CN107739245A - A kind of environment-friendly type compound fertilizer anticaking agent aqua and preparation method thereof and application method - Google Patents
A kind of environment-friendly type compound fertilizer anticaking agent aqua and preparation method thereof and application method Download PDFInfo
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- CN107739245A CN107739245A CN201711105840.4A CN201711105840A CN107739245A CN 107739245 A CN107739245 A CN 107739245A CN 201711105840 A CN201711105840 A CN 201711105840A CN 107739245 A CN107739245 A CN 107739245A
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- Prior art keywords
- anticaking agent
- compound fertilizer
- environment
- humic acid
- friendly type
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- Granted
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 121
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 94
- 150000001875 compounds Chemical class 0.000 title claims abstract description 90
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims description 20
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical class C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000002131 composite material Substances 0.000 claims abstract description 32
- 239000004021 humic acid Substances 0.000 claims abstract description 26
- 239000008187 granular material Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- 239000007921 spray Substances 0.000 claims abstract description 15
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 239000003153 chemical reaction reagent Substances 0.000 claims description 49
- 241000894006 Bacteria Species 0.000 claims description 16
- 241000209094 Oryza Species 0.000 claims description 14
- 235000007164 Oryza sativa Nutrition 0.000 claims description 14
- 235000009566 rice Nutrition 0.000 claims description 14
- 235000015099 wheat brans Nutrition 0.000 claims description 14
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical group CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 229960003237 betaine Drugs 0.000 claims description 7
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 6
- QZRMKGRPCTVXBS-UHFFFAOYSA-N 2,6,8-trimethylnonan-4-yl dihydrogen phosphate Chemical compound CC(C)CC(C)CC(CC(C)C)OP(O)(O)=O QZRMKGRPCTVXBS-UHFFFAOYSA-N 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 6
- 235000013339 cereals Nutrition 0.000 claims description 6
- RKIQXVFUVYXZCD-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)C(OS(O)(=O)=O)(CCO)CCCCCCCCCCCCCCCCCC Chemical group C(CCCCCCCCCCCCCCCCC)C(OS(O)(=O)=O)(CCO)CCCCCCCCCCCCCCCCCC RKIQXVFUVYXZCD-UHFFFAOYSA-N 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 239000003093 cationic surfactant Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical compound CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 claims description 4
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 4
- 108700003601 dimethylglycine Proteins 0.000 claims description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 3
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 238000000855 fermentation Methods 0.000 claims description 2
- 230000004151 fermentation Effects 0.000 claims description 2
- -1 oleoyl amine Chemical class 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 claims 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 229940051841 polyoxyethylene ether Drugs 0.000 claims 1
- 229920000056 polyoxyethylene ether Polymers 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 239000002689 soil Substances 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 5
- 230000000903 blocking effect Effects 0.000 abstract description 4
- 238000005054 agglomeration Methods 0.000 abstract description 3
- 230000002776 aggregation Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000012545 processing Methods 0.000 abstract description 3
- 238000004806 packaging method and process Methods 0.000 abstract description 2
- 230000008635 plant growth Effects 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 230000008859 change Effects 0.000 description 9
- 239000000843 powder Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 239000001692 EU approved anti-caking agent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000193830 Bacillus <bacterium> Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ACZVSMNFVFBOTM-UHFFFAOYSA-O 2-carboxyethyl(trimethyl)azanium Chemical compound C[N+](C)(C)CCC(O)=O ACZVSMNFVFBOTM-UHFFFAOYSA-O 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- JDGVUSPBIZNZFS-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCCC(CCCCCCCCCCCCCCCCCC)(OCC)OS(=O)(=O)O Chemical compound CCCCCCCCCCCCCCCCCCC(CCCCCCCCCCCCCCCCCC)(OCC)OS(=O)(=O)O JDGVUSPBIZNZFS-UHFFFAOYSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 241000235342 Saccharomycetes Species 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- ZYWVUGXNGJVBAL-UHFFFAOYSA-N propan-1-amine;sulfuric acid Chemical compound CCCN.OS(O)(=O)=O ZYWVUGXNGJVBAL-UHFFFAOYSA-N 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 238000013441 quality evaluation Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/02—Other organic fertilisers from peat, brown coal, and similar vegetable deposits
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The present invention gives a kind of environment-friendly type compound fertilizer anticaking agent aqua and its preparation, application, is related to composite fertilizer's anti-caking processing technology field, it is characterised in that including：Modified humic acid salt and surfactant, wherein the ratio between modified humic acid salt and surfactant qualities are 1:0.5~2, after modified humic acid salt is mixed with water, heat while stirring, humate dissolving to be modified is added completely into surfactant, and manufactured anticaking agent aqua preserves after being added to atomised form spray on compound fertilizer granules through drying sealed packaging.The beneficial effects of the invention are as follows：Anticaking agent is environmental type product, and raw material is to soil without any pollution, easy degraded and abundance；Humic acid substance, which has, promotes plant growth, the effect of improving quality and soil texture；With more preferable agglomeration preventing performance, preferable preventing blocking effect can be reached, and addition is easy to operate, and cost is low.
