CN107740261A - A kind of method for bleaching of soybean fiber - Google Patents

A kind of method for bleaching of soybean fiber Download PDF

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Publication number
CN107740261A
CN107740261A CN201711136101.1A CN201711136101A CN107740261A CN 107740261 A CN107740261 A CN 107740261A CN 201711136101 A CN201711136101 A CN 201711136101A CN 107740261 A CN107740261 A CN 107740261A
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CN
China
Prior art keywords
bleaching
soybean fiber
soybean
whiteness
ultraviolet light
Prior art date
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Granted
Application number
CN201711136101.1A
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Chinese (zh)
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CN107740261B (en
Inventor
曹机良
孟春丽
李晓春
许志忠
郭金爱
陆辉
陈艺佳
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Henan Institute of Engineering
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Henan Institute of Engineering
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Priority to CN201711136101.1A priority Critical patent/CN107740261B/en
Publication of CN107740261A publication Critical patent/CN107740261A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/50Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs by irradiation or ozonisation
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/13Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/70Multi-step processes

Abstract

The invention discloses a kind of method for bleaching of soybean fiber, by the way that soybean fiber is first irradiated with ultraviolet light, the soybean fiber of irradiating ultraviolet light is bleached with hydrogen peroxide again, then white goods washed, dry acquisition bleaching finished product, ultraviolet light destroys in soybean fiber the pigmentary structures for being difficult to remove during hydrogen peroxide bleaching, substantially increases the bleaching whiteness of soybean fiber fabric.The bleaching for realizing high whiteness soybean fiber fabric by the method for the present invention is processed, the indices such as the whiteness of blanching soya beans azelon fabric, strength, dyeability meet the requirements, the whiteness of soybean fiber fabric is the method increase, guarantee is provided for the bright color of soybean fiber fabric, light color, iridescent dyeing.

