CN107778025A - A kind of preparation method of high shock resistance cement polyphenyl formwork concrete wall - Google Patents

A kind of preparation method of high shock resistance cement polyphenyl formwork concrete wall Download PDF

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Publication number
CN107778025A
CN107778025A CN201711148102.8A CN201711148102A CN107778025A CN 107778025 A CN107778025 A CN 107778025A CN 201711148102 A CN201711148102 A CN 201711148102A CN 107778025 A CN107778025 A CN 107778025A
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polyphenyl formwork
shock resistance
concrete wall
preparation
high shock
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CN201711148102.8A
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CN107778025B (en
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刘玉峰
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Jilin Jianzhu University
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Jilin Jianzhu University
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B2/00Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
    • E04B2/84Walls made by casting, pouring, or tamping in situ
    • E04B2/86Walls made by casting, pouring, or tamping in situ made in permanent forms
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/76Use at unusual temperatures, e.g. sub-zero

Abstract

The invention discloses a kind of preparation method of high shock resistance cement polyphenyl formwork concrete wall, on the basis of traditional cement polyphenyl formwork, adds graphene oxide and is handled using antidetonation treatment fluid.The main component of antidetonation treatment fluid is organosilicon, and main function is under ultrasound condition, is distributed to inside cement polyphenyl formwork, forms network structure, and so as to reach superpower anti seismic efficiency, the effect for adding cerium oxide is to accelerate networking speed, lifts networking effect.Graphene oxide functions as carrier, provides support for the networking of organosilicon, networking space is bigger, and density is higher;Simultaneous oxidation graphene and organosilicon are further combined with coming earthquake, forming stable network structure, stability is good.The high shock resistance cement polyphenyl formwork concrete wall of the present invention, light-weight aseismatic, fire-proof and thermal-insulation, load-bearing antidetonation not only with traditional cement polyphenyl formwork, it is resistance to freeze the advantages of durable and saving of work and time saves money, and its anti seismic efficiency is superpower.

