CN107747104A - A kind of environment protection metal cleansing article agent and preparation method thereof - Google Patents

A kind of environment protection metal cleansing article agent and preparation method thereof Download PDF

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Publication number
CN107747104A
CN107747104A CN201710966830.3A CN201710966830A CN107747104A CN 107747104 A CN107747104 A CN 107747104A CN 201710966830 A CN201710966830 A CN 201710966830A CN 107747104 A CN107747104 A CN 107747104A
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CN
China
Prior art keywords
parts
sodium
agent
environment protection
aeo
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201710966830.3A
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Chinese (zh)
Inventor
曾伟平
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Sihui City Eic Information Advisory Services Ltd
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Sihui City Eic Information Advisory Services Ltd
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Publication date
Application filed by Sihui City Eic Information Advisory Services Ltd filed Critical Sihui City Eic Information Advisory Services Ltd
Priority to CN201710966830.3A priority Critical patent/CN107747104A/en
Publication of CN107747104A publication Critical patent/CN107747104A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/06Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using emulsions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention provides a kind of environment protection metal cleansing article agent and preparation method thereof, is related to cleaning agent field, including following composition:15 22 parts of Sodium Polyacrylate, 13 17 parts of trichloro ethylene, 58 parts of AEO, 8 10 parts of four potassium of phosphoric acid, 59 parts of assistant for emulsifying agent, 5 10 parts of sucrose-fatty sodium, 12 16 parts of sodium pyrophosphate, 46 parts of tertiary sodium phosphate, 58 parts of sodium citrate, 58 parts of polycarboxylic acids aqueous dispersion, 25 parts of pH adjusting agent, 46 parts of toluene, 12 parts of odium stearate, 10 20 parts of polyvinyl alcohol, 8 12 parts of AEO, 58 parts of glycerine, 25 parts of anion surfactant, 15 parts of corrosion inhibiter, 23 35 parts of deionized water;The present invention has stronger dirt-removing power, can with it is fast and effective remove the dust of solar components glass, sand and dust, birds droppings, shellac, etc. dirt;Cleaning agent of the present invention is environment-protecting and non-poisonous pollution-free, and occupation mode of the present invention is simple, only need to be sprayed at surface of metal product, is dried after slightly dry with cotton, without being rinsed with water.