Description

A kind of method for bleaching of soybean fiber
Technical field
The invention belongs to dyeing and finishing technique field, is related to a kind of method being combined using ultraviolet light and hydrogen peroxide bleaching The method that soybean fiber obtains high bleaching whiteness is realized, can especially realize soybean fiber light color, bright color and fluorescence The dyeing of color.
Background technology
Soybean fiber is a kind of azlon comfortable and easy to wear, soft, good hygroscopicity, its knitted fabric It is the preferable fabric for making underwear and children's garment.But soybean fiber causes because of the presence of isoflavones, and its whiteness is very low, yellowing Very high, the Oxidizing and Reducing Agents such as conventional hydrogen peroxide bleaching process is difficult to obtain high bleaching whiteness, it is difficult to meets light, fresh The dyeing process of gorgeous color and iridescent.
Patent of invention CN 1277018C disclose the method that a kind of soybean fiber elder generation reducing bleach reoxidizes bleaching, The B of patent of invention CN 103173992 disclose a kind of method of soybean fiber hydrogen peroxide and bleach-activating bleaching, hair The bright A of patent CN 105484010 disclose a kind of soybean fiber and first use hydrogen peroxide bleaching, then white goods is entered with daylight The method of row irradiation, above-mentioned soybean protein fiber bleaching method can improve the whiteness of soybean fiber fabric, have no at present Bleaching, which is successively carried out in two steps, on soybean fiber ultraviolet light and hydrogen peroxide obtains the high report for bleaching whiteness method.
The content of the invention
The technical problems to be solved by the invention are using conventional oxidation and reduction drift for current soybean fiber Whitening method is difficult to obtain high bleaching whiteness, it is difficult to realizes soybean fiber light color, bright color and iridescent dyeing process Shortcoming, there is provided it is a kind of by being first irradiated the method bleached again with hydrogen peroxide with ultraviolet light to soybean fiber, it is real The dyeing and finishing processing of the existing high bleaching whiteness of soybean fiber.
In order to solve the above technical problems, the present invention uses following technical scheme:
A kind of method for bleaching of soybean fiber, is first irradiated using ultraviolet light to soybean fiber, then with chemistry Bleaching agent is bleached to the soybean fiber through ultraviolet light, finally by soybean fiber washing, the baking after bleaching It is dry.
The ultraviolet light intensity is 200-1000W, irradiation time 2-20min.
The prescription of the chemical bleaching agent is:Hydrogen peroxide 3-10g/L, sodium metasilicate 2-7g/L.
Described bleaching temperature is 70-100 DEG C, bleaching time 20-100min.
Beneficial effects of the present invention:The present invention provides one and used again by being first irradiated to soybean fiber with ultraviolet light The method that hydrogen peroxide is bleached, realize the dyeing and finishing processing of the high bleaching whiteness of soybean fiber.Ultraviolet light destroys greatly It is difficult to during hydrogen peroxide bleaching the pigmentary structures removed in legumin fiber, substantially increases soybean fiber fabric Bleach whiteness.The bleaching for realizing high whiteness soybean fiber fabric by the method for the present invention is processed, blanching soya beans protein fiber The indices such as the whiteness of dimensional fabric, strength, dyeability meet the requirements, and the method increase the white of soybean fiber fabric Degree, guarantee is provided for the bright color of soybean fiber fabric, light color, iridescent dyeing.Technical scheme technique Simple possible, to raw material, auxiliary agent, fabric without particular/special requirement, large-scale production is achieved that using conventional printing and dyeing mill's bleaching equipment, Have broad application prospects.
Embodiment
With reference to specific embodiment, the present invention will be further described.It should be understood that following examples are merely to illustrate this Invention can make one not for limitation the scope of the present invention, the person skilled in the art in the field according to the content of foregoing invention A little nonessential modifications and adaptations.
Embodiment 1
A kind of method for bleaching of soybean fiber, its process are as follows:
By soybean protein fiber knitted fabrics 300W ultra violet lamp 5min, then with 10g/L hydrogen peroxide, 3g/L sodium metasilicate is 90 DEG C soybean fiber fabric is bleached, bleaching time 30min, then wash, dry after obtain bleaching finished product.
Embodiment 2
A kind of method for bleaching of soybean fiber, its process are as follows:
By soybean protein fiber knitted fabrics 500W ultra violet lamp 10min, then with 20g/L hydrogen peroxide, 2g/L sodium metasilicate, 95 DEG C are bleached to soybean fiber fabric, bleaching time 50min, are then washed, are obtained bleaching finished product after drying.
Embodiment 3
A kind of method for bleaching of soybean fiber, its process are as follows:
By soybean protein fiber knitted fabrics 800W ultra violet lamp 2min, then with 5g/L hydrogen peroxide, 7g/L sodium metasilicate, 100 DEG C are bleached to soybean fiber fabric, bleaching time 20min, are then washed, are obtained bleaching finished product after drying.
Embodiment 4
A kind of method for bleaching of soybean fiber, its process are as follows:
By soybean protein fiber knitted fabrics 1000W ultra violet lamp 2min, then with 10g/L hydrogen peroxide, 5g/L sodium metasilicate, 70 DEG C are bleached to soybean fiber fabric, bleaching time 70min, are then washed, are obtained bleaching finished product after drying.
Embodiment 5
A kind of method for bleaching of soybean fiber, its process are as follows:
By soybean protein fiber knitted fabrics 900W ultra violet lamp 3min, then with 8g/L hydrogen peroxide, 3g/L sodium metasilicate, 80 DEG C soybean fiber fabric is bleached, bleaching time 35min, then wash, dry after obtain bleaching finished product.
Embodiment 6
A kind of method for bleaching of soybean fiber, its process are as follows:
By soybean protein fiber knitted fabrics 400W ultra violet lamp 12min, then with 8g/L hydrogen peroxide, 4.5g/L sodium metasilicate, Soybean fiber fabric is bleached at 75 DEG C, bleaching time 25min, then wash, obtain bleaching finished product after drying.
Embodiment 7
A kind of method for bleaching of soybean fiber, its process are as follows:
By soybean protein fiber knitted fabrics 700W ultra violet lamp 14min, then with 3g/L hydrogen peroxide, 5g/L sodium metasilicate, 90 DEG C are bleached to soybean fiber fabric, bleaching time 100min, are then washed, are obtained bleaching finished product after drying.
Embodiment 8
A kind of method for bleaching of soybean fiber, its process are as follows:
By soybean protein fiber knitted fabrics 200W ultra violet lamp 20min, then with 6g/L hydrogen peroxide, 4g/L sodium metasilicate, 85 DEG C are bleached to soybean fiber fabric, bleaching time 30min, are then washed, are obtained bleaching finished product after drying.
The implementation result of the present invention
After 1 ~ 8 first ultraviolet light of embodiment again hydrogen peroxide bleaching processing, white goods enters soybean fiber fabric to it The following test of row, test result are shown in Table 1.
1)White goods measuring brightness
ISO whiteness is tested using PN-48B types leucometer, every piece of cloth specimen builds up four layers, takes different positions to measure respectively 6 times, takes The average value of 6 data is as final data, as a result as shown in table 1.
2)White goods bursting strength determines
According to《The measure steel ball method of GB/T 19976-2005 textile bursting strengths》Test, as a result as shown in table 1.
3)White goods dyeability determines
4,40 DEG C of Acid cyanine 5R 2%o.m.f, pH enters dye, is warming up to 90 DEG C with 1 DEG C/min programming rate, is incubated 60min, Dyeing terminates test dye uptake(E%), formula is pressed using raffinate method(1)Calculate, dye liquor absorbance is in TU-1800 UV, visible lights Spectrophotometer(The general analysis in Beijing)Upper measure.A in formula0And A1Respectively dye stoste and the absorbance of raffinate.Measurement result such as table Shown in 1.
(1)
Table 1 implements the test result of blanching soya beans azelon fabric
As shown in Table 1, technical scheme provided by the present invention can assign soybean fiber fabric higher bleaching whiteness, drift The strength loss of fabric is smaller after white, and dyeability does not decline substantially.And 15g/L hydrogen peroxide is used first to soybean fiber Bleached, then do not had with the soybean fiber 5min after ultraviolet light hydrogen peroxide bleaching, the whiteness of soybean fiber Significantly improve, its bleaching effect is far below the whiteness of hydrogen peroxide bleaching soybean fiber after first ultraviolet light.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The skill of the industry For art personnel it should be appreciated that the present invention is not limited to the above embodiments, described in above-described embodiment and specification is explanation The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and Its equivalent thereof.

