CN107805510A - Purification reactor is reformed in a kind of SOLID ORGANIC matter pyrolytic gasification coupling - Google Patents
Purification reactor is reformed in a kind of SOLID ORGANIC matter pyrolytic gasification coupling Download PDFInfo
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- CN107805510A CN107805510A CN201711015079.5A CN201711015079A CN107805510A CN 107805510 A CN107805510 A CN 107805510A CN 201711015079 A CN201711015079 A CN 201711015079A CN 107805510 A CN107805510 A CN 107805510A
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- pyrolytic gasification
- reaction zone
- organic matter
- reformed
- reforming reaction
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/10—Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
- C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/18—Modifying the properties of the distillation gases in the oven
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Abstract
The present invention relates to a kind of SOLID ORGANIC matter pyrolytic gasification couple reform purification reactor, including pyrolytic gasification reaction zone, be arranged on pyrolytic gasification reaction zone side reforming reaction area and reform filtering area；Material inlet and the first catalyst inlet are provided with the top of the pyrolytic gasification reaction zone, bottom is provided with the first returning charge valve；Top is separated by dividing plate between the pyrolytic gasification reaction zone and reforming reaction area, and bottom is separated by grid, and the dividing plate and grid are connected with each other；Product gas outlet and the second catalyst inlet are respectively equipped with the top of the reforming reaction area, bottom is provided with the second returning charge valve；The reformation filtering area is arranged between reforming reaction area and product gas outlet, and top is provided with the 3rd catalyst inlet, and bottom is provided with regulating valve.The reactor integrates pyrolytic gasification, reformation and filtering function, without fluidized wind, has gas-phase product high without tar, calorific value, composition is easily controllable, and structure of reactor is compact, is easy to the remarkable advantage of arrangement.
Description
Technical field
The invention belongs to field of energy utilization, and in particular to purification reaction is reformed in a kind of SOLID ORGANIC matter pyrolytic gasification coupling
Device.
Background technology
When the SOLID ORGANIC such as coal, biomass, domestic waste matter is pyrolyzed under different reaction conditions, all can
Generate gas, liquid and solid three-phase product.The producing synthesis gas by the way of gasification, then it is most to carry out follow-up synthesis conversion
With one of development potentiality technology, it is referred to as indirect liquefaction.Wherein gasification technology is the basic and crucial of indirect liquefaction.
Whether gasification technology is by can be divided into using gasifying agent and without using two kinds of gasifying agent using gasifying agent.Use gasifying agent
Gasification can be divided into air gasification, oxygen gasified, steam gasification, carbon dioxide gasification and mixing gasifying etc..Research is found, is used
The gasification reaction process of gasifying agent is a chemical reaction system for complicated multicomponent polymorphic type, including oxidation reaction, reduction are instead
Should and solid matter cracking etc..Because gasification reaction is generally an endothermic reaction, it is necessary to which providing enough heats could tie up
Hold reaction to carry out, therefore, select gasifying agent to generally comprise air or oxygen.Make gasifying agent using air, due to containing in air
There is substantial amounts of nitrogen, cause flow rate in product low, later separation cost is high；Make gasifying agent using oxygen, then need to increase
Add a set of air separation plant.Only have pyrolytic gasification a kind of without gasifying agent gasification, it is the gas carried out in the case of complete anaerobic
Change reaction, there is the advantages of product calorific value is high, course of reaction is simple, but how to provide external heat source becomes key issue,
Therefore, gasification reactor and reaction process are designed to for emphasis.
Gasification reactor is broadly divided into fixed-bed gasification furnace and fluidized-bed gasification furnace.Fixed-bed gasification furnace is according to gas vent
And the difference of furnace type structure, downdraft, updraft type, horizontal draft and happy formula etc. can be divided into, its advantage is that apparatus structure is simple, hard
Gu durable, operation is convenient and reliable, and operation is low with investment cost；Shortcoming is that internal-response process is difficult to control, heat transfer and mass transfer compared with
Difference, tar and bridge formation are also easy to produce, production intensity is small, is not suitable with the requirement of large-scale development.Fluidized-bed gasification furnace is according to fluidisation shape
State can be divided into bubbling fluidized bed, recirculating fluidized bed and air flow bed etc., and its advantage is that heat and mass is uniform, and gasification reaction speed is fast,
Efficiency of carbon con version is high, easily industry amplification；Shortcoming is device structure complexity, and fixed investment is big, and raw material needs dispersion and fining, ash in combustible gas
Point content is high and tar be present.
