CN107790290A - The beneficiation method of fluorite is reclaimed in a kind of white tungsten rough concentrate - Google Patents

The beneficiation method of fluorite is reclaimed in a kind of white tungsten rough concentrate Download PDF

Info

Publication number
CN107790290A
CN107790290A CN201711011044.4A CN201711011044A CN107790290A CN 107790290 A CN107790290 A CN 107790290A CN 201711011044 A CN201711011044 A CN 201711011044A CN 107790290 A CN107790290 A CN 107790290A
Authority
CN
China
Prior art keywords
fluorite
white tungsten
preconcentration
concentrate
rough concentrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201711011044.4A
Other languages
Chinese (zh)
Other versions
CN107790290B (en
Inventor
王延锋
贾宗植
车文芳
郭明杰
简建军
郑灿辉
王向辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Molybdenum Co Ltd
Original Assignee
China Molybdenum Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Molybdenum Co Ltd filed Critical China Molybdenum Co Ltd
Priority to CN201711011044.4A priority Critical patent/CN107790290B/en
Publication of CN107790290A publication Critical patent/CN107790290A/en
Application granted granted Critical
Publication of CN107790290B publication Critical patent/CN107790290B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00Specified materials treated by the flotation agents; specified applications
    • B03D2203/02Ores
    • B03D2203/04Non-sulfide ores

Landscapes

  • Manufacture And Refinement Of Metals (AREA)

Abstract

The beneficiation method of fluorite is reclaimed in a kind of white tungsten rough concentrate of the present invention, fluorite recovery technical field of beneficiation is reclaimed in more particularly to white tungsten rough concentrate, successfully solve that Luoyang Luanchuan Area skarn type scheelite bed Associated Fluorite grade is low, is difficult to the problem that reclaims, obtain good economic benefit and social benefit.Using white tungsten rough concentrate preconcentration-preconcentration mine tailing fluorite flow, it is 93.02% that can obtain grade, and the rate of recovery is 41.76% fluorite concentrate.Calcite grade is 3.68% in fluorite concentrate, and the loss late of tungsten is only 0.344%.

