CN107747226A - A kind of preparation method of dress ornament antibacterial finish agent - Google Patents

A kind of preparation method of dress ornament antibacterial finish agent Download PDF

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Publication number
CN107747226A
CN107747226A CN201711237398.0A CN201711237398A CN107747226A CN 107747226 A CN107747226 A CN 107747226A CN 201711237398 A CN201711237398 A CN 201711237398A CN 107747226 A CN107747226 A CN 107747226A
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Prior art keywords
parts
good
preparation
dress ornament
agent
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CN201711237398.0A
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Inventor
郭新华
张会良
叶萍
韩建钢
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Thai Fashion Apparel (suzhou) Co Ltd
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Thai Fashion Apparel (suzhou) Co Ltd
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Priority to CN201711237398.0A priority Critical patent/CN107747226A/en
Publication of CN107747226A publication Critical patent/CN107747226A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71—Salts of phosphoric acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/392—Nitroso compounds; Nitro compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/31—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated nitriles
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01—Stain or soil resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A kind of preparation method this application discloses dress ornament with antibacterial finish agent, weighs pure water, protease, colouring agent, azodicarbonamide, sodium acetate, sodium citrate, ammonium phosphate, polyacrylonitrile fibre, diphenylguanidine, dinitrophenol and amido silicon oil；Preparation method is simple, and anti-mold effect is good, mildewproof, and the 5MPa of tensile strength 3, resistance to moisture is excellent, makes dress ornament more soft, good hand touch；Skin-friendly is good, increases gloss, adhesion 1 grade, good corrosion resistance, abrasion resistance 250 450 times, dirt-removing power is strong；Antistatic property is good, and 80 90 acarids of water-wash resistance walk quickly and keep away rate 93 97%, and pliability 1mm, glossiness is good, and hydrophobic oil repellency is good；Hydrophilicity is good, extends embroidery service life, fast drying, fire resistance is good, and anti-microbial property is good, to Escherichia coli bacteriostasis rate 98 99%, can extensively produce and constantly replace current material.