Description

A kind of environment protection metal cleansing article agent and preparation method thereof
Technical field
The present invention relates to cleaning agent field, and in particular to a kind of environment protection metal cleansing article agent and preparation method thereof.
Background technology
Metal is a kind of material with gloss, rich in the property such as ductility, easy conduction, heat conduction.In nature, absolutely Most metals exist with compound state, and a few metals such as gold, platinum, silver, bismuth exist with free state.Metalliferous mineral majority is oxidation Thing and sulfide.Other existence forms have chloride, sulfate, carbonate and silicate.Metal is being processed, handling and used Different degrees of oxidation, corrosion etc. often occur in journey, reduces the service life of metal material or hardware, therefore, needs Metal surface is handled, increase its anti-oxidant, erosion-resisting ability, increase the service life.Typically use metal at present Cleaning agent cleans to metal surface, but metal cleaner in the market, mostly cleaning performance are bad, therefore, exploitation It is a kind of it is new have low to environmental hazard, cost is cheap, and cleaning performance is excellent, to the less metal cleaner of metal attack, Have become that those skilled in the art are too impatient to wait to be solved the problems, such as.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of environment protection metal cleansing article agent and preparation method thereof, bag Include following composition:Sodium Polyacrylate 15-22 parts, trichloro ethylene 13-17 parts, AEO 5-8 parts, the potassium 8- of phosphoric acid four 10 parts, assistant for emulsifying agent 5-9 parts, sucrose-fatty sodium 5-10 parts, sodium pyrophosphate 12-16 parts, tertiary sodium phosphate 4-6 parts, sodium citrate 5-8 parts, polycarboxylic acids aqueous dispersion 5-8 parts, pH adjusting agent 2-5 parts, toluene 4-6 parts, odium stearate 1-2 parts, polyvinyl alcohol 10- 20 parts, AEO 8-12 parts, glycerine 5-8 parts, anion surfactant 2-5 parts, corrosion inhibiter 1-5 parts, go Ionized water 23-35 parts.
Preferably, the pH adjusting agent is the one or more in sodium hydroxide, triethanolamine, sodium metasilicate and sodium carbonate.
Preferably, the assistant for emulsifying agent is in absolute ethyl alcohol, n-butanol, polyglycerol ester, propane diols, ethylene glycol, glycerine It is one or more of.
Preferably, the preparation method of described environment protection metal cleansing article agent, comprises the following steps:
1) by Sodium Polyacrylate, trichloro ethylene, AEO, the potassium of phosphoric acid four, sucrose-fatty sodium, pyrophosphoric acid Sodium, tertiary sodium phosphate, sodium citrate, polycarboxylic acids aqueous dispersion, pH adjusting agent, toluene, odium stearate, polyvinyl alcohol, fatty alcohol APEO, glycerine, anion surfactant are put into reactor, standby;
2) regulating step 1) in the rotating speed of reactor be 3000-3500r/min, temperature range is 65-75 DEG C, the reaction time It is standby for 30-40 minutes;
3) assistant for emulsifying agent, corrosion inhibiter are put into step 2) reactor;
4) temperature range of reactor is adjusted to 50-60 DEG C, rotating speed 200-250r/min, and the reaction time is 15-20 points Clock, it is standby;
5) raw material obtained by step 4) is put into vacuum emulsifying machine to be stirred, you can.
The invention provides a kind of environment protection metal cleansing article agent and preparation method thereof, has stronger dirt-removing power, can With the fast and effective removing dust of surface of metal product, sand and dust, birds droppings, shellac, etc. dirt;The environment-protecting and non-poisonous nothing of cleaning agent of the present invention Pollution, and occupation mode of the present invention is simple, only need to be sprayed at surface of metal product, is dried after slightly dry with cotton, without Rinsed with water.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention In, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention Part of the embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not having The every other embodiment obtained under the premise of creative work is made, belongs to the scope of protection of the invention.
Embodiment 1:
A kind of environment protection metal cleansing article agent and preparation method thereof, including following composition:Sodium Polyacrylate 15-22 parts, three Vinyl chloride 13-17 parts, AEO 5-8 parts, the potassium 8-10 parts of phosphoric acid four, assistant for emulsifying agent 5-9 parts, sucrose-fatty sodium 5-10 parts, sodium pyrophosphate 12-16 parts, tertiary sodium phosphate 4-6 parts, sodium citrate 5-8 parts, polycarboxylic acids aqueous dispersion 5-8 parts, pH are adjusted Save agent 2-5 parts, toluene 4-6 parts, odium stearate 1-2 parts, polyvinyl alcohol 10-20 parts, AEO 8-12 parts, the third three Alcohol 5-8 parts, anion surfactant 2-5 parts, corrosion inhibiter 1-5 parts, deionized water 23-35 parts.
Preferably, the pH adjusting agent is the one or more in sodium hydroxide, triethanolamine, sodium metasilicate and sodium carbonate.
Preferably, the assistant for emulsifying agent is in absolute ethyl alcohol, n-butanol, polyglycerol ester, propane diols, ethylene glycol, glycerine It is one or more of.
Embodiment 2:
A kind of environment protection metal cleansing article agent and preparation method thereof, including following composition:Sodium Polyacrylate 15-22 parts, three Vinyl chloride 13-17 parts, AEO 5-8 parts, the potassium 8-10 parts of phosphoric acid four, assistant for emulsifying agent 5-9 parts, sucrose-fatty sodium 5-10 parts, sodium pyrophosphate 12-16 parts, tertiary sodium phosphate 4-6 parts, sodium citrate 5-8 parts, polycarboxylic acids aqueous dispersion 5-8 parts, pH are adjusted Save agent 2-5 parts, toluene 4-6 parts, odium stearate 1-2 parts, polyvinyl alcohol 10-20 parts, AEO 8-12 parts, the third three Alcohol 5-8 parts, anion surfactant 2-5 parts, corrosion inhibiter 1-5 parts, deionized water 23-35 parts.
Preferably, the pH adjusting agent is the one or more in sodium hydroxide, triethanolamine, sodium metasilicate and sodium carbonate.
Preferably, the assistant for emulsifying agent is in absolute ethyl alcohol, n-butanol, polyglycerol ester, propane diols, ethylene glycol, glycerine It is one or more of.
Preferably, the preparation method of described environment protection metal cleansing article agent, comprises the following steps:
1) by Sodium Polyacrylate, trichloro ethylene, AEO, the potassium of phosphoric acid four, sucrose-fatty sodium, pyrophosphoric acid Sodium, tertiary sodium phosphate, sodium citrate, polycarboxylic acids aqueous dispersion, pH adjusting agent, toluene, odium stearate, polyvinyl alcohol, fatty alcohol APEO, glycerine, anion surfactant are put into reactor, standby;
2) regulating step 1) in the rotating speed of reactor be 3000-3500r/min, temperature range is 65-75 DEG C, the reaction time It is standby for 30-40 minutes;
3) assistant for emulsifying agent, corrosion inhibiter are put into step 2) reactor;
4) temperature range of reactor is adjusted to 50-60 DEG C, rotating speed 200-250r/min, and the reaction time is 15-20 points Clock, it is standby;
5) raw material obtained by step 4) is put into vacuum emulsifying machine to be stirred, you can.
Experiment
Cleaning agent made from embodiment 1,2 is tested, and contrasted with the common cleaning agent in market.Result of the test is such as Under:
Project Embodiment 1 Embodiment 2 Common cleaning agent
Electrostatic remains (%) 2.3 1.6 56
Dirt remains (%) 1.3 1.5 5
Cleaning agent remains (%) 3.3 5.6 10.2
Cleaning agent pH value 7 7.1 8.5
Experiment proves:Cleaning agent various aspects of performance provided by the invention is superior, has stronger dirt-removing power, can be quick Effectively remove the dust of surface of metal product, sand and dust, birds droppings, shellac, etc. dirt;Cleaning agent of the present invention is environment-protecting and non-poisonous pollution-free, And occupation mode of the present invention is simple, surface of metal product only need to be sprayed at, is dried after slightly dry with cotton, without being rushed with water Wash.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality Body or operation make a distinction with another entity or operation, and not necessarily require or imply and deposited between these entities or operation In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to Nonexcludability includes, so that process, method, article or equipment including a series of elements not only will including those Element, but also the other element including being not expressly set out, or it is this process, method, article or equipment also to include Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that Other identical element also be present in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention is described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic;And these modification or Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (4)

