CN107853321A - A kind of Recompounded pesticide effervescent tablet - Google Patents
A kind of Recompounded pesticide effervescent tablet Download PDFInfo
- Publication number
- CN107853321A CN107853321A CN201711054701.3A CN201711054701A CN107853321A CN 107853321 A CN107853321 A CN 107853321A CN 201711054701 A CN201711054701 A CN 201711054701A CN 107853321 A CN107853321 A CN 107853321A
- Authority
- CN
- China
- Prior art keywords
- parts
- effervescent tablet
- pesticide
- weight
- recompounded pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000575 pesticide Substances 0.000 title claims abstract description 32
- 239000007938 effervescent tablet Substances 0.000 title claims abstract description 19
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004480 active ingredient Substances 0.000 claims abstract description 8
- -1 glidant Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 6
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 4
- 239000002270 dispersing agent Substances 0.000 claims abstract description 4
- 239000000945 filler Substances 0.000 claims abstract description 4
- 239000011973 solid acid Substances 0.000 claims abstract description 4
- 238000009736 wetting Methods 0.000 claims abstract description 4
- 239000011230 binding agent Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000002574 poison Substances 0.000 claims description 2
- 231100000614 poison Toxicity 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 240000000111 Saccharum officinarum Species 0.000 description 15
- 235000007201 Saccharum officinarum Nutrition 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 7
- 241000238631 Hexapoda Species 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 description 2
- 241000134979 Ceratovacuna lanigera Species 0.000 description 2
- 239000005888 Clothianidin Substances 0.000 description 2
- 241000122106 Diatraea saccharalis Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 241001515929 Fulmekiola serrata Species 0.000 description 2
- 241000256602 Isoptera Species 0.000 description 2
- 241000270708 Testudinidae Species 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000002363 herbicidal effect Effects 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- MTXSIJUGVMTTMU-UHFFFAOYSA-N Neonicotine Natural products N1CCCCC1C1=CC=CN=C1 MTXSIJUGVMTTMU-UHFFFAOYSA-N 0.000 description 1
- VXMNDQDDWDDKOQ-UHFFFAOYSA-N Pyrazosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=CC=2C(O)=O)C)=N1 VXMNDQDDWDDKOQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 230000035987 intoxication Effects 0.000 description 1
- 231100000566 intoxication Toxicity 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- NNKVPIKMPCQWCG-UHFFFAOYSA-N methamidophos Chemical compound COP(N)(=O)SC NNKVPIKMPCQWCG-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/04—Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Recompounded pesticide effervescent tablet, it is formulated by 60% pesticide active ingredient and 40% auxiliary agent；Wherein, pesticide active ingredient includes following parts by weight of component：67 parts of left-handed α terpinols, 3 parts of Hostathions, 25 36 portions of chlopyrifos, 59 parts of indoxacarbs；Described auxiliary agent includes two kinds or two or more mixtures in solid acid, carbon dioxide source, wetting dispersing agent, glidant, binding agent, drier and filler.
Description
Technical field
The invention belongs to agriculture field, especially a kind of Recompounded pesticide effervescent tablet.
Background technology
Sugarcane borer, sugarcane tortoise, sugar cane cottony aphid, Sugarcane Thrips, sugarcane root prionid and termite are the primary pest in sugarcane production, such as
Fruit preventing and treating is improper will to be caused sugarcane to drop in production over a large area and reduce sugarcane quality.In the preventing and treating of Sugarcane Pests, sugarcane grower often makes
Prevented and treated with high-toxic pesticide, it is annual caused by intoxication accident it is of common occurrence, therefore China has put into effect a series of limit and has used high poison
Pesticide Policies.The situation disabled comprehensively is faced for high-toxic pesticides such as acephatemet, carbofuran, omethoates, absorbability is promoted in exploitation
Good, efficient, less toxic, environmentally friendly novel pesticide substitutes high-toxic pesticide and seems very urgent in current sugarcane production.On the other hand, by
Grown in sugarcane breeding time, fertilizer requirement is big, and a large amount of artificially applying fertilizers are needed in sugarcane production.The agricultures such as desinsection, fertilising business workload is big, consumption
Duration, the problem of adding agriculture production cost be present.Neonicotine pesticide clothianidin and organophosphorus insecticides chlopyrifos
It is two very important kinds in low-toxin farm chemicals, can is that sugarcane production improves nutrition using Hostathion, chlopyrifos research and development
The anti-sugarcane medicine fertilizer got rid of insects of and can has very great practical significance.