Description

A kind of preparation method of dress ornament antibacterial finish agent
Technical field
The application belongs to dress material field, more particularly to a kind of dress ornament preparation method of antibacterial finish agent.
Background technology
During the application of antibacterial finishing agent originates from World War II, German army was due to wearing antibacterial military uniform and significantly at that time Reduce the bacterium infection of the wounded.Antibacterial finishing agent can make clothing more comfortable, improve the hygiene and health of people's living environment Deng.
Resin finishing agent is intended to prevent or improved contraction or the wrinkle phenomenon that fabric occurs in wearing process, in its printing and dyeing Chemical finishing (being commonly called as resin finishing) is carried out with synthetic resin after processing, such as shrinkproof, wrinkle resistant resin arranges.Material used is referred to as Resin finishing agent.
Textile finishing is to apply a kind of finishing agent on fabric, and it can change the surface property of fabric, so as to assign fabric Special function.Such as it is to handle fabric with the finishing agent with low surface tension that hydrophobic and oil repellent, which arranges, changes the surface of fiber Characteristic, fabric face is set to be not easy by water or glossy wet and sprawl, so as to reach the purpose of hydrophobic and oil repellent.Soil resistant finish and easy decontamination Arrangement is the surface property or surface state by changing fiber, makes fabric be not easy to attach dirt under dress, use condition, or The dirt attached is easy to wash to the processing technology of not recontamination.
Nano-silver antibacterial finishing agent is a kind of to should be primarily used to the whole of each kind fabric such as various textiles, non-woven fabrics, leather Manage agent.
High-efficiency antimicrobial, it is mould proof, drive mite textile finshing agent be three-in-one polymer-function material, suitable for cotton, viscose glue, The fabrics such as LYOCELL;Suitable for protein fibre fabrics such as wool, silks；Suitable for chemistry such as polyamide fibre, terylene, spandexs Fabric；It is also applied for the blended fabric such as cellulose and terylene, polyamide fibre, spandex, PPT.Treated fabric, which has, to be held Long, antibacterial, mildew-proof function and certain drive mite effect efficiently, stable.
With the improvement of living standards, people increasingly pay attention to the quality of life, it would be desirable to obtaining has the clothing of comfort, And the living environment of hygiene and health.For various textiles require more and more higher, particularly safely, feel at ease, comfortably, The formation of " green " ideas such as health, health, cleaning, the antibacterial of textile, mould proof, deodorization final finishing processing is set to be more exposed to people Attention.
In life, people inevitably touch the microorganisms such as various bacteriums, fungi, and these microorganisms exist It under suitable external condition, can rapidly breed, and be spread disease by the mode such as contacting, influence the health of people and normal Work, studying and living.Fiber belongs to porous material, can form the polylayer forest in countless spaces after superposition braiding again, therefore Fabric is easier to adsorb mushroom.Antibiotic finish is exactly fabric is had the function of suppressing fungus grown, maintains the clothing life of health Environment living, ensures health.
The content of the invention
The technical problem of solution：
The application is directed to above-mentioned technical problem, there is provided a kind of preparation method of dress ornament antibacterial finish agent, solves existing dress ornament and uses Antibacterial finish agent anti-mold effect is poor, anti-wrinkle effect difference and the technical problem such as fungistatic effect difference.
Technical scheme：
A kind of dress ornament preparation method of antibacterial finish agent, comprises the following steps：
The first step：100 parts of pure water, protease 25-45 parts, colouring agent 0.8-1.2 parts, azo two are weighed according to parts by weight proportioning Formamide 15-35 parts, sodium acetate 0.1-2 parts, sodium citrate 5-25 parts, ammonium phosphate 20-40 parts, polyacrylonitrile fibre 15-25 parts, Diphenylguanidine 1-5 parts, dinitrophenol 0.5-4.5 parts and amido silicon oil 1-5 parts；
