CN105572770B - Antireflection film used in blue-light-proof spectacle lens - Google Patents

Antireflection film used in blue-light-proof spectacle lens Download PDF

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Publication number
CN105572770B
CN105572770B CN201610105323.6A CN201610105323A CN105572770B CN 105572770 B CN105572770 B CN 105572770B CN 201610105323 A CN201610105323 A CN 201610105323A CN 105572770 B CN105572770 B CN 105572770B
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layer
silicon
light
blue light
silicon dioxide
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CN105572770A (en
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蒲长江
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Jiangxi Lanjing Photoelectric Technology Co ltd
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Zhongshan Lanjing Optical Co ltd
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/113Anti-reflection coatings using inorganic layer materials only
    • G02B1/115Multilayers
    • G02B1/116Multilayers including electrically conducting layers
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/113Anti-reflection coatings using inorganic layer materials only
    • G02B1/115Multilayers

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Eyeglasses (AREA)

Abstract

The antireflection film used in the blue-light-proof spectacle lens has natural appearance, simple manufacturing process and low production cost, sequentially comprises a first silicon dioxide layer, a first zirconium oxide layer, a second silicon dioxide layer, a first titanium oxide layer, a first aluminum oxide layer, a second zirconium dioxide layer, a first silicon carbonate layer, a second titanium dioxide layer, a second silicon carbonate layer, a second aluminum oxide layer and a third silicon dioxide layer according to the sequence of being far away from the lens substrate, and further comprises a conducting layer formed by indium tin oxide.