The development of limitation gasification technology and industrialized major obstacle are the elimination problems of accessory substance tar at present.Tar is deposited
Easily cause the blocking, corrosion and the damage of equipment of gasification system, cause the inactivation of downstream catalyst and serious environment
Pollution etc..
The content of the invention
Reformed in view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of SOLID ORGANIC matter pyrolytic gasification coupling
Purification reactor, the reactor integrate pyrolytic gasification, reformation and filtering function, without fluidized wind, have gas-phase product not
High containing tar, calorific value, composition is easily controllable, and structure of reactor is compact, is easy to the remarkable advantage of arrangement.
Technical scheme provided by the present invention is：
Purification reactor is reformed in a kind of coupling of SOLID ORGANIC matter pyrolytic gasification, including pyrolytic gasification reaction zone, is arranged on heat
The reforming reaction area of solution gasification reaction zone side and reformation filtering area；
Material inlet and the first catalyst inlet are provided with the top of the pyrolytic gasification reaction zone, bottom is provided with the first returning charge
Valve；Top is separated by dividing plate between the pyrolytic gasification reaction zone and reforming reaction area, and bottom is separated by grid, it is described every
Plate and grid are connected with each other；Product gas outlet and the second catalyst inlet, bottom are respectively equipped with the top of the reforming reaction area
Provided with the second returning charge valve；The reformation filtering area is arranged between reforming reaction area and product gas outlet, and top is provided with the 3rd
Catalyst inlet, bottom are provided with regulating valve.
In above-mentioned technical proposal, raw material solid organic matter particle is entered by material inlet, and pyrolytic gasification catalyst is by first
Catalyst inlet enters, and both realize quick mixing heating and vigorous reaction, heat by mutually colliding in pyrolytic gasification reaction zone
The gas-phase product of solution gasification reaction zone generation is entered in reforming reaction area by grid, with the reforming catalyst in reforming reaction area
Contact continues reforming reaction, and the gas after reformation is further reformed by reforming filtering area and served air filtration
The effect of dust in phase product.Reacted catalyst enters catalyst regeneration system by returning charge valve.
Preferably, the SOLID ORGANIC matter particle includes coal, biomass, domestic waste etc..
Preferably, the wall that the reformation filtering area contacts with reforming reaction area and product gas outlet uses screen cloth；Institute
The aperture for stating screen cloth is less than the particle diameter for reforming catalyst in filtering area.
Preferably, reactiveness is moving bed in the reformation filtering area, and catalyst falling speed is by adjusting regulating valve
To control.
Preferably, if being provided with dry material mixed plate in the pyrolytic gasification reaction zone；The material mixed plate is shaped as
Triangular prism, it be arranged in parallel between each other and is layered Heterogeneous Permutation, the number of plies of the material mixed plate is 8-30 layers.Material mixed plate
Contact area between SOLID ORGANIC matter particle and catalyst can be increased, promote reaction complete.More preferably 8~11 layers.
Preferably, if being provided with dry material mixed plate in the reforming reaction area；The material mixed plate is shaped as Mitsubishi
Post, it be arranged in parallel between each other and is layered Heterogeneous Permutation, the number of plies of the material mixed plate is 3-10 layers.Material mixed plate can
Increase contact area between gas-phase product and catalyst, promote reaction complete.More preferably 3~5 layers.
Preferably, the cross section of the material mixed plate is isosceles triangle, and drift angle scope is 45-90 °.
Preferably, the grid is spaced by inverted v-shaped flase floor and formed；The inverted v-shaped flase floor is asymmetry
Structure, positioned at the angle of pyrolytic gasification reaction zone side edges of boards and vertical direction be less than positioned at reforming reaction area side edges of boards with
The angle of vertical direction.
Preferably, it is 15-45 ° positioned at the angular range of pyrolytic gasification reaction zone side edges of boards and vertical direction；Positioned at weight
The angular range of whole reaction zone side edges of boards and vertical direction is 15-75 °.
Preferably, the inverted v-shaped flase floor is located at the bottom position of pyrolytic gasification reaction zone side edges of boards less than next
The tip position of layer inverted v-shaped flase floor；The bottom position that the inverted v-shaped flase floor is located at reforming reaction area side edges of boards is neat
Put down in the tip position of next layer of inverted v-shaped flase floor.
Preferably, the spacing distance between the inverted v-shaped flase floor is less than the grain of catalyst in pyrolytic gasification reaction zone
Footpath.
