CN111471360A - Water-based paint for paint film bleeding of wood paint and preparation method thereof - Google Patents
Water-based paint for paint film bleeding of wood paint and preparation method thereof Download PDFInfo
- Publication number
- CN111471360A CN111471360A CN202010407664.5A CN202010407664A CN111471360A CN 111471360 A CN111471360 A CN 111471360A CN 202010407664 A CN202010407664 A CN 202010407664A CN 111471360 A CN111471360 A CN 111471360A
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- CN
- China
- Prior art keywords
- parts
- paint
- water
- acid
- bleeding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003973 paint Substances 0.000 title claims abstract description 87
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 230000000740 bleeding effect Effects 0.000 title claims abstract description 35
- 239000002023 wood Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims description 13
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 claims abstract description 39
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 27
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000004922 lacquer Substances 0.000 claims abstract description 21
- 150000007524 organic acids Chemical class 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 14
- 239000004375 Dextrin Substances 0.000 claims abstract description 13
- 229920001353 Dextrin Polymers 0.000 claims abstract description 13
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 235000019425 dextrin Nutrition 0.000 claims abstract description 13
- 235000011187 glycerol Nutrition 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 235000009518 sodium iodide Nutrition 0.000 claims abstract description 13
- 235000015393 sodium molybdate Nutrition 0.000 claims abstract description 13
- 239000011684 sodium molybdate Substances 0.000 claims abstract description 13
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000011007 phosphoric acid Nutrition 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 235000013311 vegetables Nutrition 0.000 claims abstract description 8
- 239000004814 polyurethane Substances 0.000 claims description 27
- 229920002635 polyurethane Polymers 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 239000000843 powder Substances 0.000 claims description 21
- 239000011941 photocatalyst Substances 0.000 claims description 19
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 239000004952 Polyamide Substances 0.000 claims description 17
- 239000004841 bisphenol A epoxy resin Substances 0.000 claims description 17
- 229920002647 polyamide Polymers 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 17
- 239000002518 antifoaming agent Substances 0.000 claims description 16
- 239000000945 filler Substances 0.000 claims description 16
- 239000000080 wetting agent Substances 0.000 claims description 15
- 239000000839 emulsion Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- 239000005543 nano-size silicon particle Substances 0.000 claims description 13
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 13
- 239000006185 dispersion Substances 0.000 claims description 12
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims description 11
- 239000004925 Acrylic resin Substances 0.000 claims description 11
- 229920000178 Acrylic resin Polymers 0.000 claims description 11
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 11
- 229940047670 sodium acrylate Drugs 0.000 claims description 11
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 6
- QAIPRVGONGVQAS-DUXPYHPUSA-N trans-caffeic acid Chemical compound OC(=O)\C=C\C1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-DUXPYHPUSA-N 0.000 claims description 6
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 4
- ACEAELOMUCBPJP-UHFFFAOYSA-N (E)-3,4,5-trihydroxycinnamic acid Natural products OC(=O)C=CC1=CC(O)=C(O)C(O)=C1 ACEAELOMUCBPJP-UHFFFAOYSA-N 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 3
- CWVRJTMFETXNAD-FWCWNIRPSA-N 3-O-Caffeoylquinic acid Natural products O[C@H]1[C@@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-FWCWNIRPSA-N 0.000 claims description 3
- 239000005711 Benzoic acid Substances 0.000 claims description 3
- PZIRUHCJZBGLDY-UHFFFAOYSA-N Caffeoylquinic acid Natural products CC(CCC(=O)C(C)C1C(=O)CC2C3CC(O)C4CC(O)CCC4(C)C3CCC12C)C(=O)O PZIRUHCJZBGLDY-UHFFFAOYSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 3
- CWVRJTMFETXNAD-KLZCAUPSSA-N Neochlorogenin-saeure Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O CWVRJTMFETXNAD-KLZCAUPSSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 235000010233 benzoic acid Nutrition 0.000 claims description 3
- 229960004365 benzoic acid Drugs 0.000 claims description 3