Second step：By sodium citrate, polyacrylonitrile fibre and diphenylguanidine input with the anti-of thermometer, mixer and heater Answer in kettle, open mixer mixing, be warming up to 50-60 DEG C, mixing velocity 250-350r/min, mix 1-3h；
3rd step：Sodium acetate, pure water and protease are sequentially added, is passed through nitrogen, regulation mixing velocity to 400- in a kettle 500 r/min, 60-100min is mixed, add surplus stock, be warming up to 90-100 DEG C, by well mixed production after dissolving completely In thing input sand mill, 20-30min is sanded, after crossing cleaner liquid, is produced after standing 6-10h.
As a preferred technical solution of the present invention：In the first step dress ornament with the raw material of antibacterial finish agent by weight Number proportioning is as follows：100 parts of pure water, 25 parts of protease, 0.8 part of colouring agent, 15 parts of azodicarbonamide, 0.1 part of sodium acetate, lemon 1 part of 5 parts of lemon acid sodium, 20 parts of ammonium phosphate, 15 parts of polyacrylonitrile fibre, 1 part of diphenylguanidine, 0.5 part of dinitrophenol and amido silicon oil.
As a preferred technical solution of the present invention：In the first step dress ornament with the raw material of antibacterial finish agent by weight Number proportioning is as follows：100 parts of pure water, 45 parts of protease, 1.2 parts of colouring agent, 35 parts of azodicarbonamide, 2 parts of sodium acetate, lemon 5 parts of sour 25 parts of sodium, 40 parts of ammonium phosphate, 25 parts of polyacrylonitrile fibre, 5 parts of diphenylguanidine, 4.5 parts of dinitrophenol and amido silicon oil.
As a preferred technical solution of the present invention：In the first step dress ornament with the raw material of antibacterial finish agent by weight Number proportioning is as follows：100 parts of pure water, 5 parts of protease 3,1 part of colouring agent, 25 parts of azodicarbonamide, 1 part of sodium acetate, citric acid 3 parts of 15 parts of sodium, 30 parts of ammonium phosphate, 20 parts of polyacrylonitrile fibre, 3 parts of diphenylguanidine, 2.5 parts of dinitrophenol and amido silicon oil.
As a preferred technical solution of the present invention：The colouring agent uses the bright red LC of rubber.
Beneficial effect：
A kind of dress ornament of the present invention uses above technical scheme compared with prior art with the preparation method of antibacterial finish agent, tool There is following technique effect：1st, preparation method is simple, and anti-mold effect is good, mildewproof, and tensile strength 3-5MPa, resistance to moisture is excellent, Make dress ornament more soft, good hand touch；2nd, skin-friendly is good, increases gloss, adhesion 1 grade, good corrosion resistance, abrasion resistance 250- 450 times, dirt-removing power is strong；3rd, antistatic property is good, and 80-90 acarid of water-wash resistance walks quickly and keeps away rate 93-97%, pliability 1mm, light Damp degree is good, and hydrophobic oil repellency is good；4th, hydrophilicity is good, extends embroidery service life, fast drying, fire resistance is good, antibiotic property Can be good, to Escherichia coli bacteriostasis rate 98-99%, it can extensively produce and constantly replace current material.
Embodiment
Embodiment 1:
100 parts of pure water, 25 parts of protease, the bright red LC0.8 parts of rubber, azodicarbonamide 15 are weighed according to parts by weight proportioning Part, 0.1 part of sodium acetate, 5 parts of sodium citrate, 20 parts of ammonium phosphate, 15 parts of polyacrylonitrile fibre, 1 part of diphenylguanidine, dinitrophenol 0.5 part and 1 part of amido silicon oil.
By reaction of sodium citrate, polyacrylonitrile fibre and the diphenylguanidine input with thermometer, mixer and heater In kettle, mixer mixing is opened, is warming up to 50 DEG C, mixing velocity 250r/min, mixes 1h.
Sodium acetate, pure water and protease are sequentially added, is passed through nitrogen, regulation mixing velocity to 400 r/ in a kettle Min, mixing 60min, adds surplus stock, is warming up to 90 DEG C, puts into well mixed product in sand mill after dissolving completely, 20min is sanded, after crossing cleaner liquid, is produced after standing 6h.