Preferably, first catalyst inlet is vertically arranged at the top of pyrolytic gasification reaction zone；The material inlet bag
Two are included, is obliquely installed respectively at the top of pyrolytic gasification reaction zone.
Preferably, two material inlets are symmetricly set at the top of pyrolytic gasification reaction zone, and material inlet and first
The angle of catalyst inlet is 15-75 °.
Preferably, second catalyst inlet and the 3rd catalyst inlet parallel connection are vertically arranged at reforming reaction area top
Portion.
Preferably, the reforming reaction area includes two, is symmetricly set on pyrolytic gasification reaction zone both sides.
Compared with the existing technology, beneficial effects of the present invention are embodied in：
Reactor provided by the present invention integrates pyrolytic gasification, reformation and filtering function, without fluidized wind, has gas
Phase product is high without tar, calorific value, and composition is easily controllable, and structure of reactor is compact, is easy to the remarkable advantage of arrangement.
Brief description of the drawings
Fig. 1 is the structural representation that purification reactor is reformed in the coupling of SOLID ORGANIC matter pyrolytic gasification in embodiment.
Wherein, 1, pyrolytic gasification reaction zone；2nd, reforming reaction area；3rd, filtering area is reformed；4th, dividing plate；5th, grid；6th, material
Mixed plate；7th, the first catalyst inlet；8th, material inlet；9th, the second catalyst inlet；10th, the 3rd catalyst inlet；11st, sieve
Net；12nd, product gas outlet；13rd, the first returning charge valve；14th, the second returning charge valve；15th, regulating valve.
Embodiment
Include pyrolytic gasification reaction zone 1 as shown in figure 1, purification reactor is reformed in the coupling of SOLID ORGANIC matter pyrolytic gasification, set
Put in the reforming reaction area 2 of the both sides of pyrolytic gasification reaction zone 1 and reform filtering area 3.
Wherein, it in the global shape actual production of pyrolytic gasification reaction zone 1 can be vertical cuboid, top is provided with two
The catalyst inlet 7 of material inlet 8 and first, bottom are provided with the first returning charge valve 13.First catalyst inlet 7 is vertically arranged at pyrolysis
The top of gasification reaction area 1, and two material inlets 8 are then respectively symmetrically inclined at the top of pyrolytic gasification reaction zone 1, material enters
The angle of the catalyst inlet 7 of mouth 8 and first is 40 °.
To be symmetrical arranged, the reformation for only introducing side herein is anti-in reforming reaction area 2 due to the both sides of pyrolytic gasification reaction zone 1
Answer area 2.The reforming reaction area 2 of pyrolytic gasification reaction zone 1 and both sides is arranged in reactor.Pyrolytic gasification reaction zone 1 with again
Top is separated by dividing plate 4 between whole reaction zone 2, and bottom is separated by grid 5, and dividing plate 4 and grid 5 are connected with each other Liang Ge areas
Domain separates.
Dividing plate 4 uses solid slab, and pyrolytic gasification reaction zone 1 and the reforming reaction area 2 of both sides are kept apart.And grid 5 by
Inverted v-shaped flase floor is spaced composition, and inverted v-shaped flase floor is dissymmetrical structure, positioned at the side plate of pyrolytic gasification reaction zone 1
The angle of side and vertical direction is less than the angle of the side edges of boards and vertical direction positioned at reforming reaction area 2.Positioned at pyrolytic gasification
The angular range of the side edges of boards of reaction zone 1 and vertical direction is 30 °；Side edges of boards and vertical direction positioned at reforming reaction area 2
Angular range be 45 °.The bottom position that inverted v-shaped flase floor is located at the side edges of boards of pyrolytic gasification reaction zone 1 is less than next layer
The tip position of inverted v-shaped flase floor；The bottom position that inverted v-shaped flase floor is located at the side edges of boards of reforming reaction area 2 is flush to
The tip position of next layer of inverted v-shaped flase floor.In addition, the spacing distance between inverted v-shaped flase floor is anti-less than pyrolytic gasification
Answer the particle diameter of pyrolytic gasification catalyst in area 1.
The top of reforming reaction area 2 is respectively equipped with the catalyst inlet 9 of product gas outlet 12 and second, and bottom is provided with second
Returning charge valve 14.And reform filtering area 3 and be then arranged between reforming reaction area 2 and product gas outlet 12, top is urged provided with the 3rd
Agent import 10, bottom are provided with regulating valve 15, and it is moving bed to reform reactiveness in filtering area 3, reforming catalyst falling speed
Controlled by adjusting regulating valve 15.