- 235000004883 caffeic acid Nutrition 0.000 claims description 3
- 229940074360 caffeic acid Drugs 0.000 claims description 3
- CWVRJTMFETXNAD-JUHZACGLSA-N chlorogenic acid Chemical compound O[C@@H]1[C@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-JUHZACGLSA-N 0.000 claims description 3
- 235000001368 chlorogenic acid Nutrition 0.000 claims description 3
- 229940074393 chlorogenic acid Drugs 0.000 claims description 3
- FFQSDFBBSXGVKF-KHSQJDLVSA-N chlorogenic acid Natural products O[C@@H]1C[C@](O)(C[C@@H](CC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O FFQSDFBBSXGVKF-KHSQJDLVSA-N 0.000 claims description 3
- BMRSEYFENKXDIS-KLZCAUPSSA-N cis-3-O-p-coumaroylquinic acid Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)cc2)[C@@H]1O)C(=O)O BMRSEYFENKXDIS-KLZCAUPSSA-N 0.000 claims description 3
- QAIPRVGONGVQAS-UHFFFAOYSA-N cis-caffeic acid Natural products OC(=O)C=CC1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-UHFFFAOYSA-N 0.000 claims description 3
- 229960004106 citric acid Drugs 0.000 claims description 3
- 235000015165 citric acid Nutrition 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- 229940099690 malic acid Drugs 0.000 claims description 3
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims description 3
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004302 potassium sorbate Substances 0.000 claims description 3
- 235000010241 potassium sorbate Nutrition 0.000 claims description 3
- 229940069338 potassium sorbate Drugs 0.000 claims description 3
- 229960004889 salicylic acid Drugs 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 229960001367 tartaric acid Drugs 0.000 claims description 3
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- IYRMWMYZSQPJKC-UHFFFAOYSA-N kaempferol Chemical compound C1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 IYRMWMYZSQPJKC-UHFFFAOYSA-N 0.000 claims 2
- UBSCDKPKWHYZNX-UHFFFAOYSA-N Demethoxycapillarisin Natural products C1=CC(O)=CC=C1OC1=CC(=O)C2=C(O)C=C(O)C=C2O1 UBSCDKPKWHYZNX-UHFFFAOYSA-N 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 claims 1
- 235000008777 kaempferol Nutrition 0.000 claims 1
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 5
- 239000002253 acid Substances 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 3
- 239000003513 alkali Substances 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003518 caustics Substances 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 230000002035 prolonged effect Effects 0.000 abstract description 2
- 230000001954 sterilising effect Effects 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 238000005536 corrosion prevention Methods 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- -1 propylene glycol ethers Chemical class 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940067596 butylparaben Drugs 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 1
- 229960004618 prednisone Drugs 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229940070527 tourmaline Drugs 0.000 description 1
- 229910052613 tourmaline Inorganic materials 0.000 description 1
- 239000011032 tourmaline Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/329—Phosphorus containing acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to the technical field of water-based paint, and discloses water-based paint for paint film bleeding of wood lacquer. The solution is formed by mixing organic acid, dextrin, sodium molybdate, phosphoric acid, sodium iodide and vegetable glycerin in the coating, and the solution is dissolved in the raw materials of the coating, so that the problems of corrosion prevention, rust prevention and sterilization of the existing water-based coating for paint film color bleeding are solved to a certain extent, oxygen and corrosive substances are prevented from entering the coating, the service life of the coating is prolonged, and the coating also has the effects of good acid and alkali resistance, wear resistance, ageing resistance and the like.
Description
Technical Field
The invention relates to the technical field of water-based paint, in particular to water-based paint for paint film bleeding of wood paint and a preparation method thereof.
Background
The water-based paint is a paint using water as a solvent or a dispersion medium, compared with an organic solvent-based paint, the water-based paint can reduce the emission of volatile organic solvents and save resources and energy, and the water-based paint for paint film bleeding of the wood paint is a pure water-based environment-friendly paint with excellent comprehensive performance and is widely applied to the coloring and coating of various paint films such as oil, water and the like in high-grade solid wood furniture and home decoration.
