CN107868680A - Improve the alcohol-based fuel of burning situation - Google Patents

Improve the alcohol-based fuel of burning situation Download PDF

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Publication number
CN107868680A
CN107868680A CN201711167737.2A CN201711167737A CN107868680A CN 107868680 A CN107868680 A CN 107868680A CN 201711167737 A CN201711167737 A CN 201711167737A CN 107868680 A CN107868680 A CN 107868680A
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China
Prior art keywords
steam
alcohol
parts
based fuel
handled
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Pending
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CN201711167737.2A
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Chinese (zh)
Inventor
陶积勇
卢昌锐
周顺
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Guilin Ganlong Environmental Protection Equipment Co Ltd
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Guilin Ganlong Environmental Protection Equipment Co Ltd
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Priority to CN201711167737.2A priority Critical patent/CN107868680A/en
Publication of CN107868680A publication Critical patent/CN107868680A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1225Inorganic compounds halogen containing compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1691Hydrocarbons petroleum waxes, mineral waxes; paraffines; alkylation products; Friedel-Crafts condensation products; petroleum resins; modified waxes (oxidised)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses the alcohol-based fuel for improving burning situation, it is characterised in that is made up of the composition of following weight parts:85.0 95.0 parts of methanol, 2.0 8.0 parts of ethanol, 2.0 5.0 parts of the tert-butyl alcohol, 1.0 2.0 parts of paraffin oil, 0.2 0.5 parts of iron chloride, 0.2 0.5 parts of methyl tertiary butyl ether(MTBE), 0.05 0.1 parts of ethyl acetate, 1.5 2.5 parts of additive;The additive is obtained by following preparation methods:1. Steam explosion treatment:The loguat leaf residue that water was extracted, it is put into the processing of steam blasting tank;2. distillation is handled:1. material that step is obtained is put into distiller, in distiller bottom, heating burning or is passed through steam, and when hot steam is filled in distiller, steam is introduced into condenser by condenser pipe, then passes through oil water separator, collects oil phase;3. high-shear homogenizing machine is handled:2. oil phase that step is obtained is handled by high-shear homogenizing machine, and nano-emulsion is made, and obtains additive.