Reform the wall that filtering area 3 contacts with reforming reaction area 2 and product gas outlet 12 and use screen cloth 11, screen cloth 11
Aperture is less than the particle diameter for reforming reforming catalyst in filtering area 3.In addition, the second catalyst inlet 9 and the 3rd catalyst inlet 10
Parallel connection is vertically arranged at the top of reforming reaction area 2.
In addition, if dry material mixed plate 6, material mixed plate 6 are equipped with pyrolytic gasification reaction zone 1 and reforming reaction area 2
Be shaped as triangular prism, both ends are individually fixed in the two side walls in pyrolytic gasification reaction zone 1 and reforming reaction area 2.Material mixes
The cross section of plate is isosceles triangle, and corner angle is 90 °, be arranged in parallel between each other and is layered Heterogeneous Permutation, pyrolytic gasification
The number of plies of material mixed plate 6 in reaction zone 1 is 11 layers, and the number of plies of the material mixed plate 6 in reforming reaction area 2 is 3 floor.
The course of work is as follows：
Raw material solid organic matter particle is passed into material inlet 8, and SOLID ORGANIC matter can be coal, biomass, urban life
Rubbish etc., and pyrolytic gasification catalyst is then passed into the first catalyst inlet 7, both are reacted by mutually colliding in pyrolytic gasification
Area 1 realizes quick mixing heating and vigorous reaction, if the dry material mixed plate 6 in pyrolytic gasification reaction zone 1 promotes raw material and heat
Solve the haptoreaction of gasifying catalyst.
Due to pyrolytic gasification reaction zone 1 and " W " the type structure setting in reforming reaction area 2 so that pyrolytic gasification reaction zone 1 is given birth to
Into gas-phase product, can enter from the bottom of pyrolytic gasification reaction zone 1 by grid 5 in reforming reaction area 2, with reforming reaction area 2
Interior reforming catalyst, which contacts, continues reforming reaction, and the reforming catalyst in reforming reaction area 2 is by the second catalyst inlet 9
It is passed through.And if equally to also promote contact of the gas-phase product with reforming catalyst anti-for the dry material mixed plate 6 in reforming reaction area 2
Should.
Reacted gas enters reformation filtering area 3 and further reacted, and filtration catalytic agent is led to by the 3rd catalyst inlet 10
Enter, and serve the effect of dust in filtering gas-phase product.The 2 reacted catalysis of pyrolytic gasification reaction zone 1 and reforming reaction area
Agent, catalyst regeneration system is respectively enterd by the first returning charge valve 13 and the second returning charge valve 14 respectively.
Claims (10)
1. purification reactor is reformed in a kind of coupling of SOLID ORGANIC matter pyrolytic gasification, it is characterised in that including pyrolytic gasification reaction zone,
It is arranged on the reforming reaction area of pyrolytic gasification reaction zone side and reforms filtering area；
Material inlet and the first catalyst inlet are provided with the top of the pyrolytic gasification reaction zone, bottom is provided with the first returning charge valve；Institute
Top between pyrolytic gasification reaction zone and reforming reaction area is stated to separate by dividing plate, bottom is separated by grid, the dividing plate and
Grid is connected with each other；Product gas outlet and the second catalyst inlet are respectively equipped with the top of the reforming reaction area, bottom is provided with
Second returning charge valve；The reformation filtering area is arranged between reforming reaction area and product gas outlet, and top is provided with the 3rd catalysis
Agent import, bottom are provided with regulating valve.
2. purification reactor is reformed in SOLID ORGANIC matter pyrolytic gasification coupling according to claim 1, it is characterised in that described
Reform the wall that filtering area contacts with reforming reaction area and product gas outlet and use screen cloth；The aperture of the screen cloth, which is less than, reforms
The particle diameter of catalyst in filtering area.
3. purification reactor is reformed in SOLID ORGANIC matter pyrolytic gasification coupling according to claim 1, it is characterised in that described
If it is provided with dry material mixed plate in pyrolytic gasification reaction zone；The material mixed plate is shaped as triangular prism, parallel between each other
Set and be layered Heterogeneous Permutation, the number of plies of the material mixed plate is 8-30 layers.
4. purification reactor is reformed in SOLID ORGANIC matter pyrolytic gasification coupling according to claim 1, it is characterised in that described
If dry material mixed plate is provided with reforming reaction area；The material mixed plate is shaped as triangular prism, be arranged in parallel between each other
And layering Heterogeneous Permutation, the number of plies of the material mixed plate is 3-10 layers.
