CN107828288A - A kind of anti-formaldehyde type interior wall sealing wax and preparation method thereof - Google Patents
A kind of anti-formaldehyde type interior wall sealing wax and preparation method thereof Download PDFInfo
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- CN107828288A CN107828288A CN201711082408.8A CN201711082408A CN107828288A CN 107828288 A CN107828288 A CN 107828288A CN 201711082408 A CN201711082408 A CN 201711082408A CN 107828288 A CN107828288 A CN 107828288A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of anti-formaldehyde type interior wall sealing wax, belongs to technical field of coatings.The anti-formaldehyde type interior wall sealing wax, by percentage to the quality, is prepared by the following raw material:Acrylic emulsion 20 30%, titanium dioxide 21 23%, kaolin 5 7%, coarse whiting 8 12%, MCC modified calcium carbonates 2 4%, anti-formaldehyde powder 6 8%, environmentally friendly cosolvent 0.8 1%, coalescents 1 1.5%, wetting agent 0.1 0.2%, multi-functional pH adjusting agent 0.1 0.2%, dispersant 0.5 0.7%, cellulose 0.3 0.5%, defoamer 0.1 0.3%, preservative 0.1 0.3%, mould inhibitor 0.5 0.8%, thickener 0.2 0.3%, water 20 25%.Anti- formaldehyde type interior wall sealing wax of the present invention has prominent purifying formaldehyde efficiency and continued effectiveness.
Description
Technical field
The present invention relates to a kind of anti-formaldehyde type interior wall sealing wax and preparation method thereof, belong to paint field.
Background technology
Anti- methanal paint is the new indoor finishing material developed newest in recent years.Expanding economy promotes people
The raising of environmental consciousness, environmental quality issues receive the extensive concern of people, and the research and development success of anti-methanal paint effectively releases
Puzzlement, worry of the consumption to interior decoration selection.Consumer a large amount of finishing materials use improve quality of the life while,
Also result in the continuous deterioration of IAQ, the harm to human body, particularly poor to resistance old man, children and pregnant woman
Harm, it has also become the hot issue of concern.
Anti- methanal paint is the environment-friendly materials of indoor internal wall finishing, can effectively reduce the main pollution of room air, subtract
Few finishing brings our harm.Anti- formaldehyde interiro wall latex paint in the market more using poromerics, acrylic emulsion and
Nano-photocatalyst prepares anti-formaldehyde interior wall coating as functional material, prepared emulsion paint there are still gloss it is higher,
The problem of covering power is slightly worse, in addition, also there is paint film spot-resistant it is poor, decompose that indoor formaldehyde persistence is poor etc. to be lacked
Point.In view of interior decoration emulsion paint quality requirement is improved for country and enhancing of the people to environment and health sense of relation,
The interior decoration emulsion paint for researching and developing anti-formaldehyde is the problem that the field technology worker facing is badly in need of solving.
The content of the invention
The technical problems to be solved by the invention are that prior art moderate resistance formaldehyde-latex paint has that glossiness is higher, covering power
Difference, paint film spot-resistant difference and decompose indoor formaldehyde persistence it is poor the problems such as, and then provide one kind can effectively anti-formaldehyde and
Anti- formaldehyde type interior wall sealing wax of the good physical properties such as glossiness, covering power, paint film spot-resistant and preparation method thereof.
In order to solve the above-mentioned technical problem, the invention provides a kind of anti-formaldehyde type interior wall sealing wax, by percentage to the quality,
It is prepared by following components:
Further, the anti-formaldehyde type interior wall sealing wax, by percentage to the quality, is prepared by following components:
Further, the MCC modified calcium carbonates average grain diameter is 10~20um, and specific surface area is 30~50 ㎡/g.
Further, the acrylic emulsion is the emulsion of styrene-acrylic copolymer, and its solid content is 47 ± 1,
MFT (i.e. MFFT) is 22-25 DEG C, resistancet of rost≤0 DEG C.
Further, the anti-formaldehyde powder is the net function of odor TK401 of Shanghai Shizhan Chemical Technology Co., Ltd.'s production, should
Net function of odor TK401 is the nanometer grade powder material using inorganic crosslinking technology, and its dioxide-containing silica 40%, titanium dioxide contains
Amount 20%, alumina content 20%, surplus are except the active ingredient of formaldehyde.