Description

A kind of antireflective coating used in anti-blue light lenses
Technical field
The present invention relates to the antireflective coating used in a kind of antireflective coating, more particularly to a kind of anti-blue light lenses.
Background technology
In prior art, the research of anti-blue light lenses is like a raging fire, especially as the development of Internet technology, including anti- The anti-radiation glasses of blue light ultraviolet radiation preventing are used widely.Generally, it is seen that optical band is approximately from 380 nanometers (nm) spectral region of the wavelength of wavelength to 780nm.About 380nm corresponds essentially to high energy blue light to the part of about 500nm.It is blue Infringement of the light to human eye especially retina be it is very big, if human eye long-time exposure may result under blue light it is serious Ophthalmic diseasess, such as age-related maculopathy, seriously even result in human eye blind.But, in above-mentioned blue wave band 465nm to 495nm part be but advantageous for health because related to human biological's cycle, being capable of blood circulation promoting.It is existing Have safety goggles against radiation filtration generally includes ultraviolet light and most of short-wave band visible ray.And in prior art, rarely have the reservation to be higher than The anti-blue light glasses of 465nm, its reason are narrower in the wave band, when 450nm and shorter wavelength is filtered, can't help just filter The blue light of more than 465nm is fallen.High-reflecting film or optical filter used in existing anti-blue light glasses is generally all wide area type diaphragm, because For Narrowband Spectral High-Reflectivity Filter Multilayers or optical filter, the process when vacuum evaporation is deposited is overflow long and complex, and manufacturing cost is high.On the other hand, even if Using narrow band pass filter, the harmful blue light come from lenses front surface reflection is filtered, but is derived between wearer rear Connect in the eye that light then can reflex to eyeglass wearer in an identical manner, these harmful blue light light for reaching wearer's retina lead to Amount can be suitable with front incidence, causes blue light to injure wearer's eyes.
It is well known that in anti-harmful blue light eyeglass, front and rear surfaces can apply UV coatings, to absorb UV light, also The coating of some other functions, such as impact-resistant coating, wear-resistant coating, anti-reflection coating, antistatic coating, polarizing coating and Anti-pollution layer and/or antifogging coating etc., and eyeglass sheet is as a transparent substrate by made by organic resin or glass, such as The materials such as thermoplastic polymer are made.
The thermoplastic for using in the substrate, such as (methyl) acrylate copolymer, polyethylene (methyl-prop E pioic acid methyl ester) (PMMA), thio (methyl) acrylic acid, polyvinyl butyral resin (PVB), Merlon (PC), polyurethane (PU), Polyethylene (thioxanthamide), polyhydric alcohol allyl carbonate, Ethylene/vinyl acetate, also such as poly- terephthaldehyde Sour second diester (PET) or polybutylene terephthalate (PBT), many episulfide compounds, polyepoxide, Merlon and polyester Copolymer, the copolymer of the copolymer of cyclenes copolymer such as ethylene and norborene or ethylene and cyclopentadiene and Combinations thereof etc..
In prior art, in order to strengthen the transmittance of anti-blue light lenses, generally in the surface coated with antireflection of eyeglass Film layer.Also known as anti-reflection film, its major function is the reflected light for reducing or eliminating lens surface to antireflective coating, so as to increase printing opacity Amount, reduces or eliminates the veiling glare of system.The requirement for reducing blue light injury and increasing light transmittance can not often get both, and turn round and look at this mistake That, it is shifting, want to reduce blue light injury, it is necessary to sacrifice light transmittance as cost.Existing motion is proposed such as third Olefin(e) acid system substrate front and rear surfaces plated film, including antireflective coating or anti-reflection film etc., it is anti-reflection to reach while anti-blue light is injured Effect.I.e. using the structure that this front and rear surfaces membrane system is different, front surface film layer efficiently prevents injury of the blue light to human eye, after Superficial film increases the transmitance of eyeglass, reaches anti-reflection effect.
For anti-reflection film, prior art commonly uses green antireflective coating, and this is more prone to due to green anti-reflection film layer Control, even if antireflection film layer layer thickness error is larger, but for Film color affects little, this is also current band on the market Have the eyeglass of antireflection film layer under daylight light irradiation, it appears that mostly in green or it is blue the reason for, if in anti-blue light eye Antireflective coating is added in eyeglass, this is impacted to outward appearance.Not yet occur with antireflective coating and outward appearance nature on the market at present Anti-blue light lenses.
The problem studied by the present invention is just to provide the antireflective coating used in a kind of natural anti-blue light lenses of outward appearance.
The content of the invention
In view of above-mentioned technical problem, it is an object of the invention to provide a kind of outward appearance nature, manufacturing process is simple, produces into Antireflective coating used in this low anti-blue light lens.
The present invention provide lenses antireflective coating by the order away from eyeglass substrate, successively including the first silicon dioxide layer 1st, the first zirconia layer 2, the second silicon dioxide layer 3, the first titanium oxide layer 4, the first alumina layer 5, the second zirconia layer 6, One carbonic acid silicon layer 7, the second titanium oxide layer 8, the second carbonic acid silicon layer 9, the second alumina layer 10, the 3rd silicon dioxide layer 11, in addition, Also include the conductive layer that tin indium oxide is formed.
Such as above-mentioned lenses antireflective coating, it is characterised in that the antireflective coating is used for anti-blue light glasses.