5. purification reactor is reformed in SOLID ORGANIC matter pyrolytic gasification coupling according to claim 1, it is characterised in that described
Grid is spaced by inverted v-shaped flase floor and formed；The inverted v-shaped flase floor is dissymmetrical structure, anti-positioned at pyrolytic gasification
The angle of Ying Qu sides edges of boards and vertical direction is less than the angle of the side edges of boards and vertical direction positioned at reforming reaction area.
6. purification reactor is reformed in SOLID ORGANIC matter pyrolytic gasification coupling according to claim 5, it is characterised in that described
Inverted v-shaped flase floor is located at top of the bottom position less than next layer of inverted v-shaped flase floor of pyrolytic gasification reaction zone side edges of boards
Portion position；The bottom position that the inverted v-shaped flase floor is located at reforming reaction area side edges of boards is flush to next floor inverted v-shaped lattice
The tip position of screen.
7. purification reactor is reformed in SOLID ORGANIC matter pyrolytic gasification coupling according to claim 5, it is characterised in that described
Spacing distance between inverted v-shaped flase floor is less than the particle diameter of catalyst in pyrolytic gasification reaction zone.
8. purification reactor is reformed in SOLID ORGANIC matter pyrolytic gasification coupling according to claim 1, it is characterised in that described
First catalyst inlet is vertically arranged at the top of pyrolytic gasification reaction zone；The material inlet includes two, is obliquely installed respectively
At the top of pyrolytic gasification reaction zone.
9. purification reactor is reformed in SOLID ORGANIC matter pyrolytic gasification coupling according to claim 1, it is characterised in that described
Second catalyst inlet and the 3rd catalyst inlet parallel connection are vertically arranged at the top of reforming reaction area.
10. purification reactor is reformed in SOLID ORGANIC matter pyrolytic gasification coupling according to claim 1, it is characterised in that institute
Stating reforming reaction area includes two, is symmetricly set on pyrolytic gasification reaction zone both sides.
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| CN201711015079.5A CN107805510B (en) | 2017-10-25 | 2017-10-25 | Pyrolysis gasification coupling reforming purification reactor for solid organic matters |
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| CN101021334A (en) * | 2007-03-16 | 2007-08-22 | 合肥工业大学 | Internal-combustion heating type biomass gasification furnace |
| US20110308155A1 (en) * | 2010-06-16 | 2011-12-22 | Paskach Thomas J | Producing Low Tar Gases in a Multi-Stage Gasifier |
| CN203269882U (en) * | 2013-04-07 | 2013-11-06 | 邢力 | Pyrolysis catalysis gasifier for domestic garbage |
| CN104031693A (en) * | 2014-05-21 | 2014-09-10 | 梁鹏 | Integrated device and process for carrying out desulfurization, dust removal and modification on coal-pyrolyzed gas |
| CN106367119A (en) * | 2016-10-26 | 2017-02-01 | 南京大学 | Pyrolysis and biomass gas catalytic reforming reactor and application thereof |
| CN207596788U (en) * | 2017-10-25 | 2018-07-10 | 浙江科技学院 | Purification reactor is reformed in a kind of SOLID ORGANIC matter pyrolytic gasification coupling |
-
2017
- 2017-10-25 CN CN201711015079.5A patent/CN107805510B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101021334A (en) * | 2007-03-16 | 2007-08-22 | 合肥工业大学 | Internal-combustion heating type biomass gasification furnace |
| US20110308155A1 (en) * | 2010-06-16 | 2011-12-22 | Paskach Thomas J | Producing Low Tar Gases in a Multi-Stage Gasifier |
| CN203269882U (en) * | 2013-04-07 | 2013-11-06 | 邢力 | Pyrolysis catalysis gasifier for domestic garbage |
| CN104031693A (en) * | 2014-05-21 | 2014-09-10 | 梁鹏 | Integrated device and process for carrying out desulfurization, dust removal and modification on coal-pyrolyzed gas |
| CN106367119A (en) * | 2016-10-26 | 2017-02-01 | 南京大学 | Pyrolysis and biomass gas catalytic reforming reactor and application thereof |
| CN207596788U (en) * | 2017-10-25 | 2018-07-10 | 浙江科技学院 | Purification reactor is reformed in a kind of SOLID ORGANIC matter pyrolytic gasification coupling |
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