid salts in water-based adhesive applications | |
| CN103788742A (en) | High-temperature resistant environment-friendly glue powder | |
| CN102432231B (en) | Powder adhesive for building | |
| CN102020947A (en) | Rubber powder for producing building adhesive through cold water fast dissolution | |
| AU595857B2 (en) | Readhering and removable adhesive | |
| JP2009235234A (en) | Aqueous pressure-sensitive adhesive composition and aqueous pressure-sensitive adhesive product | |
| CN106833444A (en) | Formula and production process of water-based environment-friendly stone back mesh adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20100224 |