Description

Improve the alcohol-based fuel of burning situation
Technical field
The present invention relates to fuel area, and in particular to improves the alcohol-based fuel of burning situation.
Background technology
Alcohol-based fuel be one kind based on methanol, be mixed with the liquid fuel of the polyalcohols such as ethanol, propyl alcohol and alkane, It is named as again " methyl fuel ".It is also a kind of biomass energy, is each as nuclear energy, solar energy, wind power energy, hydraulic energy The environment protection clean energy that government of state widelys popularize at present.The calorific value of alcohol-based fuel is bavin typically between 2011-2610MJ/kg 60% or so of the exotic fuels calorific value such as oil, liquefied gas, belongs to low heat value liquid fuel, and alcohol-based fuel can be with water with any Ratio is mutually dissolved, but does not form azeotropic mixture with water, and the calorific value of aqueous fuel will be lower.
The research of present alcohol-based fuel is a lot, such as Chinese patent CN102625825A, discloses a kind of methanol-based liquid combustion The production method of material, methods described include:By the methanol of 55-80% by volume, by volume 23-50% water and press body Product meter 2-5% accelerator is mixed to form premix, premix is subjected in mechanical high frequency ultrasound reactor High frequency ultrasound vibrates, and is added after that the catalyst of 3%-5% by volume, then premix is passed through pressure filtration Device, it is finally set to seal at least 48 hours, so as to produce liquid fuel.The ratio of formula reclaimed water can at most account for 50%, can be with It is interpreted as " water becomes oil ".And for example Chinese patent CN103184081A, a kind of alcohol-group fuel oil is disclosed, by following parts by weight Component forms:Methanol 70-75 parts, dimethylbenzene 4-6 parts, No. 200 solvent naphtha 4-6 parts, paraffin oil 4-6 parts, glycerine 4-6 parts, water 5- 10 parts.But there is also deficiency, add water in order to reduce cost so that methanol content makes combustion below 75% in fuel Expect that calorific value is very low.Although in alcohol radical liquid fuel, appropriate water can be contained, it is aqueous to improve flash temperature, reduce The danger of fire, but moisture is mixed into fuel, two aspects are shown to metal erosion:First, moisture can directly cause metal Chemical nuclear power chemical attack;Second, as some sulfur-bearing and sour corrosion materials in fuel be dissolved in water when, then accelerate gold The corrosion process of category.Harm of the free water to metal in fuel is very big, and it can corrode various steel components.Such as steel oil tank, oil Bucket, pipeline, valve and other parts.The micro-moisture being dissolved in fuel can only cause low content steel corrosion.Moisture is to low Steel alloy has stronger corrosiveness, also corrodes the non-ferrous metal such as copper and zinc, and corrosion is not produced to bronze.Chinese patent CN103923709A, while the content of methanol is improved, the content of moisture is reduced, but in reality in use, also sending out Some existing problems, for example, causing fuel insufficient without specialist additive is added in product, black smoke, carbon distribution, black-cooking pot being present Bottom, no raffinate residue, occurs the problems such as smoked people, dazzling in use.
In the prior art, many alcohol-based fuel producers declare to the addition of stabilizer, emulsifying agent in fuel, calorific value after burning Height, discharge amount of exhaust gas are extremely low.Although some manufacturing enterprises claim that added emulsifying agent has good effect, actually The various so-called stabilizers being exclusively formulated, emulsifying agent are often the mixing of the chemicals such as flavor enhancement, coloring agent, metal ion Mixing liquid after the dissolving of thing, typically 6-9 kinds industrial chemicals, the relation with environmental emission reduction in combustion process is not too Greatly.Part producer declares to have it is possible to additionally incorporate additive in alcohol-based fuel to improve calorific value, can greatly improve combustion The calorific value of material.But in fact, unless disregard into local other fuel for adding high heating value, otherwise, only add with all kinds ofization Additive based on work raw material can only make alcohol-based fuel low heat value be changed in a small range, and the alcohol-based fuel after adjustment is low Calorific value is difficult often to break through 27MJ/kg.In actual use, rear kitchen personnel not only have product after generally reflecting fuel combustion Carbon, and flue gas smokes eye, it is necessary to air draft ability normal work is forced with blower fan, problem is still present.
The content of the invention
The purpose of the present invention is overcome the deficiencies in the prior art, there is provided improves the alcohol-based fuel of burning situation, alcohol radical combustion Material can be used for external-burning combustion field, alternative diesel oil and traditional fuel oil.
To reach above-mentioned purpose, the present invention is achieved through the following technical solutions, improves the alcohol-based fuel of burning situation It is made up of the composition of following weight parts:
The additive is obtained by following preparation methods:
1. Steam explosion treatment:The loguat leaf residue that water was extracted, it is put into the processing of steam blasting tank;
2. distillation is handled:1. material that step is obtained is put into distiller, and in distiller bottom, heating is burnt or is passed through Steam, when hot steam is filled in distiller, steam is introduced into condenser, then pass through water-oil separating by condenser pipe Device, collect oil phase;
3. high-shear homogenizing machine is handled:2. oil phase that step is obtained is handled by high-shear homogenizing machine, and nanometer is made Breast, obtain additive.
Of the present invention to be put into the processing of steam blasting tank, preferably burst pressure 3.0-3.5Mpa, the dwell time maintains 150-200s。
High-shear homogenizing machine processing of the present invention, preferred linear velocity 30-40m/s, time 3-5min.
In the present invention, ethanol, the tert-butyl alcohol are added, calorific value can be increased, reach good combustion efficiency, while can change Become the proportion of alcohol-based fuel.
The tert-butyl alcohol, iron chloride improve alcohol-based fuel calorific value, flameholding, easily igniting, burnt as combustion-supporting gain of heat agent Efficiency high.
The proportion of paraffin oil is lighter than methanol, and boiling point is very high about 110 DEG C, and paraffin oil will not be dissolved by methanol, methanol Directly being contacted with air to be volatilized, and iron chloride is added in the present invention and can be very good to avoid such case, can improve alcohol radical combustion Intersolubility in material system, prevent from being layered so that paraffin oil and methanol in alcohol-based fuel are combined closely, and are improved so as to reach The purpose of flash-point, it is contemplated that cost factor, paraffin oil addition should not be too big.
Ethyl acetate, as corrosion inhibitor, by physical absorption film forming or chemisorbed membrane formation mechanism to iron, copper, aluminium Corrosion Deng black, non-ferrous metal forms inhibitory action, particularly controls hydroxyl corrosion, while suppress to parts such as rubber Corrosion, extend the maintenance cycle of equipment.
Methyl tertiary butyl ether(MTBE), as stabilizer, octane number and Cetane number are effectively improved, make burning more stable, can be Initial Stage after Ignition increases fulminant burning, makes igniting easy, the problem for solving cold-starting.Overcome vapour lock problem.
Compared with prior art, the advantage of the invention is that:
1st, in the prior art, some producers add dimethyl ether (DEM) and higher alcohols as additive, but not only need Complicated technique, also can greatly improve the production cost of alcohol-based fuel.And the additive arrived of the present invention, have and belong to ratio Water is light, calorific value is high, safety and environmental protection, hardly possible are volatilized, are flammable but nonflammable, the oil-based liquid organic matter of energy completely burned noresidue, makees It is very suitable for the additive of alcohol-based fuel.
2nd, prior art, usually simple not only reduces alcohol radical combustion by addition calorific value enhancer, increase hydrocarbon content The security performance of material, and the rising of alcohol-based fuel cost price is result in, it is unfavorable for the popularization of alcohol-based fuel.The present invention's adds Add agent, it, which is acted on, mainly functionally improves fuel combustion operating mode, such as reduces consumption, increase flammability, security, reduces Corrosivity, flue gas when preventing from using smoke eye.Moreover, the additive of the present invention have passed through high-shear homogenizing machine processing, with nanometer The form of breast adds alcohol-based fuel as additive, is that obtained alcohol-based fuel is easily atomized, vaporizes, evaporated.
3rd, additive of the invention derives from the residue of plant extracts, many plant extracts, after entering water extraction, Offal treatment is usually used as, and it is of the invention, the plant residue after water extraction is especially chosen, compared to the plant after alcohol extracting Thing residue, there is the liposoluble constituent such as substantial amounts of essential oil to exist in the plant residue after water extraction, day of the present invention is quick-fried by steam Tear reason, distillation processing, high-shear homogenizing machine processing, the plants essential oil in residue after vegetation water is extracted can be fully discharged, is done Arrive to twice laid, killed two birds with one stone.
Embodiment
With embodiment, the invention will be further described below, but the invention is not limited in these embodiments.
Embodiment 1:
Preparing improves the alcohol-based fuel of burning situation, (is stirred at room temperature i.e. according to following components and ratio mixing Can) obtain the alcohol-based fuel of improvement burning situation:
The additive is obtained by following preparation methods:
1. Steam explosion treatment:The loguat leaf residue that water was extracted, it is put into steam blasting tank, burst pressure 3.0- 3.5Mpa, dwell time maintain 150-200s;
2. distillation is handled:1. material that step is obtained is put into distiller, and in distiller bottom, heating is burnt or is passed through Steam, when hot steam is filled in distiller, steam is introduced into condenser, then pass through water-oil separating by condenser pipe Device, collect oil phase;
3. high-shear homogenizing machine is handled:2. oil phase that step is obtained is handled by high-shear homogenizing machine, linear velocity 30- 40m/s, time 3-5min, is made nano-emulsion, obtains additive.
Embodiment 2:
Preparing improves the alcohol-based fuel of burning situation, (is stirred at room temperature i.e. according to following components and ratio mixing Can) obtain the alcohol-based fuel of improvement burning situation:
The additive is obtained by following preparation methods:
1. Steam explosion treatment:The loguat leaf residue that water was extracted, it is put into steam blasting tank, burst pressure 3.0- 3.5Mpa, dwell time maintain 150-200s;
2. distillation is handled:1. material that step is obtained is put into distiller, and in distiller bottom, heating is burnt or is passed through Steam, when hot steam is filled in distiller, steam is introduced into condenser, then pass through water-oil separating by condenser pipe Device, collect oil phase;
3. high-shear homogenizing machine is handled:2. oil phase that step is obtained is handled by high-shear homogenizing machine, linear velocity 30- 40m/s, time 3-5min, is made nano-emulsion, obtains additive.
Embodiment 3:
Preparing improves the alcohol-based fuel of burning situation, (is stirred at room temperature i.e. according to following components and ratio mixing Can) obtain the alcohol-based fuel of improvement burning situation:
The additive is obtained by following preparation methods:
1. Steam explosion treatment:The loguat leaf residue that water was extracted, it is put into steam blasting tank, burst pressure 3.0- 3.5Mpa, dwell time maintain 150-200s;
2. distillation is handled:1. material that step is obtained is put into distiller, and in distiller bottom, heating is burnt or is passed through Steam, when hot steam is filled in distiller, steam is introduced into condenser, then pass through water-oil separating by condenser pipe Device, collect oil phase;
3. high-shear homogenizing machine is handled:2. oil phase that step is obtained is handled by high-shear homogenizing machine, linear velocity 30- 40m/s, time 3-5min, is made nano-emulsion, obtains additive.
Comparative example 1:
Alcohol-based fuel is prepared, alcohol-based fuel is obtained according to following components and ratio mixing (stirring at room temperature):
Comparative example 2:
Alcohol-based fuel is prepared, alcohol-based fuel is obtained according to following components and ratio mixing (stirring at room temperature):
The additive is obtained by following preparation methods:
1. Steam explosion treatment:The loguat leaf residue that water was extracted, it is put into steam blasting tank, burst pressure 3.0- 3.5Mpa, dwell time maintain 150-200s;
2. distillation is handled:1. material that step is obtained is put into distiller, and in distiller bottom, heating is burnt or is passed through Steam, when hot steam is filled in distiller, steam is introduced into condenser, then pass through water-oil separating by condenser pipe Device, oil phase is collected, obtains additive.
Experimental example:
Combustion characteristics Experimental comparison's research is carried out to embodiment 3, the alcohol-based fuel of comparative example, 0# diesel oil.Fuel oil passes through Pipeline enters combustion chambers burn by burner nozzle, heats 20kg water, water temperature from 40 DEG C to 80 DEG C, air by air blower from Combustor sidewalls drum people combustion chamber, flue gas caused by burning is discharged into air by flue, and extracts flue gas with smoke sampling device and pass through Flue gas analyzer measurement (the average value of test data when the numerical value of flue gas is 40 DEG C, 50 DEG C, 60 DEG C, 70 DEG C, 80 DEG C, by relative Air compress pump is that 1.1 conversions draw alcohol-based fuel burning, the relative amount of diesel combustion smoke components).
By embodiment 3 and comparative example 1, the comparison of comparative example 2, compare from fuel value and flame temperature, carry Rise, reason is that the additive of embodiment 3 have passed through high-shear homogenizing machine processing, is added in the form of nano-emulsion as additive Enter alcohol-based fuel, so as to get alcohol-based fuel be easily atomized, vaporize, evaporate, and importantly, reduce CO generation, Smoked eye, dazzling problem when also improving use.