Description
Technical field
The present invention relates to a kind of environment-friendly type compound fertilizer anticaking agent aqua.
The invention further relates to a kind of preparation method of environment-friendly type compound fertilizer anticaking agent aqua.
The present invention further relates to a kind of application method of environment-friendly type compound fertilizer anticaking agent aqua.
Background technology
With continuous improvement of the people to the understanding that applies fertilizers scientifically, to composite fertilizer's N, P, K nutrient formula more rationally, science and
Environmental protection, but due to conditions such as air humidity, temperature, pressure store and storage times, cause the caking phenomenon of compound fertilizer, give
Composite heat transfer and use bring the problem of many, and the compound fertilizer of caking must be crushed again and screening process again, this
Necessarily increase extra manpower and materials.It is a necessary production to carry out anti-caking processing to compound fertilizer using anticaking agent
Link and most simple and effective process meanses, it can effectively solve the problem that many production and application problem that compound fertilizer from caking brings, energy
No effectively anti-caking has turned into an important indicator of compound fertilizer quality evaluation.
Existing powder-type, water aqua type, the molten three kinds of compound fertilizer anticaking agents of type of oil, wherein, powder-type anticaking agent is to utilize
The formation of crystal brige, mainly de- including zeolite powder, talcum powder, silicon dioxide powder, lime stone, illiteracy between inert powder barrier fertiliser granulates
Stone, diatomite, bentonite, kaolin, calcium carbonate and clay etc., oily matter is sprayed into during use to adhere to inert powder；It is water-soluble
Formulation anticaking agent is then that surfactant is dissolved in the water, and mainly includes anionic surfactant with sulfate, sulphur
Using more, cationic surfactant mainly has octadecylamine and its esters, nonionic surfactant for hydrochlorate, phosphate
There are polyethylene glycol oxide, ester, the aldehyde and ketone of low molecule amount, be sprayed at fertilizer surface, to reach the purpose for reducing fertilizer surface tension force
And play the effect of anti-caking；Oil solvent type anticaking agent has the advantages of easy to use, effect is good, but conventional method needs to add
Mineral oil is difficult to degrade with fertilizer as solvent, these mineral oil into soil, and certain journey is caused to soil and surrounding enviroment
The pollution of degree.
In order to meet the above-mentioned market demand, number of patent application is the " a kind of degradable compound of CN201410604026.7
Fertile anticaking agent and its preparation method and application " utilizes fatty amine or its salt, stearic acid, oleic acid, refined glycerine and discarded edible
A kind of degradable compound fertilizer anticaking agent of oil and fat preparation, although certain lyophobic dust of addition, moistureproof and waterproof are integrally imitated
Fruit is not satisfactory all the time；Number of patent application is CN200710011185.6 " a kind of high-nitrogen compound fertilizer anticaking agent and its preparation
And application " use paraffin, alkylamine, Arlacel-80, mineral oil to prepare paste oil-soluble anticaking agent for raw material, the technology is main
Wrapped up using hydrophobic substances such as paraffin in fertilizer surface, form one layer of hydrophobic membrane, it is still, this kind of anti-so as to prevent caking from being formed
Agglomeration agent is due to having used the difficult degradation raw material such as paraffin, mineral oil, thus obtained anticaking agent is also to be difficult to be degraded；
Number of patent application is that CN201110008370.6 " a kind of straw powder-based anti-blocking agent of compound fertilizer " utilizes the stalk of 60-3000 mesh
Powder, stearic acid, stearylamine, hydramine, white oil or solid paraffin and the component of natural oil six prepare anticaking agent, anticaking agent tool
There are biodegradability and good environment friendly, long-term use will not cause bad to soil, crops and farm environment
Influence, but adding proportion of this anticaking agent in composite fertilizer is excessive, and also too high no nutrient additive also can
The formulation cost of composite fertilizer is improved, therefore the actual use value of stalk anticaking agent is not high.
