CN108101277A - The circulation comprehensive of seaweed processing waste water utilizes system and technical method - Google Patents

The circulation comprehensive of seaweed processing waste water utilizes system and technical method Download PDF

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Publication number
CN108101277A
CN108101277A CN201711324146.1A CN201711324146A CN108101277A CN 108101277 A CN108101277 A CN 108101277A CN 201711324146 A CN201711324146 A CN 201711324146A CN 108101277 A CN108101277 A CN 108101277A
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China
Prior art keywords
waste water
seaweed
processing
technical method
water
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Pending
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CN201711324146.1A
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Chinese (zh)
Inventor
车升亮
车元昊
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Lianyungang Zijin Seaweed Industry Research And Development Center
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Lianyungang Zijin Seaweed Industry Research And Development Center
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Priority to CN201711324146.1A priority Critical patent/CN108101277A/en
Publication of CN108101277A publication Critical patent/CN108101277A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5263Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The circulation comprehensive of seaweed processing waste water utilizes system and technical method, belongs to the wastewater processing technology of field of agricultural products processing, falls within the discarded object integrated treatment utilization technology of field of agricultural products processing.With technical method provided by the invention, problem of environmental pollution caused by the direct discharging of waste water in seaweed process can be solved;With technical method provided by the invention, seaweed processing waste water cycling and reutilization can be made, reduce the water resources consumption of seaweed processing;With technical method provided by the invention, the impurity of removal can carry out down-stream processing with high added-value, be conducive to the sustainable health development of seaweed industry.

