CN107868591A - A kind of method for improving alkyd resin water paint durability - Google Patents
A kind of method for improving alkyd resin water paint durability Download PDFInfo
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- CN107868591A CN107868591A CN201711042032.8A CN201711042032A CN107868591A CN 107868591 A CN107868591 A CN 107868591A CN 201711042032 A CN201711042032 A CN 201711042032A CN 107868591 A CN107868591 A CN 107868591A
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- pentacite
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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Abstract
The present invention relates to the research and development technology field of water paint, discloses a kind of method for improving alkyd resin water paint durability, prepares following raw material in parts by weight：60 70 parts of pentacite, 46 parts of emulsifying agent, 79 parts of nertralizer, 5 10 parts of terpinol, 3.5 4.5 parts of filler, 2.0 3.0 parts of auxiliary agent, 0.6 0.8 parts of calgon, 0.3 0.5 parts of sodium polymethacrylate, 0.2 0.4 parts of activated zeolite powder, 0.1 0.2 parts of cobalt chloride, 30 40 parts of water, on the one hand reacted using the pentacite emulsion being prepared and cobalt chloride, improve the stability of emulsion coatings, on the other hand the hydrophilic radical contained in film forming matter can be changed arrangement architecture without ordered meso-porous structure using activated zeolite powder, make the reduction of its water imbibition, the corrosion resistance of film is improved, accelerate construction and dry solidification process.
Description
Technical field
The invention belongs to the research and development technology field of water paint, and in particular to a kind of raising alkyd resin water paint durability
Method.
Background technology
Compared with traditional coating, water paint replaces organic solvent with water, has the advantages of nontoxic, environmentally friendly, with
The pressure of environmental protection policy, the continuous lifting of consumer's environmental consciousness, provinces and cities especially in all parts of the country have put into effect VOC emission limitation mark
Standard, encouragement use non-solvent coating, and the development to environmental protection coating materials such as water paints brings opportunity.Although traditional coating still accounts for
According to the larger market share, but water paint is pollution-free industry, is the direction for painting class future development.The development of water paint and
The shared market share has been undisputable fact increasing year by year, and has the trend of speed-raising.Some enterprises have appreciated that
The wide market potential of water paint, research and develop, march one after another, expanding water paint market.
Alkyd resin water paint is to use relatively broad a kind of coating, although water paint superior biography on environmental-protecting performance
System paint, but in physical property, the presence construction of water paint product is difficult, not water-fast, easily takes off poor, difference of hardness of skin, richness etc.
Defect.Paint is tolerant due to having the characteristics that strong hardness, paint film richness height, construction, when being still many people's decorations
Preferred coating.Only the defects of physical property is resolved, or even beyond tradition paint, consumer just can more actively select
Use water paint.Only consumer is catered on environmental-protecting performance, consumer can not be met on construction technology, decorative effect,
The market of water paint is difficult still to open.This needs water paint manufacturing enterprise to do technological innovation in water paint performance.
The content of the invention
The purpose of the present invention is to be directed to the problem of existing, there is provided a kind of side for improving alkyd resin water paint durability
Method, the pliability and lower temperature resistance of alkyd resin water paint can be adjusted, prevents coating from occurring during storage and use
The problems such as corruption comes off.
The present invention is achieved by the following technical solutions：
A kind of method for improving alkyd resin water paint durability, method comprise the following steps：
（1）Prepare following raw material in parts by weight：Pentacite 60-70 parts, emulsifying agent 4-6 parts, nertralizer 7-
9 parts, terpinol 5-10 parts, filler 3.5-4.5 parts, auxiliary agent 2.0-3.0 parts, calgon 0.6-0.8 parts, polymethylacrylic acid
Sodium 0.3-0.5 parts, activated zeolite powder 0.2-0.4 parts, cobalt chloride 0.1-0.2 parts, water 30-40 parts；
（2）It is put into after pentacite is dried into 2-3 hours at 80-90 DEG C in reactor, is warming up to 130-140
DEG C, add emulsifying agent and 45-50 minutes are stirred under 300-400 revs/min, cooled, temperature starts to drip when reaching 85-90 DEG C
Add nertralizer, rate of addition is 3-5 ml/mins, is stirred insulation during dropwise addition, temperature control in 80-85 DEG C of scope,
After dripping nertralizer, 15-20 minutes are stirred, stand 30-40 minutes, operates 2-3 times, gradually cools within 3-4 hours repeatedly
To room temperature, pentacite emulsion is obtained；
（3）Cobalt chloride is dissolved using water, is added in the pentacite emulsion being prepared, is added after being well mixed
Enter terpinol, be heated to 130-140 DEG C and reacted, 80-90 DEG C is cooled to after reacting 2-3 hours, add activated zeolite powder and
Auxiliary agent, residual components are stirring evenly and then adding into, normal temperature preserves after mixing.