Further, the coalescents are Lauryl Alcohol ester;The titanium dioxide is surface using the processing of sial coating
Titanium white powder pigment;The kaolin is the calcined kaolin that particle diameter is 4000 mesh;The coarse whiting is the heavy carbon that particle diameter is 800 mesh
Sour calcium.
Further, present invention also offers the preparation method of the anti-formaldehyde type interior wall sealing wax, comprise the following steps:
(1) first the water of precise is added in reactor, in the state of low speed 400-600r/min, sequentially adds fibre
Dimension element, multi-functional pH adjusting agent, then the scattered 15-20min of high speed 1000-1200r/min, form gel state;
(2) and then environmentally friendly cosolvent is sequentially added, dispersant, wetting agent, defoamer, preservative, mould inhibitor, adds and complete
Afterwards, continue to stir 1-2min under 700-900r/min middling speed states;
(3) titanium dioxide is sequentially added, kaolin, coarse whiting, MCC modified calcium carbonates, anti-formaldehyde powder, improves rotating speed to 1000-
1200r/min, disperse 30-35 minutes to fineness≤55um;
(4) acrylic emulsion is added under low speed 400-600r/min states, coalescents, 2-3min is stirred, adds
It is 100-105KU that thickener, which is adjusted to the viscosity at 23 ± 2 DEG C, is stirred for 10-15 minutes, and anti-formaldehyde type interior wall sealing wax is made.
The present invention has the following advantages that compared with prior art:
(1) anti-formaldehyde interior wall sealing wax of the present invention, using use environmentally friendly solvent polymerizing styrene acrylic ester type emulsion as
Base-material, adds MCC modified calcium carbonates and anti-formaldehyde powder, and three's synergy can be can farthest ensure anti-formaldehyde powder
Photocatalyst effect can permanent releasing negative oxygen ion and hydroxyl radical free radical, so as to effective decomposing formaldehyde, there is product and protrude
Purifying formaldehyde efficiency and continued effectiveness.In addition, under the specific conditions of mixture ratios of composition of the present invention, the anti-first that is prepared
Aldehyde type interior wall sealing wax also has very high extinction effect, and improves scrub performance, lifts covering power, reduces light pollution to people
The harm of body, meet national bull's eye product requirement, belong to environmental type product.
(2) anti-formaldehyde interior wall sealing wax of the present invention, using use environmentally friendly solvent polymerizing styrene acrylic ester type emulsion as
Base-material, coordinate low-shear viscosity, high yield polyurethanes thickener, there is the regulation thixotropic performance of product, improve spray
Nebulization efficiency and the parcel ability to color stuffing are applied, improves coating surface hardness and feel.
Embodiment
With reference to embodiments, the present invention is further described in detail, but is not limited to this.
Raw material employed in following embodiments is as follows, is commercially available original unless otherwise specified in following raw materials
Material.
The acrylic emulsion is styrene-acrylic copolymer emulsion, and its solid content is 47 ± 1, MFFT 22-25
DEG C, resistancet of rost≤0 DEG C, such as the 7048G of BASF.
The MCC modified calcium carbonates are the MCC modified calcium carbonates of Ou meter Ya companies production, and average grain diameter is 10~20um,
Specific surface area is 30~50 ㎡/g;
The net function of odor TK401 that the anti-formaldehyde powder produces for Shanghai Shizhan Chemical Technology Co., Ltd., nanometer grade powder
Material, its dioxide-containing silica 40%, content of titanium dioxide 20%, alumina content 20%, surplus be except formaldehyde it is effective into
Point;
The coalescents are the C12 compound of 255 DEG C of boiling point;
The titanium dioxide uses the titanium white powder pigment of sial coating processing, specifically chosen bright river board-rutile-type for surface
Titanium dioxide R944;
The kaolin is the calcined kaolin that particle diameter is 4000 mesh;
The coarse whiting is the powdered whiting that particle diameter is 800 mesh.
