CN107815250A - A kind of paint film bleeding water paint of woodcare paint and preparation method thereof - Google Patents
A kind of paint film bleeding water paint of woodcare paint and preparation method thereof Download PDFInfo
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- CN107815250A CN107815250A CN201711140112.7A CN201711140112A CN107815250A CN 107815250 A CN107815250 A CN 107815250A CN 201711140112 A CN201711140112 A CN 201711140112A CN 107815250 A CN107815250 A CN 107815250A
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- paint
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- woodcare
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention discloses paint film bleeding water paint of a kind of woodcare paint and preparation method thereof, belongs to guarantor's type paint field, including component A and B component；The component A by weight percentage, including 3 5% water-based acrylic resins, 3 5% water-based third linseed oil resins, 0.3 0.5% wetting agent, 0.3 0.7% levelling agent, 0.2 0.4% defoamer, 10 15% hydrophilizing agents, 5 10% bleeding agent, 0.1 0.2% preservative, 0.5 0.8%pH values conditioning agent, 5.5 6.5% thickeners, 55 75% water；The B component includes water-based color essence；The component A is mixed and made into coating with B component, and the dosage of B component accounts for the 5 15% of the component mixing total amount of A, B two.The woodcare paint paint film bleeding water paint of the present invention has the advantages that normal temperature bleeding is stable, construction resist sagging is good, process is easy, color clarity is good and environmentally friendly.
Description
Technical field
The present invention relates to paint film bleeding water paint of a kind of woodcare paint and preparation method thereof, belongs to guarantor's type coating neck
Domain.
Background technology
The paint film bleeding of woodcare paint has normal with the water-based environment-friendly type coating that water paint is a kind of high comprehensive performance
The features such as warm bleeding is stable, construction resist sagging is good, process is easy, color clarity is good, is widely used in high-grade solid wood furniture
And the coloring and coating of medium oil, water-based etc. all kinds of paint films of house decoration, substitute traditional color refine color or colored varnish.It is commercially available same
After the construction of class product, drawbacks common is shown as：Bleeding is too fast easily to grow dim or not bleeding, the easy sagging of construction, the dismal permeability of color
Difference etc., this is a difficult problem for perplexing the transparent coloured application of coating industry new method popularization and application.
The content of the invention
In view of the above-mentioned problems of the prior art, the present invention provides, a kind of normal temperature bleeding is stable, construction resist sagging is good,
Woodcare paint paint film bleeding water paint that process is easy, color clarity is good and preparation method thereof.
To achieve these goals, the paint film bleeding water paint of a kind of woodcare paint of the invention, including component A and B
Component；
The component A by weight percentage, including the water-based third linseed oil tree of 3-5% water-based acrylic resins, 3-5%
Fat, 0.3-0.5% wetting agents, 0.3-0.7% levelling agents, 0.2-0.4% defoamers, 10-15% hydrophilizing agents, 5-10% bleedings
Agent, 0.1-0.2% preservatives, 0.5-0.8%pH values conditioning agent, 5.5-6.5% thickeners, 55-75% water；
The B component includes water-based color essence；
The component A is mixed and made into coating with B component, and the dosage of B component accounts for the 5-15% of the component mixing total amount of A, B two.
The wetting agent uses LCN-407.
The levelling agent uses BYK-333.
The defoamer uses AIREX902W.
The hydrophilizing agent uses propane diols.
The bleeding agent uses propylene glycol methyl ether acetate.
The preservative uses S103.
The pH value regulator uses AMP-95.
The thickener uses ASE-60.
A kind of paint film bleeding water paint of woodcare paint, specifically includes following steps：
1) preparation of component A：By 3-5% water-based acrylic resins, the water-based third linseed oil resins of 3-5%, 0.3-0.5%
Wetting agent, 0.2-0.4% levelling agents, 0.1-0.2% defoamers, 30-40% water, 10-15% hydrophilizing agents and 5-10% bleeding agent,
Homogenizer is sequentially added, under 800-1200r/min rotating speed, is dispersed with stirring to fineness≤20um, then adds successively again
Enter 0.1-0.2% preservatives, 0.5-0.8%pH values conditioning agent, 5.5-6.5% thickeners, 0.1-0.3% levelling agents, 0.1-
0.2% defoamer, 25-35% water, stirring is disperseed under 800-1200r/min rotating speed, until scraping glass plate without shrinkage cavity, fineness
≤ 20um, regulation viscosity obtain component A to 8000-10000mpa.S/25 DEG C；
2) preparation of water paint：The water-based color essence of B component is added in component A into step 1), is mixed evenly,
Water paint is produced, the addition of the B component is the 5-15% of the component mixing total amount of A, B two.