1. a kind of environment protection metal cleansing article agent, it is characterised in that including following composition:Sodium Polyacrylate 15-22 parts, three chloroethenes Alkene 13-17 parts, AEO 5-8 parts, the potassium 8-10 parts of phosphoric acid four, assistant for emulsifying agent 5-9 parts, sucrose-fatty sodium 5-10 Part, sodium pyrophosphate 12-16 parts, tertiary sodium phosphate 4-6 parts, sodium citrate 5-8 parts, polycarboxylic acids aqueous dispersion 5-8 parts, pH adjusting agent 2-5 parts, toluene 4-6 parts, odium stearate 1-2 parts, polyvinyl alcohol 10-20 parts, AEO 8-12 parts, glycerine 5- 8 parts, anion surfactant 2-5 parts, corrosion inhibiter 1-5 parts, deionized water 23-35 parts.
2. environment protection metal cleansing article agent as claimed in claim 1, it is characterised in that the pH adjusting agent be sodium hydroxide, One or more in triethanolamine, sodium metasilicate and sodium carbonate.
3. environment protection metal cleansing article agent as claimed in claim 1, it is characterised in that the assistant for emulsifying agent be absolute ethyl alcohol, One or more in n-butanol, polyglycerol ester, propane diols, ethylene glycol, glycerine.
4. the preparation method of environment protection metal cleansing article agent as claimed in claim 1, it is characterised in that comprise the following steps:
1) by Sodium Polyacrylate, trichloro ethylene, AEO, the potassium of phosphoric acid four, sucrose-fatty sodium, sodium pyrophosphate, Tertiary sodium phosphate, sodium citrate, polycarboxylic acids aqueous dispersion, pH adjusting agent, toluene, odium stearate, polyvinyl alcohol, fatty alcohol polyoxy Vinethene, glycerine, anion surfactant are put into reactor, standby;
2) regulating step 1) in the rotating speed of reactor be 3000-3500r/min, temperature range is 65-75 DEG C, and the reaction time is It is 30-40 minutes, standby;
3) assistant for emulsifying agent, corrosion inhibiter are put into step 2) reactor;
4) temperature range of reactor is adjusted to 50-60 DEG C, rotating speed 200-250r/min, and the reaction time is 15-20 minutes, standby With;
5) raw material obtained by step 4) is put into vacuum emulsifying machine to be stirred, you can.
CN201710966830.3A 2017-10-17 2017-10-17 A kind of environment protection metal cleansing article agent and preparation method thereof Pending CN107747104A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109518204A (en) * 2018-11-30 2019-03-26 佛山市海明威生态科技股份有限公司 A kind of demoulding soaking and washing agent of die casting aluminium and its preparation
CN109852981A (en) * 2019-04-10 2019-06-07 广州洁生日化有限公司 A kind of metal detergent

