CN107867774A - The circulation comprehensive of seaweed processing waste water utilizes system and technical method - Google Patents

The circulation comprehensive of seaweed processing waste water utilizes system and technical method Download PDF

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Publication number
CN107867774A
CN107867774A CN201711089685.1A CN201711089685A CN107867774A CN 107867774 A CN107867774 A CN 107867774A CN 201711089685 A CN201711089685 A CN 201711089685A CN 107867774 A CN107867774 A CN 107867774A
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China
Prior art keywords
waste water
seaweed
processing
separator
technical method
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CN201711089685.1A
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Chinese (zh)
Inventor
车元昊
车子路
车升亮
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Lianyungang Zijin Seaweed Industry Research And Development Center
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Lianyungang Zijin Seaweed Industry Research And Development Center
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Priority to CN201711089685.1A priority Critical patent/CN107867774A/en
Publication of CN107867774A publication Critical patent/CN107867774A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/38Treatment of water, waste water, or sewage by centrifugal separation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5263Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/122Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/127Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering by centrifugation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The circulation comprehensive of seaweed processing waste water utilizes system and technical method, belongs to the wastewater processing technology in processing of farm products field, falls within the discarded object integrated treatment utilization technology in processing of farm products field.With technical method provided by the invention, problem of environmental pollution caused by the direct discharging of waste water in seaweed process can solve the problem that;With technical method provided by the invention, seaweed processing waste water cycling and reutilization can be made, reduce the water resources consumption of seaweed processing;With technical method provided by the invention, the impurity of removal can carry out down-stream processing with high added-value, be advantageous to the sustainable health development of seaweed industry.