Description

A kind of preparation method of high shock resistance cement polyphenyl formwork concrete wall
Technical field
The present invention relates to building material technical field, more particularly to a kind of high shock resistance cement polyphenyl formwork concrete wall Preparation method.
Background technology
Cement polyphenyl mould case lattice type concrete wall is the cement and expanded granular polystyrene formwork and scene by plant produced The assembled wall that the lattice concrete frame poured is formed, abbreviation lattice type concrete wall.Cement polyphenyl formwork lattice Concrete wall have design, construction is simple, low engineering cost, shock resistant heat insulating performance is good, increase usable floor area the advantages that, at present It has been used widely.
Products characteristics
Lightweight:This product is pressed into formwork by polystyrene granule foaming material mix cement, additive, and thousand density are 350kg/ m3;Antidetonation:Wall reaches more than 75% with polyphenyl materials average thickness more than 150mm, no cold bridge, building energy conservation;It is heat-insulated:Heat conduction Coefficient is not more than 0.081W/ (mK);Sound insulation:Polyphenyl expanded material inherently has a soundproof effect, and sound transmission loss is average>50DB; Fire resisting:For cement polyphenyl mould case lattice type concrete wall after the 4h that burns, wall is still complete;Environmental protection:Cement polyphenyl formwork is comprehensive Conjunction utilizes waste and old resource, reduces cost, turns waste into wealth, reduces environmental pollution.
Outside exterior wall while the popularization of anti-seismic technology Shan speed, there is also many unsatisfactory places, state planted agent at present Situations below be present with antidetonation system outside more polyphenyl plate thin plastering exterior wall:
Outer layer is plastered surface crack, fiberglass gridding cloth improper use, node and special parts treatment is improper, styrofoam It is pasted not strongly, using improper works material etc..Cement polyphenyl mould case lattice type concrete wall, basic model formwork thickness are 250mm, core bore concrete is removed, for the antidetonation granular polystyrene average thickness of wall up to more than 100mm, anti seismic efficiency is good, real Detected in the application of border, building enclosure is 0.8W/ (mK) to heat transfer coefficient, and different according to power conservation requirement, can produce thickness is 300mm or 350mm formwork, cold and severe cold area residential housing winter antidetonation can be met;Heat inertia index meets south Regional house summer heat-insulated basic demand.Can be all using the building of cement polyphenyl mould case lattice type concrete wall.Such as floor Also the six face antidetonations in each room then be can be achieved using cement polyphenyl formwork, anti seismic efficiency more preferably, its construct also reduce template and The usage amount of concrete.
The present invention improves the formula of polyphenyl formwork, improves polyphenyl on the basis of traditional cement polyphenyl formwork The anti seismic efficiency of form wall, superpower anti seismic efficiency is can reach under conditions of thickness is below 200mm, is highly suitable for The building requirements in the multiple area of earthquake.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of high shock resistance cement polyphenyl formwork concrete The preparation method of wall.
Technical scheme is as follows:
A kind of preparation method of high shock resistance cement polyphenyl formwork concrete wall, comprises the following steps:
A, graphene oxide and spinelle are subjected to wet ball grinding jointly, after crossing 325 mesh sieves, extracting screen underflow is dissolved in water, adds Enter foaming agent, obtain mixed foaming agent;
B, after proportionally mixing cement, granular polystyrene and mixed foaming agent, stir, obtain slurry;
C, slurry is cast in die for molding, heating maintenance, the demoulding, obtains blank;
D, the blank after cutting is immersed in antidetonation treatment fluid, 10-15min is handled under ultrasound condition;
E, steam press maintenance after taking out, matched moulds, cooling, polyphenyl formwork is obtained;
F, using polyphenyl formwork as framework, the assembled wall of cast in situs lattice concrete frame composition, you can.
Preferably, in described step A, in described mixed foaming agent, the composition of following percentage by weight is included:Oxidation Graphene 0.01-0.03%, spinelle 1-5%, foaming agent 1-3% and water surplus.
Preferably, in described step B, the percentage by weight of cement, granular polystyrene and mixed foaming agent is respectively 70- 80%th, 3-7% and surplus.
Preferably, in described step D, described ultrasound condition is 300-800Hz, 150-400W.
Preferably, in described step D, the main component of antidetonation treatment fluid is organosilicon, cerium oxide, dispersant, acetic acid Ethyl ester and water.
In described step D, the composition of the percentage by weight of antidetonation treatment fluid is:Organosilicon 1-3%, cerium oxide 0.5- 1%th, dispersant 2-5%, ethyl acetate 12-20% and water surplus.
The present invention is advantageous in that:
The high shock resistance cement polyphenyl formwork concrete wall of the present invention, resists in the lightweight of traditional cement polyphenyl formwork Shake, fire-proof and thermal-insulation, load-bearing antidetonation, it is resistance to freeze on the basis of durable and saving of work and time saves money, in order to further improve its anti seismic efficiency, Add graphene oxide and handled using antidetonation treatment fluid.
The main component of antidetonation treatment fluid is organosilicon, and main function is under ultrasound condition, is distributed to cement and polystyrene mould Inside shell, network structure is formed, so as to reach superpower anti seismic efficiency, the effect for adding cerium oxide is to accelerate into network speed Rate, lift networking effect.
Wherein, graphene oxide functions as carrier, for the networking of organosilicon provides support, and networking space is bigger, Density is higher;Simultaneous oxidation graphene and organosilicon are further combined with coming earthquake, forming stable network structure, surely Spend calmly.
The high shock resistance cement polyphenyl formwork concrete wall of the present invention, it not only has traditional cement polyphenyl formwork Light-weight aseismatic, fire-proof and thermal-insulation, load-bearing antidetonation, it is resistance to freeze the advantages of durable and saving of work and time saves money, and its anti seismic efficiency is superpower.
Embodiment
Embodiment 1:
A kind of preparation method of high shock resistance cement polyphenyl formwork concrete wall, comprises the following steps:
A, graphene oxide and spinelle are subjected to wet ball grinding jointly, after crossing 325 mesh sieves, extracting screen underflow is dissolved in water, adds Enter foaming agent, obtain mixed foaming agent;
B, after proportionally mixing cement, granular polystyrene and mixed foaming agent, stir, obtain slurry;
C, slurry is cast in die for molding, heating maintenance, the demoulding, obtains blank;
D, the blank after cutting is immersed in antidetonation treatment fluid, 12.5min is handled under ultrasound condition;
E, steam press maintenance after taking out, matched moulds, cooling, polyphenyl formwork is obtained;
F, using polyphenyl formwork as framework, the assembled wall of cast in situs lattice concrete frame composition, you can.
In described step A, in described mixed foaming agent, include the composition of following percentage by weight:Graphene oxide 0.08%th, spinelle 7%, foaming agent 0.8% and water surplus.
In described step B, the percentage by weight of cement, granular polystyrene and mixed foaming agent is respectively 75%, 5% and Surplus.
In described step D, described ultrasound condition is 550Hz, 275W.
In described step D, the composition of the percentage by weight of antidetonation treatment fluid is:Organosilicon 1%, cerium oxide 1%, disperse Agent 3%, ethyl acetate 15% and water surplus.
Embodiment 2:
A kind of preparation method of high shock resistance cement polyphenyl formwork concrete wall, comprises the following steps:
A, graphene oxide and spinelle are subjected to wet ball grinding jointly, after crossing 325 mesh sieves, extracting screen underflow is dissolved in water, adds Enter foaming agent, obtain mixed foaming agent;
B, after proportionally mixing cement, granular polystyrene and mixed foaming agent, stir, obtain slurry;
C, slurry is cast in die for molding, heating maintenance, the demoulding, obtains blank;
D, the blank after cutting is immersed in antidetonation treatment fluid, 10min is handled under ultrasound condition;
E, steam press maintenance after taking out, matched moulds, cooling, polyphenyl formwork is obtained;
F, using polyphenyl formwork as framework, the assembled wall of cast in situs lattice concrete frame composition, you can.
In described step A, include the composition of following percentage by weight:Graphene oxide 0.05%, spinelle 8%, hair Infusion 0.5% and water surplus.
In described step B, the percentage by weight of cement, granular polystyrene and mixed foaming agent is respectively 70%, 7% and Surplus.
In described step D, described ultrasound condition is 300Hz, 150W.
In described step D, the composition of the percentage by weight of antidetonation treatment fluid is:Organosilicon 1.5%, cerium oxide 0.8%, Dispersant 5%, ethyl acetate 12% and water surplus.
Embodiment 3:
A kind of preparation method of high shock resistance cement polyphenyl formwork concrete wall, comprises the following steps:
A, graphene oxide and spinelle are subjected to wet ball grinding jointly, after crossing 325 mesh sieves, extracting screen underflow is dissolved in water, adds Enter foaming agent, obtain mixed foaming agent;
B, after proportionally mixing cement, granular polystyrene and mixed foaming agent, stir, obtain slurry;
C, slurry is cast in die for molding, heating maintenance, the demoulding, obtains blank;
D, the blank after cutting is immersed in antidetonation treatment fluid, 15min is handled under ultrasound condition;
E, steam press maintenance after taking out, matched moulds, cooling, polyphenyl formwork is obtained;
F, using polyphenyl formwork as framework, the assembled wall of cast in situs lattice concrete frame composition, you can.
In described step A, in described mixed foaming agent, include the composition of following percentage by weight:Graphene oxide 0.1%th, spinelle 3%, foaming agent 1% and water surplus.
In described step B, the percentage by weight of cement, granular polystyrene and mixed foaming agent is respectively 80%, 3% and Surplus.
In described step D, described ultrasound condition is 800Hz, 400W.
In described step D, the composition of the percentage by weight of antidetonation treatment fluid is:Organosilicon 3%, cerium oxide 0.5%, divide Powder 2%, ethyl acetate 20% and water surplus.
Embodiment 4:
A kind of preparation method of high shock resistance cement polyphenyl formwork concrete wall, comprises the following steps:
A, graphene oxide and spinelle are subjected to wet ball grinding jointly, after crossing 325 mesh sieves, extracting screen underflow is dissolved in water, adds Enter foaming agent, obtain mixed foaming agent;
B, after proportionally mixing cement, granular polystyrene and mixed foaming agent, stir, obtain slurry;
C, slurry is cast in die for molding, heating maintenance, the demoulding, obtains blank;
D, the blank after cutting is immersed in antidetonation treatment fluid, 11min is handled under ultrasound condition;
E, steam press maintenance after taking out, matched moulds, cooling, polyphenyl formwork is obtained;
F, using polyphenyl formwork as framework, the assembled wall of cast in situs lattice concrete frame composition, you can.
In described step A, in described mixed foaming agent, include the composition of following percentage by weight:Graphene oxide 0.08%th, spinelle 7%, foaming agent 0.8% and water surplus.
In described step B, the percentage by weight of cement, granular polystyrene and mixed foaming agent is respectively 78%, 6% and Surplus.
In described step D, described ultrasound condition is 500Hz, 250W.
In described step D, the composition of the percentage by weight of antidetonation treatment fluid is:Organosilicon 1.7%, cerium oxide 0.8%, Dispersant 2.5%, ethyl acetate 17.5% and water surplus.
Comparative example 1
Antidetonation treatment fluid ultrasound treatment step in embodiment 1 is removed, remaining preparation condition is constant.
Comparative example 2
By in embodiment 1, the cerium oxide in heat-insulated treatment fluid removes, and remaining preparation condition is constant.
Embodiment 1-4 and comparative example 1-2 samples anti seismic efficiency are detected below, while using the routine of in the market Cement polyphenyl formwork contrasted.
It is of the invention in depth of focus 5km, the simulation seismic test of 7.0 grades of earthquake grade by simulating seismic test Cement polyphenyl formwork does not have any breakage, has super shock-resistant effect;And comparative example 1-2 samples have a certain degree of break Split;The conventional cement polyphenyl formwork wall of in the market has phenomenon appearance of collapsing.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (6)