The traditional water-based paint for paint film color bleeding uses water-soluble resin as a film forming material, the corrosion resistance and the rust resistance are still poor in long-time air exposure, the content of VOC in the raw materials is large, the health of a human body is seriously harmed, the traditional water-based paint for paint film color bleeding does not have an antibacterial effect, toxic gas is easily generated, and therefore the water-based paint for paint film color bleeding of the wood lacquer and the preparation method thereof are provided.
Disclosure of Invention
In order to solve the technical problems, the invention provides a water-based paint for paint film bleeding of wood paint and a preparation method thereof, which are achieved by the following specific technical means:
a water-based paint for paint film bleeding of wood lacquer is composed of the following raw materials in parts by weight:
15-20 parts of water-based acrylic resin;
5-8 parts of a film forming auxiliary agent;
3-6 parts of bisphenol A epoxy resin;
1-3 parts of polyamide;
2-6 parts of photocatalyst powder;
0.1-0.5 part of defoaming agent;
0.3-0.8 part of a leveling agent;
0.4-0.6 part of wetting agent;
0.3-0.7 part of sodium acrylate;
0.5-0.9 part of polyurethane;
0.2-0.8 parts of diatom ooze filler;
0.5-2 parts of sodium polyacrylate;
0.1-0.3 part of polyurethane;
0.3-0.6 part of pH regulator;
3-5 parts of wax emulsion;
0.1-0.3 part of organic acid;
0.3-0.5 part of dextrin;
0.5-0.9 part of sodium molybdate;
0.3-0.6 part of phosphoric acid;
1-3 parts of vegetable glycerin;
0.1-0.4 part of sodium iodide;
1-4 parts of isothiazolinone;
2-3 parts of nano silicon oxide;
5-7 parts of deionized water.
Preferably, the defoaming agent is one or more of silicones, long-chain alcohols and fatty acid amides.
Preferably, the film forming aid is one or more of diethanol ethers, propylene glycol ethers and N-methylpyrrolidone.
Preferably, the polyurethane is one or more of potassium sorbate, methylparaben, butylparaben, and cason.
Preferably, the organic acid is any one of citric acid, tartaric acid, malic acid, chlorogenic acid, benzoic acid, salicylic acid and caffeic acid.
According to the waterborne paint for paint film bleeding of the wood lacquer, the preparation method of the waterborne paint for paint film bleeding of the wood lacquer is provided, and comprises the following steps:
s1, adding the weighed deionized water and the water-based acrylic resin into a reaction kettle, measuring the leveling agent, the sodium acrylate, the wetting agent and the wax emulsion in the formula, and adding in sequence, and controlling the rotating speed to be 800-1200 r/min for stirring;
s2, weighing bisphenol A epoxy resin, photocatalyst powder, polyamide and diatom ooze filler in formula amount in sequence according to proportion, placing the bisphenol A epoxy resin, the photocatalyst powder, the polyamide, the diatom ooze filler, isothiazolinone and nano silicon oxide in a dispersing container in sequence, dispersing for 30 minutes until the fineness after dispersion is not less than 20 microns, and pouring the dispersed materials into a reaction kettle for reaction;
s3, organic acid, dextrin, sodium molybdate, phosphoric acid and deionized water in the formula are weighed and placed in a mixing tank to be stirred at a constant speed at room temperature, then glycerin and sodium iodide are added to be stirred for 20 minutes, and then polyurethane, sodium polyacrylate, polyurethane, a defoaming agent and a film forming aid are added in sequence to be mixed uniformly to form a solution and taken out for later use;
and S4, sequentially adding the materials in the S3 and the weighed PH regulator into a reaction kettle, stirring and mixing, controlling the rotating speed at 600-800 r/min, stirring uniformly, and obtaining the water-based paint for paint film bleeding when the PH value in the reaction kettle is 6-8.