Description

The circulation comprehensive of seaweed processing waste water utilizes system and technical method
Technical field
Circulation comprehensive the present invention relates to a main laver processing waste water belongs to processing of farm products using system and technical method The wastewater processing technology in field falls within the discarded object integrated treatment utilization technology of field of agricultural products processing.
Background technology
Seaweed is the general designation of Bangiales section Porphyra marine algae, including Porphyra yezoensis, porphyra haitanensis, laver, circle seaweed, Numerous kinds such as side seaweed, the kind cultivated extensively at present are Porphyra yezoensis, porphyra haitanensis, laver.
Laver nutritive enriches, according to the difference of growth time section, protein content per 100g dry lavers in 35-50%, The content 25% or so of polysaccharide, fat content 3% or so, the lubricant component in seaweed is mainly polyunsaturated fatty acid.Especially It is worth lifting, also containing a kind of special acid --- the taurine all not contained in any land plant in seaweed, in purple The content of taurine is 1% or so in dish, this content is even above many marine animals.
There is more than 1000 platform set of laver processing machine group in China at present, is distributed mainly on Jiangsu, Fujian, Zhejiang, Along The Coast of Shandong Province.
Seaweed processing season concentrates on the April in December to next year.
It is continuously run when laver processing machine is often 24 small in processing season, seaweed processing needs substantial amounts of water, and processing is used Water uses city tap-water, to meet drinking water standard.Every processing machine daily when small (24) with about 100-120 cubes of water Rice, calculates accordingly, and the annual seaweed processing water consumption in the whole nation is 7200-8640 ten thousand steres.
The seaweed processing waste water that all seaweed processing enterprises generate at present is all directly to discharge.Seaweed processing waste water mainly by The organic matters such as seaweed fragment, soluble protein and silt composition.Seaweed process time concentrates on winter-spring season, the waste water of discharge The harm of pollution environment will not be shown at that time, and with the rise of temperature, the organic matter in waste water starts to ferment, and color gradually becomes It is red, until blackening, stench is given out, adds environmental pressure.
Application publication number is 102948830 A of CN, and data of publication of application on 03 06th, 2013 is entitled " a kind of to seaweed The application for a patent for invention of the method that processing is recycled with water ", the processing for being related to seaweed processing waste water utilize, content Beverage mainly is produced by raw material of seaweed processing waste water, the statutory status of the patent application is " after application for a patent for invention is announced Deemed withdrawal ", October 29 2014 statutory status effective date.
Application publication number is 105601732 A of CN, data of publication of application on May 25th, 2016, entitled " to be processed from seaweed The application for a patent for invention of the method that phycobniliprotein is separated in waste water ", is related to and separates phycobniliprotein from seaweed processing waste water, this is specially In the specification of profit application and entitlement requests book, detail how that impurity is removed from seaweed waste water obtains phycobniliprotein, And not to isolating the waste water of phycobniliprotein for further processing or being used, also the impurity of removal is not made further It handles or is used, content is not to handle seaweed processing waste water just for the sake of obtaining phycobniliprotein.
The present invention provides direct, complete, beyond all doubt technical methods, are applied at seaweed processing waste water Reason field can make processed waste water cycling and reutilization in seaweed production process, and in waste water seaweed fragment, solubility The organic matters such as protein and silt carry out processing utilization.
The present invention is to No. 201710904765.1 patent applications of Application No. and Application No. 201711089685.1 The improvement of patent application.
The content of the invention
The problem of causing environmental pollution the invention solves direct discharging of waste water in existing seaweed process.The present invention carries Direct, complete, beyond all doubt technical method has been supplied, using the technical method seaweed processing waste water Xun Huan can have been made sharp again With, seaweed processing water resources consumption is reduced, the impurity of removal can also carry out down-stream processing with high added-value, reduce environmental pollution, Seaweed processing industry chain is elongated, is more advantageous to the cluster development of seaweed industry sustainable health development and seaweed industry.
In order to solve the above technical problems, technical solution provided by the invention is as follows:
Waste water collection tank, waste water collection tank are masonry concrete structure or steel plate structure or macromolecule Material structure.Waste water collection tank is that monomer slot can also be the conjuncted slot to communicate with one another that more than two monomer slots are formed.Waste water It is any type of without being carried out to seaweed machining machine and workshop where collecting tank build laver processing machine at the discharge outlet of workshop Transformation.
Waste water delivery pump, waste water delivery pump select noncorrosive pump, can be by the seaweed containing impurity such as seaweed fragment, silts Processing waste water is transported to next procedure.
Waste water filter press is carried out dehydrating the waste water that last process is sent, and solidity substance is made to be separated from waste water Out form filter cake, the filter cake separated there are many processing method, can directly compost, can as feed, can carry out Deep processing is as the raw material for extracting taurine, polysaccharide, protein, seaweed oil.
Separator is precipitated, the waste water that last process is separated, into precipitation separator, precipitation separator is stirred equipped with low speed Device is mixed, can separate the organic matter precipitation in waste water after adding in flocculant, flocculant can select inorganic matter to flocculate Agent, organic polymer coargulator, biological flocculant etc., the waste water after this process can be referred to as " middle water ".
Filter press is precipitated, press filtration processing, the liquid separated are carried out to the flocculate precipitate discharged in precipitation separator Substance sends precipitation separator back to, and precipitation separates again with waste water merging, and obtained filter cake is buried or is used for as solid waste Planting vegetable.
Membrane filtration system is made of the ceramic membrane of various membrane fluxs, polymer compound film, can be filtered out exhausted big in middle water Partial impurities.
Sterilization process is made of ozone sterilization and ultraviolet disinfection.
Online water quality monitoring process, is made of online water quality monitor.
Clear water storage tank and pumping system, from sterilization process come out water, kept in by clear water storage tank, according to production needs, by Clear water is pumped into production process use.
List nine systems altogether above, some systems may be incorporated in together, and some systems can be segmented further, herein Nine systematic names are enumerated as, is to be described in detail, is not just to control system quantity at nine.
Description of the drawings
Fig. 1 is flow diagram
Specific embodiment
Technical scheme is elaborated further with reference to specific embodiments and the drawings;
As shown in Figure 1, seaweed processing waste water WS1 enters waste water collection tank 1, waste water collection tank volume 500 cubic metres one, When liquid level reaches production requirement, start water pump B1, extract waste water and be fed directly to waste water filter press 2;
After waste water enters waste water filter press 2, most of water is removed, the water of removing enters precipitation separator 3, and press filtration obtains Solid content can be referred to as filter cake, filter cake is left concentratedly in filter cake storage tank LB1, collective conveyance carry out deep processing, this implementation In example, filter cake is taken as the raw material of extraction taurine, extracts the inventor of taurine patent of invention and contacting for present patent application People (the 3rd inventor) is same person;
The waste water that waste water filter press comes out enters in precipitation separator 3, and it is heavy that flocculant is added to by flocculant storage tank XN1 It is sufficiently mixed with waste water in shallow lake separator 3, and occurs with inorganic matters such as organic matters, the heavy metals such as protein, the polysaccharide in waste water Flocculation reaction generates flocculate precipitate, and flocculate precipitate is discharged by valve F1 in precipitation filter press 2-1, by press filtration point The liquid substance separated out is sent back to merge to precipitate again with waste water in precipitation separator 3 and be separated, and obtained filter cake is stored in filter cake In storage tank LB2, filter cake can regard solid waste and bury, and can be used for planting vegetable, and flocculant uses in the present embodiment Biopolymer chelating agent, flocculation chitin;
Middle water after flocculation sediment enters membrane filtration process 4, and the present embodiment is answered using ceramic membrane and macromolecule Close film integrated system associated with film;
Water after membrane filtration process, into ozone sterilization process 5, ozone in water content is controlled in 0.1g/L--- 0.4g/L, keeps concentration 5 minutes;
By the water of ozone sterilization process, into ultraviolet disinfection process 6, ultraviolet radiation intensity is controlled in 20mW/ cm2---40mW/cm2, 5 seconds time;
Water quality is by online water quality monitoring system 7, on-line uninterruption monitoring;
By the water of ultraviolet disinfection process, into clear water storage tank 8, being sent to seaweed workshop by clarified water pump B2 makes With, Drinking Water can also be regarded, it can also be as the industrial water of seaweed deep processing;
Above embodiment is used for illustrative purposes only rather than limitation of the present invention, the technology in relation to technical field The various change or replacement that personnel are made in the case where not departing from the invention spirit and scope, are based even on this hair Bright deteriorates technical solution, should all belong to the scope of protection of the present invention.