Description

The beneficiation method of fluorite is reclaimed in a kind of white tungsten rough concentrate
Technical field:
The present invention relates to fluorite technical field of beneficiation, the beneficiation method of fluorite is reclaimed in especially a kind of white tungsten rough concentrate.
Background technology:
Skarn type scheelite bed, containing substantial amounts of quartz, it is associated with a certain amount of calcium carbonate, fluorite etc., but the product of fluorite Position is not general high, does not reach the economic balanced grade of comprehensive reutilization.The scheelite of Luoyang, henan city Luanchuan Area is typical silicon Card lithotype mineral deposit, the day processing of white tungsten flotation reach 50000 tpds, and fluorite grade is between 7%-10% in raw ore, and grade is too It is low, always can not comprehensive reutilization.Wherein in white tungsten rougher process, the grade of fluorite is enriched with and is enriched with also with white tungsten, The grade of fluorite is 28%-30% in white tungsten rough concentrate, and there is very high recycling to be worth.
The content of the invention:
Above-mentioned in order to overcome the shortcomings of, the invention provides the beneficiation method that fluorite is reclaimed in a kind of white tungsten rough concentrate.
The technical solution adopted for the present invention to solve the technical problems:
The beneficiation method of fluorite is reclaimed in a kind of white tungsten rough concentrate, is comprised the following steps:
Firstth, white tungsten rough concentrate preconcentration flotation
Inhibitor waterglass 3000-4000g/t is added in white tungsten rough concentrate, carries out white tungsten preconcentration;
White tungsten preconcentration concentrate enters white tungsten heating concentration, and white tungsten preconcentration mine tailing enters fluorite;
Secondth, preconcentration mine tailing fluorite
White tungsten preconcentration mine tailing adds collecting agent NAK550-650g/t, obtains fluorite rough concentrate;
Fluorite rough concentrate is carried out successively ten times it is selected, ten times it is selected in sequentially add inhibitor acidified sodium silicate 800-1000g/ t、800-1000g/t、650-800g/t、650-800g/t、500-650g/t、400-500g/t、400-500g/t、400- 500g/t, 300-400g/t, 200-300g/t, add inhibitor ATM100-150g/t, 100-120g/t, 80-120g/t, 60- 80g/t、50-60g/t、40-50g/t;、30-40g/t、20-30g/t、10-20g/t;, 10-20g/t, fluorite mine tailing X and First time fluorite cleaner tailings and second of fluorite cleaner tailings return to white tungsten roughing together;
Third time fluorite cleaner tailings to the tenth fluorite cleaner tailings carries out tentatively taking off tungsten processing together, and adds ATM40- 60g/t, do further flotation;
Fluorite chats M is returned into white tungsten heating concentration, it is selected that concentrate returns to third time fluorite.
Due to using technical scheme as described above, the present invention has following superiority:
The beneficiation method of fluorite is reclaimed in a kind of white tungsten rough concentrate of the present invention, successfully solves skarn type scheelite Bed Associated Fluorite head grade is low, is difficult to the problem that reclaims, obtains good economic benefit and social benefit.
Brief description of the drawings:
Fig. 1 is the flow chart of the present invention.
Embodiment:
The present invention can be explained in more detail by example below, the open purpose of the present invention is intended to protect in the scope of the invention All changes and improvements, the invention is not limited in the following examples;
The beneficiation method of fluorite is reclaimed in a kind of white tungsten rough concentrate, is comprised the following steps:
Firstth, white tungsten rough concentrate preconcentration flotation
Inhibitor waterglass 3500g/t is added in white tungsten rough concentrate, carries out white tungsten preconcentration;
White tungsten preconcentration concentrate enters white tungsten heating concentration, and white tungsten preconcentration mine tailing enters fluorite;
Secondth, preconcentration mine tailing fluorite
White tungsten preconcentration mine tailing adds collecting agent NAK600g/t, obtains fluorite rough concentrate;
Fluorite rough concentrate is carried out successively ten times it is selected, ten times it is selected in sequentially add inhibitor acidified sodium silicate 900g/t, 900g/t, 700g/t, 700g/t, 600g/t, 450g/t, 450g/t, 450g/t, 350g/t, 250g/t, add inhibitor ATM100g/t、100g/t、80g/t、70g/t、60g/t、50g/t;、40g/t、0g/t、20g/t;, 10g/t, fluorite tail Ore deposit X and first time fluorite cleaner tailings and second of fluorite cleaner tailings return to white tungsten roughing together;
Third time fluorite cleaner tailings to the tenth fluorite cleaner tailings carries out tentatively taking off tungsten processing together, and adds ATM50g/ T, do further flotation;
Fluorite chats M is returned into white tungsten heating concentration, it is selected that concentrate returns to third time fluorite.
Final fluorite concentrate grade is 93.02%, the rate of recovery 41.76%, and calcite grade is 3.68% in fluorite concentrate, The loss late of tungsten is only 0.344%.
It is prior art not state part in above content carefully, therefore does not run business into particular one and state.

Claims (1)

1. the beneficiation method of fluorite is reclaimed in a kind of white tungsten rough concentrate, it is characterised in that:Comprise the following steps:
Firstth, white tungsten rough concentrate preconcentration flotation
Inhibitor waterglass 3000-4000g/t is added in white tungsten rough concentrate, carries out white tungsten preconcentration;
White tungsten preconcentration concentrate enters white tungsten heating concentration, and white tungsten preconcentration mine tailing enters fluorite;
Secondth, preconcentration mine tailing fluorite
White tungsten preconcentration mine tailing adds collecting agent NAK550-650g/t, obtains fluorite rough concentrate;
Fluorite rough concentrate is carried out successively ten times it is selected, ten times it is selected in sequentially add inhibitor acidified sodium silicate 800-1000g/ t、800-1000g/t、650-800g/t、650-800g/t、500-650g/t、400-500g/t、400-500g/t、400- 500g/t, 300-400g/t, 200-300g/t, add inhibitor ATM100-150g/t, 100-120g/t, 80-120g/t, 60- 80g/t、50-60g/t、40-50g/t;、30-40g/t、20-30g/t、10-20g/t;, 10-20g/t, fluorite mine tailing X and First time fluorite cleaner tailings and second of fluorite cleaner tailings return to white tungsten roughing together;
Third time fluorite cleaner tailings to the tenth fluorite cleaner tailings carries out tentatively taking off tungsten processing together, and adds ATM40- 60g/t, do further flotation;
Fluorite chats M is returned into white tungsten heating concentration, it is selected that concentrate returns to third time fluorite.
CN201711011044.4A 2017-10-26 2017-10-26 Beneficiation method for recovering fluorite from scheelite rough concentrate Active CN107790290B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711011044.4A CN107790290B (en) 2017-10-26 2017-10-26 Beneficiation method for recovering fluorite from scheelite rough concentrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711011044.4A CN107790290B (en) 2017-10-26 2017-10-26 Beneficiation method for recovering fluorite from scheelite rough concentrate