Advantageous effects
Compared with the prior art, the invention provides the water-based paint for paint film bleeding of the wood lacquer and the preparation method thereof, and the water-based paint has the following beneficial effects:
1. the paint film color bleeding water-based paint of the wood lacquer and the preparation method thereof are characterized in that isothiazolinone, nano silicon oxide and photocatalyst powder are organically combined, the isothiazolinone has strong inhibiting and killing effects on bacteria, fungi and algae in the paint process in the paint, the bacteria are prevented from being generated, the thickening effect of the nano silicon oxide is utilized, the bonding strength of the components in the paint is increased, the photocatalyst powder is dispersed in water, harmful substances such as free formaldehyde, benzene, ammonia and the like in the air can be rapidly captured by utilizing the bioactivity of the photocatalyst, and the double sterilization effect is good.
2. According to the water-based paint for paint film bleeding of the wood lacquer and the preparation method thereof, the solution formed by mixing organic acid, dextrin, sodium molybdate, phosphoric acid, sodium iodide and vegetable glycerin inside the paint is neutralized with bisphenol A epoxy resin and polyamide to generate good wear resistance, corrosion resistance and rust resistance, so that the corrosion resistance and rust resistance of the existing water-based paint for paint film bleeding are improved, oxygen and corrosive substances are prevented from entering the paint, the service life of the paint is prolonged, and the paint also has the effects of good acid and alkali resistance, aging resistance, good adhesive force and the like.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention is further described below by way of examples:
the first embodiment is as follows:
a water-based paint for paint film bleeding of wood lacquer comprises water-based acrylic resin, a film forming additive, bisphenol A epoxy resin, polyamide, photocatalyst powder, a defoaming agent, a leveling agent, a wetting agent, sodium acrylate, polyurethane, diatom ooze filler, sodium polyacrylate, polyurethane, a pH regulator, wax emulsion, organic acid, dextrin, sodium molybdate, phosphoric acid, vegetable glycerin, sodium iodide, isothiazolinone, nano silicon oxide and deionized water.
Wherein the defoaming agent is one or more of organic silicon, long-chain alcohol and fatty acid amide.
Wherein the film-forming assistant is one or more of diethanol ether, propylene glycol ether and N-methylpyrrolidone.
Wherein the polyurethane is one or more of potassium sorbate, methyl parahydroxybenzoate, butyl parahydroxybenzoate and prednisone.
Wherein the organic acid is any one of citric acid, tartaric acid, malic acid, chlorogenic acid, benzoic acid, salicylic acid, and caffeic acid.
According to the waterborne paint for paint film bleeding of the wood lacquer, the preparation method of the waterborne paint for paint film bleeding of the wood lacquer is provided, and comprises the following steps:
s1, preparing the following raw materials in percentage by mass:
15 parts of water-based acrylic resin, 5 parts of film-forming assistant, 3 parts of bisphenol A epoxy resin, 1 part of polyamide, 2 parts of photocatalyst powder, 0.1 part of defoaming agent, 0.3 part of flatting agent, 0.4 part of wetting agent, 0.3 part of sodium acrylate, 0.5 part of polyurethane, 0.2 part of diatom ooze filler, 0.5 part of sodium polyacrylate, 0.1 part of polyurethane, 0.3 part of pH regulator, 3 parts of wax emulsion, 0.1 part of organic acid, 0.3 part of dextrin, 0.5 part of sodium molybdate, 0.3 part of phosphoric acid, 1 part of vegetable glycerin, 0.1 part of sodium iodide, 1 part of isothiazolinone, 2 parts of nano silicon oxide and 5 parts of deionized water.
S2, adding the weighed deionized water and the water-based acrylic resin into a reaction kettle, measuring the leveling agent, the sodium acrylate, the wetting agent and the wax emulsion in the formula, and adding in sequence, and controlling the rotating speed to be 800-1200 r/min for stirring;
s3, weighing bisphenol A epoxy resin, photocatalyst powder, polyamide and diatom ooze filler in formula amount in sequence according to proportion, placing the bisphenol A epoxy resin, the photocatalyst powder, the polyamide, the diatom ooze filler, isothiazolinone and nano silicon oxide in a dispersing container in sequence, dispersing for 30 minutes until the fineness after dispersion is not less than 20 microns, and pouring the dispersed materials into a reaction kettle for reaction;
s4, organic acid, dextrin, sodium molybdate, phosphoric acid and deionized water in the formula are weighed and placed in a mixing tank to be stirred at a constant speed at room temperature, then glycerin and sodium iodide are added to be stirred for 20 minutes, and then polyurethane, sodium polyacrylate, polyurethane, a defoaming agent and a film forming aid are added in sequence to be mixed uniformly to form a solution and taken out for later use;
and S5, sequentially adding the materials in the S4 and the weighed PH regulator into a reaction kettle, stirring and mixing, controlling the rotating speed at 600-800 r/min, stirring uniformly, and obtaining the water-based paint for paint film bleeding when the PH value in the reaction kettle is 6-8.