1. a kind of preparation method of high shock resistance cement polyphenyl formwork concrete wall, it is characterised in that comprise the following steps:
A, graphene oxide and spinelle are subjected to wet ball grinding jointly, after crossing 325 mesh sieves, extracting screen underflow is dissolved in water, adds hair Infusion, obtain mixed foaming agent;
B, after proportionally mixing cement, granular polystyrene and mixed foaming agent, stir, obtain slurry;
C, slurry is cast in die for molding, heating maintenance, the demoulding, obtains blank;
D, the blank after cutting is immersed in antidetonation treatment fluid, 10-15min is handled under ultrasound condition;
E, steam press maintenance after taking out, matched moulds, cooling, polyphenyl formwork is obtained;
F, using polyphenyl formwork as framework, the assembled wall of cast in situs lattice concrete frame composition, you can.
2. the preparation method of high shock resistance cement polyphenyl formwork concrete wall as claimed in claim 1, it is characterised in that institute In the step A stated, in described mixed foaming agent, include the composition of following percentage by weight:Graphene oxide 0.05-0.1%, Spinelle 3-8%, foaming agent 0.5-1% and water surplus.
3. the preparation method of high shock resistance cement polyphenyl formwork concrete wall as claimed in claim 1, it is characterised in that institute In the step B stated, the percentage by weight of cement, granular polystyrene and mixed foaming agent is respectively 70-80%, 3-7% and surplus.
4. the preparation method of high shock resistance cement polyphenyl formwork concrete wall as claimed in claim 1, it is characterised in that institute In the step D stated, described ultrasound condition is 300-800Hz, 150-400W.
5. the preparation method of high shock resistance cement polyphenyl formwork concrete wall as claimed in claim 1, it is characterised in that institute In the step D stated, the main component of antidetonation treatment fluid is organosilicon, cerium oxide, dispersant, ethyl acetate and water.
6. the preparation method of high shock resistance cement polyphenyl formwork concrete wall as claimed in claim 1, it is characterised in that institute In the step D stated, the composition of the percentage by weight of antidetonation treatment fluid is:Organosilicon 1-3%, cerium oxide 0.5-1%, dispersant 2- 5%th, ethyl acetate 12-20% and water surplus.
CN201711148102.8A 2017-11-17 2017-11-17 Preparation method of high-shock-resistance cement polyphenyl formwork concrete wall Active CN107778025B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112062599A (en) * 2020-09-28 2020-12-11 史建平 Preparation method of strong waterproof cement polyphenyl formwork concrete wall
CN112081256A (en) * 2020-09-28 2020-12-15 史建平 Preparation method of concrete wall with strong heat insulation cement polyphenyl formwork
CN112430047A (en) * 2020-12-23 2021-03-02 湖州良柏新材料科技有限公司 Preparation method of flame-retardant seawater-proof cement polyphenyl formwork concrete wall
CN112456936A (en) * 2020-12-22 2021-03-09 湖州良柏新材料科技有限公司 Preparation method of seawater corrosion resistant cement polyphenyl formwork concrete wall