The content of the invention
The technical problems to be solved by the invention are to provide that a kind of cost is low, preventing blocking effect is good, degradable environment-friendly
Compound fertilizer anticaking agent aqua.
The technical problems to be solved by the invention are also to provide a kind of preparation side of environment-friendly type compound fertilizer anticaking agent aqua
Method.
The technical problems to be solved by the invention are and provide a kind of user of environment-friendly type compound fertilizer anticaking agent aqua
Method.
In order to solve the above technical problems, the invention provides a kind of preparation side of environment-friendly type compound fertilizer anticaking agent aqua
Method, comprise the following steps：
A) modified humic acid reagent is prepared：
Culture 15 is sealed by fermentation in the environment of 45~65 DEG C after taking humic acid reagent, EM bacterium, rice bran, wheat bran and water mixing
~20 days, each component mass percent was humic acid reagent 50~60%, EM bacterium 0.5~1%, rice bran 5~10%, wheat bran
5~10%, water 20~39%, once stirred and evenly mixed every 3 days, obtain being modified humic acid reagent；
B) anticaking agent aqua is prepared：
After the modified humic acid reagent that step a) is obtained is mixed with required water, heat while stirring, keeping temperature 50
~60 DEG C, humic acid reagent dissolving to be modified is added completely into surfactant, modified humic acid reagent and surfactant qualities
The ratio between be 1:0.5~2, do not ferment complete rice bran and wheat bran are finally filtered out, obtains salt containing modified humic acid and surface-active
Agent is total to account for the 2~5% of anticaking agent aqua gross mass.
As it is of the invention preferably, humic acid reagent is 70% corruption by the mass fraction of active ingredient in the step a)
The one or more grown in acid, potassium humate, ammonium humate mix.
Humate is made up of polycyclic aromatic core and active function groups, has the characters such as hydrophily, hydrophobicity, interfacial activity,
Humate hydrophilic radical is wrapped in bibulous component in compound fertilizer granules Adsorption on Surface compound fertilizer granules, hydrophobic grouping
Compound fertilizer granules surface overcoats are enclosed in, hinder the compound fertilizer granules moisture absorption to avoid luming.
Above-mentioned EM bacterium are purchased in Henan Zhong Bang biological products Co., Ltd, and product type is the special concentration EM bacterium powders of compost.
EM bacterium are combined by cellulose-decomposing bacterium, lactic acid bacteria, bacillus, hay bacillus, photosynthetic bacteria, saccharomycete,
EM bacterium have the function that to decompose humate, because humate is in the nature the organic mixture of macromolecular chain, by EM bacterium oxygen
Change after decomposing, strand reduces, and hydrophilic functional group's increase such as hydroxyl, carboxyl, improves hydrophilicity and the biochemical effect of humic acid
Fruit.
It is anion surfactant, cationic surfactant, two as of the invention preferred, described surfactant
Property ionic surface active agent, the one or more combination in nonionic surfactant, the absorption of surfactant hydrophilic radical is multiple
Bibulous component in the particle of Hefei, hydrophobic grouping are enclosed in compound fertilizer granules surface overcoats, hinder the compound fertilizer granules moisture absorption
Avoid luming.
It is 1-isobutyl-3,5-dimethylhexylphosphoric acid as of the invention preferred, described anion surfactant, lauryl alcohol polyoxyethylene
The one or more combination of ether sulfosuccinates disodium, ethoxylated dodecyl alcohol carboxylic acid sodium.
Be distearyl hydroxyethyl methyl sulfuric acid formicester ammonium as of the invention preferred, described cationic surfactant,
The one or two kinds of combinations of hexadecyltrimethylammonium chloride.
It is coco imidoazolinium as of the invention preferred, described zwitterionic surfactant, cocamidopropyl propyl amide two
The one or more combination of methyl betaine, cocamidopropyl propyl amide hydroxyl sulphonic acid betaine.
It is Dodecyl Glucoside as of the invention preferred, described nonionic surfactant, aliphatic alcohol polyethenoxy, nonyl
The one or more combination of base phenol polyethenoxy ether.