Description

The circulation comprehensive of seaweed processing waste water utilizes system and technical method
Technical field
The present invention relates to the circulation comprehensive of a main laver processing waste water to utilize system and technical method, belongs to processing of farm products The wastewater processing technology in field, fall within the discarded object integrated treatment utilization technology in processing of farm products field.
Background technology
Seaweed is the general designation of Bangiales section Porphyra marine algae, including Porphyra yezoensis, porphyra haitanensis, laver, circle seaweed, Numerous kinds such as side seaweed, the kind cultivated extensively at present are Porphyra yezoensis, porphyra haitanensis, laver.
Laver nutritive enriches, according to the difference of growth time section, protein content per 100g dry lavers in 35-50%, The content 25% or so of polysaccharide, fat content 3% or so, the lubricant component in seaweed is mainly polyunsaturated fatty acid.Especially It is worth lifting, a kind of special acid --- the taurine all not contained in any land plant is also contained in seaweed, The content of taurine is 1% or so in seaweed, and this content is even above many marine animals.
There is the platform set of laver processing machine group more than 1000 in China at present, is distributed mainly on Jiangsu, Fujian, Zhejiang, Along The Coast of Shandong Province.
Seaweed processing season concentrates on the April in December to next year.
It is often to continuously run for 24 hours to process laver processing machine in season, and seaweed processing needs substantial amounts of water, and processing is used Water uses city tap-water, to meet drinking water standard.Every processing machine daily (24 hours) with about 100-120 cubes of water Rice, is calculated accordingly, and the annual seaweed processing water consumption in the whole nation is 7200-8640 ten thousand steres.
Seaweed processing waste water caused by current all seaweed processing enterprises is all directly to discharge.Seaweed processing waste water mainly by The organic matters such as seaweed fragment, soluble protein and silt composition.Seaweed process time concentrates on winter-spring season, and discharge is given up Water will not show at that time pollution environment harm, with the rise of temperature, the organic matter in waste water starts to ferment, color by Gradual change is red, until blackening, gives out stench, adds environmental pressure.
Application publication number is the A of CN 102948830, and data of publication of application 2013 year 03 month 06 day, entitled " one kind is to purple The application for a patent for invention of the method that dish processing is recycled with water ", the processing for being related to seaweed processing waste water utilize, its Content mainly produces beverage by raw material of seaweed processing waste water, and the statutory status of the patent application is that " application for a patent for invention is public Deemed withdrawal after cloth ", October 29 2014 statutory status effective date.
Application publication number is the A of CN 105601732, data of publication of application 2016 year 05 month 25 days, entitled " from seaweed plus The application for a patent for invention of the method that phycobniliprotein is separated in work waste water ", is related to and separates phycobniliprotein from seaweed processing waste water, In the specification and entitlement requests book of the patent application, detail how to go the removal of impurity to obtain algae courage egg from seaweed waste water In vain, and not to isolating the waste water of phycobniliprotein for further processing or being used, also the impurity of removal is not made into one The processing of step is used, and its content is not useless in order to handle seaweed processing just for the sake of obtaining phycobniliprotein Water.
The invention provides direct, complete, beyond all doubt technical method, is applied at seaweed processing waste water Reason field, treated waste water circulation can be made to be reused in seaweed production process, and to the seaweed fragment in waste water, solubility The organic matters such as protein and silt carry out processing utilization.
The present invention is the improvement of the patent application to Application No. 210710904765.1.
The content of the invention
The problem of causing environmental pollution the invention solves direct discharging of waste water in existing seaweed process.The present invention carries Direct, complete, beyond all doubt technical method has been supplied, can make the circulation of seaweed processing waste water again using the technical method Utilize, reduce seaweed processing water resources consumption, the impurity of removal can also carry out down-stream processing with high added-value, reduce environment dirt Dye, seaweed processing industry chain is elongated, be more beneficial for the cluster development of seaweed industry sustainable health development and seaweed industry.
In order to solve the above technical problems, technical scheme provided by the invention is as follows:
Waste water collection tank, waste water collection tank are masonry concrete structure or steel plate structure or high score Sub- material structure.Waste water collection tank is that monomer groove can also be the conjuncted groove to communicate with one another that two or more monomer groove is formed.It is useless Where water collecting groove build laver processing machine at the discharge outlet of factory building, without machining machine and any shape of factory building progress to seaweed The transformation of formula.
Waste water delivery pump, waste water delivery pump select noncorrosive pump, can be by the purple containing impurity such as seaweed fragment, silts Dish processing waste water is transported to next procedure.