Preparation method is simple, and anti-mold effect is good, mildewproof, and tensile strength 3MPa, resistance to moisture is excellent, makes dress ornament more soft It is soft, good hand touch；Skin-friendly is good, increases gloss, adhesion 1 grade, good corrosion resistance, abrasion resistance 250 times, dirt-removing power is strong；It is anti- Antistatic property is good, and 80-90 acarid of water-wash resistance walks quickly and keeps away rate 93%, and pliability 1mm, glossiness is good, and hydrophobic oil repellency is good；Parent Water-based energy is good, extends embroidery service life, fast drying, fire resistance is good, and anti-microbial property is good, can to Escherichia coli bacteriostasis rate 98% To produce extensively and constantly replace current material.
Embodiment 2:
100 parts of pure water, 45 parts of protease, the bright red LC1.2 parts of rubber, azodicarbonamide 35 are weighed according to parts by weight proportioning Part, 2 parts of sodium acetate, 25 parts of sodium citrate, 40 parts of ammonium phosphate, 25 parts of polyacrylonitrile fibre, 5 parts of diphenylguanidine, dinitrophenol 4.5 5 parts of part and amido silicon oil.
By reaction of sodium citrate, polyacrylonitrile fibre and the diphenylguanidine input with thermometer, mixer and heater In kettle, mixer mixing is opened, is warming up to 60 DEG C, mixing velocity 350r/min, mixes 3h.
Sodium acetate, pure water and protease are sequentially added, is passed through nitrogen, regulation mixing velocity to 500 r/ in a kettle Min, 100min is mixed, add surplus stock, be warming up to 100 DEG C, well mixed product is put into sand mill after dissolving completely In, 30min is sanded, after crossing cleaner liquid, is produced after standing 10h.
Preparation method is simple, and anti-mold effect is good, mildewproof, and tensile strength 4MPa, resistance to moisture is excellent, makes dress ornament more soft It is soft, good hand touch；Skin-friendly is good, increases gloss, adhesion 1 grade, good corrosion resistance, abrasion resistance 300 times, dirt-removing power is strong；It is anti- Antistatic property is good, and 85 acarids of water-wash resistance walk quickly and keep away rate 95%, and pliability 1mm, glossiness is good, and hydrophobic oil repellency is good；Hydrophily Can be good, extend embroidery service life, fast drying, fire resistance is good, and anti-microbial property is good, can be with to Escherichia coli bacteriostasis rate 98.5% Produce extensively and constantly replace current material.
Embodiment 3:
According to parts by weight proportioning weigh 100 parts of pure water, 5 parts of protease 3, the bright red LC1 parts of rubber, 25 parts of azodicarbonamide, 1 part of sodium acetate, 15 parts of sodium citrate, 30 parts of ammonium phosphate, 20 parts of polyacrylonitrile fibre, 3 parts of diphenylguanidine, 2.5 parts of dinitrophenol With 3 parts of amido silicon oil.
By reaction of sodium citrate, polyacrylonitrile fibre and the diphenylguanidine input with thermometer, mixer and heater In kettle, mixer mixing is opened, is warming up to 55 DEG C, mixing velocity 300r/min, mixes 2h.
Sodium acetate, pure water and protease are sequentially added, is passed through nitrogen, regulation mixing velocity to 450 r/ in a kettle Min, mixing 80min, adds surplus stock, is warming up to 95 DEG C, puts into well mixed product in sand mill after dissolving completely, 25min is sanded, after crossing cleaner liquid, is produced after standing 8h.
Preparation method is simple, and anti-mold effect is good, mildewproof, and tensile strength 5MPa, resistance to moisture is excellent, makes dress ornament more soft It is soft, good hand touch；Skin-friendly is good, increases gloss, adhesion 1 grade, good corrosion resistance, abrasion resistance 350 times, dirt-removing power is strong；It is anti- Antistatic property is good, and 90 acarids of water-wash resistance walk quickly and keep away rate 97%, and pliability 1mm, glossiness is good, and hydrophobic oil repellency is good；Hydrophily Can be good, extend embroidery service life, fast drying, fire resistance is good, and anti-microbial property is good, to Escherichia coli bacteriostasis rate 99%, Ke Yiguang It is general to produce and constantly replace current material.
Composition all components in above example can be with commercially available.
The above embodiments are intended to illustrate the present invention, rather than limitation, therefore with the present invention's Any change in claims suitable implication and scope, all it is considered as being included within the scope of the claims.