Preparation environment-friendly type composite fertilizer anti-caking can be made using the preparation method of above-mentioned environment-friendly type compound fertilizer anticaking agent aqua
Block agent aqua is simpler, cost is lower.
In order to solve the above technical problems, the invention provides a kind of environment-friendly type compound fertilizer anticaking agent aqua, use are above-mentioned
Environment-friendly type compound fertilizer anticaking agent aqua the obtained environment-friendly type compound fertilizer anticaking agent aqua of preparation method.
This environment-friendly type compound fertilizer anticaking agent aqua is environmental type product, and selected raw material is to soil without any dirt
Dye, easy degraded and abundance；Humic acid substance, which has, promotes plant growth, the effect of improving quality and soil texture；
With preferable agglomeration preventing performance, preferable preventing blocking effect can be reached.
In order to solve the above technical problems, the invention provides a kind of user of environment-friendly type compound fertilizer anticaking agent aqua
Method, comprise the following steps：In the prilling of production composite fertilizer, fertile grain forming to be composite, will when particle diameter reaches 3~4mm
Above-mentioned environment-friendly type compound fertilizer anticaking agent aqua is added on compound fertilizer granules surface with atomised form spray, is sufficiently stirred mixing,
Then 65 DEG C of freeze-day with constant temperature are passed through, anticaking agent dosage is added to composite fertilizer with 1.0~3.0kg/t of butt quality standard spray
On particle.
It can ensure that the proportioning of environment-friendly type compound fertilizer anticaking agent aqua and chemical fertilizer is more reasonable using the application method, mist
It is more abundant that the form of change can also be such that environment-friendly type compound fertilizer anticaking agent aqua is contacted with chemical fertilizer butt.
Embodiment
In order that the technological means of the present invention, character of innovation, achieve the goal is easy to understand with effect, with reference to tool
Body example, is expanded on further the present invention.
Embodiment 1：
The preparation method of this environment-friendly type compound fertilizer anticaking agent aqua, comprises the following steps：
This environment-friendly type compound fertilizer anticaking agent aqua includes following raw material：Modified humic acid reagent, 1-isobutyl-3,5-dimethylhexylphosphoric acid
And Dodecyl Glucoside.
Modified humic acid reagent by 55kg active ingredients mass fraction be 70% humic acid, 0.5kgEM bacterium, 5kg rice brans,
5kg wheat bran and 34.5kg water, under 55 DEG C of temperature conditionss, fermented and cultured obtains for 15 days, is made and takes modified humic acid reagent.
Take modified humic acid reagent 2kg to be added in 96kg water, heat while stirring, keeping temperature is 50 DEG C, waits to change
Property the dissolving of humic acid reagent be added completely into 1-isobutyl-3,5-dimethylhexylphosphoric acid 1kg and Dodecyl Glucoside 1kg, stir to abundant dissolving, treat
Modified humic acid reagent, 1-isobutyl-3,5-dimethylhexylphosphoric acid and Dodecyl Glucoside dissolving are complete, filter out in modified humic acid reagent not
Ferment complete rice bran and wheat bran, obtains reagent containing modified humic acid, 1-isobutyl-3,5-dimethylhexylphosphoric acid and Dodecyl Glucoside dissolving and closes
Meter accounts for the environment-friendly type compound fertilizer anticaking agent aqua I of above-mentioned solution gross mass 4%.
The application method of this environment-friendly type compound fertilizer anticaking agent aqua, comprises the following steps：In the granulation of production composite fertilizer
In technique, fertile grain forming to be composite, when particle diameter reaches 3~4mm, by above-mentioned environment-friendly type compound fertilizer anticaking agent aqua I with
Atomised form spray is added on compound fertilizer granules surface, is sufficiently stirred mixing, then by 65 DEG C of freeze-day with constant temperature, is finally dispensed
It is sealed, anticaking agent dosage is to be added to butt quality 2.5kg/t standard spray on compound fertilizer granules.
Embodiment 2 to 10：
Embodiment 2 to 10 is weighed according to table 1 below material rate successively, and the method recorded by embodiment 1, with difference
Modified humic acid reagent and surfactant compound fertilizer anticaking agent II~Ⅹ is respectively prepared.
The compound fertilizer anticaking agent of the different material of table 1 and ratio
Compound fertilizer from caking is tested
Above-mentioned anticaking agent aqua is added in compound fertilizer granules Granulation Equipments with the atomization spray of the equipment such as spray gun, passes through rolling
Wheel rotates anticaking agent aqua and is evenly distributed in compound fertilizer granules surface, and processing is then dried to it, finally carries out
Sealed packaging, while the sample for being not added with anticaking agent is taken as blank.
Quick caking test is carried out to composite fertilizer, composite fertilizer's sample is put into moisture absorption apparatus, control relative humidity 96%,
After temperature is 60 DEG C, 4 hours, sample is taken out, is transferred in 60 DEG C of baking oven and dries, when fertile moisture content to be composite is 2~3%,
Composite fertilizer is fitted into hermetic bag by every bag of 100g, is put into 60 DEG C of baking ovens and heats 4 hours, after taking-up, is placed in 10 DEG C of environment, it is cold
But 3 hours, during heating-cooling, one weight of pressure above hermetic bag, hermetic bag is born 10kPa pressure, repeat above-mentioned reality
Condition is tested,, will by hermetic bag from 0.5 meter of height level's freely falling body to hard plane after recycling heating-cooling once
Composite fertilizer in hermetic bag takes out, and separates caking and the composite fertilizer do not lumpd, weigh and with formula below calculate caking rate and
With respect to caking rate：
Composite fertilizer's gross mass in composite fertilizer's quality/hermetic bag of caking rate=caking；
With respect to caking rate=(addition anticaking agent compound fertilizer from caking rate/it is not added with anticaking agent compound fertilizer from caking rate) ×
100%；
Different compound fertilizer anticaking agents is with the addition of to see the table below the caking rate of composite fertilizer and relative caking rate influence result
2：
The anticaking agent of the different amounts of table 2 influences on the relative caking rate of different composite fertilizer
Note：Anticaking agent (%) represents the anticaking agent of addition different amounts (in terms of butt).
By finding out in table 2, compared to space management, the compound fertilizer anticaking agent of addition produces to the relative caking rate of composite fertilizer
Raw significant change, caking rate are decreased obviously, and the composite fertilizer of different ratio, Different adding amount, different anticaking agents are to phase
Anti-caking rate is had an impact；It is in inverse relation with respect to caking rate and anticaking agent dosage when composite fertilizer is high nitrogen type, may
It is that N element in compound fertilizer is wrapped up by the hydrophilic radical of the modified humic acid salt in anticaking agent and surfactant component,
Hydrophobic grouping is enclosed in the generation of the surface prevention moisture absorption phenomenon of compound fertilizer granules, effectively prevents caking phenomenon；When using anti-caking
It is minimum with respect to caking rate during block agent V, illustrate using the anticaking agent containing modified humic acid and Dodecyl Glucoside to compound
Fertile particle preventing blocking effect is best.
Embodiment 11：
The preparation method of this environment-friendly type compound fertilizer anticaking agent aqua, comprises the following steps：
This environment-friendly type compound fertilizer anticaking agent aqua includes following raw material：Modified humic acid reagent, distearyl ethoxy
Methylsulfuric acid formicester ammonium and hexadecyltrimethylammonium chloride.
Modified humic acid reagent by 50kg active ingredients mass fraction be 70% humic acid, 1kgEM bacterium, 5kg rice brans,
5kg wheat bran and 39kg water, under the conditions of 45 DEG C, fermented and cultured obtains for 20 days, is made and takes modified humic acid reagent.
Take modified humic acid reagent 2kg to be added in 147kg water, heat while stirring, keeping temperature is 60 DEG C, waits to change
Property the dissolving of humic acid reagent be added completely into distearyl hydroxyethyl methyl sulfuric acid formicester ammonium 0.5kg and cetyl trimethyl chlorination
Ammonium 0.5kg, stir to abundant dissolving, humic acid reagent, distearyl hydroxyethyl methyl sulfuric acid formicester ammonium and hexadecane to be modified
The dissolving of base trimethyl ammonium chloride is complete, filters out fermented in humic acid reagent to be modified complete rice bran and wheat bran, obtains containing changing
Property humic acid reagent, distearyl hydroxyethyl methyl sulfuric acid formicester ammonium and hexadecyltrimethylammonium chloride dissolving it is total account for it is above-mentioned
Solution gross mass 2%, obtain environment-friendly type compound fertilizer anticaking agent aqua Ⅺ.
The application method of this environment-friendly type compound fertilizer anticaking agent aqua, comprises the following steps：In the granulation of production composite fertilizer
In technique, fertile grain forming to be composite, when particle diameter reaches 3mm, by above-mentioned environment-friendly type compound fertilizer anticaking agent aqua Ⅺ with mist
The spray of change form is added on compound fertilizer granules surface, is sufficiently stirred mixing, then by 65 DEG C of freeze-day with constant temperature, is finally dispensed close
Envelope preserves, and anticaking agent dosage is to be added to butt quality 1.0kg/t standard spray on compound fertilizer granules.
Embodiment 12：
The preparation method of this environment-friendly type compound fertilizer anticaking agent aqua, comprises the following steps：
This environment-friendly type compound fertilizer anticaking agent aqua includes following raw material：Modified humic acid reagent, Dodecyl Glucoside and
Aliphatic alcohol polyethenoxy.
Modified humic acid reagent by 60kg active ingredients mass fraction be 70% humic acid, 0.5kgEM bacterium, 5kg rice brans,
5kg wheat bran and 29.5kg water, under the conditions of 65 DEG C, fermented and cultured obtains for 18 days, is made and takes modified humic acid reagent.
Take modified humic acid reagent 1kg to be added in 57kg water, heat while stirring, keeping temperature is 55 DEG C, waits to change
Property the dissolving of humic acid reagent be added completely into Dodecyl Glucoside 1kg and aliphatic alcohol polyethenoxy 1kg, stir to abundant dissolving, treat
Modified humic acid reagent, Dodecyl Glucoside and aliphatic alcohol polyethenoxy dissolving are complete, filter out in humic acid reagent to be modified
Ferment complete rice bran and wheat bran, obtains reagent containing modified humic acid, Dodecyl Glucoside and aliphatic alcohol polyethenoxy dissolving and closes
Meter accounts for above-mentioned solution gross mass 5%, obtains environment-friendly type compound fertilizer anticaking agent aqua Ⅻ.
The application method of this environment-friendly type compound fertilizer anticaking agent aqua, comprises the following steps：In the granulation of production composite fertilizer
In technique, fertile grain forming to be composite, when particle diameter reaches 4mm, by above-mentioned environment-friendly type compound fertilizer anticaking agent aqua Ⅻ with mist
The spray of change form is added on compound fertilizer granules surface, is sufficiently stirred mixing, then by 65 DEG C of freeze-day with constant temperature, is finally dispensed close
Envelope preserves, and anticaking agent dosage is to be added to butt quality 3.0kg/t standard spray on compound fertilizer granules.
Embodiment 13：
The preparation method of this environment-friendly type compound fertilizer anticaking agent aqua, comprises the following steps：
This environment-friendly type compound fertilizer anticaking agent aqua includes following raw material：Modified humic acid reagent, coco imidoazolinium and
Cocoamidopropyl dimethyl glycine betaine.
Modified humic acid reagent is 70% humic acid, 0.5kgEM bacterium, 10kg rice by 59.5kg active ingredients mass fraction
Chaff, 10kg wheat bran and 20kg water, under the conditions of 65 DEG C, fermented and cultured obtains for 18 days, is made and takes modified humic acid reagent.
Take modified humic acid reagent 1kg to be added in 72kg water, heat while stirring, keeping temperature is 55 DEG C, waits to change
Property the dissolving of humic acid reagent be added completely into coco imidoazolinium 1kg and cocoamidopropyl dimethyl glycine betaine 1kg, stirring is to filling
Divide dissolving, humic acid reagent, coco imidoazolinium and the dissolving of cocoamidopropyl dimethyl glycine betaine to be modified completely, filter out
Ferment complete rice bran and wheat bran in humic acid reagent to be modified, obtains reagent containing modified humic acid, coco imidoazolinium and coconut palm
The dissolving of oleamide propyl-dimethyl glycine betaine is total to account for above-mentioned solution gross mass 4%, obtains environment-friendly type compound fertilizer anticaking agent water
Agent Ⅹ III.
The application method of this environment-friendly type compound fertilizer anticaking agent aqua, comprises the following steps：In the granulation of production composite fertilizer
In technique, fertile grain forming to be composite, when particle diameter reaches 3.5mm, by above-mentioned environment-friendly type compound fertilizer anticaking agent aqua Ⅹ III
It is added to atomised form spray on compound fertilizer granules surface, is sufficiently stirred mixing, then by 65 DEG C of freeze-day with constant temperature, finally divides
Dress is sealed, and anticaking agent dosage is to be added to butt quality 3.0kg/t standard spray on compound fertilizer granules.
General principle, principal character and the advantages of the present invention of the present invention, the technology of the industry has been shown and described above
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also have various changes and modifications, these changes
It will be fallen into improving in scope of the claimed invention.The scope of protection of present invention, by appended claims
And its equivalent thereof.
Claims (9)
1. a kind of preparation method of environment-friendly type compound fertilizer anticaking agent aqua, comprises the following steps：
A) modified humic acid reagent is prepared：
Culture 15~20 is sealed by fermentation in the environment of 45~65 DEG C after taking humic acid reagent, EM bacterium, rice bran, wheat bran and water mixing
My god, each component mass percent be humic acid reagent 50~60%, EM bacterium 0.5~1%, rice bran 5~10%, wheat bran 5~
10%th, water 20~39%, once stirred and evenly mixed every 3 days, obtain being modified humic acid reagent；
B) anticaking agent aqua is prepared：
After the modified humic acid reagent that step a) is obtained is mixed with required water, heat while stirring, keeping temperature is 50~60
DEG C, humic acid reagent dissolving to be modified is added completely into surfactant, the ratio between modified humic acid reagent and surfactant qualities
For 1:0.5~2, do not ferment complete rice bran and wheat bran are finally filtered out, salt containing modified humic acid is obtained and surfactant closes
Meter accounts for the 2~5% of anticaking agent aqua gross mass.
2. according to a kind of preparation method of environment-friendly type compound fertilizer anticaking agent aqua described in claim 1, it is characterised in that：
Humic acid reagent is 70% humic acid, potassium humate, ammonium humate by the mass fraction of active ingredient in the step a)
In one or more mix.
3. according to a kind of preparation method of environment-friendly type compound fertilizer anticaking agent aqua described in claim 1, it is characterised in that：
Described surfactant is anion surfactant, cationic surfactant, zwitterionic surfactant, non-
One or more combination in ionic surface active agent.
4. according to a kind of preparation method of environment-friendly type compound fertilizer anticaking agent aqua described in claim 3, it is characterised in that：
Described anion surfactant be 1-isobutyl-3,5-dimethylhexylphosphoric acid, Dodecyl Polyoxyethylene Ether sulfosuccinate disodium,
The one or more combination of ethoxylated dodecyl alcohol carboxylic acid sodium.
5. according to a kind of preparation method of environment-friendly type compound fertilizer anticaking agent aqua described in claim 3, it is characterised in that：
Described cationic surfactant is distearyl hydroxyethyl methyl sulfuric acid formicester ammonium, hexadecyltrimethylammonium chloride
One or two combination.
6. according to a kind of preparation method of environment-friendly type compound fertilizer anticaking agent aqua described in claim 3, it is characterised in that：
Described zwitterionic surfactant is coco imidoazolinium, cocoamidopropyl dimethyl glycine betaine, coconut oleoyl amine
The one or more combination of propyl group hydroxyl sulphonic acid betaine.
7. according to a kind of preparation method of environment-friendly type compound fertilizer anticaking agent aqua described in claim 3, it is characterised in that：
Described nonionic surfactant is Dodecyl Glucoside, aliphatic alcohol polyethenoxy, the one of NPE
Kind or several combinations.
A kind of 8. environment-friendly type compound fertilizer anticaking agent aqua, it is characterised in that：Using as any one of claim 1 to 8
The preparation method of environment-friendly type compound fertilizer anticaking agent aqua obtain environment-friendly type compound fertilizer anticaking agent aqua.
9. a kind of application method of environment-friendly type compound fertilizer anticaking agent aqua, comprises the following steps：
In the prilling of production composite fertilizer, fertile grain forming to be composite, when particle diameter reaches 3~4mm, by claim 1~8
Environment-friendly type compound fertilizer anticaking agent aqua during any one is described is added on compound fertilizer granules surface with atomised form spray, is fully stirred
Mixing is mixed, is then added by 65 DEG C of freeze-day with constant temperature, anticaking agent dosage with 1.0~3.0kg/t of butt quality standard spray
Onto compound fertilizer granules.
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