CN107828173A - A kind of TV remote controller shell ABS material - Google Patents
A kind of TV remote controller shell ABS material Download PDFInfo
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- CN107828173A CN107828173A CN201710896159.XA CN201710896159A CN107828173A CN 107828173 A CN107828173 A CN 107828173A CN 201710896159 A CN201710896159 A CN 201710896159A CN 107828173 A CN107828173 A CN 107828173A
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- remote controller
- rubber
- controller shell
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/04—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of TV remote controller shell ABS material, its raw material includes by weight：70 80 parts of major ingredient, 12 parts of TBHP, 2 0.5 1.2 parts of mercapto alcohol radical benzothiazoles, 12 parts of tetramethylthiuram monosulfide, 60 70 parts of filler, 12 parts of titanate coupling agent, 0.4 1 parts of coumarone indene resin, 0.2 0.8 parts of pine tar, 1 1.6 parts of epoxidized soybean oil, 12 parts of toughener, 12 parts of antioxidant BLE, 12 parts of age resistor ODA.Inventive formulation is simple, and service life length, impact strength is high, and drop resistant performance is good, is less prone to aging yellowing phenomenon, can effectively reduce such as illumination, the injury of temperature, humidity, and is easier scattered, can effectively reduce the temperature of expressing technique.
Description
Technical field
The present invention relates to TV remote controller technical field, more particularly to a kind of TV remote controller shell ABS material.
Background technology
ABS, Chinese are acrylonitrile-butadiene-styrene copolymer, because with good comprehensive physical performance, good
The advantages that chemical resistance well, easy-formation are processed, are cheap, and bloom effect can be realized, thus it is widely used in electricity
The shell of sub- equipment, such as be used as remote controller casing, due to long-time and human contact, on hand caused sweat cause shell oxygen
Change, yellowing occur, it would be highly desirable to solve.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of TV remote controller shell ABS material, matches somebody with somebody
Side is simple, and service life length, impact strength is high, and drop resistant performance is good, is less prone to aging yellowing phenomenon, can effectively reduce such as light
According to, the injury of temperature, humidity, and it is easier scattered, can effectively reduces the temperature of expressing technique.
A kind of TV remote controller shell ABS material proposed by the present invention, its raw material include by weight：Major ingredient 70-80
Part, TBHP 1-2 parts, MBT 0.5-1.2 parts, tetramethylthiuram monosulfide 1-2 parts, filling
Agent 60-70 parts, titanate coupling agent 1-2 parts, coumarone indene resin 0.4-1 parts, pine tar 0.2-0.8 parts, epoxidized soybean oil 1-1.6
Part, toughener 1-2 parts, antioxidant BLE 1-2 parts, age resistor ODA 1-2 parts.
Preferably, filler includes by weight：Powdered whiting 45-55 parts, tossa 2-6 parts, zeolite powder 2-5
Part, calcined kaolin 4-10 parts.
Preferably, major ingredient includes by weight：ABS resin 40-60 parts, modified EPT rubber 15-24 parts.
Preferably, modified EPT rubber is prepared using following technique：Ethylene propylene diene rubber dissolving is added into toluene
Completely, styrene, acrylonitrile are added, heating stirring, methyl ethyl ketone peroxide is added and continues to stir, under nitrogen protection, heating is stirred
Mix, absolute ethyl alcohol is added dropwise, filter, washing, be dried to obtain modified EPT rubber.
Preferably, modified EPT rubber is prepared using following technique：Ethylene propylene diene rubber dissolving is added into toluene
Completely, styrene, acrylonitrile are added, is warming up to 40-50 DEG C of stirring 20-40min, methyl ethyl ketone peroxide is added and continues to stir 4-
12min, under nitrogen protection, 120-135 DEG C of stirring 15-35min is warming up to, absolute ethyl alcohol is added dropwise, filters, washing, is dried to obtain
Modified EPT rubber.