Waste water separator, there are overfall, sewage draining exit, can be tentatively by the impurity such as silt and seaweed in seaweed processing waste water Fragment is separated, and the impurity such as silt is discharged through sewage draining exit, and planting vegetable is used for after collection, and the waste water containing seaweed fragment enters Next procedure.
Waste water filter press, the waste water containing seaweed fragment sent to last process carry out dewater treatment, make seaweed fragment Separate to form filter cake from waste water Deng solidity material, the filter cake separated there are a variety of processing methods, can direct heap Fertilizer, feed can be used as, the deep processing raw material oily as taurine, polysaccharide, protein, seaweed is extracted can be carried out.
Separator is precipitated, the waste water that last process is separated, into precipitation separator, precipitation separator is provided with low speed Agitating device, it can separate the organic matter precipitation in waste water after adding flocculant, flocculant can select inorganic matter to wad a quilt with cotton Solidifying agent, organic polymer coargulator, biological flocculant etc., the waste water after this process, can be referred to as " reclaimed water ".
Filter press is precipitated, press filtration processing, the liquid separated are carried out to the flocculate precipitate discharged in precipitation separator Material, which sends precipitation separator and waste water back to and merges precipitation again, to be separated, and obtained filter cake is buried as solid waste or with giving up The silt discharged in separator merges for planting vegetable.
Membrane filtration system, it is made up of, can filters out exhausted in reclaimed water the ceramic membrane of various membrane fluxs, polymer compound film Most of impurity.
Sterilization process, it is made up of ozone sterilization and ultraviolet disinfection.
Online water quality monitoring process, is made up of online water quality monitor.
Clear water storage tank and pumping system, from sterilization process come out water, kept in by clear water storage tank, according to production needs, by Clear water is pumped into production process use.
List ten systems altogether above, some systems may be incorporated in together, and some systems can be segmented further, This is enumerated as ten systematic names, is to describe in detail, is not just to which system quantity is controlled at ten.
Brief description of the drawings
Fig. 1 is schematic flow sheet
Embodiment
Technical scheme is elaborated further with reference to specific embodiments and the drawings;
As shown in figure 1, seaweed processing waste water WS1 enters waste water collection tank 1,500 cubic metre one of waste water collection tank volume It is individual, when liquid level reaches production requirement, start water pump B1, extract waste water and deliver to waste water separator 2, waste water is entered with tangential direction In separator 2, the heavier contamination precipitation such as swirling current, silt is formed in separator 2 to bottom, every 2 hours Open valves F1, which is released after the impurity such as impurity, silt such as silt are stacked, is used for planting vegetable, and the impurity such as silt released from valve F1 can also Deliver to filter press 3-1 and merge press filtration with the valve F2 flocculate precipitates excluded, the waste water outflow containing seaweed fragment to waste water pressure In filter 3;
After waste water enters waste water filter press 3, most of water is removed, the water of removing enters precipitation separator 4, and press filtration obtains To solid content can be referred to as filter cake, filter cake is left concentratedly in filter cake storage tank LB1, collective conveyance carry out deep processing, this reality Apply in example, filter cake is taken as feed;
The waste water that waste water filter press comes out enters in precipitation separator 4, and flocculant is added to by flocculant storage tank XN1 It is sufficiently mixed with waste water in precipitation separator 4, and is sent out with inorganic matters such as organic matter, the heavy metals such as the protein in waste water, polysaccharide Raw flocculation reaction, flocculate precipitate is generated, flocculate precipitate is discharged into precipitation filter press 3-1 by valve F2, by press filtration The liquid substance separated is sent back to merge to precipitate again with waste water in precipitation separator 4 and separated, and obtained filter cake is stored in filter In cake storage tank LB2, filter cake can regard solid waste and bury, and can also merge with the silt discharged in waste water separator 2 and use Flocculant uses biopolymer chelating agent, flocculation chitin in planting vegetable, the present embodiment;
Reclaimed water after flocculation sediment enters membrane filtration process 5, and the present embodiment is answered using ceramic membrane and macromolecule Close film integrated system associated with film;
Water after membrane filtration process, into ozone sterilization process 6, ozone in water content is controlled in 0.1g/L--- 0.4g/L, keeps concentration 5 minutes;
By the water of ozone sterilization process, into ultraviolet disinfection process 7, ultraviolet radiation intensity is controlled in 20mW/ cm2---40mW/cm2, 5 seconds time;
Water quality is by online water quality monitoring system 8, on-line uninterruption monitoring;
By the water of ultraviolet disinfection process, into clear water storage tank 9, seaweed workshop is sent to by clarified water pump B2 Use, Drinking Water can also be regarded, the industrial water of seaweed deep processing can also be regarded;
Above embodiment is used for illustrative purposes only, rather than limitation of the present invention, the technology about technical field The various change or replacement that personnel are made in the case where not departing from the invention spirit and scope, are based even on this hair Bright deteriorates technical scheme, should all belong to protection scope of the present invention.