The environmentally friendly cosolvent is one or both of propane diols or ethylene glycol;
The dispersant is the Sodium Polyacrylate dipersant that effective solid content is 40wt%;
The cellulose is hydroxyethyl cellulose, and 2wt% hydroxyethyl cellulose solution is 1500- in 25 DEG C of viscosity
2500mPa.s.;
The wetting agent is fat alcohol alkoxy compound;
The multi-functional pH adjusting agent is silicic acid potassium alcoholate class pH adjusting agent;
The defoamer agent is any one in polysiloxane-polyether copolymer type of latex type, mineral oils;
The preservative is Kathon CG class preservative;
The mould inhibitor be using imidazoles, OIT, phenylurea as main component mould proof algicide;
The thickener is the one or two that hydrophobically-modified alkali is swelled class thickener or polyurethanes thickener;
The water is ordinary tap water or underground water.
Each embodiment specific implementation formula such as table 1:
1 each embodiment of table matches
Embodiment 1
Anti- formaldehyde type interior wall sealing wax described in present embodiment, by percentage to the quality, is made up of following component:Styrene
Type the emulsion 30wt%, titanium dioxide 21wt%, kaolin 5wt% of acrylate copolymer, coarse whiting 12wt%, MCC are modified carbonic acid
Calcium 2wt%, anti-formaldehyde powder 6wt%, environmentally friendly co-solvents propylene glycol 0.8wt%, coalescents Lauryl Alcohol ester 1.2wt%, are soaked
Agent 0.1wt%, multi-functional pH adjusting agent 0.1wt%, dispersant 0.6wt%, cellulose 0.3wt%, polysiloxane-polyether copolymerization
Thing type of latex type defoamer 0.1wt%, preservative 0.1wt%, mould inhibitor 0.5wt%, polyurethanes thickener 0.2wt%, water
20wt%.
The preparation method of anti-formaldehyde type interior wall sealing wax is as follows described in the present embodiment:
(1) said ratio is pressed, precise water is added in reactor, in the state of 600r/min, is added successively by proportioning
Enter cellulose, multi-functional pH adjusting agent, 15min is then disperseed under 1200r/min rotating speeds, form gel state;
(2) said ratio is pressed, sequentially adds environmentally friendly cosolvent, dispersant, wetting agent, defoamer, preservative, mould inhibitor,
After the completion of addition, continue to stir 1min under 900r/min middling speed states;
(3) said ratio is pressed, titanium dioxide is sequentially added, kaolin, coarse whiting, MCC modified calcium carbonates, anti-formaldehyde powder, improves
Rotating speed disperses 30 minutes to fineness≤55um to 1200r/min;
(4) acrylic emulsion is added under low speed 600r/min states, coalescents, 2min is stirred, adds thickener
It is 100-105KU to be adjusted to the viscosity at 23 ± 2 DEG C, is stirred for 15 minutes, and anti-formaldehyde type interior wall sealing wax is made.
Embodiment 2
Anti- formaldehyde type interior wall sealing wax described in present embodiment, by percentage to the quality, is made up of following component:Styrene
Type the emulsion 24wt%, titanium dioxide 22wt%, kaolin 6wt% of acrylate copolymer, coarse whiting 11wt%, MCC are modified carbonic acid
Calcium 3wt%, anti-formaldehyde powder 7wt%, environmentally friendly cosolvent ethylene glycol 0.9wt%, coalescents Lauryl Alcohol ester 1.4wt%, are soaked
Agent 0.15wt%, multi-functional pH adjusting agent 0.2wt%, dispersant 0.7wt%, cellulose 0.4wt%, mineral oil defoaming agent
0.2wt%, preservative 0.2wt%, mould inhibitor 0.6wt%, polyurethanes thickener 0.25wt%, water 22wt%.
The preparation method of anti-formaldehyde type interior wall sealing wax, comprises the following steps described in above-mentioned embodiment:
(1) first the water of precise is added in reactor, in the state of low speed 500r/min, sequentially adds fiber
Element, multi-functional pH adjusting agent, then the scattered 18min of high speed 1100r/min, form gel state;
(2) and then environmentally friendly cosolvent is sequentially added, dispersant, wetting agent, defoamer, preservative, mould inhibitor, adds and complete
Afterwards, continue to stir 2min under 800r/min middling speed states;
(3) titanium dioxide is sequentially added, kaolin, coarse whiting, MCC modified calcium carbonates, anti-formaldehyde powder, improves rotating speed to 1100r/
Min, disperse 32 minutes to fineness≤55um;
(4) acrylic emulsion is added under low speed 500r/min states, coalescents, 2.5min is stirred, adds thickening
It is 100-105KU that agent, which is adjusted to the viscosity at 23 ± 2 DEG C, is stirred for 12 minutes, and anti-formaldehyde type interior wall sealing wax is made.