Preferably, modified EPT rubber is prepared using following technique：By weight 10- is added into 100 parts of toluene
18 parts of ethylene propylene diene rubber dissolvings are complete, add 4-12 parts styrene, 5-15 part acrylonitrile, are warming up to 40-50 DEG C of stirring 20-
40min, add 0.5-1.2 part methyl ethyl ketone peroxides and continue to stir 4-12min, under nitrogen protection, be warming up to 120-135 DEG C of stirring
15-35min, 100-140 part absolute ethyl alcohols are added dropwise, filter, washing, be dried to obtain modified EPT rubber.
Inventive formulation is simple, and service life length, impact strength is high, and drop resistant performance is good, and it is existing to be less prone to aging jaundice
As, can effectively it reduce such as illumination, the injury of temperature, humidity, and it is easier scattered, it can effectively reduce the temperature of expressing technique.
In the modified EPT rubber of the present invention, ethylene propylene diene rubber is dissolved in toluene, uses ethylene propylene diene rubber as grafting
Matrix, its strand main chain are free of double bond, and only a small amount of side base contains double bond, and addition styrene, acrylonitrile are grafted monomers, after solidification
It is not oxidizable and there is excellent thermo oxidative aging, anti-Weather and anti-aging xanthochromia performance；Modified EPT rubber with
It is major ingredient that ABS resin, which coordinates, and after cured, not only crosslinking rate is moderate, is less prone to incipient scorch phenomenon, and can suppress polymer
Chain rupture, elongation at break is good with tensile strength, and coumarone indene resin, pine tar, epoxidized soybean oil can promote major ingredient and filler
Between it is scattered, surface com-patibilising effect is good, reaches with major ingredient and dissolves each other well, make it is of the invention there is less linear expansion coefficient,
Larger bending modulus, material stiffness is good, and in the effect of titanate coupling agent, adhesion is strong to each other, before toughness is ensured
Put, hardness is higher, and the specific structure of formation make it that shock resistance is good when stress of the present invention acts on, and meets remote controller casing
Demand.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of TV remote controller shell ABS material, its raw material include by weight：70 parts of major ingredient, tert-butyl hydroperoxide
2 parts of hydrogen, 0.5 part of MBT, 2 parts of tetramethylthiuram monosulfide, 60 parts of filler, 2 parts of titanate coupling agent,
0.4 part of coumarone indene resin, 0.8 part of pine tar, 1 part of epoxidized soybean oil, 2 parts of toughener, 1 part of antioxidant BLE, age resistor ODA2
Part.
Embodiment 2
A kind of TV remote controller shell ABS material, its raw material include by weight：80 parts of major ingredient, tert-butyl hydroperoxide
1 part of hydrogen, 1.2 parts of MBT, 1 part of tetramethylthiuram monosulfide, 70 parts of filler, 1 part of titanate coupling agent,
1 part of coumarone indene resin, 0.2 part of pine tar, 1.6 parts of epoxidized soybean oil, 1 part of toughener, 2 parts of antioxidant BLE, age resistor ODA 1
Part.
Major ingredient includes by weight：40 parts of ABS resin, 24 parts of modified EPT rubber.Filler includes by weight：
45 parts of powdered whiting, 6 parts of tossa, 2 parts of zeolite powder, 10 parts of calcined kaolin.
Modified EPT rubber is prepared using following technique：It is complete that ethylene propylene diene rubber dissolving is added into toluene, then
Styrene, acrylonitrile are added, heating stirring, methyl ethyl ketone peroxide is added and continues to stir, under nitrogen protection, heating stirring, is added dropwise
Absolute ethyl alcohol, filter, washing, be dried to obtain modified EPT rubber.
Embodiment 3
A kind of TV remote controller shell ABS material, its raw material include by weight：72 parts of major ingredient, tert-butyl hydroperoxide
1.8 parts of hydrogen, 0.6 part of MBT, 1.8 parts of tetramethylthiuram monosulfide, 63 parts of filler, titanate coupling agent
1.8 parts, 0.6 part of coumarone indene resin, 0.6 part of pine tar, 1.2 parts of epoxidized soybean oil, 1.6 parts of toughener, antioxidant BLE 1.2
Part, 1.8 parts of age resistor ODA.