Example two:
the preparation method of the water-based paint for paint film bleeding of the wood lacquer comprises the following steps:
s1, preparing the following raw materials in percentage by mass:
20 parts of water-based acrylic resin, 8 parts of film-forming assistant, 6 parts of bisphenol A epoxy resin, 3 parts of polyamide, 6 parts of photocatalyst powder, 0.5 part of defoaming agent, 0.8 part of flatting agent, 0.6 part of wetting agent, 0.7 part of sodium acrylate, 0.9 part of polyurethane, 0.8 part of diatom ooze filler, 2 parts of sodium polyacrylate, 0.3 part of polyurethane, 0.6 part of pH regulator, 5 parts of wax emulsion, 0.2 part of organic acid, 0.4 part of dextrin, 0.7 part of sodium molybdate, 0.4 part of phosphoric acid, 2 parts of vegetable glycerin, 0.2 part of sodium iodide, 2.5 parts of isothiazolinone, 2.5 parts of nano silicon oxide and 7 parts of deionized water.
S2, adding the weighed deionized water and the water-based acrylic resin into a reaction kettle, measuring the leveling agent, the sodium acrylate, the wetting agent and the wax emulsion in the formula, and adding in sequence, and controlling the rotating speed to be 800-1200 r/min for stirring;
s3, weighing bisphenol A epoxy resin, photocatalyst powder, polyamide and diatom ooze filler in formula amount in sequence according to proportion, placing the bisphenol A epoxy resin, the photocatalyst powder, the polyamide, the diatom ooze filler, isothiazolinone and nano silicon oxide in a dispersing container in sequence, dispersing for 30 minutes until the fineness after dispersion is not less than 20 microns, and pouring the dispersed materials into a reaction kettle for reaction;
s4, organic acid, dextrin, sodium molybdate, phosphoric acid and deionized water in the formula are weighed and placed in a mixing tank to be stirred at a constant speed at room temperature, then glycerin and sodium iodide are added to be stirred for 20 minutes, and then polyurethane, sodium polyacrylate, polyurethane, a defoaming agent and a film forming aid are added in sequence to be mixed uniformly to form a solution and taken out for later use;
and S5, sequentially adding the materials in the S4 and the weighed PH regulator into a reaction kettle, stirring and mixing, controlling the rotating speed at 600-800 r/min, stirring uniformly, and obtaining the water-based paint for paint film bleeding when the PH value in the reaction kettle is 6-8.
Example three:
the preparation method of the water-based paint for paint film bleeding of the wood lacquer comprises the following steps:
s1, preparing the following raw materials in percentage by mass:
17 parts of water-based acrylic resin, 6 parts of film-forming assistant, 5 parts of bisphenol A epoxy resin, 2 parts of polyamide, 4 parts of photocatalyst powder, 0.3 part of defoaming agent, 0.5 part of flatting agent, 0.5 part of wetting agent, 0.5 part of sodium acrylate, 0.7 part of polyurethane, 0.5 part of diatom ooze filler, 1.4 parts of sodium polyacrylate, 0.2 part of polyurethane, 0.4 part of pH regulator, 4 parts of wax emulsion, 0.3 part of organic acid, 0.5 part of dextrin, 0.9 part of sodium molybdate, 0.6 part of phosphoric acid, 3 parts of vegetable glycerin, 0.4 part of sodium iodide, 4 parts of isothiazolinone, 3 parts of nano silicon oxide and 7 parts of deionized water.
