TWI571657B - Blu-ray filter elements - Google Patents

Blu-ray filter elements Download PDF

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TWI571657B
TWI571657B TW104125971A TW104125971A TWI571657B TW I571657 B TWI571657 B TW I571657B TW 104125971 A TW104125971 A TW 104125971A TW 104125971 A TW104125971 A TW 104125971A TW I571657 B TWI571657 B TW I571657B
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refractive index
blue light
coating
layer
index coating
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TW104125971A
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TW201706635A (en
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葉倍宏
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崑山科技大學
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藍光之濾光元件 Blue light filter element

本發明為係關於一種濾光元件,尤指針對有害藍光的平均反射率為20%±5%之濾光元件。 The present invention relates to a filter element, particularly a filter element having an average reflectance of 20% ± 5% for harmful blue light.

由於目前有許多螢幕係採用LED背光模組,其使用上會發出強烈藍光,若眼睛長時間接收藍光便容易造成眼部疲勞、眼部黃斑部退化、白內障等問題。 Since many screens use LED backlight modules, they will emit strong blue light. If the eyes receive blue light for a long time, they will easily cause eye fatigue, degeneration of the macula, cataracts and other problems.

因此有相關業者研發有濾藍光元件,相關前案例如有中華民國專利公開號201418821之「選擇性藍光過濾之光學器件」,其主要包含:一眼科透鏡以及一選擇性光波長濾鏡,其中,該眼科透鏡選自於由下列所構成之組群:眼鏡鏡片、隱形眼鏡鏡片、眼內水晶體、角膜鑲嵌體、角膜覆蓋物、角膜移植片及角膜組織;該選擇性光波長濾鏡係阻隔5-50%之具有範圍在400至500奈米內之一波長的光,以及透射至少80%之橫跨該可見光譜的光,該選擇性波長濾鏡包含該染料或染料混合物。 Therefore, related companies have developed a blue-light filter element. For example, there is a "selective blue-filtering optical device" of the Republic of China Patent Publication No. 201418821, which mainly includes an ophthalmic lens and a selective light wavelength filter, wherein The ophthalmic lens is selected from the group consisting of a spectacle lens, a contact lens, an intraocular lens, a corneal mosaic, a corneal covering, a corneal graft, and a corneal tissue; the selective light wavelength filter is blocked 5 - 50% of light having a wavelength in the range of 400 to 500 nm, and transmitting at least 80% of light across the visible spectrum, the selective wavelength filter comprising the dye or mixture of dyes.

但上述前案的濾鏡是採用染料或染料混合物,因此容易影響影像呈現的立體效果、造成嚴重的色差問題,以及容易隨著時間而逐漸失去濾光效果,實用性較為不足。 However, the filter of the above case uses a dye or a mixture of dyes, so it is easy to affect the stereoscopic effect of the image, cause serious chromatic aberration problems, and gradually lose the filter effect over time, and the utility is insufficient.

另經檢索有非採用染料或染料混合物的濾光元件,如專利公告號M461811「濾藍光之光學膜片及所製之螢幕保護貼」、專利公告號M503319之「液晶螢幕用濾藍光貼膜」等。 Filter elements that are not dyed or dyed, such as Patent Publication No. M461811, "Blu-ray Optical Films and Screen Protectors", and Patent Publication No. M503319, "Filter Screens for LCD Screens", etc. .

但上述前案濾除全波段藍光30%以上,而容易造成影像色調偏向黃色,影響視覺效果。再者上述貼膜相關前案僅具濾藍光的單一功能,並不具濾除紫外光的功能,而難以充分保護眼睛。 However, the above case filters out more than 30% of the full-band blue light, and it is easy to cause the image tones to be yellowish, which affects the visual effect. Furthermore, the above-mentioned film-related pre-sales only have a single function of filtering blue light, and does not have the function of filtering out ultraviolet light, and it is difficult to fully protect the eyes.

爰此,為改善一般染色鏡片濾藍光的不足處,本發明人提出一種藍光之濾光元件,包含:一基板;以及一濾有害藍光鍍膜層,結合於該基板的其中一面,該濾有害藍光鍍膜層於波長範圍介於415奈米至455奈米之有害藍光的平均反射率為20%±5%,而其餘可見光波長範圍之光的平均反射率不高於2%。 Therefore, in order to improve the deficiencies of the general dyed lens for filtering blue light, the inventors propose a blue light filter element comprising: a substrate; and a filter harmful blue light coating layer bonded to one side of the substrate, the filter harmful blue light The average reflectance of the coating layer in the harmful blue light having a wavelength ranging from 415 nm to 455 nm is 20% ± 5%, and the average reflectance of the light in the remaining visible wavelength range is not more than 2%.