Further described as to such scheme, the activated zeolite powder, preparation method thereof is：Purity is reached 99.9%
Original ore powder is further crushed to 400-500 mesh, and the hydrochloric acid solution that concentration is 20-30% impregnates 8-10 hours, then done
It is dry, calcined in the Muffle furnace of preheating 3-5 hours, calcining heat is 400-450 DEG C, and particle diameter is further crushed to after calcining and is existed
10-50 nanometer ranges.
Further described as to such scheme, the breast that described pentacite emulsion uses in preparation
Agent contains following component according to mass percent meter：Lauryl sodium sulfate accounts for 20-25%, neopelex accounts for 18-
20%th, dodecyl sodium sulfate accounts for 15-17%, lignosulfonates account for 12-15%, phosphate diester salt accounts for 8-10%, monoalkyl phosphate
Account for 6-8%, remaining as petroleum sulfonate.
Further described as to such scheme, the pentacite emulsion used in preparation in and
Agent is respectively in parts by weight：Ammoniacal liquor 10-15 parts, triethanolamine 8-10 parts, diethanol amine 5-8 parts, sodium hydroxide 3-5 parts,
Potassium hydroxide 1-2 parts, water 50-60 parts.
The present invention has advantages below compared with prior art：In order to solve asking for existing alkyd resin water paint poor durability
Topic, the invention provides a kind of method for improving alkyd resin water paint durability, on the one hand utilize the Ji Wusi being prepared
Alcohol alkide resin emulsion reacts with cobalt chloride, improves the stability of emulsion coatings, on the other hand utilizes unordered Jie of activated zeolite powder
Pore structure can by the hydrophilic radical contained in film forming matter change arrangement architecture, make its water imbibition reduction, film it is corrosion-resistant
Property be improved, accelerate construction and dry solidification process, the pliability and lower temperature resistance of alkyd resin water paint can be adjusted, prevent
Only there is the problems such as corruption comes off during storage and use in coating, can be by life 3-5, and expands alkyd
The application of resin water paint, there are extremely important development and application values.
Embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment 1
A kind of method for improving alkyd resin water paint durability, method comprise the following steps：
（1）Prepare following raw material in parts by weight：60 parts of pentacite, 4 parts of emulsifying agent, 7 parts of nertralizer, pine tar
5 parts of alcohol, 3.5 parts of filler, 2.0 parts of auxiliary agent, 0.6 part of calgon, 0.3 part of sodium polymethacrylate, activated zeolite powder 0.2
Part, 0.1 part of cobalt chloride, 30 parts of water；
（2）It is put into after pentacite is dried 2 hours at 80 DEG C in reactor, is warming up to 130 DEG C, adds emulsification
Agent is stirred 45 minutes under 300 revs/min, is cooled, and temperature starts that nertralizer, rate of addition 3 is added dropwise when reaching 85 DEG C
Ml/min, insulation is stirred during dropwise addition, temperature control is in 80-85 DEG C of scope, after dripping nertralizer, stirring 15
Minute, 30 minutes are stood, is operated 2 times repeatedly, was gradually cooled to room temperature in 3 hours, obtains pentacite emulsion；
（3）Cobalt chloride is dissolved using water, is added in the pentacite emulsion being prepared, is added after being well mixed
Enter terpinol, be heated to 130 DEG C and reacted, reaction is cooled to 80 DEG C after 2 hours, add activated zeolite powder and auxiliary agent, stirring
Residual components are added after uniformly, normal temperature preserves after mixing.
