CN107728239A - A kind of anti-blue light anti-dazzle plated film resin lens and preparation method thereof - Google Patents

A kind of anti-blue light anti-dazzle plated film resin lens and preparation method thereof Download PDF

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CN107728239A
CN107728239A CN201711193340.0A CN201711193340A CN107728239A CN 107728239 A CN107728239 A CN 107728239A CN 201711193340 A CN201711193340 A CN 201711193340A CN 107728239 A CN107728239 A CN 107728239A
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layer
thickness
silicon dioxide
titanium dioxide
blue light
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CN107728239B (en
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储林兴
黄健
苏凡神
金松日
王传宝
严清波
黄景润
黄添鸟
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SHANGHAI KANGNAITE OPTICS CO Ltd
Jiangsu Kang Naite Optical Co Ltd
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SHANGHAI KANGNAITE OPTICS CO Ltd
Jiangsu Kang Naite Optical Co Ltd
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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14—Protective coatings, e.g. hard coatings
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11—Anti-reflection coatings
    • G02B1/113—Anti-reflection coatings using inorganic layer materials only
    • G02B1/115—Multilayers
    • G—PHYSICS
    • G02—OPTICS
    • G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00—Optical parts
    • G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses

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  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
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  • Ophthalmology & Optometry (AREA)
  • General Health & Medical Sciences (AREA)
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  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Eyeglasses (AREA)

Abstract

The invention discloses a kind of anti-blue light anti-dazzle plated film resin lens and preparation method thereof, the eyeglass includes eyeglass matrix, the two sides of eyeglass matrix is equipped with stiffening layer, and the surface of stiffening layer is provided with anti-blue light anti-dazzle film layer, and anti-blue light anti-dazzle film layer is followed successively by silicon dioxide layer from inside to outside, titanium dioxide layer, silicon dioxide layer, titanium dioxide zirconium layer, silicon dioxide layer, titanium dioxide layer, silicon dioxide layer, titanium dioxide layer, silicon dioxide layer, titanium dioxide layer, silicon dioxide layer, titanium dioxide zirconium layer, indium tin oxide layer, silicon dioxide layer, waterproof layer.Its preparation method includes the dip-coating and vacuum coating of stiffening layer.The present invention is by way of dip-coating and the mode of vacuum coating forms stiffening layer and anti-blue light anti-dazzle film layer, makes film layer difficult for drop-off, sustainability is strong, and simplifies the working process of eyeglass, improves production efficiency and product quality, reduces production and operation cost.

Description

A kind of anti-blue light anti-dazzle plated film resin lens and preparation method thereof
Technical field
The present invention relates to resin lens field, more particularly, to a kind of anti-blue light anti-dazzle plated film resin lens and its Preparation method.
Background technology
In visible ray, blue light is a kind of short wavelength light of the high energy of great energy, and blue light can easily penetrate glasses Crystalline lens and reach at retina, eyes are caused with a kind of infringement of spectrochemical property, rapidly accelerate eyes macular region Oxidizing process and eyes are produced with greatly injury, cause that eye is dry, eye is puckery and the symptoms such as eyes are ached, can also result in cataract Postoperative damage of fundus.Blue light can suppress the secretion of epiphysin, bother sleep, improve the incidence of itself major disease.
In addition, dazzle is a kind of serious light pollution, sudden Whiteout, eyesight illusion, the dizzy mesh of people can be caused Dizzy, some occasions can trigger accident, and when brightness is excessive, cornea and crystalline lens can produce light diffusion, damage eyes, eyesight, knowledge Not, speed etc. declines regarding function.
With the development of the society, the development of science and technology, the living standard more and more higher of people is above-mentioned in order to solve simultaneously Two kinds of phenomenons, many people all select wear with anti-blue light anti-dazzle ophthalmic len, and at present it is common on the market while have There is the eyeglass of the anti-dazzle light effect of anti-blue light, a kind of is by sticking the plastics with anti-blue light anti-dazzle function in lens surface Film, the eyeglass light transmittance of this legal system is low, and processing is unstable, and sustainability is not strong, and plastic foil easily comes off；Also one kind is By contaminating eyeglass, after eyeglass has anti-blue light anti-dazzle function, by carrying out stiffened plated film to it to improve Light transmittance, and program is complicated in process for this method, low production efficiency, product light transmittance is low, high processing costs.Therefore, it is Solve the above problems, spy provides a kind of new technical scheme to meet to require.