Claims (6)

1. the circulation comprehensive of seaweed processing waste water utilizes system and technical method, the described method comprises the following steps:The system by Waste water collection tank, waste water delivery pump, waste water filter press, precipitation separator, precipitation filter press, membrane filtration system, sterilization process, Line water quality monitoring process, clear water storage tank pumping system are formed.
(1) waste water collection tank:Waste water collection tank is masonry concrete structure or steel plate structure or macromolecule Material structure.Waste water collection tank is that monomer slot can also be the conjuncted slot to communicate with one another that more than two monomer slots are formed.Waste water It is any type of without being carried out to seaweed machining machine and workshop where collecting tank build laver processing machine at the discharge outlet of workshop Transformation.
(2) waste water delivery pump:Waste water delivery pump selects noncorrosive pump.
(3) waste water filter press:Select plate and frame filter press and centrifuge.
(4) separator is precipitated:Precipitation separator has stirring at low speed device to promote flocculation reaction.
(5) filter press is precipitated:Select plate and frame filter press and centrifuge.
(6) membrane filtration system:For film integrated system associated with ceramic membrane and polymer compound film.
(7) sterilization process:It is made of ozone sterilizer and ultraviolet sterilizer.
(8) online water quality monitoring process:It is made of online water quality monitor.
(9) clear water storage tank pumping system:It is made of clear water storage tank, clarified water pump, metering device.
2. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: The waste water that seaweed processing generates, the waste water including being generated during processing Porphyra yezoensis, waste water, bag including being generated during processing porphyra haitanensis Include process other Porphyra algae when generate waste water, including processing other algae when (such as kelp) generate waste water.
3. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: The waste water of seaweed generation is processed after the system is handled, can be reused directly in seaweed process, can be worked as and do manual labour Drinking water, the industrial water that seaweed deep processing can be regarded.
4. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: The filter cake that waste water filter press 2 generates can be as extraction taurine, extraction protein, extraction polysaccharide, the raw material for extracting seaweed oil; Feed can also be used as after drying;Feed addictive can also be regarded;Can also directly compost be processed into Crop fertilizer.
5. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: The flocculant used in precipitation separator 3, by being preferably flocculation chitin.
6. the circulation comprehensive of seaweed processing waste water according to claim 1 utilizes system and technical method, it is characterised in that: The flocculate precipitate generated in precipitation separator 3 is sent to precipitation filter press 2-1 and carries out press filtration, and it is heavy that obtained liquid substance is sent to Shallow lake separator 3 merges precipitation again with waste water and separates, and obtained filter cake buries as solid waste or for planting vegetable.
CN201711324146.1A 2017-11-30 2017-11-30 The circulation comprehensive of seaweed processing waste water utilizes system and technical method Pending CN108101277A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108947046A (en) * 2018-06-29 2018-12-07 连云港紫金海藻产业研究发展中心 The circulation comprehensive of seaweed processing waste water utilizes system and technical method
CN112079475A (en) * 2020-07-31 2020-12-15 张家港市大新污水处理有限公司 Low-energy-consumption reclaimed water recycling production process

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004358343A (en) * 2003-06-04 2004-12-24 Yanmar Co Ltd Recycling water generation device, and recycling water generation method
CN101103835A (en) * 2007-07-24 2008-01-16 宁波大学 Cleaning device used in laver processing course and its cleaning method
CN102948830A (en) * 2011-08-30 2013-03-06 苏州思维德生物科技有限公司 Method for recycling water in laver processing
CN105293812A (en) * 2014-06-23 2016-02-03 高嵩 Sewage treatment method suitable for seaweed processing industry
CN105601732A (en) * 2016-03-30 2016-05-25 南通中国科学院海洋研究所海洋科学与技术研究发展中心 Method for separating phycobiliprotein from laver processing wastewater

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004358343A (en) * 2003-06-04 2004-12-24 Yanmar Co Ltd Recycling water generation device, and recycling water generation method
CN101103835A (en) * 2007-07-24 2008-01-16 宁波大学 Cleaning device used in laver processing course and its cleaning method
CN102948830A (en) * 2011-08-30 2013-03-06 苏州思维德生物科技有限公司 Method for recycling water in laver processing
CN105293812A (en) * 2014-06-23 2016-02-03 高嵩 Sewage treatment method suitable for seaweed processing industry
CN105601732A (en) * 2016-03-30 2016-05-25 南通中国科学院海洋研究所海洋科学与技术研究发展中心 Method for separating phycobiliprotein from laver processing wastewater

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108947046A (en) * 2018-06-29 2018-12-07 连云港紫金海藻产业研究发展中心 The circulation comprehensive of seaweed processing waste water utilizes system and technical method
CN112079475A (en) * 2020-07-31 2020-12-15 张家港市大新污水处理有限公司 Low-energy-consumption reclaimed water recycling production process

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Application publication date: 20180601