Major ingredient includes by weight：60 parts of ABS resin, 15 parts of modified EPT rubber.Filler includes by weight：
55 parts of powdered whiting, 2 parts of tossa, 5 parts of zeolite powder, 4 parts of calcined kaolin.
Modified EPT rubber is prepared using following technique：It is complete that ethylene propylene diene rubber dissolving is added into toluene, then
Styrene, acrylonitrile are added, is warming up to 45 DEG C of stirring 30min, methyl ethyl ketone peroxide is added and continues to stir 8min, nitrogen protection
Under, 128 DEG C of stirring 25min are warming up to, absolute ethyl alcohol is added dropwise, filters, washing, is dried to obtain modified EPT rubber.
Embodiment 4
A kind of TV remote controller shell ABS material, its raw material include by weight：78 parts of major ingredient, tert-butyl hydroperoxide
1.2 parts of hydrogen, 1 part of MBT, 1.2 parts of tetramethylthiuram monosulfide, 67 parts of filler, titanate coupling agent
1.4 parts, 0.8 part of coumarone indene resin, 0.4 part of pine tar, 1.4 parts of epoxidized soybean oil, 1.4 parts of toughener, antioxidant BLE 1.6
Part, 1.4 parts of age resistor ODA.
Major ingredient includes by weight：45 parts of ABS resin, 22 parts of modified EPT rubber.Filler includes by weight：
48 parts of powdered whiting, 5 parts of tossa, 3 parts of zeolite powder, 8 parts of calcined kaolin.
Modified EPT rubber is prepared using following technique：10 parts of ternary second are added by weight into 100 parts of toluene
Third rubber solution is complete, adds 12 parts of styrene, 5 parts of acrylonitrile, is warming up to 50 DEG C of stirring 20min, adds 1.2 parts of peroxidating
MEK continues to stir 4min, under nitrogen protection, is warming up to 135 DEG C of stirring 15min, 140 parts of absolute ethyl alcohols are added dropwise, filtering, wash
Wash, be dried to obtain modified EPT rubber.
Embodiment 5
A kind of TV remote controller shell ABS material, its raw material include by weight：75 parts of major ingredient, tert-butyl hydroperoxide
1.5 parts of hydrogen, 0.8 part of MBT, 1.5 parts of tetramethylthiuram monosulfide, 65 parts of filler, titanate coupling agent
1.6 parts, 0.7 part of coumarone indene resin, 0.5 part of pine tar, 1.3 parts of epoxidized soybean oil, 1.5 parts of toughener, antioxidant BLE 1.4
Part, 1.6 parts of age resistor ODA.
Major ingredient includes by weight：55 parts of ABS resin, 18 parts of modified EPT rubber.Filler includes by weight：
52 parts of powdered whiting, 3 parts of tossa, 4 parts of zeolite powder, 6 parts of calcined kaolin.
Modified EPT rubber is prepared using following technique：18 parts of ternary second are added by weight into 100 parts of toluene
Third rubber solution is complete, adds 4 parts of styrene, 15 parts of acrylonitrile, is warming up to 40 DEG C of stirring 40min, adds 0.5 part of peroxidating
MEK continues to stir 12min, under nitrogen protection, is warming up to 120 DEG C of stirring 35min, 100 parts of absolute ethyl alcohols are added dropwise, filtering, wash
Wash, be dried to obtain modified EPT rubber.
Using the gained TV remote controller shell of the embodiment of the present invention 5 with ABS material and commercially available TV remote controller shell ABS
Material, common ABS material carry out performance test, and its result is as follows：
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (6)
1. a kind of TV remote controller shell ABS material, it is characterised in that its raw material includes by weight：Major ingredient 70-80 parts,
TBHP 1-2 parts, MBT 0.5-1.2 parts, tetramethylthiuram monosulfide 1-2 parts, filler
60-70 parts, titanate coupling agent 1-2 parts, coumarone indene resin 0.4-1 parts, pine tar 0.2-0.8 parts, epoxidized soybean oil 1-1.6
Part, toughener 1-2 parts, antioxidant BLE 1-2 parts, age resistor ODA 1-2 parts.