The beneficial effects of the invention are as follows：The woodcare paint paint film bleeding of the present invention is with water paint using bleeding agent to woodcare paint
Non-swelling, the reduction coating surface intensity of film, then water-based color essence is dissolved in into paint film with hydrophilizing agent, there is normal temperature bleeding stabilization, apply
The advantages that work resist sagging is good, process is easy, color clarity is good and environmentally friendly.
Embodiment
To make the object, technical solutions and advantages of the present invention of greater clarity, below by embodiment, the present invention is entered
Row is further described.However, it should be understood that the specific embodiments described herein are merely illustrative of the present invention, and do not have to
In limitation the scope of the present invention.
Unless otherwise defined, all technical terms and scientific terminology used herein are led with belonging to the technology of the present invention
The implication that the technical staff in domain is generally understood that is identical, and used term is intended merely to retouch in the description of the invention herein
State the purpose of specific embodiment, it is not intended that in the limitation present invention.
Embodiment 1
A kind of paint film bleeding water paint of woodcare paint, specifically includes following steps：
1) preparation of component A：By 3% water-based acrylic resin, 5% water-based third linseed oil resin, 0.3% wetting agent,
0.2% levelling agent, 0.1% defoamer, 40% water, 10% hydrophilizing agent and 10% bleeding agent, sequentially add homogenizer, in
Under 800r/min rotating speed, it is dispersed with stirring to fineness≤20um, then sequentially adds 0.2% preservative, the regulation of 0.5%pH values
Agent, 5.5% thickener, 0.1% levelling agent, 0.1% defoamer, 25% water, stirring is disperseed under 800r/min rotating speed, until
Scrape glass plate and obtain component A to 8000-10000mpa.S/25 DEG C without shrinkage cavity, fineness≤20um, regulation viscosity；
2) preparation of water paint：The water-based color essence of B component is added in component A into step 1), is mixed evenly,
Water paint is produced, the addition of the B component is the 5% of the component mixing total amount of A, B two.
The wetting agent uses Weng Kaier LCN-407, and surface tension is low, and flow leveling is good.It is or high public using German enlightening
The KL-245 of department, composition are polyether siloxane copolymer；Or use soybean lecithin, thio-alcohol, hydrazides class and mercaptan acetals
Deng it is any.
For the levelling agent using the BYK-333 of Bi Ke chemistry, composition is polyether-modified dimethyl silicone polymer, is had excellent
Ground lubrication and flow leveling, there is good water solubility and oil-soluble, moreover it is possible to the generation for the defects of preventing shrinkage cavity, orange peel.
The auxiliary agent can acutely reduce the surface tension of coating system, can promote substrate wettability especially, prevent shrinkage cavity.Or use polypropylene
Any of acid, carboxymethyl cellulose.
The defoamer uses the high AIREX902W of enlightening, and composition is polyether siloxane copolymer, can effectively suppress the production of foam
It is raw.Or use polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxy
Any of propylene polyoxyethylene glycerol ether.
The hydrophilizing agent uses the propane diols of Jiangsu day sound.
The bleeding agent uses the propylene glycol methyl ether acetate of Jiangsu day sound.
The preservative is using any of enlightening U.S. S103, sodium benzoate, potassium sorbate.
The pH value regulator use DOW Chemical AMP-95, composition be the -2- aminomethyl-1,2s containing 5% moisture content -
Propyl alcohol, it is a kind of multifunction amine auxiliary agent, adjusts the effect that the pH value of emulsion adhesive is very stable, also moistens, disperses.
The thickener uses the ASE-60 of ROHM AND HAAS, is alkali swollen thickener, composition：There is the cross-linking type of acidic-group
Macromolecule.ASE-60 is a kind of cross-linked type macromolecule emulsion thickener containing acidic-group, when being neutralized with water latting drown and with alkali
When, its latex particle expands quickly, under these conditions, emulsion will become clarification and it is very sticky.ASE-60 can effectively improve low
Shear viscosity, make coating system that there is higher pseudoplastic behavior.With ASE-60 decide thickener prepare coating, have higher surrender
Value and gel structure, this structure can show after shearing force disappearance, therefore ASE-60 is applied to preparation and has appropriateness vertical
The coating of body effect of decorative patterns.Or use any in methylcellulose, hydroxypropyl methyl cellulose, amino alcohol solvay-type titanate esters
Kind.