Embodiment 3
Anti- formaldehyde type interior wall sealing wax described in present embodiment, by percentage to the quality, is made up of following component:Styrene
Acrylate copolymer type emulsion 20wt%, titanium dioxide 23wt%, kaolin 7wt%, coarse whiting 8wt%, MCC modified calcium carbonate
4wt%, anti-formaldehyde powder 8wt%, environmentally friendly co-solvents propylene glycol 1wt%, coalescents Lauryl Alcohol ester 1wt%, wetting agent
0.2wt%, multi-functional pH adjusting agent 0.2wt%, dispersant 0.5wt%, cellulose 0.5wt%, mineral oil defoaming agent
0.3wt%, preservative 0.3wt%, mould inhibitor 0.8wt%, hydrophobically-modified alkali swelling class thickener 0.2wt%, water 25wt%.
The preparation method of anti-formaldehyde type interior wall sealing wax, comprises the following steps described in above-mentioned embodiment:
(1) first the water of precise is added in reactor, in the state of low speed 400r/min, sequentially adds fiber
Element, multi-functional pH adjusting agent, then the scattered 20min of high speed 1000r/min, form gel state;
(2) and then environmentally friendly cosolvent is sequentially added, dispersant, wetting agent, defoamer, preservative, mould inhibitor, adds and complete
Afterwards, continue to stir 2min under 800r/min middling speed states;
(3) titanium dioxide is sequentially added, kaolin, coarse whiting, MCC modified calcium carbonates, anti-formaldehyde powder, improves rotating speed to 1000r/
Min, disperse 35 minutes to fineness≤55um;
(4) acrylic emulsion is added under low speed 400r/min states, coalescents, 3min is stirred, adds thickener
It is 100-105KU to be adjusted to the viscosity at 23 ± 2 DEG C, is stirred for 10 minutes, and anti-formaldehyde type interior wall sealing wax is made.
Comparative example 1:By embodiment:The type emulsion of styrene-acrylic copolymer described in 1 all replaces with equivalent
Common styrene-acrylic emulsion RS916W, other components are constant.
Comparative example 2:It is 10~20um by the particle diameter that MCC modified calcium carbonates described in embodiment 2 all replace with equivalent, than
Surface area is 30~50 ㎡/g ordinary calcium carbonate;
Comparative example 3:Anti- formaldehyde powder described in embodiment 2 is all replaced with to the photochemical catalyst copper-doped titanium dioxide of equivalent
Powder, other components are constant.
In addition, the present invention for the anti-formaldehyde type interior wall sealing wax described in above-described embodiment 1 to embodiment 3 according to national standard GB/
T9756-2009《Resin latex dope national standard》、GB18582-2008《Indoor decorating and refurnishing materials interior wall applies
Limits of harmful substances in material》、JC/T1074-2008《Function of purifying indoor air coating material purifying property》Carry out performance inspection
Survey.The all technical measured is shown in Table 2:
The test result of table 2
From above-mentioned test result:(1) styrene-acrylic copolymer type emulsion and MCC modified calcium carbonates are to product
Abrasion resistance have a great influence, both, which act synergistically, can greatly improve the abrasion resistance of product, while both are total to anti-formaldehyde powder
Same-action, the purifying formaldehyde efficiency and purifying formaldehyde effect persistence of product can be greatly improved.(2) first of the anti-formaldehyde powder to product
Aldehyde purification efficiency and purifying formaldehyde effect persistence have considerable influence, anti-formaldehyde powder and the other components of the present invention, are necessarily matching
Under comprehensive function so that product of the present invention has prominent purifying formaldehyde efficiency and continued effectiveness.(3) using the present invention
The specific components, the anti-formaldehyde type interior wall sealing wax being prepared under specific proportioning also have a good scrubbing resistance, covering power,
Gloss is low, has more, and meets national bull's eye product requirement, belongs to environmental type product.
Obviously, above-described embodiment is only intended to clearly illustrate example, and is not the restriction to embodiment.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of change or
Change.There is no necessity and possibility to exhaust all the enbodiments, and the obvious change thus extended out or
Among changing still in the invention scope of the claims.