According to the present invention, the antireflective coating includes at least one high refractive index layer and at least one low-index layer.Formed For 7 layers~11 Rotating fields, high refractive index layer and low-index layer can be with alternative stackeds, it is also possible to not alternative expression lamination.The present invention In, the high index of refraction refers to refractive index higher than 1.70, and low-refraction refers to refractive index less than 1.47, and they are all referring to normal The lower refractive index for 550nm wavelength of temperature.
According to the present invention, the material such as zirconium oxide (ZrO2) of the high refractive index layer employing, titanium oxide (TiO2), oxidation Aluminum (Al2O3), tantalum pentoxide (Ta2O5) etc., material such as silicon dioxide (SiO2) that low-index layer is adopted, or titanium dioxide Silicon and alumina mixture etc..The outer layer of antireflective coating of the present invention is typically low-index layer, it is preferred to use silicon dioxide (SiO2) as outer layer.
According to the present invention, carbonic acid silicon is employed as low-refraction layer material, not yet find pertinent literature report at present.Adopt With carbonic acid silicon substrate in following consideration, first, carbonic acid silicon is a kind of preferably to diseases such as cardiovascular disease, dermatosiss, obesity Material with certain curative effect, and being present in the collagen protein of human body, if in antireflective film can effective integration carbonic acid silicon be Wholesome, secondly, carbonic acid silicon has the characteristic of class ceramics, so be widely used as in grinding-material, if the attempt to will Which is applied to the low-index layer material of antireflective film, reflectance can not only substantially reduced, also with higher comprcssive strength.But It is that carbonic acid silicon is a kind of not bery stable inorganic compound of chemical property, so should try not to destroy its change in deposition Learn form.Through the careful thinking of applicant and diligent test, find that really its antireflective effect is very outstanding, this may be netted with which Structure is relevant.Especially it is applied in combination with alumina layer, plays antireflective effect significantly, and is no longer presented under light irradiation Green and blueness, and be close to colourless.
According to the present invention, at least one of which conductive layer is had also combined in the antireflective film outer layer, for release electrostatic.The conductive layer Material is made using tin indium oxide (ITO).
According to the present invention, effective anti-harmful blue light is not only able to, wearer's eyes is protected, and visual contrast can also be improved Degree, protects the light of vision to increase transmission to green etc..
Description of the drawings
Fig. 1 is to illustrate antireflective coating structural representation of the present invention.
Specific embodiment
As shown in figure 1, the lenses antireflective coating that the present invention is provided is included successively by the order away from eyeglass substrate 100 First silicon dioxide layer 1, the first zirconia layer 2, the second silicon dioxide layer 3, the first titanium oxide layer 4, the first alumina layer 5, Titanium dioxide zirconium layer 6, the first carbonic acid silicon layer 7, the second titanium oxide layer 8, the second carbonic acid silicon layer 9, the second alumina layer 10, the 3rd dioxy SiClx layer 11, in addition, also including the conductive layer 12 that tin indium oxide is formed.
In the present invention, the antireflective coating is used for anti-blue light glasses.
According to the present invention, the antireflective coating includes at least one high refractive index layer and at least one low-index layer.Formed For 7 layers~11 Rotating fields, high refractive index layer and low-index layer can be with alternative stackeds, it is also possible to not alternative expression lamination.The present invention In, the high index of refraction refers to refractive index higher than 1.70, and low-refraction refers to refractive index less than 1.47, and they are all referring to normal The lower refractive index for 550nm wavelength of temperature.
According to the present invention, the material such as zirconium oxide (ZrO2) of the high refractive index layer employing, titanium oxide (TiO2), oxidation Aluminum (Al2O3), tantalum pentoxide (Ta2O5) etc., material such as silicon dioxide (SiO2) that low-index layer is adopted, or titanium dioxide Silicon and alumina mixture etc..The outer layer of antireflective coating of the present invention is typically low-index layer, it is preferred to use silicon dioxide (SiO2) as outer layer.
According to the present invention, carbonic acid silicon is employed as low-refraction layer material, be especially applied in combination with alumina layer, rise The antireflective effect for arriving significantly, and has no longer been presented green and blueness under light irradiation, and is close to colourless.
According to the present invention, at least one of which conductive layer is had also combined in the antireflective film outer layer, for release electrostatic.The conductive layer Material is made using tin indium oxide (ITO).
In the present invention, each film layer of the antireflective coating is completed by being deposited with vacuum coating equipment, for conduction Layer, using ion beam or electron beam-induced deposition.Vacuum vapour deposition and ion beam or electron beam process depositing operation are The processing technique of comparative maturity in prior art, the present invention can be using technique realization, reflectance spectrums in these prior arts Can be designed by professional software of the prior art.
According to the present invention, effective anti-harmful blue light is not only able to, wearer's eyes is protected, and visual contrast can also be improved Degree, protects the light of vision to increase transmission to green etc..
The present invention is described in detail above by specific embodiment, but it should be recognized that the present invention is not limited In the specific embodiment, the present invention can carry out various modifications and change on this basis.It is all without departing from the present invention spirit and The equivalents such as any modification that principle is made, should be included within the scope of the present invention.