The content of the invention
The purpose of the present invention is to be directed to problem above, and design one kind anti-blue light while visible light transmissivity is ensured is anti-dazzle Light, and the anti-blue light anti-dazzle plated film resin lens that film layer is difficult for drop-off, and disclose its preparation method.
To achieve these goals, the present invention provides a kind of anti-blue light anti-dazzle plated film resin lens, including eyeglass matrix, The two sides of eyeglass matrix is equipped with stiffening layer, and the surface of stiffening layer is provided with anti-blue light anti-dazzle film layer.
Eyeglass matrix of the present invention is polycarbonate substrate or acrylic polymer substrate.
Stiffening layer of the present invention is organosilicon stiffening layer or nano silicon oxide stiffening layer, and its thickness is 1.5-4 μm.
Anti-blue light anti-dazzle thicknesses of layers of the present invention is 430-860nm.
Above-mentioned anti-blue light anti-dazzle film layer is 15 layers, is followed successively by first layer silicon dioxide layer, the second layer two from inside to outside Titanium oxide layer, third layer silicon dioxide layer, the 4th layer of titanium dioxide zirconium layer, layer 5 silicon dioxide layer, layer 6 titanium dioxide layer, Layer 7 silicon dioxide layer, the 8th layer of titanium dioxide layer, the 9th layer of silicon dioxide layer, the tenth layer of titanium dioxide layer, eleventh floor Silicon dioxide layer, Floor 12 titanium dioxide zirconium layer, the 13rd layer of indium tin oxide layer, the 14th layer of silicon dioxide layer, the 15th layer Waterproof layer.Each thickness degree difference is as follows：
(1) first layer silicon dioxide layer thickness is 11-66nm；
(2) second layer titanium dioxide layer thickness is 10-44nm；
(3) third layer silicon dioxide layer thickness is 70-110nm；
(4) the 4th layers of zirconium dioxide thickness degree are 50-66nm；
(5) layer 5 silicon dioxide layer thickness is 55-68nm；
(6) layer 6 titanium dioxide layer thickness is 50-56nm；
(7) layer 7 silicon dioxide layer thickness is 20-40nm；
(8) the 8th layers of titanium dioxide layer thickness are 37-46nm；
(9) the 9th layers of silicon dioxide layer thickness are 1-6nm；
(10) the tenth layers of titanium dioxide layer thickness are 10-16nm；
(11) eleventh floor silicon dioxide layer thickness are 89-110nm；
(12) Floor 12 zirconium dioxide thickness degree are 12-44nm；
(13) the 13rd layers of indium tin oxide layer thickness are 4-6nm；
(14) the 14th layers of silicon dioxide layer thickness are 8-25nm；
(15) the 15th layers of waterproof layer thickness degree are 10-20nm.
The preparation method of anti-blue light anti-dazzle plated film resin lens of the present invention comprises the following steps：
(1) eyeglass matrix is cleaned and be dried for standby；
(2) the eyeglass matrix that step (1) is handled well is subjected to dip-coating in hardening liquid, then in 110-130 DEG C of condition Lower solidification 2.5-3.5h, the hardening liquid are that organosilicon or nano silicon oxide with methanol are 1 according to mass ratio:9 are mixed to prepare Solution.