Effervescent tablet technology is applied in medical pharmacy, to phase earlier 1970s Japan start by
Effervescent tablet technology is applied in formulations of pesticide processing.China also begins to the research of this respect in recent years, currently on the market
The pesticide effervescence piece for beginning with several kinds is sold, the 18% benzyl dichloro effervescent tablet produced such as Red Sun Group Co., Ltd.
Herbicide, 20% pyrazosulfuron effervescent tablet of Anhui chemical research institute production.But current effervescent tablet single varieties, have
Kind herbicide controlling spectrum to be also present narrow, it is dangerous to rice, the shortcomings that being not suitable for using in South Rice Region of China.
The content of the invention
For above-mentioned deficiency, the present invention is intended to provide a kind of delay Recompounded pesticide effervescent tablet caused by the resistance to the action of a drug of insect
Agent.
In order to realize above-mentioned technique effect, technical scheme provided by the invention is such：A kind of Recompounded pesticide effervescent tablet
Agent, it is formulated by 60% pesticide active ingredient and 40% auxiliary agent；
Wherein, pesticide active ingredient includes following parts by weight of component：6-7 part levogyrate alpha-terpineols, 3 parts of Hostathions, 25-36
Part chlopyrifos, 5-9 part indoxacarbs；Described auxiliary agent includes solid acid, carbon dioxide source, wetting dispersing agent, glidant, bonding
Two kinds or two or more mixtures in agent, drier and filler.
Preferably, the pesticide active ingredient includes following parts by weight of component：6 parts of levogyrate alpha-terpineols, 3 parts of Hostathions,
27-35 part chlopyrifos, 6-8 part indoxacarbs.
Wherein, in addition to the defoamer of 2-4 parts by weight, the thickener of 2-4 parts by weight, 2-4 parts by weight antifreezing agent in one
Kind or more than one combination.
Wherein, described defoamer is polypropylene glycerol aether, polyether-modified silicon or silicone emulsion.
Wherein, described antifreezing agent is polyethylene glycol, glycerine or sorbierite.
Wherein, described thickener is polyvinyl alcohol, dispersed silica or alumina silicate.
Recompounded pesticide of the present invention can be applicable to preventing and treating sugarcane borer, sugar cane cottony aphid, Sugarcane Thrips, sugarcane tortoise, sugarcane root saw day
Among the pest and disease damage such as ox and termite.
Recompounded pesticide of the present invention mutually has synergistic function, not only maintains many excellent of former agricultural chemicals single dose
Point, but also each component concentration in the case where activity is not lost in mixture is reduced, increased so as to the activity of mixture
Add.
Agricultural chemicals in the present invention is a kind of efficiently killing above and below ground insect preparation.Clothianidin has excellent Uptake and translocation
Property, it is easy to each position of plant is transmitted to by the Root Absorption of sugarcane, thus to sugarcane aerial part and the underground part of causing harm
The insect divided all plays killing action.
The present invention effervescent table as agricultural chemical the characteristics of be：Efficiently, wide spectrum, easy to use, accurate measurement, a drug is with regard to energy
Paddy field weed effectively is prevented and kill off, low toxicity highly safe to rice seedlings is good with environment blending
Embodiment
With reference to embodiment, the claim of the present invention is described in further detail, but not formed pair
Any restrictions of the present invention, any limited number of time modification made in the claims in the present invention protection domain, still the present invention's
In claims.
Embodiment 1
A kind of Recompounded pesticide effervescent tablet, including following parts by weight of component：6 parts of levogyrate alpha-terpineols, 3 parts of Hostathions, 36
Part chlopyrifos, 5 parts of indoxacarbs.
Wherein, in addition to the defoamer of 4 parts by weight, the thickener of 2 parts by weight, 4 parts by weight antifreezing agent in it is a kind of or
More than one combination.
Wherein, described defoamer is polypropylene glycerol aether, polyether-modified silicon or silicone emulsion.
Wherein, described antifreezing agent is polyethylene glycol, glycerine or sorbierite.
Wherein, described thickener is polyvinyl alcohol, dispersed silica or alumina silicate.
Embodiment 2
A kind of Recompounded pesticide effervescent tablet, including following parts by weight of component：6 parts of levogyrate alpha-terpineols, 3 parts of Hostathions, 27
Part chlopyrifos, 6 parts of indoxacarbs.