Claims (1)

1. a kind of anti-blue light lenses antireflective coating, by the order away from eyeglass substrate, successively including the first silicon dioxide layer, One zirconia layer, the second silicon dioxide layer, the first titanium oxide layer, the first alumina layer, the second zirconia layer, the first carbonic acid silicon Layer, the second titanium oxide layer, the second carbonic acid silicon layer, the second alumina layer, the 3rd silicon dioxide layer, in addition, also including tin indium oxide The conductive layer of formation, the antireflective coating is under light irradiation close to colourless.
CN201610105323.6A 2016-02-25 2016-02-25 Antireflection film used in blue-light-proof spectacle lens Active CN105572770B (en)

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* Cited by examiner, † Cited by third party
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CN107422402B (en) * 2016-05-24 2022-11-18 蓝思科技股份有限公司 Scratch-resistant transparent film and preparation method thereof
KR102556516B1 (en) 2016-08-11 2023-07-17 엘지이노텍 주식회사 Camera module
CN107728239B (en) * 2017-11-24 2020-08-21 江苏康耐特光学有限公司 Blue-light-preventing anti-glare coated resin lens and preparation method thereof
CN107957600B (en) * 2018-01-17 2020-08-21 江苏康耐特光学有限公司 Anti-reflection anti-infrared coated resin lens and preparation method thereof
CN108318944A (en) * 2018-02-07 2018-07-24 无锡奥芬光电科技有限公司 A kind of resin anti-reflection film and preparation method thereof
CN110187425B (en) * 2019-05-06 2023-06-13 厦门大学 Material with blue light prevention function and protective film using material
CN116300142A (en) * 2022-12-30 2023-06-23 江苏万新光学有限公司 Weak-absorption day-night low-reflection bottom-color blue-light-resistant resin lens and preparation method thereof

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CN1564052A (en) * 2004-04-12 2005-01-12 温州众生科技有限公司 Health lens for preventing blue light harm and its mfg. method
CN101529311A (en) * 2006-08-23 2009-09-09 高效光学技术有限公司 System and method for selective light inhibition
CN202771111U (en) * 2012-04-26 2013-03-06 曾勇 Radiation resistant spectacles
CN203519943U (en) * 2013-10-25 2014-04-02 上海伟星光学有限公司 Film-coated blue-ray-preventing resin lens
CN203688926U (en) * 2013-12-31 2014-07-02 上海希尔康光学眼镜有限公司 Blue-ray film resin eyeglasses
WO2015079087A1 (en) * 2013-11-27 2015-06-04 Indo Optical S.L. Ophthalmic lens comprising a base of polymeric material with a coating having an interferential, anti-reflective, anti-iridescent and ir filter multiple layer structure.
CN104704420A (en) * 2012-10-11 2015-06-10 埃西勒国际通用光学公司 Photochromic ophthalmic lens

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1564052A (en) * 2004-04-12 2005-01-12 温州众生科技有限公司 Health lens for preventing blue light harm and its mfg. method
CN101529311A (en) * 2006-08-23 2009-09-09 高效光学技术有限公司 System and method for selective light inhibition
CN202771111U (en) * 2012-04-26 2013-03-06 曾勇 Radiation resistant spectacles
CN104704420A (en) * 2012-10-11 2015-06-10 埃西勒国际通用光学公司 Photochromic ophthalmic lens
CN203519943U (en) * 2013-10-25 2014-04-02 上海伟星光学有限公司 Film-coated blue-ray-preventing resin lens
WO2015079087A1 (en) * 2013-11-27 2015-06-04 Indo Optical S.L. Ophthalmic lens comprising a base of polymeric material with a coating having an interferential, anti-reflective, anti-iridescent and ir filter multiple layer structure.
CN203688926U (en) * 2013-12-31 2014-07-02 上海希尔康光学眼镜有限公司 Blue-ray film resin eyeglasses

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Inventor after: Pu Changjiang

Inventor before: Hou Xuhua

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Address after: 528400 Guangdong Province, Zhongshan City, the town of the village of the crow village, west of the main street, Lane 6, on the first floor, No. two

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Address before: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118

Applicant before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd.

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Address after: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118

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Address after: 528400 4th floor, No.8, Quanyuan Road, Quanyan village, Sanxiang Town, Zhongshan City, Guangdong Province

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Address before: 528400 Guangdong Province, Zhongshan City, the town of the village of the crow village, west of the main street, Lane 6, on the first floor, No. two

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