2. TV remote controller shell ABS material according to claim 1, it is characterised in that filler includes by weight：
Powdered whiting 45-55 parts, tossa 2-6 parts, zeolite powder 2-5 parts, calcined kaolin 4-10 parts.
3. TV remote controller shell ABS material according to claim 1 or claim 2, it is characterised in that major ingredient wraps by weight
Include：ABS resin 40-60 parts, modified EPT rubber 15-24 parts.
4. according to any one of the claim 1-3 TV remote controller shell ABS materials, it is characterised in that modified ternary second
Third rubber is prepared using following technique：It is complete that ethylene propylene diene rubber dissolving is added into toluene, adds styrene, acrylonitrile,
Heating stirring, add methyl ethyl ketone peroxide and continue to stir, under nitrogen protection, heating stirring, absolute ethyl alcohol is added dropwise, filters, washing,
It is dried to obtain modified EPT rubber.
5. according to any one of the claim 1-4 TV remote controller shell ABS materials, it is characterised in that modified ternary second
Third rubber is prepared using following technique：It is complete that ethylene propylene diene rubber dissolving is added into toluene, adds styrene, acrylonitrile,
40-50 DEG C of stirring 20-40min is warming up to, methyl ethyl ketone peroxide is added and continues to stir 4-12min, under nitrogen protection, be warming up to
120-135 DEG C of stirring 15-35min, is added dropwise absolute ethyl alcohol, filters, washing, be dried to obtain modified EPT rubber.
6. according to any one of the claim 1-5 TV remote controller shell ABS materials, it is characterised in that modified ternary second
Third rubber is prepared using following technique：It is complete that the dissolving of 10-18 parts ethylene propylene diene rubber is added by weight into 100 parts of toluene,
4-12 parts styrene, 5-15 part acrylonitrile are added, 40-50 DEG C of stirring 20-40min is warming up to, adds 0.5-1.2 part peroxidating
MEK continues to stir 4-12min, under nitrogen protection, is warming up to 120-135 DEG C of stirring 15-35min, 100-140 part nothings are added dropwise
Water-ethanol, filter, washing, be dried to obtain modified EPT rubber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710896159.XA CN107828173A (en) | 2017-09-28 | 2017-09-28 | A kind of TV remote controller shell ABS material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710896159.XA CN107828173A (en) | 2017-09-28 | 2017-09-28 | A kind of TV remote controller shell ABS material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107828173A true CN107828173A (en) | 2018-03-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710896159.XA Withdrawn CN107828173A (en) | 2017-09-28 | 2017-09-28 | A kind of TV remote controller shell ABS material |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07103267B2 (en) * | 1988-01-29 | 1995-11-08 | エヌオーケー株式会社 | Gas shielding rubber composition and method for producing the same |
| CN101754599A (en) * | 2008-12-16 | 2010-06-23 | 金发科技股份有限公司 | Application of injection molding wood plastic composite in producing electric appliance housing |
| CN101787204A (en) * | 2009-11-09 | 2010-07-28 | 上海锦湖日丽塑料有限公司 | Low water absorption polyamide composite and preparation method thereof |
| CN101864118A (en) * | 2010-05-28 | 2010-10-20 | 金发科技股份有限公司 | Styrene-based non-halogen flame-retardant injection-grade wood-plastic composite material and preparation method thereof |
-
2017
- 2017-09-28 CN CN201710896159.XA patent/CN107828173A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07103267B2 (en) * | 1988-01-29 | 1995-11-08 | エヌオーケー株式会社 | Gas shielding rubber composition and method for producing the same |
| CN101754599A (en) * | 2008-12-16 | 2010-06-23 | 金发科技股份有限公司 | Application of injection molding wood plastic composite in producing electric appliance housing |
| CN101787204A (en) * | 2009-11-09 | 2010-07-28 | 上海锦湖日丽塑料有限公司 | Low water absorption polyamide composite and preparation method thereof |
| CN101864118A (en) * | 2010-05-28 | 2010-10-20 | 金发科技股份有限公司 | Styrene-based non-halogen flame-retardant injection-grade wood-plastic composite material and preparation method thereof |
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Application publication date: 20180323 |