Publications (2)

Publication Number Publication Date
CN107790290A true CN107790290A (en) 2018-03-13
CN107790290B CN107790290B (en) 2020-04-17

Family

ID=61547318

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711011044.4A Active CN107790290B (en) 2017-10-26 2017-10-26 Beneficiation method for recovering fluorite from scheelite rough concentrate

Country Status (1)

Country Link
CN (1) CN107790290B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108672091A (en) * 2018-04-28 2018-10-19 武汉科技大学 A kind of method of dolomite type fluorite flotation fluorite
CN108722660A (en) * 2018-05-18 2018-11-02 中国地质科学院郑州矿产综合利用研究所 Beneficiation method of low-grade scheelite
CN109092564A (en) * 2018-06-29 2018-12-28 湖南柿竹园有色金属有限责任公司 A kind of beneficiation method of black and white tungsten tin bulk concentrate
CN111068925A (en) * 2019-12-23 2020-04-28 中南大学 Application of 2- (3-substituted ureido) -N-hydroxy-2-oxyacetonitride cyanide compounds in flotation
CN111841826A (en) * 2020-06-11 2020-10-30 矿冶科技集团有限公司 Beneficiation method for high-calcium carbonate type low-grade scheelite
CN114653479A (en) * 2022-04-11 2022-06-24 湖南有色郴州氟化学有限公司 Multi-metal co-associated fluorite ore de-drug flotation method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2319550C1 (en) * 2006-07-11 2008-03-20 ФГУП "Всероссийский научно-исследовательский институт химической технологии" Collector for floatation of fluorite ores
CN103316770A (en) * 2013-05-23 2013-09-25 包钢集团矿山研究院(有限责任公司) Mineral processing technology for recycling fluorite from baotite, magnetite and tailing
CN103316772A (en) * 2013-06-08 2013-09-25 中南大学 Beneficiation method for centralized processing of middlings of high-calcium-carbonate low-grade fluorite mine
CN105170335A (en) * 2015-05-29 2015-12-23 洛阳栾川钼业集团股份有限公司 Process for floatation of high-concentration scheelite rough concentrate
CN106311488A (en) * 2016-10-25 2017-01-11 洛阳栾川钼业集团股份有限公司 Beneficiation method for recovery of fluorite in white tungsten heating cleaner tailings

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2319550C1 (en) * 2006-07-11 2008-03-20 ФГУП "Всероссийский научно-исследовательский институт химической технологии" Collector for floatation of fluorite ores
CN103316770A (en) * 2013-05-23 2013-09-25 包钢集团矿山研究院(有限责任公司) Mineral processing technology for recycling fluorite from baotite, magnetite and tailing
CN103316772A (en) * 2013-06-08 2013-09-25 中南大学 Beneficiation method for centralized processing of middlings of high-calcium-carbonate low-grade fluorite mine
CN105170335A (en) * 2015-05-29 2015-12-23 洛阳栾川钼业集团股份有限公司 Process for floatation of high-concentration scheelite rough concentrate
CN106311488A (en) * 2016-10-25 2017-01-11 洛阳栾川钼业集团股份有限公司 Beneficiation method for recovery of fluorite in white tungsten heating cleaner tailings

