CN103059360A - Rubber film - Google Patents

Rubber film Download PDF

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Publication number
CN103059360A
CN103059360A CN2012105847890A CN201210584789A CN103059360A CN 103059360 A CN103059360 A CN 103059360A CN 2012105847890 A CN2012105847890 A CN 2012105847890A CN 201210584789 A CN201210584789 A CN 201210584789A CN 103059360 A CN103059360 A CN 103059360A
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China
Prior art keywords
rubber
rubber film
film according
agent
parts
Prior art date
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Pending
Application number
CN2012105847890A
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Chinese (zh)
Inventor
王明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LONGMEN DUOTAI INDUSTRIAL Co Ltd
Original Assignee
LONGMEN DUOTAI INDUSTRIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by LONGMEN DUOTAI INDUSTRIAL Co Ltd filed Critical LONGMEN DUOTAI INDUSTRIAL Co Ltd
Priority to CN2012105847890A priority Critical patent/CN103059360A/en
Publication of CN103059360A publication Critical patent/CN103059360A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a rubber film. The rubber film comprises, by weight, 100 parts of rubber, 15 to 45 parts of a hardening agent, 1 to 3 parts of a yellowing-resistant agent, 1 to 5 parts of a vulcanizing agent, 1 to 5 parts of a vulcanizing accelerating agent, 1 to 3 parts of an aging resistant agent and 1 to 10 parts of an inorganic pigment. The rubber film has high chemical inertness, resists high-corrosivity substances such as acids and alkalis, has certain hardness and deflection, has good luster and an appropriate color, has a low production cost and an appropriate price, can effectively satisfy demands, and is scratched difficultly or has wear resistance.