進一步,該濾有害藍光鍍膜層於波長範圍介於320奈米至400奈米之紫外光的平均反射率高於99%。 Further, the filtered harmful blue light coating layer has an average reflectance of more than 99% in ultraviolet light having a wavelength ranging from 320 nm to 400 nm.

進一步,該濾有害藍光鍍膜層係複數層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,且該高折射率鍍膜係選自於由下列組群中之一:五氧化二鉭(Ta2O5)、五氧化二鈮(Nb2O5)、二氧化鉿(HfO2)、二氧化鋯(ZrO2);該低折射率鍍膜係選自下列組群中之一:氟鋁酸鈉(Na3AlF6)、氟化鎂(MgF2)、二氧化矽(SiO2)。 Further, the filter harmful blue light coating layer is a periodic structure composed of a high refractive index coating and a low refractive index coating of a plurality of layers, and the high refractive index coating is selected from one of the following groups: Bismuth pentoxide (Ta 2 O 5 ), niobium pentoxide (Nb 2 O 5 ), hafnium oxide (HfO 2 ), zirconium dioxide (ZrO 2 ); the low refractive index coating is selected from the following groups One of them: sodium fluoroaluminate (Na 3 AlF 6 ), magnesium fluoride (MgF 2 ), cerium oxide (SiO 2 ).

進一步,該濾有害藍光鍍膜層係13層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其中該高折射率鍍膜為五氧化二鉭(Ta2O5),該低折射率鍍膜為氟化鎂(MgF2),而該週期性結構每一層的厚度自相鄰空氣的一端起算,依序為22.40奈米、72.49奈米、48.07奈米、61.14奈米、38.01奈米、63.91奈米、39.75奈米、60.06奈米、34.56nm、65.66奈米、40.81奈米、50.83奈米、34.97奈米,使該濾光元件於波長範圍介於320至380奈米之紫外光的平均反射率高於99.27%,於波長範圍介於415奈米至455奈米之有害藍光的平均反射率為21.98%,於波長範圍介於500奈米至780奈米之光的平均反射率1.88%。 Further, the filter harmful blue light coating layer is a periodic structure composed of a 13-layer alternating stack of a high refractive index coating and a low refractive index coating, wherein the high refractive index coating is tantalum pentoxide (Ta 2 O 5 ), The low refractive index coating is magnesium fluoride (MgF 2 ), and the thickness of each layer of the periodic structure is from the end of the adjacent air, and is sequentially 22.40 nm, 72.49 nm, 48.07 nm, 61.14 nm, 38.01 nm, 63.91 nm, 39.75 nm, 60.06 nm, 34.56 nm, 65.66 nm, 40.81 nm, 50.83 nm, 34.97 nm, making the filter element in the wavelength range from 320 to 380 nm The average reflectance of ultraviolet light is higher than 99.27%, and the average reflectance of harmful blue light in the wavelength range from 415 nm to 455 nm is 21.98%, and the wavelength is in the range of 500 nm to 780 nm. The average reflectance is 1.88%.

進一步,該基板選自下列組群中之一:玻璃、聚甲基丙烯酸甲酯(Polymethylmethacrylate,PMMA)、聚對苯二甲酸乙二酯(polyethylene terephthalate,PET)、聚碳酸酯(Polycarbonate,PC)、甲基丙烯酸羥乙酯(Hydroxyethyl methacrylate,HEMA)。 Further, the substrate is selected from one of the following groups: glass, polymethylmethacrylate (PMMA), polyethylene terephthalate (PET), polycarbonate (Polycarbonate, PC). , Hydroxyethyl methacrylate (HEMA).

更包括一抗反射鍍膜層,結合於該基板的另一面,該抗反射鍍膜層對波長範圍介於320奈米至780奈米之光的反射率低於2.5%。 Further comprising an anti-reflective coating layer bonded to the other side of the substrate, the anti-reflective coating layer has a reflectance of less than 2.5% for light having a wavelength ranging from 320 nm to 780 nm.