Embodiment 2
A kind of paint film bleeding water paint of woodcare paint, specifically includes following steps：
1) preparation of component A：By 4% water-based acrylic resin, 4% water-based third linseed oil resin, 0.4% wetting agent,
0.3% levelling agent, 0.2% defoamer, 35% water, 12% hydrophilizing agent and 8% bleeding agent, sequentially add homogenizer, in
Under 1000r/min rotating speed, it is dispersed with stirring to fineness≤20um, then sequentially adds 0.1% preservative, 0.6%pH values are adjusted
Agent, 6% thickener, 0.2% levelling agent, 0.2% defoamer, 29% water are saved, stirring is disperseed under 1000r/min rotating speed, directly
To glass plate is scraped component A is obtained without shrinkage cavity, fineness≤20um, regulation viscosity to 8000-10000mpa.S/25 DEG C；
2) preparation of water paint：The water-based color essence of B component is added in component A into step 1), is mixed evenly,
Water paint is produced, the addition of the B component is the 10% of the component mixing total amount of A, B two.
The wetting agent LCN-407 (Weng Kaier).
The levelling agent BYK-333 (Bi Ke chemistry).
The defoamer AIREX902W (enlightening is high).
The hydrophilizing agent propane diols (Jiangsu day sound).
The bleeding agent propylene glycol methyl ether acetate (Jiangsu day sound).
The preservative S103 (Di Mei).
The pH value regulator AMP-95 (DOW Chemical).
The thickener ASE-60 (ROHM AND HAAS).
Embodiment 3
A kind of paint film bleeding water paint of woodcare paint, specifically includes following steps：
1) preparation of component A：By 5% water-based acrylic resin, 3% water-based third linseed oil resin, 0.5% wetting agent,
0.4% levelling agent, 0.2% defoamer, 30% water, 15% hydrophilizing agent and 5% bleeding agent, sequentially add homogenizer, in
Under 1200r/min rotating speed, it is dispersed with stirring to fineness≤20um, then sequentially adds 0.1% preservative, 0.8%pH values are adjusted
Agent, 6.5% thickener, 0.3% levelling agent, 0.2% defoamer, 33% water are saved, stirring is disperseed under 1200r/min rotating speed,
Until scraping glass plate component A is obtained without shrinkage cavity, fineness≤20um, regulation viscosity to 8000-10000mpa.S/25 DEG C；
2) preparation of water paint：The water-based color essence of B component is added in component A into step 1), is mixed evenly,
Water paint is produced, the addition of the B component is the 15% of the component mixing total amount of A, B two.
The wetting agent uses Weng Kaier LCN-407, and surface tension is low, and flow leveling is good..
The levelling agent can acutely reduce the surface tension of coating system using BYK-333 chemical Bi Ke, the auxiliary agent, especially
Substrate wettability can be promoted, prevent shrinkage cavity.
The defoamer uses the high AIREX902W of enlightening, prevents the generation of microvesicle and pin hole in coating.
The hydrophilizing agent uses the propane diols of Jiangsu day sound.
The bleeding agent uses the propylene glycol methyl ether acetate of Jiangsu day sound.
The preservative uses enlightening U.S. S103.
The pH value regulator uses the AMP-95 of DOW Chemical, is a kind of multifunction amine auxiliary agent, adjusts emulsion adhesive
PH value it is very stable, also moisten, scattered effect.
The thickener uses the ASE-60 of ROHM AND HAAS.
There is the advantages of notable with like product on the market for the water paint of the comparative analysis present invention, it is special by the present invention
The product of embodiment 1 and the bleeding coating bought on the market carry out performance comparison, the results are shown in Table 1, table 2.