S2, adding the weighed deionized water and the water-based acrylic resin into a reaction kettle, measuring the leveling agent, the sodium acrylate, the wetting agent and the wax emulsion in the formula, and adding in sequence, and controlling the rotating speed to be 800-1200 r/min for stirring;
s3, weighing bisphenol A epoxy resin, photocatalyst powder, polyamide and diatom ooze filler in formula amount in sequence according to proportion, placing the bisphenol A epoxy resin, the photocatalyst powder, the polyamide, the diatom ooze filler, isothiazolinone and nano silicon oxide in a dispersing container in sequence, dispersing for 30 minutes until the fineness after dispersion is not less than 20 microns, and pouring the dispersed materials into a reaction kettle for reaction;
s4, organic acid, dextrin, sodium molybdate, phosphoric acid and deionized water in the formula are weighed and placed in a mixing tank to be stirred at a constant speed at room temperature, then glycerin and sodium iodide are added to be stirred for 20 minutes, and then polyurethane, sodium polyacrylate, polyurethane, a defoaming agent and a film forming aid are added in sequence to be mixed uniformly to form a solution and taken out for later use;
and S5, sequentially adding the materials in the S4 and the weighed PH regulator into a reaction kettle, stirring and mixing, controlling the rotating speed at 600-800 r/min, stirring uniformly, and obtaining the water-based paint for paint film bleeding when the PH value in the reaction kettle is 6-8.
Comparative example one:
s1, preparing the following raw materials in percentage by mass:
80 parts of water-based acrylic emulsion, 0.3 part of mildew-proof bactericide L XE, 0.2 part of defoaming agent 024, 0.1 part of 902W, 0.3 part of dispersing wetting agent 760W, 3280.2 parts of base material wetting agent, 2 parts of leveling agent 2020 and 455 water in a ratio of 1:1, 4 parts of film-forming assistant, 4 parts of multifunctional assistant AMP-950.125, 2 parts of surface assistant wax emulsion, 3 parts of antibacterial insecticide, 5 parts of tourmaline powder and lanthanide anion powder, 0.7 part of polyurethane thickener and the balance of deionized water.
S2, adding deionized water into a dispersion tank, and sequentially adding a dispersion wetting agent, a defoaming agent, an antibacterial insecticide, a multifunctional assistant and anion powder at a dispersion rotation speed of 500 r/min; the dispersion rotating speed is increased to 1200-1500r/min, and the dispersion is carried out until the fineness is below 30 mu m;
s3, adding the water-based acrylic emulsion, the surface auxiliary agent, the film-forming auxiliary agent, the base material wetting agent, the residual mildew-proof bactericide, the leveling agent and the polyurethane thickener at the dispersion speed of 900 r/min; filtering with 220 meshes after full dispersion to obtain the wood lacquer coating.
And (3) performance testing:
the test is set under indoor normal temperature environment, four boards with 2 cubic meters of clean and flat surfaces are vertically placed in the sun in sequence, the water-based wood paints of the first embodiment, the second embodiment, the third embodiment and the first comparative embodiment are respectively coated, the natural air-drying time of the boards is respectively recorded, after the air-drying is finished, the boards are placed in a water pool under a normal temperature state, the time for generating water bubbles is respectively detected, samples of the water-based wood paints are taken in a test tube, the content in each sample is measured, and the test result is recorded as follows:
the detection data of the table show that the waterborne coating for paint film bleeding provided by the embodiment of the invention has more excellent corrosion resistance and rust resistance and better antibacterial rate, can inhibit bacteria in the coating process, and also has the effects of good acid and alkali resistance, aging resistance, good adhesion and the like.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (6)
1. A water-based paint for paint film color bleeding of wood lacquer is characterized in that: the composite material is prepared from the following raw materials in parts by weight:
15-20 parts of water-based acrylic resin;
5-8 parts of a film forming auxiliary agent;
3-6 parts of bisphenol A epoxy resin;
1-3 parts of polyamide;
2-6 parts of photocatalyst powder;
0.1-0.5 part of defoaming agent;
0.3-0.8 part of a leveling agent;
0.4-0.6 part of wetting agent;
0.3-0.7 part of sodium acrylate;
0.5-0.9 part of polyurethane;
0.2-0.8 parts of diatom ooze filler;
0.5-2 parts of sodium polyacrylate;
0.1-0.3 part of polyurethane;
0.3-0.6 part of pH regulator;
3-5 parts of wax emulsion;
0.1-0.3 part of organic acid;
0.3-0.5 part of dextrin;
0.5-0.9 part of sodium molybdate;
0.3-0.6 part of phosphoric acid;
1-3 parts of vegetable glycerin;
0.1-0.4 part of sodium iodide;
1-4 parts of isothiazolinone;
2-3 parts of nano silicon oxide;
5-7 parts of deionized water.