Claims (7)
1. a kind of anti-formaldehyde type interior wall sealing wax, it is characterised in that by percentage to the quality, be prepared by following components:
2. anti-formaldehyde type interior wall sealing wax according to claim 1, it is characterised in that by percentage to the quality, by following components
It is prepared:
3. anti-formaldehyde type interior wall sealing wax according to claim 1 or claim 2, it is characterised in that the average grain of the MCC modified calcium carbonates
Footpath is 10~20um, and specific surface area is 30~50 ㎡/g.
4. according to any anti-formaldehyde type interior wall sealing wax of claims 1 to 3, it is characterised in that the acrylic emulsion is benzene
Ethylene acrylate copolymer emulsion, its solid content are 47 ± 1wt%, and MFT is 22-25 DEG C, resistancet of rost≤0
℃。
5. according to any anti-formaldehyde type interior wall sealing wax of Claims 1 to 4, it is characterised in that the anti-formaldehyde powder is Shanghai
The TK401 of Shi Zhan Chemical Industry Science Co., Ltd.
6. according to any anti-formaldehyde type interior wall sealing wax of claims 1 to 3, it is characterised in that the coalescents are boiling point
255 DEG C of Lauryl Alcohol ester;The titanium dioxide is the titanium white powder pigment that surface uses the processing of sial coating;The kaolin is grain
Footpath is the calcined kaolin of 4000 mesh;The coarse whiting is the powdered whiting that particle diameter is 800 mesh.
7. the preparation method of any anti-formaldehyde type interior wall sealing wax of claim 1~6, comprises the following steps:
(1) first the water of precise is added in reactor, in the state of low speed 400-600r/min, sequentially adds fiber
Element, multi-functional pH adjusting agent, then the scattered 15-20min of high speed 1000-1200r/min, form gel state;
(2) and then environmentally friendly cosolvent is sequentially added, dispersant, wetting agent, defoamer, preservative, mould inhibitor, after the completion of addition,
Continue to stir 1-2min under 700-900r/min middling speed states;
(3) titanium dioxide is sequentially added, kaolin, coarse whiting, MCC modified calcium carbonates, anti-formaldehyde powder, improves rotating speed to 1000-
1200r/min, disperse 30-35 minutes to fineness≤55um;
(4) acrylic emulsion is added under low speed 400-600r/min states, coalescents, 2-3min is stirred, adds thickening
It is 100-105KU that agent, which is adjusted to the viscosity at 23 ± 2 DEG C, is stirred for 10-15 minutes, and anti-formaldehyde type interior wall sealing wax is made.
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---|---|---|---|---|
CN1673294A (en) * | 2004-12-16 | 2005-09-28 | 许绍凰 | Nanometer nagative ion inner wall latex paint |
CN103756467A (en) * | 2014-01-10 | 2014-04-30 | 大连工业大学 | Preparation method of environment-friendly interior wall top coating for preforming catalytic degradation on formaldehyde in air during photocatalysis and chemical oxidation |
CN106590201A (en) * | 2016-12-14 | 2017-04-26 | 广东维拓化工股份有限公司 | Special-effect formaldehyde and smell removal wall finish and preparation method thereof |
CN107118627A (en) * | 2017-05-11 | 2017-09-01 | 东莞市金基环保科技有限公司 | Ultralow radiation removes formaldehyde low-carbon health coating |
-
2017
- 2017-11-07 CN CN201711082408.8A patent/CN107828288A/en active Pending
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1673294A (en) * | 2004-12-16 | 2005-09-28 | 许绍凰 | Nanometer nagative ion inner wall latex paint |
CN103756467A (en) * | 2014-01-10 | 2014-04-30 | 大连工业大学 | Preparation method of environment-friendly interior wall top coating for preforming catalytic degradation on formaldehyde in air during photocatalysis and chemical oxidation |
CN106590201A (en) * | 2016-12-14 | 2017-04-26 | 广东维拓化工股份有限公司 | Special-effect formaldehyde and smell removal wall finish and preparation method thereof |
CN107118627A (en) * | 2017-05-11 | 2017-09-01 | 东莞市金基环保科技有限公司 | Ultralow radiation removes formaldehyde low-carbon health coating |
Non-Patent Citations (1)
Title |
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李干佐等: "《表面活性剂在能源和选矿工业中的应用》", 30 April 2002, 中国轻工业出版社 * |
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Application publication date: 20180323 |