Wherein, in addition to the defoamer of 4 parts by weight, the thickener of 2 parts by weight, 4 parts by weight antifreezing agent in it is a kind of or
More than one combination.
Wherein, described defoamer is polypropylene glycerol aether, polyether-modified silicon or silicone emulsion.
Wherein, described antifreezing agent is polyethylene glycol, glycerine or sorbierite.
Wherein, described thickener is polyvinyl alcohol, dispersed silica or alumina silicate.
In embodiment 1-2, in addition to solid acid, carbon dioxide source, wetting dispersing agent, glidant, binding agent, drier and
Two kinds or two or more mixtures in filler.
Above-described is only presently preferred embodiments of the present invention, all timess done in the range of the spirit and principles in the present invention
What modifications, equivalent substitutions and improvements etc., should be included within the scope of the present invention.
Claims (6)
1. a kind of Recompounded pesticide effervescent tablet, it is characterised in that be formulated by 60% pesticide active ingredient and 40% auxiliary agent；
Wherein, pesticide active ingredient includes following parts by weight of component：6-7 part levogyrate alpha-terpineols, 3 parts of Hostathions, 25-36 parts poison
Dead tick, 5-9 part indoxacarbs；Described auxiliary agent includes solid acid, carbon dioxide source, wetting dispersing agent, glidant, binding agent, dry
Two kinds or two or more mixtures in drying prescription and filler.
2. a kind of Recompounded pesticide effervescent tablet according to claim 1, it is characterised in that the pesticide active ingredient includes
Following parts by weight of component：6 parts of levogyrate alpha-terpineols, 3 parts of Hostathions, 27-35 part chlopyrifos, 6-8 part indoxacarbs.
3. according to a kind of Recompounded pesticide effervescent tablet described in any one of claim 1 or 2, it is characterised in that：Also include 2-4 weights
Measure the defoamer of part, the thickener of 2-4 parts by weight, 2-4 parts by weight antifreezing agent in one or more than one kinds of combination.
4. a kind of Recompounded pesticide effervescent tablet according to claim 3, it is characterised in that described defoamer is polyoxy third
Alkene glycerin ether, polyether-modified silicon or silicone emulsion.
5. a kind of Recompounded pesticide effervescent tablet according to claim 3, it is characterised in that described antifreezing agent is poly- second two
Alcohol, glycerine or sorbierite.
6. a kind of Recompounded pesticide effervescent tablet according to claim 3, it is characterised in that described thickener is polyethylene
Alcohol, dispersed silica or alumina silicate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711054701.3A CN107853321A (en) | 2017-11-01 | 2017-11-01 | A kind of Recompounded pesticide effervescent tablet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711054701.3A CN107853321A (en) | 2017-11-01 | 2017-11-01 | A kind of Recompounded pesticide effervescent tablet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107853321A true CN107853321A (en) | 2018-03-30 |
Family
ID=61697490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711054701.3A Pending CN107853321A (en) | 2017-11-01 | 2017-11-01 | A kind of Recompounded pesticide effervescent tablet |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107853321A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1358436A (en) * | 2000-12-15 | 2002-07-17 | 广西金燕子农药有限公司 | Chlorpyrifos and triazophos compound pesticide |
| CN102177906A (en) * | 2011-03-16 | 2011-09-14 | 广西壮族自治区化工研究院 | Herbicide effervescent tablets and preparation method thereof |
| CN104012570A (en) * | 2014-06-27 | 2014-09-03 | 济南东泽生物科技有限公司 | Indoxacarb-chlorpyrifos suspoemulsion and preparation method thereof |
| CN104126605A (en) * | 2014-07-07 | 2014-11-05 | 广西三晶化工科技有限公司 | Compound pesticide |
-
2017
- 2017-11-01 CN CN201711054701.3A patent/CN107853321A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1358436A (en) * | 2000-12-15 | 2002-07-17 | 广西金燕子农药有限公司 | Chlorpyrifos and triazophos compound pesticide |
| CN102177906A (en) * | 2011-03-16 | 2011-09-14 | 广西壮族自治区化工研究院 | Herbicide effervescent tablets and preparation method thereof |
| CN104012570A (en) * | 2014-06-27 | 2014-09-03 | 济南东泽生物科技有限公司 | Indoxacarb-chlorpyrifos suspoemulsion and preparation method thereof |
| CN104126605A (en) * | 2014-07-07 | 2014-11-05 | 广西三晶化工科技有限公司 | Compound pesticide |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20180330 |