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1911781A1 (en) * 2006-10-12 2008-04-16 Arizona Chemical Company Oil absorbing foam
CN102731031A (en) * 2012-06-25 2012-10-17 葛兆明 Cement polyphenyl granule concrete lattice composite wall shuttering, its manufacturing method, lattice composite wall and its manufacturing method
CN104773987A (en) * 2014-01-10 2015-07-15 西北民族大学 Glass fiber gridding cloth reinforced polystyrene particle foam concrete insulation board, and production method thereof
CN106566101A (en) * 2016-06-12 2017-04-19 吉林建筑大学 An organic-inorganic composite flame-retardant heat-insulating material and a producing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1911781A1 (en) * 2006-10-12 2008-04-16 Arizona Chemical Company Oil absorbing foam
CN102731031A (en) * 2012-06-25 2012-10-17 葛兆明 Cement polyphenyl granule concrete lattice composite wall shuttering, its manufacturing method, lattice composite wall and its manufacturing method
CN104773987A (en) * 2014-01-10 2015-07-15 西北民族大学 Glass fiber gridding cloth reinforced polystyrene particle foam concrete insulation board, and production method thereof
CN106566101A (en) * 2016-06-12 2017-04-19 吉林建筑大学 An organic-inorganic composite flame-retardant heat-insulating material and a producing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112062599A (en) * 2020-09-28 2020-12-11 史建平 Preparation method of strong waterproof cement polyphenyl formwork concrete wall
CN112081256A (en) * 2020-09-28 2020-12-15 史建平 Preparation method of concrete wall with strong heat insulation cement polyphenyl formwork
CN112456936A (en) * 2020-12-22 2021-03-09 湖州良柏新材料科技有限公司 Preparation method of seawater corrosion resistant cement polyphenyl formwork concrete wall
CN112430047A (en) * 2020-12-23 2021-03-02 湖州良柏新材料科技有限公司 Preparation method of flame-retardant seawater-proof cement polyphenyl formwork concrete wall

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