CN107762081A - 去味防霉墙布及其制备方法 - Google Patents

去味防霉墙布及其制备方法 Download PDF

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CN107762081A
CN107762081A CN201710937451.1A CN201710937451A CN107762081A CN 107762081 A CN107762081 A CN 107762081A CN 201710937451 A CN201710937451 A CN 201710937451A CN 107762081 A CN107762081 A CN 107762081A
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parts
wall paper
mould proof
surfacing
proof wall
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厉秀华
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Huzhou Donke Textile Co Ltd
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Huzhou Donke Textile Co Ltd
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    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/02—2 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/103—Metal fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B2262/14—Mixture of at least two fibres made of different materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/758—Odour absorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00—Walls, panels
    • B32B2607/02—Wall papers, wall coverings

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Abstract

本发明涉及一种去味防霉墙布，包括表面材料、背衬材料以及涂布在表面材料和背衬材料之间的胶粘剂层，表面材料由以下重量份数的各组分组成：大豆蛋白纤维6～12份，玉米纤维3～5份，牛奶纤维2～4份，芦荟纤维10～15份，竹炭纤维8～11份，纳米银纤维15～20份，活性炭纤维14～18份，柚子皮20～24份，橘子皮12～16份，麦饭石5～8份，电气石3～6份，金红石7～10份，硅酸钠2～8份，硅酸钾1～5份，氢氧化钙4～9份，双氧水6～8份，聚乙烯4～7份，硼酸3～5份。本发明还涉及所述去味防霉墙布的制备方法，所制得墙布可去除异味，帮助清新空气，尤其适合新装修的房间，并具备防霉防虫的功效，抑制细菌滋生，具有广阔的市场前景。