Claims (5)

1. a kind of dress ornament preparation method of antibacterial finish agent, it is characterised in that comprise the following steps：
The first step：100 parts of pure water, protease 25-45 parts, colouring agent 0.8-1.2 parts, azo two are weighed according to parts by weight proportioning Formamide 15-35 parts, sodium acetate 0.1-2 parts, sodium citrate 5-25 parts, ammonium phosphate 20-40 parts, polyacrylonitrile fibre 15-25 parts, Diphenylguanidine 1-5 parts, dinitrophenol 0.5-4.5 parts and amido silicon oil 1-5 parts；
Second step：By sodium citrate, polyacrylonitrile fibre and diphenylguanidine input with the anti-of thermometer, mixer and heater Answer in kettle, open mixer mixing, be warming up to 50-60 DEG C, mixing velocity 250-350r/min, mix 1-3h；
3rd step：Sodium acetate, pure water and protease are sequentially added, is passed through nitrogen, regulation mixing velocity to 400- in a kettle 500 r/min, 60-100min is mixed, add surplus stock, be warming up to 90-100 DEG C, by well mixed production after dissolving completely In thing input sand mill, 20-30min is sanded, after crossing cleaner liquid, is produced after standing 6-10h.
2. the dress ornament according to claim 1 preparation method of antibacterial finish agent, it is characterised in that：Taken in the first step Decorations are as follows with the raw materials by weight portion proportioning of antibacterial finish agent：100 parts of pure water, 25 parts of protease, 0.8 part of colouring agent, azo 15 parts of diformamide, 0.1 part of sodium acetate, 5 parts of sodium citrate, 20 parts of ammonium phosphate, 15 parts of polyacrylonitrile fibre, 1 part of diphenylguanidine, two 1 part of 0.5 part of nitrophenol and amido silicon oil.
3. the dress ornament according to claim 1 preparation method of antibacterial finish agent, it is characterised in that：Taken in the first step Decorations are as follows with the raw materials by weight portion proportioning of antibacterial finish agent：100 parts of pure water, 45 parts of protease, 1.2 parts of colouring agent, azo 35 parts of diformamide, 2 parts of sodium acetate, 25 parts of sodium citrate, 40 parts of ammonium phosphate, 25 parts of polyacrylonitrile fibre, 5 parts of diphenylguanidine, two 5 parts of 4.5 parts of nitrophenol and amido silicon oil.
4. the dress ornament according to claim 1 preparation method of antibacterial finish agent, it is characterised in that：Taken in the first step Decorations are as follows with the raw materials by weight portion proportioning of antibacterial finish agent：100 parts of pure water, 5 parts of protease 3,1 part of colouring agent, azo two 25 parts of formamide, 1 part of sodium acetate, 15 parts of sodium citrate, 30 parts of ammonium phosphate, 20 parts of polyacrylonitrile fibre, 3 parts of diphenylguanidine, dinitro 3 parts of 2.5 parts of base phenol and amido silicon oil.
5. the dress ornament according to claim 1 preparation method of antibacterial finish agent, it is characterised in that：The colouring agent uses The bright red LC of rubber.
CN201711237398.0A 2017-11-30 2017-11-30 A kind of preparation method of dress ornament antibacterial finish agent Pending CN107747226A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109837759A (en) * 2019-02-25 2019-06-04 朱建余 A kind of denim fabric antibacterial flame-retardant finishing agent and preparation method thereof
CN112323169A (en) * 2020-10-21 2021-02-05 广州市双雄化纤有限公司 Production process of regenerated anti-static polyester staple fibers

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CN103757890A (en) * 2013-12-31 2014-04-30 苏州市轩德纺织科技有限公司 Suit finishing agent and preparation method thereof
CN105568678A (en) * 2016-03-11 2016-05-11 湖州宏鑫绸厂 Antibacterial finishing method of wool fabric
CN106245321A (en) * 2016-07-29 2016-12-21 吴国强 A kind of fabric antimildew and antibacterial inorganic agent

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN103757890A (en) * 2013-12-31 2014-04-30 苏州市轩德纺织科技有限公司 Suit finishing agent and preparation method thereof
CN105568678A (en) * 2016-03-11 2016-05-11 湖州宏鑫绸厂 Antibacterial finishing method of wool fabric
CN106245321A (en) * 2016-07-29 2016-12-21 吴国强 A kind of fabric antimildew and antibacterial inorganic agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109837759A (en) * 2019-02-25 2019-06-04 朱建余 A kind of denim fabric antibacterial flame-retardant finishing agent and preparation method thereof
CN109837759B (en) * 2019-02-25 2021-12-03 朱建余 Antibacterial flame-retardant finishing agent for denim fabric and preparation method thereof
CN112323169A (en) * 2020-10-21 2021-02-05 广州市双雄化纤有限公司 Production process of regenerated anti-static polyester staple fibers

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Application publication date: 20180302