Further described as to such scheme, the activated zeolite powder, preparation method thereof is：Purity is reached 99.9%
Original ore powder is further crushed to 400 mesh, and the hydrochloric acid solution that concentration is 20% impregnates 8 hours, is then dried, preheating
Muffle furnace in calcine 3 hours, calcining heat is 400 DEG C, particle diameter is further crushed to after calcining in 10-50 nanometer ranges i.e.
Can.
Further described as to such scheme, the breast that described pentacite emulsion uses in preparation
Agent contains following component according to mass percent meter：Lauryl sodium sulfate accounts for 20%, neopelex and accounts for 18%, ten
Dialkyl sulfonates, which account for 15%, lignosulfonates and account for 12%, phosphate diester salt and account for 8%, monoalkyl phosphate, accounts for 6%, remaining as oil
Sulfonate.
Further described as to such scheme, the pentacite emulsion used in preparation in and
Agent is respectively in parts by weight：10 parts of ammoniacal liquor, 8 parts of triethanolamine, 5 parts of diethanol amine, 3 parts of sodium hydroxide, potassium hydroxide 1
Part, 50 parts of water.
Embodiment 2
A kind of method for improving alkyd resin water paint durability, method comprise the following steps：
（1）Prepare following raw material in parts by weight：65 parts of pentacite, 5 parts of emulsifying agent, 8 parts of nertralizer, pine tar
7 parts of alcohol, 4.0 parts of filler, 2.5 parts of auxiliary agent, 0.7 part of calgon, 0.4 part of sodium polymethacrylate, activated zeolite powder 0.3
Part, 0.15 part of cobalt chloride, 35 parts of water；
（2）It is put into after pentacite is dried 2.5 hours at 85 DEG C in reactor, is warming up to 135 DEG C, adds breast
Agent stirs 48 minutes under 350 revs/min, is cooled, and temperature starts that nertralizer is added dropwise when reaching 88 DEG C, and rate of addition is
4 ml/mins, insulation is stirred during dropwise addition, temperature control is in 80-85 DEG C of scope, after dripping nertralizer, stirring 18
Minute, 35 minutes are stood, operates 2 times repeatedly, room temperature was gradually cooled in 3.5 hours, obtains pentacite breast
Liquid；
（3）Cobalt chloride is dissolved using water, is added in the pentacite emulsion being prepared, is added after being well mixed
Enter terpinol, be heated to 135 DEG C and reacted, reaction is cooled to 85 DEG C after 2.5 hours, add activated zeolite powder and auxiliary agent, stir
Residual components are added after mixing uniformly, normal temperature preserves after mixing.
Further described as to such scheme, the activated zeolite powder, preparation method thereof is：Purity is reached 99.9%
Original ore powder is further crushed to 450 mesh, and the hydrochloric acid solution that concentration is 25% impregnates 9 hours, is then dried, preheating
Muffle furnace in calcine 4 hours, calcining heat is 430 DEG C, particle diameter is further crushed to after calcining in 10-50 nanometer ranges i.e.
Can.
Further described as to such scheme, the breast that described pentacite emulsion uses in preparation
Agent contains following component according to mass percent meter：Lauryl sodium sulfate accounts for 22%, neopelex and accounts for 19%, ten
Dialkyl sulfonates, which account for 16%, lignosulfonates and account for 13%, phosphate diester salt and account for 9%, monoalkyl phosphate, accounts for 7%, remaining as oil
Sulfonate.
Further described as to such scheme, the pentacite emulsion used in preparation in and
Agent is respectively in parts by weight：13 parts of ammoniacal liquor, 9 parts of triethanolamine, 6 parts of diethanol amine, 4 parts of sodium hydroxide, potassium hydroxide 1.5
Part, 55 parts of water.