Claims (4)

  1. A kind of 1. method for bleaching of soybean fiber, it is characterised in that:First soybean fiber is shone using ultraviolet light Penetrate, then the soybean fiber through ultraviolet light is bleached with chemical bleaching agent, finally by the soybean egg after bleaching White fiber washing, drying.
  2. 2. the method for bleaching of soybean fiber according to claim 1, it is characterised in that:The ultraviolet light intensity For 200-1000W, irradiation time 2-20min.
  3. 3. the method for bleaching of soybean fiber according to claim 1, it is characterised in that:The chemical bleaching agent prescription For:Hydrogen peroxide 3-10g/L, sodium metasilicate 2-7g/L.
  4. 4. the method for bleaching of soybean fiber according to claim 1, it is characterised in that:Described bleaching temperature is 70-100 DEG C, bleaching time 20-100min.
CN201711136101.1A 2017-11-16 2017-11-16 Bleaching method of soybean protein fiber Active CN107740261B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711136101.1A CN107740261B (en) 2017-11-16 2017-11-16 Bleaching method of soybean protein fiber

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CN107740261B CN107740261B (en) 2020-06-05

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115467178A (en) * 2022-09-21 2022-12-13 江西给力纺织有限公司 Fading treatment method for leftover materials of spandex-containing waste cloth

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5057334A (en) * 1990-07-13 1991-10-15 Ort's Inc. Process for recovery of cellulose
CN1673443A (en) * 2004-03-24 2005-09-28 独立行政法人产业技术综合研究所 Method for bleaching fibrous articles
CN101405451A (en) * 2006-03-28 2009-04-08 日清纺织株式会社 Bleaching/reforming apparatus for fiber and fiber structure
CN103966832A (en) * 2014-05-05 2014-08-06 芜湖富春染织有限公司 Method for preparing composite photocatalysis bleaching system and textile bleaching technology
CN105484010A (en) * 2015-12-19 2016-04-13 张家港市振新印染有限公司 Bleaching technology for soybean protein fibers

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5057334A (en) * 1990-07-13 1991-10-15 Ort's Inc. Process for recovery of cellulose
CN1673443A (en) * 2004-03-24 2005-09-28 独立行政法人产业技术综合研究所 Method for bleaching fibrous articles
CN101405451A (en) * 2006-03-28 2009-04-08 日清纺织株式会社 Bleaching/reforming apparatus for fiber and fiber structure
CN103966832A (en) * 2014-05-05 2014-08-06 芜湖富春染织有限公司 Method for preparing composite photocatalysis bleaching system and textile bleaching technology
CN105484010A (en) * 2015-12-19 2016-04-13 张家港市振新印染有限公司 Bleaching technology for soybean protein fibers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115467178A (en) * 2022-09-21 2022-12-13 江西给力纺织有限公司 Fading treatment method for leftover materials of spandex-containing waste cloth

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