Description

去味防霉墙布及其制备方法
技术领域
本发明涉及墙布领域，更具体地，涉及一种去味防霉墙布及其制备方法。
背景技术
墙布是一种室内墙面装饰材料，是通过运用材料、设备与工艺手法，以色彩与图纹设计组合为特征，表现力无限丰富、可便捷满足多样性个性审美要求与时尚需求，因此也被称为墙上的时装，具有艺术与工艺附加值。墙布不仅有着与壁纸一样的环保特性，而且更新也很简便，在质感上则比壁纸更胜一筹，其本身的柔韧性、无毒、无味、耐擦洗等特点，使其既适合铺装在人多热闹的客厅或餐厅，也更适合铺装在儿童房或有老人的居室里。目前市面上的墙布多种多样，还具备吸音、隔音、防火等性能，受到广大消费者的青睐，然而兼具去味防霉功能的墙布却较为少见。
发明内容
本发明的目的是提供一种去味防霉墙布。
本发明的另一目的是提供一种所述去味防霉墙布的制备方法。
本发明目的通过以下技术方案予以实现：
提供一种去味防霉墙布，包括表面材料、背衬材料以及涂布在表面材料和背衬材料之间的胶粘剂层。
优选地，所述背衬材料为玻璃纤维布。
进一步地，所述表面材料由以下重量份数的各组分组成：大豆蛋白纤维6～12份，玉米纤维3～5份，牛奶纤维2～4份，芦荟纤维10～15份，竹炭纤维8～11份，纳米银纤维15～20份，活性炭纤维14～18份，柚子皮20～24份，橘子皮12～16份，麦饭石5～8份，电气石3～6份，金红石7～10份，硅酸钠2～8份，硅酸钾1～5份，氢氧化钙4～9份，双氧水6～8份，聚乙烯4～7份，硼酸3～5份。
进一步地，所述表面材料的制备方法包括以下步骤：
（1）将麦饭石、电气石、金红石研磨过10目筛，再加入大豆蛋白纤维、玉米纤维、牛奶纤维、芦荟纤维、竹炭纤维、纳米银纤维、活性炭纤维，在压力为180kPa～220 kPa，温度为180～250℃下进行机械破碎和研磨制得粉末；
（2）将风干的柚子皮、橘子皮粉碎过80目筛，加入质量浓度为90%的乙醇溶液，乙醇溶液的加入量为柚子皮和橘子皮总重量的0.3倍，搅拌10～20min；升温至40～60℃，加入硅酸钠、硅酸钾、氢氧化钙、双氧水、聚乙烯、硼酸，搅拌30～60min，得到纺丝原液；
（3）将纺丝原液过滤后，在30～60℃下真空静置脱泡20～30min，然后用常规的湿法纺丝进行纺丝和后处理，得到化纤丝，将化纤丝织造而成布料，得到表面材料。
进一步地，所述胶粘剂由以下重量份数的各组分组成：鱼粉25～32份，明胶15～23份，水杨酸5～10份，丙烯酸4～9份，聚醚胺2～4份，己二胺1～3份，苯醌2～5份，苯乙烯3～7份，壳聚糖6～9份，松香甘油酯3～5份，甘油4～7份，滑石粉9～12份，云母粉3～6份，硅烷偶联剂5～8份，乙酸乙酯7～11份。
进一步地，所述胶粘剂的制备方法包括以下步骤：在30～40℃下，将鱼粉、明胶、水杨酸、丙烯酸加入到110～120份去离子水中，搅拌10～20min，升温至50～60℃，加入剩余原材料，搅拌30～40min，制得胶粘剂。
本发明还提供了所述去味防霉墙布的制备方法，包括以下步骤：在背衬材料上均匀涂覆胶粘剂，在压力为20kPa～30kPa，温度为30～40℃下将表面材料与背衬材料贴合，保持牵伸作用30～50min使布平整，干燥后得到去味防霉墙布。
与现有技术相比，本发明具有以下有益效果：
本发明提供了一种去味防霉墙布，可去除异味，帮助清新空气，尤其适合新装修的房间，并具备防霉防虫的功效，抑制细菌滋生，制备工艺过程简单，制备成本低，可实现产业化生产，具有广阔的市场前景。
具体实施方式
下面结合具体实施例对本发明作进一步的说明。
实施例1
本实施例公开了一种去味防霉墙布，包括表面材料、背衬材料以及涂布在表面材料和背衬材料之间的胶粘剂层，所述背衬材料为玻璃纤维布。
所述表面材料由以下重量份数的各组分组成：大豆蛋白纤维8份，玉米纤维4份，牛奶纤维3份，芦荟纤维12份，竹炭纤维10份，纳米银纤维18份，活性炭纤维16份，柚子皮22份，橘子皮14份，麦饭石7份，电气石5份，金红石8份，硅酸钠5份，硅酸钾4份，氢氧化钙8份，双氧水7份，聚乙烯5份，硼酸4份。
所述表面材料的制备方法包括以下步骤：
（1）将麦饭石、电气石、金红石研磨过10目筛，再加入大豆蛋白纤维、玉米纤维、牛奶纤维、芦荟纤维、竹炭纤维、纳米银纤维、活性炭纤维，在压力为200 kPa，温度为220℃下进行机械破碎和研磨制得粉末；
（2）将风干的柚子皮、橘子皮粉碎过80目筛，加入质量浓度为90%的乙醇溶液，乙醇溶液的加入量为柚子皮和橘子皮总重量的0.3倍，搅拌15min；升温至50℃，加入硅酸钠、硅酸钾、氢氧化钙、双氧水、聚乙烯、硼酸，搅拌50min，得到纺丝原液；
（3）将纺丝原液过滤后，在40℃下真空静置脱泡25min，然后用常规的湿法纺丝进行纺丝和后处理，得到化纤丝，将化纤丝织造而成布料，得到表面材料。
所述胶粘剂由以下重量份数的各组分组成：鱼粉28份，明胶20份，水杨酸8份，丙烯酸5份，聚醚胺3份，己二胺2份，苯醌3份，苯乙烯4份，壳聚糖7份，松香甘油酯4份，甘油5份，滑石粉10份，云母粉5份，硅烷偶联剂6份，乙酸乙酯8份。
所述胶粘剂的制备方法包括以下步骤：在35℃下，将鱼粉、明胶、水杨酸、丙烯酸加入到115份去离子水中，搅拌15min，升温至55℃，加入剩余原材料，搅拌35min，制得胶粘剂。
实施例2
取实施例1的重量组分制备去味防霉墙布，制备步骤如下：
在背衬材料上均匀涂覆胶粘剂，在压力为30kPa，温度为40℃下将表面材料与背衬材料贴合，保持牵伸作用40min使布平整，干燥后得到去味防霉墙布。