Embodiment 3
A kind of method for improving alkyd resin water paint durability, method comprise the following steps：
（1）Prepare following raw material in parts by weight：70 parts of pentacite, 6 parts of emulsifying agent, 9 parts of nertralizer, pine tar
10 parts of alcohol, 4.5 parts of filler, 3.0 parts of auxiliary agent, 0.8 part of calgon, 0.5 part of sodium polymethacrylate, activated zeolite powder 0.4
Part, 0.2 part of cobalt chloride, 40 parts of water；
（2）It is put into after pentacite is dried 3 hours at 90 DEG C in reactor, is warming up to 140 DEG C, adds emulsification
Agent is stirred 50 minutes under 400 revs/min, is cooled, and temperature starts that nertralizer, rate of addition is added dropwise when reaching 85-90 DEG C
For 5 ml/mins, insulation is stirred during dropwise addition, temperature control is in 80-85 DEG C of scope, after dripping nertralizer, stirring
20 minutes, 40 minutes are stood, operates 3 times repeatedly, room temperature was gradually cooled in 4 hours, obtains pentacite breast
Liquid；
（3）Cobalt chloride is dissolved using water, is added in the pentacite emulsion being prepared, is added after being well mixed
Enter terpinol, be heated to 140 DEG C and reacted, reaction is cooled to 90 DEG C after 3 hours, add activated zeolite powder and auxiliary agent, stirring
Residual components are added after uniformly, normal temperature preserves after mixing.
Further described as to such scheme, the activated zeolite powder, preparation method thereof is：Purity is reached 99.9%
Original ore powder is further crushed to 500 mesh, and the hydrochloric acid solution that concentration is 30% impregnates 10 hours, is then dried, preheating
Muffle furnace in calcine 5 hours, calcining heat is 450 DEG C, particle diameter is further crushed to after calcining in 10-50 nanometer ranges i.e.
Can.
Further described as to such scheme, the breast that described pentacite emulsion uses in preparation
Agent contains following component according to mass percent meter：Lauryl sodium sulfate accounts for 25%, neopelex and accounts for 20%, ten
Dialkyl sulfonates, which account for 17%, lignosulfonates and account for 15%, phosphate diester salt and account for 10%, monoalkyl phosphate, accounts for 8%, remaining as oil
Sulfonate.
Further described as to such scheme, the pentacite emulsion used in preparation in and
Agent is respectively in parts by weight：15 parts of ammoniacal liquor, 10 parts of triethanolamine, 8 parts of diethanol amine, 5 parts of sodium hydroxide, potassium hydroxide 2
Part, 60 parts of water.
Comparative example 1
With differing only in for embodiment 1, the addition of cobalt chloride is omitted, remaining is consistent.
Comparative example 2
With differing only in for embodiment 2, the addition of activated zeolite powder is omitted, remaining is consistent.
Comparative example 3
With differing only in for embodiment 3, after dripping nertralizer in the preparation process of pentacite emulsion, stir
Mix 60 minutes, stand 2 hours, remaining is consistent.
Contrast experiment
Alkyd resin water paint is prepared using embodiment 1-3 and comparative example 1-3 method respectively, while with existing basic model alcohol
Acid resin water paint compares, using identical experimental subjects and japanning mode, to paint film property intensity（After film 3 months）Enter
Row measure, it is as a result as shown in the table：
| Project | Adhesive strength（MPa） | Tensile strength（MPa） | Paint film spalling rate（%） | Rate of drying improves（Times） |
| Embodiment 1 | 5.93 | 492 | 0.01 | 8 |
| Embodiment 2 | 5.98 | 495 | 0.01 | 10 |
| Embodiment 3 | 5.95 | 493 | 0.01 | 9 |
| Comparative example 1 | 3.67 | 416 | 0.36 | 4 |
| Comparative example 2 | 4.05 | 432 | 0.57 | 3 |
| Comparative example 3 | 3.32 | 386 | 0.62 | 4 |
| Control group | 2.21 | 324 | 0.95 | Control |
As can be seen here：The method provided by the invention for improving alkyd resin water paint durability solves water paint by poor durability
The problem of, improve the rate of drying and mechanical strength of paint film, additionally it is possible to adjust the pliability of alkyd resin water paint and resistance to low
Warm nature, prevent coating from the problems such as corruption comes off occur during storage and use, can be by life 3-5, and expand
The big application of alkyd resin water paint, has extremely important development and application values.