2. The waterborne coating for paint film bleeding of the wood lacquer as claimed in claim 1, which is characterized in that: the defoaming agent is one or more of organic silicon, long-chain alcohol and fatty acid amide.
3. The waterborne coating for paint film bleeding of the wood lacquer as claimed in claim 1, which is characterized in that: the film-forming auxiliary agent is one or more of diethanol ether, propylene glycol ether and N-methyl pyrrolidone.
4. The waterborne coating for paint film bleeding of the wood lacquer as claimed in claim 1, which is characterized in that: the polyurethane is one or more of potassium sorbate, methyl p-hydroxybenzoate, butyl p-hydroxybenzoate and kaempferol.
5. The waterborne coating for paint film bleeding of the wood lacquer as claimed in claim 1, which is characterized in that: the organic acid is any one of citric acid, tartaric acid, malic acid, chlorogenic acid, benzoic acid, salicylic acid and caffeic acid.
6. The waterborne paint for paint film bleeding of the wood lacquer according to claim 1, which provides a preparation method of the waterborne paint for paint film bleeding of the wood lacquer, and is characterized by comprising the following steps:
s1, adding the weighed deionized water and the water-based acrylic resin into a reaction kettle, measuring the leveling agent, the sodium acrylate, the wetting agent and the wax emulsion in the formula, and adding in sequence, and controlling the rotating speed to be 800-1200 r/min for stirring;
s2, weighing bisphenol A epoxy resin, photocatalyst powder, polyamide and diatom ooze filler in formula amount in sequence according to proportion, placing the bisphenol A epoxy resin, the photocatalyst powder, the polyamide, the diatom ooze filler, isothiazolinone and nano silicon oxide in a dispersing container in sequence, dispersing for 30 minutes, wherein the fineness after dispersion is not less than 20 micrometers, and pouring the dispersed material into a reaction kettle for reaction;
s3, independently putting organic acid, dextrin, sodium molybdate, phosphoric acid and deionized water in a formula into a mixing tank, stirring at a constant speed at room temperature, adding glycerol and sodium iodide, stirring for 20 minutes, sequentially adding polyurethane, sodium polyacrylate, polyurethane, a defoaming agent and a film-forming aid, uniformly mixing to form a solution, and taking out the solution for later use;
and S4, sequentially adding the materials in the S3 and the weighed PH regulator into a reaction kettle, stirring and mixing, controlling the rotating speed at 600-800 r/min, stirring uniformly, and obtaining the water-based paint for paint film bleeding when the PH value in the reaction kettle is 6-8.
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| CN107815250A (en) * | 2017-11-16 | 2018-03-20 | 中山市阿里大师新材料有限公司 | A kind of paint film bleeding water paint of woodcare paint and preparation method thereof |
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2020
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101792908A (en) * | 2009-12-22 | 2010-08-04 | 金福东 | Environment-friendly rust remover and production method thereof |
| CN102206450A (en) * | 2011-05-26 | 2011-10-05 | 开平市日固力涂料有限公司 | Composite photocatalysis coating |
| CN103360851A (en) * | 2012-03-30 | 2013-10-23 | 唐述华 | Development method of novel water-based timber rubbling coloring agent |
| CN104403474A (en) * | 2014-12-26 | 2015-03-11 | 成都展辰化工有限公司 | Water-based nano polyacrylate wood paint |
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