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106498427A (en) * 2016-12-27 2017-03-15 河南八灵电子科技有限公司 A kind of steel surface cleaning agent and its preparation method and application and its preparation method and application
CN106521539A (en) * 2016-12-05 2017-03-22 郑州丽福爱生物技术有限公司 Steel surface detergent
CN106555202A (en) * 2015-09-30 2017-04-05 无锡市尚新金属制品有限公司 Metal conditioner and preparation method thereof
CN106567100A (en) * 2015-10-10 2017-04-19 无锡市尚新金属制品有限公司 Cleaning agent for external layer of metal
CN106868519A (en) * 2017-03-07 2017-06-20 马鞍山拓锐金属表面技术有限公司 Aqua type metal cleaner and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106555202A (en) * 2015-09-30 2017-04-05 无锡市尚新金属制品有限公司 Metal conditioner and preparation method thereof
CN106567100A (en) * 2015-10-10 2017-04-19 无锡市尚新金属制品有限公司 Cleaning agent for external layer of metal
CN106521539A (en) * 2016-12-05 2017-03-22 郑州丽福爱生物技术有限公司 Steel surface detergent
CN106498427A (en) * 2016-12-27 2017-03-15 河南八灵电子科技有限公司 A kind of steel surface cleaning agent and its preparation method and application and its preparation method and application
CN106868519A (en) * 2017-03-07 2017-06-20 马鞍山拓锐金属表面技术有限公司 Aqua type metal cleaner and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109518204A (en) * 2018-11-30 2019-03-26 佛山市海明威生态科技股份有限公司 A kind of demoulding soaking and washing agent of die casting aluminium and its preparation
CN109852981A (en) * 2019-04-10 2019-06-07 广州洁生日化有限公司 A kind of metal detergent
CN109852981B (en) * 2019-04-10 2020-01-14 广州洁生日化有限公司 Metal detergent

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Application publication date: 20180302