(3) eyeglass with stiffening layer is put into vacuum vapor plating room, utilizes magnetic core logical circuit deflection electron beam successively evaporant Material plated film in stiffening layer；Plated film room temperature is set in 50-60 DEG C, and vacuum is evacuated to 3.5 × 10-5Pa, set each layer and burn medicine evaporation Speed, first layer silicon dioxide layer 10nm/s, second layer titanium dioxide layer 2nm/s, third layer silicon dioxide layer 10nm/s, the 4th Layer titanium dioxide zirconium layer 8nm/s, layer 5 silicon dioxide layer 10nm/s, layer 6 titanium dioxide layer 2nm/s, layer 7 silica Layer 10nm/s, the 8th layer of titanium dioxide layer 2nm/s, the 9th layer of silicon dioxide layer 2nm/s, the tenth layer of titanium dioxide layer 2nm/s, the Eleventh floor silicon dioxide layer 10nm/s, Floor 12 titanium dioxide zirconium layer 8nm/s, the 13rd layer of indium tin oxide layer 1.5nm/s, the tenth Four layers of silicon dioxide layer 10nm/s, the 15th layer of waterproof layer 2nm/s.
Compared with prior art, beneficial effects of the present invention are：
(1) present invention is by way of dip-coating and the mode of vacuum coating forms stiffening layer and anti-blue light anti-dazzle film layer, Make film layer difficult for drop-off, sustainability is strong, and simplifies the working process of eyeglass, improves production efficiency and product quality, Reduce production and operation cost.
(2) setting of stiffening layer and anti-blue light anti-dazzle film layer can improve visible light transmittance rate, while effectively prevent blue Light and can prevent strong illumination produce dizziness.
(3) anti-blue light anti-dazzle film layer sequentially sets the material of multilayer different refractivity and cohesive force and controls thickness, both Visible light transmittance rate anti-blue light anti-dazzle simultaneously can be improved, and can, which improves film layer cohesive force, prevents film layer from coming off.
Brief description of the drawings
Fig. 1 is the structural representation of anti-blue light anti-dazzle plated film resin lens of the present invention.
Fig. 2 is the structural representation of anti-blue light anti-dazzle film layer of the present invention.
In figure：1- eyeglass matrixes, 2- stiffening layer, 3- anti-blue light anti-dazzle film layers, 4- first layer silicon dioxide layers, 5- second Layer titanium dioxide layer, 6- third layer silicon dioxide layers, the 4th layer of titanium dioxide zirconium layer of 7-, 8- layer 5 silicon dioxide layers, 9- the 6th Layer titanium dioxide layer, 10- layer 7 silicon dioxide layers, the 8th layer of titanium dioxide layer of 11-, the 9th layer of silicon dioxide layer of 12-, 13- Tenth layer of titanium dioxide layer, 14- eleventh floor silicon dioxide layers, 15- Floor 12 titanium dioxide zirconium layer, the 13rd layer of oxidation of 16- Indium tin layer, the 14th layer of silicon dioxide layer of 17-, the 15th layer of waterproof layer of 18-.
Embodiment
The preferred embodiment of the present invention is more fully described below with reference to specific embodiment.
Embodiment 1
A kind of anti-blue light anti-dazzle plated film resin lens, are made by following steps：
(1) eyeglass matrix 1 is cleaned and be dried for standby, eyeglass matrix selects 1.50 (CR-39)；
(2) the eyeglass matrix 1 that step (1) is handled well is subjected to dip-coating in hardening liquid, then in 110-130 DEG C of condition Lower solidification 2.5-3.5h, obtains stiffening layer 2, thickness control is at 1.5-4 μm；Hardening liquid is nano silicon oxide and methanol according to mass ratio For 1:9 solution being mixed to prepare.
(3) eyeglass with stiffening layer 2 is put into vacuum vapor plating room, utilizes magnetic core logical circuit deflection electron beam successively evaporant Material plated film in stiffening layer 2；Plated film room temperature is set in 50-60 DEG C, and vacuum is evacuated to 3.5 × 10-5Pa, set each layer and burn medicine evaporation Speed, first layer silicon dioxide layer 10nm/s, second layer titanium dioxide layer 2nm/s, third layer silicon dioxide layer 10nm/s, the 4th Layer titanium dioxide zirconium layer 8nm/s, layer 5 silicon dioxide layer 10nm/s, layer 6 titanium dioxide layer 2nm/s, layer 7 silica Layer 10nm/s, the 8th layer of titanium dioxide layer 2nm/s, the 9th layer of silicon dioxide layer 2nm/s, the tenth layer of titanium dioxide layer 2nm/s, the Eleventh floor silicon dioxide layer 10nm/s, Floor 12 titanium dioxide zirconium layer 8nm/s, the 13rd layer of indium tin oxide layer 1.5nm/s, the tenth Four layers of silicon dioxide layer 10nm/s, the 15th layer of waterproof layer (HT-100, DON degree benefactor department) 2nm/s.
It is 11-66nm to control each thickness degree to be followed successively by the thickness of first layer silicon dioxide layer 4 from inside to outside；Second layer titanium dioxide The thickness of titanium layer 5 is 10-44nm；The thickness of third layer silicon dioxide layer 6 is 70-110nm；The 4th layer of thickness of titanium dioxide zirconium layer 7 is 50- 66nm；The thickness of layer 5 silicon dioxide layer 8 is 55-68nm；The thickness of layer 6 titanium dioxide layer 9 is 50-56nm；Layer 7 dioxy The thickness of SiClx layer 10 is 20-40nm；The 8th layer of thickness of titanium dioxide layer 11 is 37-46nm；The 9th layer of thickness of silicon dioxide layer 12 For 1-6nm；The tenth layer of thickness of titanium dioxide layer 13 is 10-16nm；The thickness of eleventh floor silicon dioxide layer 14 is 89-110nm；The The thickness of Floor 12 titanium dioxide zirconium layer 15 is 12-44nm；The 13rd layer of thickness of indium tin oxide layer 16 is 4-6nm；14th layer of dioxy The thickness of SiClx layer 17 is 8-25nm；The 15th layer of thickness of waterproof layer 18 is 10-20nm.
Comparative example 1
(1) eyeglass matrix is cleaned and be dried for standby, eyeglass matrix selects 1.50 (CR-39)；
(2) the eyeglass matrix that step (1) is handled well is subjected to dip-coating in hardening liquid, then in 110-130 DEG C of condition Lower solidification 2.5-3.5h, obtains stiffening layer, thickness control is at 1.5-4 μm；Hardening liquid is nano silicon oxide and methanol according to mass ratio For 1:9 solution being mixed to prepare.
(3) eyeglass with stiffening layer is put into vacuum vapor plating room, utilizes magnetic core logical circuit deflection electron beam successively evaporant Material plated film in stiffening layer；Plated film room temperature is set in 50-60 DEG C, and vacuum is evacuated to 3.5 × 10-5Pa, set each layer and burn medicine evaporation Speed, and each thickness degree is controlled, first layer silicon dioxide layer 10nm/s, thickness 81-176nm are followed successively by from inside to outside；Second Layer titanium dioxide layer 2nm/s, thickness 60-100nm；Third layer titanium dioxide zirconium layer 8nm/s, thickness 62-110nm；4th layer Silicon dioxide layer 10nm/s, thickness 55-68nm；Layer 5 silicon dioxide layer 10nm/s, thickness 55-68nm；Layer 6 two Titanium oxide layer 2nm/s, thickness 37-46nm；Layer 7 silicon dioxide layer 2nm/s, thickness 1-6nm；8th layer of titanium dioxide Layer 2nm/s, thickness 10-16nm；9th layer of silicon dioxide layer 10nm/s, thickness 89-110nm；Tenth layer of indium tin oxide layer 1.5nm/s, thickness 4-6nm；Eleventh floor silicon dioxide layer 10nm/s, thickness 8-25nm；Floor 12 waterproof layer (HT- 100, DON degree benefactor departments) 2nm/s, thickness 10-20nm.
Comparative example 2
(1) eyeglass matrix is cleaned and be dried for standby, eyeglass matrix selects 1.50 (CR-39)；
(2) the eyeglass matrix that step (1) is handled well is subjected to dip-coating in hardening liquid, then in 110-130 DEG C of condition Lower solidification 2.5-3.5h, obtains stiffening layer, thickness control is at 1.5-4 μm；Hardening liquid is nano silicon oxide and methanol according to mass ratio For 1:9 solution being mixed to prepare.
(3) eyeglass with stiffening layer is put into vacuum vapor plating room, utilizes magnetic core logical circuit deflection electron beam successively evaporant Material plated film in stiffening layer；Plated film room temperature is set in 50-60 DEG C, and vacuum is evacuated to 3.5 × 10-5Pa, set each layer and burn medicine evaporation Speed, and each thickness degree is controlled, first layer silicon dioxide layer 10nm/s, thickness 11-66nm are followed successively by from inside to outside；The second layer Titanium dioxide zirconium layer 8nm/s, thickness 50-66nm；Third layer silicon dioxide layer 10nm/s, thickness 70-110nm；4th layer two Titanium oxide layer 2nm/s, thickness 10-44nm；Layer 5 silicon dioxide layer 10nm/s, thickness 55-68nm；Layer 6 titanium dioxide Titanium layer 2nm/s, thickness 50-56nm；Layer 7 silicon dioxide layer 10nm/s, thickness 20-40nm；8th layer of titanium dioxide layer 2nm/s, thickness 37-46nm；9th layer of silicon dioxide layer 2nm/s, thickness 1-6nm；Tenth layer of titanium dioxide layer 2nm/s, Thickness is 10-16nm；Eleventh floor silicon dioxide layer 10nm/s, thickness 89-110nm；Floor 12 titanium dioxide zirconium layer 8nm/ S, thickness 12-44nm；13rd layer of indium tin oxide layer 1.5nm/s, thickness 4-6nm；14th layer of silicon dioxide layer 10nm/ S, thickness 8-25nm；15th layer of waterproof layer (HT-100, DON degree benefactor department) 2nm/s, thickness 10-20nm.
Comparative example 3
(1) eyeglass matrix is cleaned and be dried for standby, eyeglass matrix selects 1.50 (CR-39)；
(2) the eyeglass matrix that step (1) is handled well is subjected to dip-coating in hardening liquid, then in 110-130 DEG C of condition Lower solidification 2.5-3.5h, obtains stiffening layer, thickness control is at 1.5-4 μm；Hardening liquid is nano silicon oxide and methanol according to mass ratio For 1:9 solution being mixed to prepare.
(3) eyeglass with stiffening layer is put into vacuum vapor plating room, utilizes magnetic core logical circuit deflection electron beam successively evaporant Material plated film in stiffening layer；Plated film room temperature is set in 50-60 DEG C, and vacuum is evacuated to 3.5 × 10-5Pa, set each layer and burn medicine evaporation Speed, and each thickness degree is controlled, first layer titanium dioxide layer 2nm/s, thickness 10-44nm are followed successively by from inside to outside；The second layer Silicon dioxide layer 10nm/s, thickness 11-66nm；Third layer titanium dioxide zirconium layer 8nm/s, thickness 50-66nm；4th layer of dioxy SiClx layer 10nm/s, thickness 70-110nm；Layer 5 titanium dioxide layer 2nm/s, thickness 50-56nm；Layer 6 titanium dioxide Silicon layer 10nm/s, thickness 55-68nm；Layer 7 titanium dioxide layer 2nm/s, thickness 37-46nm；8th layer of silicon dioxide layer 10nm/s, thickness 20-40nm；9th layer of titanium dioxide layer 2nm/s, thickness 10-16nm；Tenth layer of silicon dioxide layer 2nm/ S, thickness 1-6nm；Eleventh floor titanium dioxide zirconium layer 8nm/s, thickness 12-44nm；Floor 12 silicon dioxide layer 10nm/s, Thickness is 89-110nm；13rd layer of indium tin oxide layer 1.5nm/s, thickness 4-6nm；14th layer of silicon dioxide layer 10nm/ S, thickness 8-25nm；15th layer of waterproof layer (HT-100, DON degree benefactor department) 2nm/s, thickness 10-20nm.
Comparative example 4
(1) eyeglass matrix is cleaned and be dried for standby, eyeglass matrix selects 1.50 (CR-39)；
(2) the eyeglass matrix that step (1) is handled well is subjected to dip-coating in hardening liquid, then in 110-130 DEG C of condition Lower solidification 2.5-3.5h, obtains stiffening layer, thickness control is at 1.5-4 μm；Hardening liquid is nano silicon oxide and methanol according to mass ratio For 1:9 solution being mixed to prepare.
(3) eyeglass with stiffening layer is put into vacuum vapor plating room, utilizes magnetic core logical circuit deflection electron beam successively evaporant Material plated film in stiffening layer；Plated film room temperature is set in 50-60 DEG C, and vacuum is evacuated to 3.5 × 10-5Pa, set each layer and burn medicine evaporation Speed, and control each thickness degree to be followed successively by first layer silicon dioxide layer 10nm/s, thickness 11-66nm from inside to outside；The second layer Titanium dioxide layer 2nm/s, thickness 10-44nm；Third layer silicon dioxide layer 10nm/s, thickness 70-110nm；4th layer two Zirconia layer 8nm/s, thickness 50-66nm；Layer 5 silicon dioxide layer 10nm/s, thickness 55-68nm；Layer 6 titanium dioxide Titanium layer 2nm/s, thickness 50-56nm；Layer 7 silicon dioxide layer 10nm/s, thickness 20-40nm；8th layer of titanium dioxide layer 2nm/s, thickness 37-46nm；9th layer of silicon dioxide layer 2nm/s, thickness 1-6nm；Tenth layer of titanium dioxide layer 2nm/s, Thickness is 10-16nm；Eleventh floor silicon dioxide layer 10nm/s, thickness 89-110nm；Floor 12 indium tin oxide layer 1.5nm/s, thickness 4-6nm；13rd layer of titanium dioxide zirconium layer 8nm/s, thickness 12-44nm；14th layer of silicon dioxide layer 10nm/s, thickness 8-25nm；15th layer of waterproof layer (HT-100, DON degree benefactor department) 2nm/s, thickness 10-20nm.
Comparative example 5
(1) eyeglass matrix is cleaned and be dried for standby, eyeglass matrix selects 1.50 (CR-39)；
(2) the eyeglass matrix that step (1) is handled well is subjected to dip-coating in hardening liquid, then in 110-130 DEG C of condition Lower solidification 2.5-3.5h, obtains stiffening layer, thickness control is at 1.5-4 μm；Hardening liquid is nano silicon oxide and methanol according to mass ratio For 1:9 solution being mixed to prepare.
(3) eyeglass with stiffening layer is put into vacuum vapor plating room, utilizes magnetic core logical circuit deflection electron beam successively evaporant Material plated film in stiffening layer；Plated film room temperature is set in 50-60 DEG C, and vacuum is evacuated to 3.5 × 10-5Pa, set each layer and burn medicine evaporation Speed, and each thickness degree is controlled, first layer silicon dioxide layer 10nm/s, thickness 11-66nm are followed successively by from inside to outside；The second layer Titanium dioxide layer 2nm/s, thickness 10-44nm；Third layer silicon dioxide layer 2nm/s, thickness 1-6nm；4th layer of titanium dioxide Zirconium layer 8nm/s, thickness 50-66nm；Layer 5 silicon dioxide layer 10nm/s, thickness 55-68nm；Layer 6 titanium dioxide layer 2nm/s, thickness 50-56nm；Layer 7 silicon dioxide layer 10nm/s, thickness 20-40nm；8th layer of titanium dioxide layer 2nm/ S, thickness 37-46nm；9th layer of silicon dioxide layer 10nm/s, thickness 70-110nm；Tenth layer of titanium dioxide layer 2nm/s, Thickness is 10-16nm；Eleventh floor silicon dioxide layer 10nm/s, thickness 89-110nm；Floor 12 titanium dioxide zirconium layer 8nm/ S, thickness 12-44nm；13rd layer of indium tin oxide layer 1.5nm/s, thickness 4-6nm；14th layer of silicon dioxide layer 10nm/ S, thickness 8-25nm；15th layer of waterproof layer waterproof layer (HT-100, DON degree benefactor department) 2nm/s, thickness 10-20nm.
By experimental verification embodiment and the anti-dazzle light effect of comparative example anti-blue light and whether fall film contrast such as following table：
Note：Tester HunterLab UltraScan PRO, film layer testing standard QB/T2506-2017.
As can be seen from the above table, by adjusting the order or thickness of different layers, comparative example 1,3,4 and 5 has film layer Come off, comparative example 2 does not fall film, but visible light transmissivity only has 73%, does not reach professional standard, and embodiment 1 both can guarantee that film Layer is not fallen off and visible light transmissivity is more than 80%, and and can effectively reduces the transmitance of blue light and dazzle, reach anti-blue light and The effect of anti-dazzle.

Claims (9)

  1. A kind of 1. anti-blue light anti-dazzle plated film resin lens, it is characterised in that including eyeglass matrix (1), the two of eyeglass matrix (1) Face is equipped with stiffening layer (2), and the surface of stiffening layer (2) is provided with anti-blue light anti-dazzle film layer (3).
  2. 2. anti-blue light anti-dazzle plated film resin lens according to claim 1, it is characterised in that the eyeglass matrix (1) is Polycarbonate substrate or acrylic polymer substrate.
  3. 3. anti-blue light anti-dazzle plated film resin lens according to claim 1, it is characterised in that the stiffening layer (2) is to have Machine silicon stiffening layer or nano silicon oxide stiffening layer, its thickness are 1.5-4 μm.
  4. 4. anti-blue light anti-dazzle plated film resin lens according to claim 1, it is characterised in that the anti-blue light anti-dazzle Film layer (3) thickness is 430-860nm.
  5. 5. the anti-blue light anti-dazzle plated film resin lens according to claim 1 or 4, it is characterised in that the anti-blue light is anti-dazzle Light film layer (3) is 15 layers, is followed successively by first layer silicon dioxide layer (4) from inside to outside, second layer titanium dioxide layer (5), the 3rd Layer silicon dioxide layer (6), the 4th layer of titanium dioxide zirconium layer (7), layer 5 silicon dioxide layer (8), layer 6 titanium dioxide layer (9), Layer 7 silicon dioxide layer (10), the 8th layer of titanium dioxide layer (11), the 9th layer of silicon dioxide layer (12), the tenth layer of titanium dioxide Layer (13), eleventh floor silicon dioxide layer (14), Floor 12 titanium dioxide zirconium layer (15), the 13rd layer of indium tin oxide layer (16), 14th layer of silicon dioxide layer (17), the 15th layer of waterproof layer (18).
  6. 6. anti-blue light anti-dazzle plated film resin lens according to claim 5, it is characterised in that the anti-blue light anti-dazzle Each thickness degree difference of film layer (3) is as follows：
    (1) first layer silicon dioxide layer (4) thickness is 11-66nm；
    (2) second layer titanium dioxide layer (5) thickness is 10-44nm；
    (3) third layer silicon dioxide layer (6) thickness is 70-110nm；
    (4) the 4th layers of titanium dioxide zirconium layer (7) thickness are 50-66nm；
    (5) layer 5 silicon dioxide layer (8) thickness is 55-68nm；
    (6) layer 6 titanium dioxide layer (9) thickness is 50-56nm；
    (7) layer 7 silicon dioxide layer (10) thickness is 20-40nm；
    (8) the 8th layers of titanium dioxide layer (11) thickness are 37-46nm；
    (9) the 9th layers of silicon dioxide layer (12) thickness are 1-6nm；
    (10) the tenth layers of titanium dioxide layer (13) thickness are 10-16nm；
    (11) eleventh floor silicon dioxide layer (14) thickness are 89-110nm；
    (12) Floor 12 titanium dioxide zirconium layer (15) thickness are 12-44nm；
    (13) the 13rd layers of indium tin oxide layer (16) thickness are 4-6nm；
    (14) the 14th layers of silicon dioxide layer (17) thickness are 8-25nm；
    (15) the 15th layers of waterproof layer (18) thickness are 10-20nm.
  7. 7. the preparation method of the anti-blue light anti-dazzle plated film resin lens described in a kind of claim 1, it is characterised in that be included in After the two sides dip-coating stiffening layer (2) of eyeglass matrix (1), then the surface vacuum plating anti-blue light anti-dazzle film layer in stiffening layer (2) (3)。
  8. 8. the preparation method of anti-blue light anti-dazzle plated film resin lens according to claim 8, it is characterised in that the leaching Apply stiffening layer (2) and specifically include following steps：Eyeglass matrix (1) is subjected to dip-coating processing in hardening liquid, then 110~ 2.5~3.5h of curing process under conditions of 130 DEG C, the hardening liquid are organosilicon or nano silicon oxide and methanol according to mass ratio For 1:9 solution being mixed to prepare.
  9. 9. the preparation method of anti-blue light anti-dazzle plated film resin lens according to claim 8, it is characterised in that described true Sky plating anti-blue light anti-dazzle film layer (3) specifically includes following steps：
    Eyeglass with stiffening layer (2) is put into vacuum vapor plating room, evaporating material successively using magnetic core logical circuit deflection electron beam exists Plated film in stiffening layer (2)；Plated film room temperature is set in 50-60 DEG C, and vacuum is evacuated to 3.5 × 10-5Pa, set each layer and burn medicine evaporation speed Rate, first layer silicon dioxide layer (4) 10nm/s, second layer titanium dioxide layer (5) 2nm/s, third layer silicon dioxide layer (6) 10nm/s, the 4th layer of titanium dioxide zirconium layer (7) 8nm/s, layer 5 silicon dioxide layer (8) 10nm/s, layer 6 titanium dioxide layer (9) 2nm/s, layer 7 silicon dioxide layer (10) 10nm/s, the 8th layer of titanium dioxide layer (11) 2nm/s, the 9th layer of silicon dioxide layer (12) 2nm/s, the tenth layer of titanium dioxide layer (13) 2nm/s, eleventh floor silicon dioxide layer (14) 10nm/s, Floor 12 dioxy Change zirconium layer (15) 8nm/s, the 13rd layer of indium tin oxide layer (16) 1.5nm/s, the 14th layer of silicon dioxide layer (17) 10nm/s, the 15 layers of waterproof layer (18) 2nm/s.
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CN108549162A (en) * 2018-06-28 2018-09-18 江苏万新光学有限公司 A kind of resin lens and its production technology being suitable for driving
CN108761615A (en) * 2018-08-28 2018-11-06 中国南玻集团股份有限公司 Film for eye, display screen and display
CN109324425A (en) * 2018-09-27 2019-02-12 镇江奥视达光学有限公司 A kind of anti-blue light screening glass and preparation method thereof
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CN111175858A (en) * 2020-01-16 2020-05-19 上海万明眼镜有限公司 Anti-dazzle lens capable of improving night vision and preparation method thereof
CN114879380A (en) * 2022-04-02 2022-08-09 江苏万新光学有限公司 Light orange super-clear background-color blue-light-proof resin lens and preparation method thereof
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CN108549162A (en) * 2018-06-28 2018-09-18 江苏万新光学有限公司 A kind of resin lens and its production technology being suitable for driving
CN108761615A (en) * 2018-08-28 2018-11-06 中国南玻集团股份有限公司 Film for eye, display screen and display
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CN109324425A (en) * 2018-09-27 2019-02-12 镇江奥视达光学有限公司 A kind of anti-blue light screening glass and preparation method thereof
CN110780463A (en) * 2019-11-13 2020-02-11 江苏汇鼎光学眼镜有限公司 Anti-dazzle blue-light-proof lens and preparation method thereof
CN111175858A (en) * 2020-01-16 2020-05-19 上海万明眼镜有限公司 Anti-dazzle lens capable of improving night vision and preparation method thereof
WO2022213763A1 (en) * 2021-04-07 2022-10-13 江苏万新光学有限公司 Anti-blue-light resin lens having ultra-low reflection and clear base color, and preparation method therefor
CN114879380A (en) * 2022-04-02 2022-08-09 江苏万新光学有限公司 Light orange super-clear background-color blue-light-proof resin lens and preparation method thereof

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