CN107790159B - 一种高选择性催化氧化醇成醛的光催化剂及其制备与应用 - Google Patents
一种高选择性催化氧化醇成醛的光催化剂及其制备与应用 Download PDFInfo
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- CN107790159B CN107790159B CN201710899693.6A CN201710899693A CN107790159B CN 107790159 B CN107790159 B CN 107790159B CN 201710899693 A CN201710899693 A CN 201710899693A CN 107790159 B CN107790159 B CN 107790159B
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- 239000011941 photocatalyst Substances 0.000 title claims abstract description 52
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- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 26
- 230000003647 oxidation Effects 0.000 title claims abstract description 25
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 title abstract 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229940073609 bismuth oxychloride Drugs 0.000 claims abstract description 28
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000002135 nanosheet Substances 0.000 claims abstract description 20
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 16
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- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 18
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 16
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- 239000003054 catalyst Substances 0.000 claims description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
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- 238000005286 illumination Methods 0.000 claims description 8
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- 229910052724 xenon Inorganic materials 0.000 claims description 7
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 7
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 6
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- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 5
- 229930195725 Mannitol Natural products 0.000 claims description 5
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- 235000010355 mannitol Nutrition 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- FBXVOTBTGXARNA-UHFFFAOYSA-N bismuth;trinitrate;pentahydrate Chemical compound O.O.O.O.O.[Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FBXVOTBTGXARNA-UHFFFAOYSA-N 0.000 claims description 4
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
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- 239000000203 mixture Substances 0.000 claims description 2
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims description 2
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- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 6
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- MSHFRERJPWKJFX-UHFFFAOYSA-N 4-Methoxybenzyl alcohol Chemical compound COC1=CC=C(CO)C=C1 MSHFRERJPWKJFX-UHFFFAOYSA-N 0.000 description 3
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- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 3
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- 239000002086 nanomaterial Substances 0.000 description 1
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- 229910000510 noble metal Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
- B01J27/13—Platinum group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/393—Metal or metal oxide crystallite size
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
- B01J37/344—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Description
序号 | 催化剂 | 照射时间(h) | 选择性(%) | 转化率(%) | 产率(%) |
1 | BiOCl-Pd | 1 | 100 | 11 | 11 |
2 | BiOCl-Pd | 3 | 97 | 41 | 39.77 |
3 | BiOCl-Pd | 5 | 94 | 80 | 75.2 |
4 | BiOCl-Pd | 8 | 93 | 99 | 92.07 |
Claims (5)
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CN201710899693.6A CN107790159B (zh) | 2017-09-28 | 2017-09-28 | 一种高选择性催化氧化醇成醛的光催化剂及其制备与应用 |
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CN201710899693.6A CN107790159B (zh) | 2017-09-28 | 2017-09-28 | 一种高选择性催化氧化醇成醛的光催化剂及其制备与应用 |
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CN107790159B true CN107790159B (zh) | 2020-05-01 |
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Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109134228A (zh) * | 2018-06-22 | 2019-01-04 | 杭州电子科技大学 | 一种室温催化苯甲醇生成苯甲醛的方法 |
CN109046400A (zh) * | 2018-07-23 | 2018-12-21 | 汕头大学 | 一种贵金属Pt改性的BiOI光催化剂及其制备与应用 |
CN109174138A (zh) * | 2018-08-08 | 2019-01-11 | 江苏大学 | 一种Bi4O5I2超薄中空纳米管光催化剂的制备方法 |
CN109701565B (zh) * | 2019-01-11 | 2022-04-29 | 中国科学院合肥物质科学研究院 | 一种适用于一步法合成安息香乙醚的卤氧铋基金属热催化剂 |
CN109794271B (zh) * | 2019-01-28 | 2021-09-10 | 江苏大学 | 一种富氧缺陷超薄PbBiO2Br纳米片的制备方法及其用途 |
CN110467219B (zh) * | 2019-06-26 | 2022-03-11 | 广东工业大学 | 一种单层量子点BiOBr及其制备方法和应用 |
CN112121851A (zh) * | 2020-09-17 | 2020-12-25 | 哈尔滨理工大学 | 一种Ni修饰的TS-1分子筛催化剂及其光催化在醇氧化中的应用 |
CN115845882B (zh) * | 2022-11-17 | 2024-03-15 | 北京师范大学 | 一种双空位和界面电场协同的超薄纳米片及其制备方法、应用 |
Citations (5)
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CN101024188A (zh) * | 2007-02-15 | 2007-08-29 | 中国科学院上海硅酸盐研究所 | 卤氧化物光催化材料及其制备方法 |
CN101850263A (zh) * | 2010-06-17 | 2010-10-06 | 江西理工大学 | 一种Ag掺杂的BiOBr催化材料及其制备方法与应用 |
CN102794186A (zh) * | 2007-02-15 | 2012-11-28 | 中国科学院上海硅酸盐研究所 | 卤氧化物光催化材料及其制备方法 |
CN106622303A (zh) * | 2016-12-02 | 2017-05-10 | 安徽理工大学 | 一种催化硝基苯酚氢化还原的催化剂及其应用 |
CN106984312A (zh) * | 2017-04-24 | 2017-07-28 | 福州大学 | 一种复合型光催化剂及其制备方法 |
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2017
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"A novel Ag_BiOBr nanoplate catalyst with high photocatalytic activity in the decomposition of dyes";Changlin Yu et al;《Reac Kinet Mech Cat》;20110215;第103卷;第141-151页 * |
"Novel noble metal (Rh, Pd, Pt)/BiOX(Cl, Br, I) composite photocatalysts with enhanced photocatalytic performance in dye degradation";Changlin Yu et al;《Separation and Purification Technology》;20131009;第120卷;第110-112页 * |
"Novel noble metal (Rh, Pd, Pt)_BiOX(Cl, Br, I) composite photocatalysts with enhanced photocatalytic performance in dye degradation";Changlin Yu et al;《Separation and Purification Technology》;20131009;第120卷;第110-112页 * |
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