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
敖迎春等: "从湖南某白钨浮选尾矿中回收萤石的试验", 《现代矿业》 *
蒋祥伟等: "国外某难处理低品位萤石选矿试验研究", 《化工矿物与加工》 *
蒲伟等: "湖南某钨尾萤石脱药浮选新工艺研究与应用", 《非金属矿》 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108672091A (en) * 2018-04-28 2018-10-19 武汉科技大学 A kind of method of dolomite type fluorite flotation fluorite
CN108722660A (en) * 2018-05-18 2018-11-02 中国地质科学院郑州矿产综合利用研究所 Beneficiation method of low-grade scheelite
CN109092564A (en) * 2018-06-29 2018-12-28 湖南柿竹园有色金属有限责任公司 A kind of beneficiation method of black and white tungsten tin bulk concentrate
CN111068925A (en) * 2019-12-23 2020-04-28 中南大学 Application of 2- (3-substituted ureido) -N-hydroxy-2-oxyacetonitride cyanide compounds in flotation
CN111068925B (en) * 2019-12-23 2020-10-16 中南大学 Application of 2- (3-substituted ureido) -N-hydroxy-2-oxyacetonitride cyanide compounds in flotation
CN111841826A (en) * 2020-06-11 2020-10-30 矿冶科技集团有限公司 Beneficiation method for high-calcium carbonate type low-grade scheelite
CN111841826B (en) * 2020-06-11 2021-12-10 矿冶科技集团有限公司 Beneficiation method for high-calcium carbonate type low-grade scheelite
CN114653479A (en) * 2022-04-11 2022-06-24 湖南有色郴州氟化学有限公司 Multi-metal co-associated fluorite ore de-drug flotation method

Also Published As

Publication number Publication date
CN107790290B (en) 2020-04-17

Similar Documents

Publication Publication Date Title
CN107790290A (en) The beneficiation method of fluorite is reclaimed in a kind of white tungsten rough concentrate
CN103418488B (en) Comprehensive recovery process of lithium polymetallic ore associated with fine niobium and tantalum
CN105435953B (en) Beneficiation method for molybdenum-containing low-grade mixed copper ore
CN101507951B (en) Mineral separation process capable of separating copper, lead, zinc polymetal sulphide ore
CN101884951B (en) Combined mineral dressing technology of fine grain and micro grain cassiterite
CN103381389B (en) Production technology for improving secondary recovery rate of tailings
CN105750093B (en) A kind of method for floating of cupric oxide ore
CN109127120B (en) Beneficiation method for tungsten-tin ore
CN107638959B (en) Flotation method for inhibiting silicate gangue minerals in fluorite ores
CN103071596B (en) Method for recycling fine and superfine cassiterites from oxidized lode tin mud tailings
CN105797868A (en) Beneficiation method for recovering low-grade zinc oxide ore from lead-zinc ore flotation tailings
CN105597926A (en) Beneficiation method for rubidium-containing feldspar quarry
CN104148163B (en) A kind of beneficiation method processing low-grade tin-lead-zinc multi-metal oxygen ore deposit
CN109806966B (en) Beneficiation method for comprehensively recovering strontium minerals from rare earth tailings
CN103301949B (en) Foaming agent for rare earth ore dressing and normal-temperature ore dressing process of low-grade refractory rare earth ore
CN103506214B (en) Separation-flotation technology of rough sand and secondary slime of vein gold ores
CN104475237A (en) Mineral processing technology of refractory molybdenum ores with molybdenite and pyrite in close symbiotic relationship
CN102274800A (en) Composite inhibitor for inhibition in flotation of copper sulfide ore
CN105597938A (en) Beneficiation method of scheelite
CN104511373A (en) Mineral separation method for high-oxidative molybdenum ore
CN105013616A (en) Method for separating molybdenum concentrate and lead-sulfur concentrate from molybdenum-lead-sulfur mixed concentrate
CN104858066B (en) A kind of direct reverse flotation technique for preparing high-purity iron concentrate
CN106492993A (en) Suppress the composite restrainer of particulate silicate gangue
CN114247559A (en) Tailing-free ore dressing method for lithium ore recovery
CN107899755A (en) A kind of refractory oxidized copper ore flotation synergist

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant