CN107738067A - A kind of random length half-hard state copper pipe bus production technology - Google Patents

A kind of random length half-hard state copper pipe bus production technology Download PDF

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Publication number
CN107738067A
CN107738067A CN201710820736.7A CN201710820736A CN107738067A CN 107738067 A CN107738067 A CN 107738067A CN 201710820736 A CN201710820736 A CN 201710820736A CN 107738067 A CN107738067 A CN 107738067A
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China
Prior art keywords
copper pipe
copper
temperature
hard state
production technology
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Pending
Application number
CN201710820736.7A
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Chinese (zh)
Inventor
王磊
申晓强
陈荣荣
张达
顾凯越
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ZHONGTIAN ALLOY TECHNOLOGY Co Ltd
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ZHONGTIAN ALLOY TECHNOLOGY Co Ltd
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Priority to CN201710820736.7A priority Critical patent/CN107738067A/en
Publication of CN107738067A publication Critical patent/CN107738067A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • B22D11/004Copper alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/006Continuous casting of metals, i.e. casting in indefinite lengths of tubes
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/08Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes

Abstract

A kind of disclosed random length half-hard state copper pipe bus production technology, comprises the following steps:Electrolysis copper weld pool → continuous up-casting oxygen-free copper pipe → tube rolling → disk is drawn → cleans after-combustion → annealing → drawing.Pass through the improvement to annealing schedule and the control of drawing working modulus, it can obtain that scale error is small, conductance is high, the uniform half-hard state copper pipe bus of mechanical performance, its copper content >=99.99%, oxygen content≤10PPM, scale error≤± 0.05m, conductance >=99%IACS, Vickers hardness is within the scope of 80 100HV.

Description

A kind of random length half-hard state copper pipe bus production technology
Technical field
The present invention relates to a kind of production technology of copper pipe bus, more particularly to a kind of random length half-hard state copper pipe bus to produce Technique.
Background technology
The high speed development of modern society be unable to do without the guarantee of electric power, and this also proposes higher to electric power correlation auxiliary products It is required that the advantages of half-hard state copper pipe bus is in power Transmission distribution applications make it that its demand is also increasing.Traditional half Hard state copper pipe bus production technology includes electrolysis copper weld pool → be cast into base → strand extruding → tube rolling → annealing → stretching → essence Whole → finished products, technological process length, high energy consumption.In addition, to reach the requirement of copper pipe half-hard state, copper pipe annealing temperature needs It is maintained within very narrow half-hard state temperature range.But traditional annealing furnace volume is larger, the protected throughput of in-furnace temperature, The influence of charge, blower fan situation etc. and produce fluctuation, it is difficult to ensure that copper pipe temperature remains at half-hard state temperature model Within enclosing, cause the performance of copper pipe unstable.
For problem, a kind of half-hard state copper pipe processing method of patent(Patent No. 2014106603981)It is proposed that use exists Line annealing replaces original annealing schedule, can obtain the copper pipe bus of stable performance.But technique during line annealing practical operation Technical sophistication, and the shortcomings that several aspects be present:(1)Online annealing speed is slow, and efficiency is low;(2)Continuous annealing furnace apparatus is in itself It is expensive, along with energy consumption is big, cause cost higher;(3)To prevent copper pipe from aoxidizing, the stove in continuous annealing furnace is generally required Reducibility gas, such as H are filled with chamber2, or H2With N2Mixed gas, certain explosion hazard be present, have certain Security risk;(4)Certain lubricating oil, the not cleaned direct-on-line of lubricating oil be present in the copper pipe surfaces externally and internally drawn through plate drawing machine Annealing, which can burn, discharges substantial amounts of smog, and has unpleasant penetrating odor, endangers employee's health, pollutes environment.
The content of the invention
To solve the above problems, the invention provides a kind of random length half-hard state copper pipe bus production technology, the producer Method makes copper pipe reach soft state on the basis of existing equipment is not changed, by changing annealing schedule, in conjunction with drawing procedure, passes through Drawing working modulus is controlled to obtain half-hard state copper pipe, the copper pipe bus load magnitude of current produced using this method is big, mechanical performance is uniform.
The technical scheme is that:A kind of random length half-hard state copper pipe bus production technology, specifically comprises the following steps:
A, it is electrolysed copper weld pool:Cathode copper is added in smelting furnace and carries out melting, and is to smelting furnace copper liquid surface addition thickness 100-150mm charcoal coating, it is 1140-1170 DEG C to control smelting temperature in smelting furnace, and the copper liquid in smelting furnace passes through The chute of lower section flows to holding furnace insulation, and holding temperature is 1150-1200 DEG C, and the copper liquid surface in holding furnace uses graphite squama Piece is as coating;
B, continuous up-casting oxygen-free copper pipe:Copper liquid in holding furnace is constantly entered into graphite crystallizer, and in the presence of cooling water Gradually solidification, the inflow temperature for controlling graphite crystallizer are 20-25 DEG C, and leaving water temperature is 25-35 DEG C, hydraulic pressure 1.0- 1.2MPa, the copper pipe after solidification is constantly pulled out by hauling machine forms continuous copper pipe, and the lead speed for controlling hauling machine is 30- 40mm/min;
C, tube rolling:Rolling device is sent into after the copper pipe for drawing to obtain in step b is perforated by feeder back and forth to be rolled 42 × 2.1mm semi-finished product copper pipe is formed, coiling winding is then carried out to semi-finished product copper pipe, the feed of wherein feeder is 5mm/ times, copper pipe thickness deviation is ± 0.05m;
D, disk is drawn:Semi-finished product copper pipe after step c is rolled is sent into plate drawing machine, by the rolling of 4-6 passage, obtains it is expected rule The copper pipe of lattice;
E, after-combustion is cleaned:Cleaning agent and sponge ball are added in copper pipe after being drawn to step d disks, connection high pressure nitrogen carries out internal blow Clear away and wash, by cleaning agent to being cleaned outside copper pipe, then to carrying out winding packing after copper pipe aligning and metering, wherein high The pressure value for pressing nitrogen purging is 6-8MPa, rolling speed 20-30m/min;
F, anneal:Copper pipe after step e is packed rolls into well annealing furnace, at purity is annealing in 99.95% nitrogen atmosphere Reason obtains soft state copper pipe volume, controls heating-up time 5h, and holding temperature is 400-450 DEG C, soaking time 2h, and temperature fall time is 5h, and tapping temperature is not higher than 40 DEG C;
G, drawing:Copper pipe volume after step f annealing enters automatic hydraulic drawbench by aligning, is selected according to customer requirement corresponding The mould of specification, drawing copper tubes are carried out by corresponding mould and obtain half-hard state copper pipe bus, then carry out cutting packaging, wherein The drawing speed of drawbench is 15-25m/min, working modulus≤15%, needs to use drawing oil to be lubricated cooling at mould.
In the step a, cathode copper is previously placed in smelting furnace fire door baking 30min, and holding surface is clear in baking process Clean no-sundries.
The granularity of charcoal is 30-50mm in the step a, and calcines 4h at a temperature of 600 DEG C.
In the step g, its copper content >=99.99% of the copper pipe of preparation, oxygen content≤10PPM, scale error≤± 0.05m, conductance >=99%IACS, Vickers hardness is within the scope of 80-100HV.
The present invention utilizes existing equipment, copper pipe is reached complete soft state by improving annealing temperature, and extend soaking time The copper pipe state in stove at diverse location is reached stable and uniform, then by controlling drawing working modulus, reach the copper pipe of soft state To half-hard state.
The beneficial effects of the invention are as follows:
1. compared with traditional production technology, this technological process of production is shorter, energy consumption is low;
2. compared with traditional production technology, the half-hard state copper pipe bus stable performance of this production technology production is uniform;
3. compared with traditional production technology, this production technology controls annealing temperature in soft state temperature range, the temperature range It is wide in range to be easily controlled, suitable working modulus is then obtained by the control to drawing mould specification, and coordinate drawing speed to make Copper pipe reaches half-hard state, and used mould is easily worked during this and precision is high.
Brief description of the drawings
Fig. 1 is the annealing schedule of production half-hard state copper pipe bus.
Embodiment
Below in conjunction with specific embodiment, clear, complete description is carried out to technical scheme.
A kind of disclosed random length half-hard state copper pipe bus production technology, specifically comprises the following steps:
A, it is electrolysed copper weld pool:Cathode copper is toasted into 30min in melting fire door in advance, and holding surface is cleaned without miscellaneous in baking process Thing, then add and melting is carried out in smelting furnace, and the charcoal for being 100-150mm to smelting furnace copper liquid surface addition thickness covers Layer, wherein the granularity of charcoal is 30-50mm, and 4h is calcined at a temperature of 600 DEG C, and melting in-furnace temperature is controlled in fusion process For 1140-1170 DEG C, the copper liquid after melting flows to holding furnace by the chute of lower section and is incubated, and holding temperature is 1150-1200 DEG C, And the copper liquid surface in holding furnace uses graphite flakes as coating;
B, continuous up-casting oxygen-free copper pipe:Copper liquid in holding furnace is sent constantly into graphite crystallizer, and in the presence of cooling water Gradually solidification, the inflow temperature for controlling graphite crystallizer are 20-25 DEG C, and leaving water temperature is 25-35 DEG C, hydraulic pressure 1.0- 1.2MPa, the copper pipe after solidification is constantly pulled out by hauling machine forms continuous copper pipe, and the lead speed for controlling hauling machine is 30- 40mm/min;
C, tube rolling:Rolling device is sent into after the copper pipe for drawing to obtain in step b is perforated by feeder back and forth to be rolled 42 × 2.1mm of Φ semi-finished product copper pipe is formed, the feed of coiling winding, wherein feeder is then carried out to semi-finished product copper pipe For 5mm/ times, copper pipe thickness deviation is ± 0.05m;
D, disk is drawn:Semi-finished product copper pipe after step c is rolled is sent into plate drawing machine, and the rolling expectation by 4-6 passage is advised The copper pipe of lattice.Exemplified by rolling the copper pipe of Φ 18 × 1mm specifications, it needs the rolling by 5 passages, every time rolling parameter It is as follows:
First passage:Size is 42 × 2.1mm of Φ before rolling, and size is 36 × 1.75mm of Φ, speed 175m/min after rolling;
Second passage:Size is 36 × 1.75mm of Φ before rolling, and size is 31.05 × 1.45mm of Φ, speed 200m/ after rolling min;
3rd passage:Size is 31.05 × 1.45mm of Φ before rolling, and size is 27 × 1.15mm of Φ, speed 300m/ after rolling min;
Four-pass:Size is 27 × 1.15mm of Φ before rolling, and size is 22.6 × 1mm of Φ, speed 250m/min after rolling;
5th passage:Size is 22.6 × 1mm of Φ before rolling, and size is 18 × 1mm of Φ, speed 250m/min after rolling;
E, after-combustion is cleaned:Cleaning agent and sponge ball are added in copper pipe after being drawn to step d disks, connection high pressure nitrogen carries out internal blow Clear away and wash, by cleaning agent to being cleaned outside copper pipe, then to carrying out winding packing after copper pipe aligning and metering, wherein high The pressure value for pressing nitrogen purging is 6-8MPa, rolling speed 20-30m/min;
F, anneal:Copper pipe after step e is packed rolls into well annealing furnace, at purity is annealing in 99.95% nitrogen atmosphere Reason, heating-up time 5h is controlled, holding temperature is 400-450 DEG C, soaking time 2h, temperature fall time 5h, and tapping temperature is not Higher than 40 DEG C, specific annealing process is as shown in Figure 1;
G, drawing:Copper pipe volume after step f annealing enters automatic hydraulic drawbench by aligning, is selected according to customer requirement different The mould of specification, by reaching the control to working modulus to the selection of mould, so as to obtain half-hard state copper pipe bus, with laggard Row cutting packaging.Wherein drawing speed is 15-25m/min, working modulus≤15%, needs to use drawing oil to be lubricated at mould Cooling.
Copper content >=99.99% of the copper pipe bus, oxygen content≤10PPM, scale error≤± 0.05m, conductance >= 99%IACS, Vickers hardness is within the scope of 80-100HV.
The change in size of copper pipe bus, working modulus and Vickers hardness relation are as shown in the table:
One embodiment of the invention is described in detail above, but the content is only the preferable of the invention Embodiment, it is impossible to be considered as the practical range for limiting the invention.It is all made according to the invention application range it is equal Deng change and improvement etc., belong within the patent covering scope of the invention.

Claims (4)

1. a kind of random length half-hard state copper pipe bus production technology, it is characterised in that comprise the following steps:
A, it is electrolysed copper weld pool:Cathode copper is added in smelting furnace and carries out melting, and is to smelting furnace copper liquid surface addition thickness 100-150mm charcoal coating, it is 1140-1170 DEG C to control smelting temperature in smelting furnace, and the copper liquid in smelting furnace passes through The chute of lower section flows to holding furnace insulation, and holding temperature is 1150-1200 DEG C, and the copper liquid surface in holding furnace uses graphite squama Piece is as coating;
B, continuous up-casting oxygen-free copper pipe:Copper liquid in holding furnace is constantly entered into graphite crystallizer, and in the presence of cooling water Gradually solidification, the inflow temperature for controlling graphite crystallizer are 20-25 DEG C, and leaving water temperature is 25-35 DEG C, hydraulic pressure 1.0- 1.2MPa, the copper pipe after solidification is constantly pulled out by hauling machine forms continuous copper pipe, and the lead speed for controlling hauling machine is 30- 40mm/min;
C, tube rolling:Rolling device is sent into after the copper pipe for drawing to obtain in step b is perforated by feeder back and forth to be rolled 42 × 2.1mm semi-finished product copper pipe is formed, coiling winding is then carried out to semi-finished product copper pipe, the feed of wherein feeder is 5mm/ times, copper pipe thickness deviation is ± 0.05m;
D, disk is drawn:Semi-finished product copper pipe after step c is rolled is sent into plate drawing machine, by the rolling of 4-6 passage, obtains it is expected rule The copper pipe of lattice;
E, after-combustion is cleaned:Cleaning agent and sponge ball are added in copper pipe after being drawn to step d disks, connection high pressure nitrogen carries out internal blow Clear away and wash, by cleaning agent to being cleaned outside copper pipe, then to carrying out winding packing after copper pipe aligning and metering, wherein high The pressure value for pressing nitrogen purging is 6-8MPa, rolling speed 20-30m/min;
F, anneal:Copper pipe after step e is packed rolls into well annealing furnace, at purity is annealing in 99.95% nitrogen atmosphere Reason obtains soft state copper pipe volume, controls heating-up time 5h, and holding temperature is 400-450 DEG C, soaking time 2h, and temperature fall time is 5h, and tapping temperature is not higher than 40 DEG C;
G, drawing:Copper pipe volume after step f annealing enters automatic hydraulic drawbench by aligning, is selected according to customer requirement corresponding The mould of specification, drawing copper tubes are carried out by corresponding mould and obtain half-hard state copper pipe bus, then carry out cutting packaging, wherein The drawing speed of drawbench is 15-25m/min, working modulus≤15%, needs to use drawing oil to be lubricated cooling at mould.
2. random length half-hard state copper pipe bus production technology according to claim 1, it is characterised in that:In the step a, Cathode copper is previously placed in smelting furnace fire door baking 30min, and holding surface cleans no-sundries in baking process.
3. random length half-hard state copper pipe bus production technology according to claim 1, it is characterised in that:In the step a The granularity of charcoal is 30-50mm, and calcines 4h at a temperature of 600 DEG C.
4. random length half-hard state copper pipe bus production technology according to claim 1, it is characterised in that:The step g systems Standby copper pipe bus, its copper content >=99.99%, oxygen content≤10PPM, scale error≤± 0.05m, conductance >=99% IACS, Vickers hardness is within the scope of 80-100HV.
CN201710820736.7A 2017-09-13 2017-09-13 A kind of random length half-hard state copper pipe bus production technology Pending CN107738067A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109433850A (en) * 2018-10-30 2019-03-08 江苏亚太航空科技有限公司 The technique of aluminum alloy round pipe drawing manufacture
CN110814069A (en) * 2019-11-18 2020-02-21 龙口市龙蓬精密铜管有限公司 Production method of semi-hard copper straight pipe and drawing die thereof
CN113290074A (en) * 2021-05-22 2021-08-24 江阴和宏特种材料有限公司 Preparation method of oxygen-free copper pipe for low-cost magnetron

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CN106694605A (en) * 2016-12-20 2017-05-24 中天合金技术有限公司 Internal thread copper pipe for radio frequency cable and preparation process of internal thread copper pipe
CN106903183A (en) * 2017-03-08 2017-06-30 常熟中佳新材料有限公司 The manufacture system and method for radio-frequency cable oxygen-free copper pipe

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CN101195199A (en) * 2007-12-13 2008-06-11 北京金鹰恒泰铜业有限公司 Special-shaped cross section copper strip process technique and special-shaped cross section copper strip produced by using the technique
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CN109433850A (en) * 2018-10-30 2019-03-08 江苏亚太航空科技有限公司 The technique of aluminum alloy round pipe drawing manufacture
CN110814069A (en) * 2019-11-18 2020-02-21 龙口市龙蓬精密铜管有限公司 Production method of semi-hard copper straight pipe and drawing die thereof
CN113290074A (en) * 2021-05-22 2021-08-24 江阴和宏特种材料有限公司 Preparation method of oxygen-free copper pipe for low-cost magnetron

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Application publication date: 20180227