Claims (4)
- A kind of 1. method for improving alkyd resin water paint durability, it is characterised in that method comprises the following steps：（1）Prepare following raw material in parts by weight：Pentacite 60-70 parts, emulsifying agent 4-6 parts, nertralizer 7-9 Part, terpinol 5-10 parts, filler 3.5-4.5 parts, auxiliary agent 2.0-3.0 parts, calgon 0.6-0.8 parts, polymethylacrylic acid Sodium 0.3-0.5 parts, activated zeolite powder 0.2-0.4 parts, cobalt chloride 0.1-0.2 parts, water 30-40 parts；（2）It is put into after pentacite is dried into 2-3 hours at 80-90 DEG C in reactor, is warming up to 130-140 DEG C, add emulsifying agent and 45-50 minutes are stirred under 300-400 revs/min, cooled, temperature starts to drip when reaching 85-90 DEG C Add nertralizer, rate of addition is 3-5 ml/mins, is stirred insulation during dropwise addition, temperature control in 80-85 DEG C of scope, After dripping nertralizer, 15-20 minutes are stirred, stand 30-40 minutes, operates 2-3 times, gradually cools within 3-4 hours repeatedly To room temperature, pentacite emulsion is obtained；（3）Cobalt chloride is dissolved using water, is added in the pentacite emulsion being prepared, is added after being well mixed Enter terpinol, be heated to 130-140 DEG C and reacted, 80-90 DEG C is cooled to after reacting 2-3 hours, add activated zeolite powder and Auxiliary agent, residual components are stirring evenly and then adding into, normal temperature preserves after mixing.
- A kind of 2. method for improving alkyd resin water paint durability as claimed in claim 1, it is characterised in that the activity boiling Stone flour preparation method is：The original ore powder that purity is reached to 99.9% is further crushed to 400-500 mesh, concentration 20-30% Hydrochloric acid solution dipping 8-10 hours, be then dried, 3-5 hours calcined in the Muffle furnace of preheating, calcining heat is 400-450 DEG C, particle diameter is further crushed to after calcining in 10-50 nanometer ranges.
- A kind of 3. method for improving alkyd resin water paint durability as claimed in claim 1, it is characterised in that described season penta The emulsifying agent that tetrol alkide resin emulsion uses in preparation contains following component according to mass percent meter：Dodecyl sulphate Sodium accounts for 20-25%, neopelex accounts for 18-20%, dodecyl sodium sulfate accounts for 15-17%, lignosulfonates account for 12- 15%th, phosphate diester salt accounts for 8-10%, monoalkyl phosphate accounts for 6-8%, remaining as petroleum sulfonate.
- A kind of 4. method for improving alkyd resin water paint durability as claimed in claim 1, it is characterised in that the Ji Wusi The nertralizer that alcohol alkide resin emulsion uses in preparation is respectively in parts by weight：Ammoniacal liquor 10-15 parts, triethanolamine 8-10 Part, diethanol amine 5-8 parts, sodium hydroxide 3-5 parts, potassium hydroxide 1-2 parts, water 50-60 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711042032.8A CN107868591A (en) | 2017-10-31 | 2017-10-31 | A kind of method for improving alkyd resin water paint durability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711042032.8A CN107868591A (en) | 2017-10-31 | 2017-10-31 | A kind of method for improving alkyd resin water paint durability |
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| CN107868591A true CN107868591A (en) | 2018-04-03 |
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| CN201711042032.8A Pending CN107868591A (en) | 2017-10-31 | 2017-10-31 | A kind of method for improving alkyd resin water paint durability |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366881A (en) * | 2016-08-31 | 2017-02-01 | 长沙维化工涂料有限公司 | Preparation method of water-based fast dry low VOC alkyd paint |
-
2017
- 2017-10-31 CN CN201711042032.8A patent/CN107868591A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366881A (en) * | 2016-08-31 | 2017-02-01 | 长沙维化工涂料有限公司 | Preparation method of water-based fast dry low VOC alkyd paint |
Non-Patent Citations (2)
| Title |
|---|
| 孙传尧: "《选矿工程师手册.第4册》", 31 March 2015, 冶金工业出版社 * |
| 涂料工艺编委会: "《涂料工艺（第三版）》", 31 December 1997, 化学工业出版社 * |
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