Claims (7)

1.一种去味防霉墙布，其特征在于，包括表面材料、背衬材料以及涂布在表面材料和背衬材料之间的胶粘剂层。
2.根据权利要求1所述的去味防霉墙布，其特征在于，所述背衬材料为玻璃纤维布2。
3.根据权利要求1或2所述的去味防霉墙布，其特征在于，所述表面材料由以下重量百分比的各组分组成：大豆蛋白纤维6～12份，玉米纤维3～5份，牛奶纤维2～4份，芦荟纤维10～15份，竹炭纤维8～11份，纳米银纤维15～20份，活性炭纤维14～18份，柚子皮20～24份，橘子皮12～16份，麦饭石5～8份，电气石3～6份，金红石7～10份，硅酸钠2～8份，硅酸钾1～5份，氢氧化钙4～9份，双氧水6～8份，聚乙烯4～7份，硼酸3～5份。
4.根据权利要求1或2或3所述的去味防霉墙布，其特征在于，所述表面材料的制备方法包括以下步骤：
（1）将麦饭石、电气石、金红石研磨过10目筛，再加入大豆蛋白纤维、玉米纤维、牛奶纤维、芦荟纤维、竹炭纤维、纳米银纤维、活性炭纤维，在压力为180kPa～220 kPa，温度为180～250℃下进行机械破碎和研磨制得粉末；
（2）将风干的柚子皮、橘子皮粉碎过80目筛，加入质量浓度为90%的乙醇溶液，乙醇溶液的加入量为柚子皮和橘子皮总重量的0.3倍，搅拌10～20min；升温至40～60℃，加入硅酸钠、硅酸钾、氢氧化钙、双氧水、聚乙烯、硼酸，搅拌30～60min，得到纺丝原液；
（3）将纺丝原液过滤后，在30～60℃下真空静置脱泡20～30min，然后用常规的湿法纺丝进行纺丝和后处理，得到化纤丝，将化纤丝织造而成布料，得到表面材料。
5.根据权利要求4所述的去味防霉墙布，其特征在于，所述胶粘剂由以下重量份数的各组分组成：鱼粉25～32份，明胶15～23份，水杨酸5～10份，丙烯酸4～9份，聚醚胺2～4份，己二胺1～3份，苯醌2～5份，苯乙烯3～7份，壳聚糖6～9份，松香甘油酯3～5份，甘油4～7份，滑石粉9～12份，云母粉3～6份，硅烷偶联剂5～8份，乙酸乙酯7～11份。
6.根据权利要求5所述的去味防霉墙布，其特征在于，所述胶粘剂的制备方法包括以下步骤：在30～40℃下，将鱼粉、明胶、水杨酸、丙烯酸加入到110～120份去离子水中，搅拌10～20min，升温至50～60℃，加入剩余原材料，搅拌30～40min，制得胶粘剂。
7.据权利要求6所述去味防霉墙布的制备方法，其特征在于，包括以下步骤： 在背衬材料上均匀涂覆胶粘剂，在压力为20kPa～30kPa，温度为30～40℃下将表面材料与背衬材料贴合，保持牵伸作用30～50min使布平整，干燥后得到去味防霉墙布。
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