1 water paint of the present invention of table and bleeding coating performance comparison result on oiliness PU paint films on the market
| Inspection project | The present invention | Outsourcing sample A | Outsourcing sample B |
| Reach the reference colour time (25 DEG C, min) | 40 | 8 | 88 |
| Construction resist sagging | It is excellent | It is good | It is good |
| Color clarity | It is excellent | Difference | It is good |
2 water paint of the present invention of table and bleeding coating performance comparison result on water soluble acrylic acid paint film on the market
| Inspection project | The present invention | Outsourcing sample A | Outsourcing sample B |
| Reach the reference colour time (25 DEG C, min) | 30 | 3 | 80 |
| Construction resist sagging | It is excellent | It is good | It is good |
| Color clarity | It is excellent | Difference | It is good |
Analytical table 1, the content of table 2 understand that woodcare paint paint film bleeding water paint of the invention has normal temperature bleeding steady
Fixed, the advantages that resist sagging is good, process is easy, color clarity is good and environmentally friendly of constructing.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modification, equivalent substitution or improvement made within refreshing and principle etc., should be included in the scope of the protection.
Claims (10)
1. the paint film bleeding water paint of a kind of woodcare paint, it is characterised in that including component A and B component；
The component A by weight percentage, including the water-based third linseed oil resin of 3-5% water-based acrylic resins, 3-5%,
0.3-0.5% wetting agents, 0.3-0.7% levelling agents, 0.2-0.4% defoamers, 10-15% hydrophilizing agents, 5-10% bleedings agent,
0.1-0.2% preservatives, 0.5-0.8%pH values conditioning agent, 5.5-6.5% thickeners, 55-75% water；
The B component includes water-based color essence；
The component A is mixed and made into coating with B component, and the dosage of B component accounts for the 5-15% of the component mixing total amount of A, B two.
A kind of 2. paint film bleeding water paint of woodcare paint according to claim 1, it is characterised in that the wetting agent
Using LCN-407.
A kind of 3. paint film bleeding water paint of woodcare paint according to claim 1, it is characterised in that the levelling agent
Using BYK-333.
A kind of 4. paint film bleeding water paint of woodcare paint according to claim 1, it is characterised in that the defoamer
Using AIREX902W.
A kind of 5. paint film bleeding water paint of woodcare paint according to claim 1, it is characterised in that the hydrophilizing agent
Using propane diols.
A kind of 6. paint film bleeding water paint of woodcare paint according to claim 1, it is characterised in that the bleeding agent
Using propylene glycol methyl ether acetate.
A kind of 7. paint film bleeding water paint of woodcare paint according to claim 1, it is characterised in that the preservative
Using S103.
8. the paint film bleeding water paint of a kind of woodcare paint according to claim 1, it is characterised in that the pH value is adjusted
Section agent uses AMP-95.
A kind of 9. paint film bleeding water paint of woodcare paint according to claim 1, it is characterised in that the thickener
Using ASE-60.
A kind of 10. paint film bleeding water paint of any one of the claim 1-9 woodcare paint, it is characterised in that specific bag
Include following steps：
1) preparation of component A：By 3-5% water-based acrylic resins, the water-based third linseed oil resins of 3-5%, 0.3-0.5% wettings
Agent, 0.2-0.4% levelling agents, 0.1-0.2% defoamers, 30-40% water, 10-15% hydrophilizing agents and 5-10% bleeding agent, successively
Homogenizer is added, under 800-1200r/min rotating speed, is dispersed with stirring to fineness≤20um, then sequentially adds
0.1-0.2% preservatives, 0.5-0.8%pH values conditioning agent, 5.5-6.5% thickeners, 0.1-0.3% levelling agents, 0.1-0.2%
Defoamer, 25-35% water, stirring is disperseed under 800-1200r/min rotating speed, until scraping glass plate without shrinkage cavity, fineness≤
20um, regulation viscosity obtain component A to 8000-10000mpa.S/25 DEG C；
2) preparation of water paint：The water-based color essence of B component is added in component A into step 1), is mixed evenly, produces
Water paint, the addition of the B component are the 5-15% of the component mixing total amount of A, B two.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711140112.7A CN107815250A (en) | 2017-11-16 | 2017-11-16 | A kind of paint film bleeding water paint of woodcare paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711140112.7A CN107815250A (en) | 2017-11-16 | 2017-11-16 | A kind of paint film bleeding water paint of woodcare paint and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251578A (en) * | 2018-07-19 | 2019-01-22 | 东莞大宝化工制品有限公司 | A kind of machine spray filler and its preparation method and application |
| CN111471360A (en) * | 2020-05-14 | 2020-07-31 | 广东泰枫环保科技有限公司 | Water-based paint for paint film bleeding of wood paint and preparation method thereof |
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