Description

A kind of rubber film
Technical field
The present invention relates to a kind of polymeric film, be specifically related to a kind of rubber film.
Background technology
Silicon rubber is to sneak into reinforced filling by the high-molecular linear polysiloxane, again through the special synthetic elastomer of heating and pressurizing sulfurationization generation, the character of the siloxane bond of silicon rubber main chain has determined that silicon rubber has advantages of that natural rubber and other rubber do not have, it has that anti-height is turbid, thermostability, electrical insulating property, weathering resistance, tearing toughness, and good thermal diffusivity and cementability and its ventilation property are strong, nonpoisonous and tasteless.Be applicable to be made into sealing-ring, pad, pipe, cable and various functional film materials of different shape etc., be widely used in the every aspect of defence and military, health care and people's daily life.And often need in the market a kind of quality soft; and chemical corrosion be used for to decorate or protect a kind of surface and cover its surface or table top rubber film; and need to have anti-skidding; the function such as anti-scald; operating table surface such as chemical laboratory table top and workshop; often can be because be spilt the material with chemical corrosivity; such as acid; the materials such as alkali; cause table top variable color even damage; need the layer overlay protective material; such protective material not only needs to have unreactiveness; and certain hardness and deflection need to be arranged; be not easy to be scratched or wear and tear; good color and luster and suitable color are preferably arranged; but the few price of this class film is higher on the market at present, demand that can't satisfying the market.
Summary of the invention
The problem that exists in order to overcome prior art, the invention provides a kind of rubber film, this rubber film has high unreactiveness, the contour corrosives of acid-and base-resisting, and certain hardness and deflection are arranged is not easy to scratch or wear-resistant, also have in addition good gloss and suitable color, and its production cost is low, and it is too high that price is unlikely, energy to satisfy effectively people's demand.
The present invention is achieved by the following technical programs: a kind of rubber film comprises following material and weight part:
Rubber 100
Hardening agent 15-45
Anti-yellowing dose of 1-3
Vulcanizing agent 1-5
Vulcanization accelerator additive 1-5
Protective agent 1-3
Mineral dye 1-10.
Described rubber comprises one or more arbitrary combination of paracril, natural rubber, chloroprene rubber, methyl vinyl silicone rubber.
Described Hardening agent comprises one or more arbitrary combination of white carbon black, barium sulfate, nitrate of baryta, bariumchloride, zinc oxide, zinc sulfate, Calucium Silicate powder, silicon-dioxide, silicate, styrene resin, resol, petroleum resin.
The described anti-yellowing dose active hydrogen polysiloxane that contains.
Preferably, described vulcanizing agent be Sulfur, thiuram disulfide, magnesium oxide,, benzoyl peroxide, bis-p-chlorobenzoyl peroxide, peroxidation two (2, the 4-dichloro-benzoyl), 2,5-dimethyl-2, the arbitrary combination of one or more of two (t-butyl peroxy) hexanes of 5-, sulfur subchloride.
Described vulcanization accelerator additive is one or more combination of zinc oxide, Zinic stearas, oleic acid.
Described protective agent is that amine system and/or phenol are protective agent.
Described mineral dye comprises one or more arbitrary combination of titanium white, chrome yellow, barba hispanica, cadmium red, cadmium yellow, zinc sulfide white, carbon black, red iron oxide, iron oxide yellow.
The present invention has following beneficial effect with respect to prior art: a kind of rubber film provided by the present invention, adopt this rubber film to have high unreactiveness, the contour corrosives of acid-and base-resisting, and certain hardness and deflection arranged, be not easy to scratch or wear-resistant, also have in addition good gloss and suitable color, and its production cost be low, it is too high that price is unlikely, energy to satisfy effectively people's demand.
Embodiment
The present invention will be described in detail below in conjunction with embodiment.
Embodiment
The invention discloses a kind of rubber film, comprise following material and weight part:
Rubber 100
Hardening agent 15-45
Anti-yellowing dose of 1-3
Vulcanizing agent 1-5
Vulcanization accelerator additive 1-5
Protective agent 1-3
Mineral dye 1-10.
Described rubber comprise have high oil resistant, the paracril of heat resistant, water tolerance and good adhesive property, have good elasticity, anti-skidding and water resistance the chloroprene rubber that natural rubber, tensile strength are high, heat-resisting, fast light, ageing-resistant performance is good, have good high-low temperature resistant and one or more arbitrary combination of the methyl vinyl silicone rubber of aging resistance.
Described Hardening agent comprises one or more arbitrary combination of white carbon black, barium sulfate, nitrate of baryta, bariumchloride, zinc oxide, zinc sulfate, Calucium Silicate powder, silicon-dioxide, silicate, styrene resin, resol, petroleum resin.These Hardening agent not with acid and alkali reaction, strengthen its resistance to acids and bases,
The described anti-yellowing dose active hydrogen polysiloxane that contains.
Preferably, described vulcanizing agent be Sulfur, thiuram disulfide, magnesium oxide,, benzoyl peroxide, bis-p-chlorobenzoyl peroxide, peroxidation two (2, the 4-dichloro-benzoyl), 2,5-dimethyl-2, the arbitrary combination of one or more of two (t-butyl peroxy) hexanes of 5-, sulfur subchloride, use above-mentioned vulcanizing agent can make rubber molecular chain play crosslinking reaction, make linear molecule form tridimensional network, elastic strength increases, make the rubber of formation have the prolongation time of scorch, improve it and do burnt performance, reduce the characteristics of thermal value.
Described vulcanization accelerator additive is one or more combination of zinc oxide, Zinic stearas, oleic acid.Adopt vulcanization accelerator can promote rubber constituent and vulcanizing agent reaction, shorten curing time, reduce curing time, reduce to vulcanize dosage, prevent the bond strength of sizing material incipient scorch, raising sizing material in the course of processing, save cost.
Described protective agent is that amine system and/or phenol are protective agent, uses protective agent can prevent the rubber premature aging, prolongs its work-ing life.
Described mineral dye comprises one or more arbitrary combination of titanium white, chrome yellow, barba hispanica, cadmium red, cadmium yellow, zinc sulfide white, carbon black, red iron oxide, iron oxide yellow, use mineral dye, its cost is lower, and very high colour stability is arranged, and can guarantee the stability of its color.
The manufacturing processed of this conductive rubber is prepared burden above-mentioned proportion scale, mix, method of calculation on mixing roll, and the control temperature is the 50-250 degree, the time fully reacted it at 10-30 minute.
The not concrete functional module of introducing all can adopt ripe functional module of the prior art among the present invention, is not repeated herein.
The above embodiment has only expressed embodiments of the present invention; it describes comparatively concrete and detailed; but can not therefore be interpreted as the restriction to claim of the present invention; as long as employing is equal to the technical scheme that the form of replacement or equivalent transformation obtains, all should drop within protection scope of the present invention.

Claims (8)

1. rubber film comprises following material and weight part:
Rubber 100
Hardening agent 15-45
Anti-yellowing dose of 1-3
Vulcanizing agent 1-5
Vulcanization accelerator additive 1-5
Protective agent 1-3
Mineral dye 1-10.
2. a kind of rubber film according to claim 1 is characterized in that: described rubber comprises one or more arbitrary combination of paracril, natural rubber, chloroprene rubber, methyl vinyl silicone rubber.
3. a kind of rubber film according to claim 1 is characterized in that: described Hardening agent comprises one or more arbitrary combination of white carbon black, barium sulfate, nitrate of baryta, bariumchloride, zinc oxide, zinc sulfate, Calucium Silicate powder, silicon-dioxide, silicate, styrene resin, resol, petroleum resin.
4. a kind of rubber film according to claim 1 is characterized in that: the described anti-yellowing dose active hydrogen polysiloxane that contains.
5. a kind of rubber film according to claim 1, it is characterized in that: described vulcanizing agent be Sulfur, thiuram disulfide, magnesium oxide,, benzoyl peroxide, bis-p-chlorobenzoyl peroxide, peroxidation two (2, the 4-dichloro-benzoyl), 2,5-dimethyl-2, the arbitrary combination of one or more of two (t-butyl peroxy) hexanes of 5-, sulfur subchloride.
6. a kind of rubber film according to claim 1 is characterized in that: described vulcanization accelerator additive is one or more combination of zinc oxide, Zinic stearas, oleic acid.
7. a kind of rubber film according to claim 1 is characterized in that: described protective agent is that amine system and/or phenol are protective agent.
8. a kind of rubber film according to claim 1 is characterized in that: described mineral dye comprises one or more arbitrary combination of titanium white, chrome yellow, barba hispanica, cadmium red, cadmium yellow, zinc sulfide white, carbon black, red iron oxide, iron oxide yellow.
CN2012105847890A 2012-12-30 2012-12-30 Rubber film Pending CN103059360A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012105847890A CN103059360A (en) 2012-12-30 2012-12-30 Rubber film