Claims (3)

1. improve the alcohol-based fuel of burning situation, it is characterised in that be made up of the composition of following weight parts:
The additive is obtained by following preparation methods:
1. Steam explosion treatment:The loguat leaf residue that water was extracted, it is put into the processing of steam blasting tank;
2. distillation is handled:1. material that step is obtained is put into distiller, in distiller bottom, heats burning or is passed through steam, When hot steam is filled in distiller, steam is introduced into condenser, then by oil water separator, receive by condenser pipe Collect oil phase;
3. high-shear homogenizing machine is handled:2. oil phase that step is obtained is handled by high-shear homogenizing machine, and nano-emulsion is made, and is obtained Additive.
2. the alcohol-based fuel according to claim 1 for improving burning situation, it is characterised in that:Described is put into steam blasting Tank processing, burst pressure 3.0-3.5Mpa, dwell time maintain 150-200s.
3. the alcohol-based fuel according to claim 1 for improving burning situation, it is characterised in that:Described high-shear homogenizing machine Processing, linear velocity 30-40m/s, time 3-5min.
CN201711167737.2A 2017-11-21 2017-11-21 Improve the alcohol-based fuel of burning situation Pending CN107868680A (en)

Priority Applications (1)

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CN201711167737.2A CN107868680A (en) 2017-11-21 2017-11-21 Improve the alcohol-based fuel of burning situation

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Application Number Priority Date Filing Date Title
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1493669A (en) * 2002-10-29 2004-05-05 符树庆 Vegeteble oil derivative liqid fuel oil environmental protection energy saving additive
US20060201056A1 (en) * 2000-04-14 2006-09-14 Oryxe Energy International, Inc. Biodiesel fuel additive
CN103265981A (en) * 2013-05-20 2013-08-28 清远市精旺环保设备有限公司 Alcohol-based fuel combustion improver and alcohol-based fuel
CN103923709A (en) * 2014-04-10 2014-07-16 桂林市淦隆环保科技有限公司 Alcohol-based fuel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060201056A1 (en) * 2000-04-14 2006-09-14 Oryxe Energy International, Inc. Biodiesel fuel additive
CN1493669A (en) * 2002-10-29 2004-05-05 符树庆 Vegeteble oil derivative liqid fuel oil environmental protection energy saving additive
CN103265981A (en) * 2013-05-20 2013-08-28 清远市精旺环保设备有限公司 Alcohol-based fuel combustion improver and alcohol-based fuel
CN103923709A (en) * 2014-04-10 2014-07-16 桂林市淦隆环保科技有限公司 Alcohol-based fuel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张晓阳等: "《纤维素生物质水解与应用》", 31 December 2012, 郑州大学出版社 *

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