Claims (7)

1. the circulation comprehensive of seaweed processing waste water utilizes system and technical method, the described method comprises the following steps:The system by Waste water collection tank, waste water delivery pump, waste water separator, waste water filter press, precipitation separator, precipitation filter press, membrane filtration system, Sterilization process, online water quality monitoring process, clear water storage tank pumping system are formed.
(1) waste water collection tank:Waste water collection tank is masonry concrete structure or steel plate structure or macromolecule Material structure.Waste water collection tank is that monomer groove can also be the conjuncted groove to communicate with one another that two or more monomer groove is formed.Waste water It is any type of without being carried out to seaweed machining machine and factory building where collecting tank build laver processing machine at the discharge outlet of factory building Transformation.
(2) waste water delivery pump:Waste water delivery pump selects noncorrosive pump.
(3) waste water separator:There are overfall, a sewage draining exit, waste water enters that to form swirling current, silt etc. heavier with tangential direction Contamination precipitation is discharged to bottom, the waste water outflow of the fragment containing seaweed.
(4) waste water filter press:From plate and frame filter press and centrifuge.
(5) separator is precipitated:Precipitation separator has stirring at low speed device to promote flocculation reaction.
(6) filter press is precipitated:From plate and frame filter press and centrifuge.
(7) membrane filtration system:For film integrated system associated with ceramic membrane and polymer compound film.
(8) sterilization process:It is made up of ozone sterilizer and ultraviolet sterilizer.
(9) online water quality monitoring process:It is made up of online water quality monitor.
(10) clear water storage tank pumping system:It is made up of clear water storage tank, clarified water pump, metering device.
2. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: Waste water caused by seaweed processing, including waste water, bag caused by waste water caused by processing Porphyra yezoensis including processing porphyra haitanensis Include waste water caused by (such as sea-tangle) when processing waste water caused by other Porphyra algae including processing other algae.
3. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: Waste water caused by seaweed is processed after the system is handled, can be reused directly in seaweed process, can be worked as and do manual labour Drinking water, the industrial water that seaweed deep processing can be regarded.
4. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: The impurity such as silt can be used for planting vegetable, can merge flocculation sediment press filtration caused by waste water separator 2.
5. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: Filter cake caused by waste water filter press 3 can be as extraction taurine, extraction protein, extraction polysaccharide, the raw material for extracting seaweed oil; Feed can also be used as after drying;Feed addictive can also be regarded;Can also directly compost be processed into Crop fertilizer.
6. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: The flocculant used in precipitation separator 4, by being preferably flocculation chitin.
7. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: Caused flocculate precipitate in separator 4 is precipitated, precipitation filter press 3-1 is delivered to and carries out press filtration, it is heavy that obtained liquid substance is sent to Shallow lake separator 4 merges precipitation again with waste water and separated, and obtained filter cake is buried as solid waste or with waste water separator 2 The silt of middle discharge merges for planting vegetable.
CN201711089685.1A 2017-10-24 2017-10-24 The circulation comprehensive of seaweed processing waste water utilizes system and technical method Pending CN107867774A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108947046A (en) * 2018-06-29 2018-12-07 连云港紫金海藻产业研究发展中心 The circulation comprehensive of seaweed processing waste water utilizes system and technical method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004358343A (en) * 2003-06-04 2004-12-24 Yanmar Co Ltd Recycling water generation device, and recycling water generation method
CN101103835A (en) * 2007-07-24 2008-01-16 宁波大学 Cleaning device used in laver processing course and its cleaning method
CN102948830A (en) * 2011-08-30 2013-03-06 苏州思维德生物科技有限公司 Method for recycling water in laver processing
CN105293812A (en) * 2014-06-23 2016-02-03 高嵩 Sewage treatment method suitable for seaweed processing industry
CN105601732A (en) * 2016-03-30 2016-05-25 南通中国科学院海洋研究所海洋科学与技术研究发展中心 Method for separating phycobiliprotein from laver processing wastewater

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004358343A (en) * 2003-06-04 2004-12-24 Yanmar Co Ltd Recycling water generation device, and recycling water generation method
CN101103835A (en) * 2007-07-24 2008-01-16 宁波大学 Cleaning device used in laver processing course and its cleaning method
CN102948830A (en) * 2011-08-30 2013-03-06 苏州思维德生物科技有限公司 Method for recycling water in laver processing
CN105293812A (en) * 2014-06-23 2016-02-03 高嵩 Sewage treatment method suitable for seaweed processing industry
CN105601732A (en) * 2016-03-30 2016-05-25 南通中国科学院海洋研究所海洋科学与技术研究发展中心 Method for separating phycobiliprotein from laver processing wastewater

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108947046A (en) * 2018-06-29 2018-12-07 连云港紫金海藻产业研究发展中心 The circulation comprehensive of seaweed processing waste water utilizes system and technical method

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Application publication date: 20180403