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Application Number Priority Date Filing Date Title
CN2012105847890A CN103059360A (en) 2012-12-30 2012-12-30 Rubber film

Publications (1)

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CN103059360A true CN103059360A (en) 2013-04-24

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194104A (en) * 2014-08-20 2014-12-10 南京信息工程大学 Tear-resistant rubber material and preparation method thereof
CN104231351A (en) * 2014-07-17 2014-12-24 安徽巢湖南方膜业有限责任公司 Formula of nitrile rubber-polyvinyl alcohol double-degradable plastic film and preparation method thereof
CN104497575A (en) * 2014-12-22 2015-04-08 广州市白云化工实业有限公司 High-thermal-conductivity organosilicone mud and preparation method thereof
CN104610589A (en) * 2015-01-30 2015-05-13 柳州市颖航汽配有限公司 Anti-fatigue rubber diaphragm formula for automobile brake chamber
CN104629101A (en) * 2013-11-07 2015-05-20 青岛博研达工业技术研究所(普通合伙) High-temperature-resistant strong-resilience high-safety mixed rubber
CN104910468A (en) * 2015-05-29 2015-09-16 安徽育安实验室装备有限公司 Acid/alkali-resistant laboratory table top pad
CN105131723A (en) * 2015-10-16 2015-12-09 青岛科技大学 Coating solution used on tire bead steel wire and preparation method of coating solution
CN107987531A (en) * 2017-11-27 2018-05-04 德阳天赐塑胶有限责任公司 A kind of flexibility frosted silica gel keyboard protective film and its preparation process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1769350A (en) * 2004-11-04 2006-05-10 上海橡胶制品研究所 Silicon rubber membrane and its production method
CN101638491A (en) * 2009-09-15 2010-02-03 上海加富橡胶制品有限公司 Rubber thin material
CN102746543A (en) * 2012-07-10 2012-10-24 山东琪美达轮胎有限公司 Environment-friendly rubber inner tube and method for producing same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1769350A (en) * 2004-11-04 2006-05-10 上海橡胶制品研究所 Silicon rubber membrane and its production method
CN101638491A (en) * 2009-09-15 2010-02-03 上海加富橡胶制品有限公司 Rubber thin material
CN102746543A (en) * 2012-07-10 2012-10-24 山东琪美达轮胎有限公司 Environment-friendly rubber inner tube and method for producing same

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104629101A (en) * 2013-11-07 2015-05-20 青岛博研达工业技术研究所(普通合伙) High-temperature-resistant strong-resilience high-safety mixed rubber
CN104629101B (en) * 2013-11-07 2017-03-22 青岛博研达工业技术研究所(普通合伙) High-temperature-resistant strong-resilience high-safety mixed rubber
CN104231351A (en) * 2014-07-17 2014-12-24 安徽巢湖南方膜业有限责任公司 Formula of nitrile rubber-polyvinyl alcohol double-degradable plastic film and preparation method thereof
CN104231351B (en) * 2014-07-17 2016-02-03 安徽巢湖南方膜业有限责任公司 A kind of paracril-polyvinyl alcohol double degradation plastic film formula and preparation method thereof
CN104194104B (en) * 2014-08-20 2016-03-30 南京信息工程大学 A kind of anti tear elastomeric material and preparation method thereof
CN104194104A (en) * 2014-08-20 2014-12-10 南京信息工程大学 Tear-resistant rubber material and preparation method thereof
CN104497575A (en) * 2014-12-22 2015-04-08 广州市白云化工实业有限公司 High-thermal-conductivity organosilicone mud and preparation method thereof
CN104497575B (en) * 2014-12-22 2017-04-26 广州市白云化工实业有限公司 High-thermal-conductivity organosilicone mud and preparation method thereof
CN104610589A (en) * 2015-01-30 2015-05-13 柳州市颖航汽配有限公司 Anti-fatigue rubber diaphragm formula for automobile brake chamber
CN104910468A (en) * 2015-05-29 2015-09-16 安徽育安实验室装备有限公司 Acid/alkali-resistant laboratory table top pad
CN105131723A (en) * 2015-10-16 2015-12-09 青岛科技大学 Coating solution used on tire bead steel wire and preparation method of coating solution
CN105131723B (en) * 2015-10-16 2017-08-22 青岛科技大学 A kind of steel bead wire coating solution and preparation method thereof
CN107987531A (en) * 2017-11-27 2018-05-04 德阳天赐塑胶有限责任公司 A kind of flexibility frosted silica gel keyboard protective film and its preparation process

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Application publication date: 20130424