更包括一抗反射鍍膜層,結合於該基板的另一面,該抗反射鍍膜層包含不影響參考波長反射率之一拓寬層,以拓寬波長介於320奈米至780奈米的低反射區的範圍,該抗反射鍍膜層依導納軌跡法分析之一導納軌跡圖如第三圖所示。 Further comprising an anti-reflective coating layer bonded to the other side of the substrate, the anti-reflective coating layer comprising a widening layer that does not affect the reflectance of the reference wavelength to broaden the low-reflection region having a wavelength between 320 nm and 780 nm. Range, the anti-reflective coating layer is one of the admittance trajectories analyzed by the admittance trajectory method as shown in the third figure.

更包括一抗反射鍍膜層,結合於該基板的另一面,該抗反射鍍膜層係8層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其中該高折射率鍍膜為五氧化二鉭(Ta2O5),該低折射率鍍膜為氟鋁酸鈉(Na3AlF6),而該週期性結構每一層的厚度自相鄰空氣的一端起算,依序為86.81奈米、18.59奈米、17.52奈米、114.07奈米、16.06奈米、25.20奈米、30.99奈米、10.31奈米,使該抗反射鍍膜層對波長範圍介於320奈米至780奈米之光的反射率低於0.5%。 Further comprising an anti-reflective coating layer bonded to the other side of the substrate, the anti-reflective coating layer is a periodic structure composed of 8 layers of a high refractive index coating and a low refractive index coating, wherein the high refractive index The coating is tantalum pentoxide (Ta 2 O 5 ), and the low refractive index coating is sodium fluoroaluminate (Na 3 AlF 6 ), and the thickness of each layer of the periodic structure is calculated from one end of the adjacent air, in order 86.81 nm, 18.59 nm, 17.52 nm, 114.07 nm, 16.06 nm, 25.20 nm, 30.99 nm, 10.31 nm, making the anti-reflective coating layer wavelength range from 320 nm to 780 nm The reflectance of the light is less than 0.5%.

根據上述技術特徵而具有下列功效: According to the above technical features, the following effects are obtained:

1.由於具有濾有害藍光鍍膜層,其選擇濾除波長範圍介於415奈米至455奈米之有害藍光、平均反射率為20%±5%,以兼具減輕藍光對眼睛的危害以及避免影像色調產生色差的功效,另一方面由於濾有害藍光鍍膜層為光學鍍膜層,因此可避免影響影像呈現的清晰效果。 1. Due to the filter harmful blue light coating layer, it chooses to filter harmful blue light with wavelength range from 415 nm to 455 nm, and the average reflectance is 20%±5%, so as to reduce the harm of blue light to the eyes and avoid The color tone of the image produces the effect of chromatic aberration. On the other hand, since the harmful blue light coating layer is an optical coating layer, the clear effect of the image presentation can be avoided.

2.對波長範圍介於320奈米至400奈米之紫外光的平均反射率高於99%而具備抗UV功能。 2. It has anti-UV function for the average reflectance of ultraviolet light with a wavelength range of 320 nm to 400 nm higher than 99%.

3.可更包括一抗反射鍍膜層,結合於該基板的另一面,如此設計可以防止從後方入射到眼睛的有害光線(上述UV光及有害藍光),以藉此更完善的保護眼睛。 3. It may further comprise an anti-reflective coating layer bonded to the other side of the substrate, so as to prevent harmful light (such as UV light and harmful blue light) incident on the eyes from the rear, thereby further protecting the eyes.

4.該抗反射鍍膜層可包含不影響參考波長反射率之一拓寬層,以拓寬低反射區的範圍。 4. The anti-reflective coating layer may comprise a widening layer that does not affect the reflectance of the reference wavelength to broaden the range of the low reflection region.

5.本發明於使用上不限於一般鏡片(如眼鏡鏡片、隱形眼鏡鏡片等眼科光學元件),亦可應用於一般濾光用之光學元件。 5. The invention is not limited to general lenses (such as ophthalmic optical elements such as spectacle lenses and contact lens lenses), and can also be applied to optical elements for general filtering.

(1)(10)‧‧‧基板 (1) (10) ‧‧‧Substrate

(11)‧‧‧其中一面 (11) ‧ ‧ ‧ one side

(12)‧‧‧另一面 (12) ‧ ‧ the other side

(2)(20)‧‧‧濾有害藍光鍍膜層 (2) (20) ‧ ‧ filter harmful blue coating layer

(3)‧‧‧抗反射鍍膜層 (3) ‧‧‧Anti-reflective coating

[第一圖]係本發明第一實施例之剖視示意圖。 [First Figure] is a schematic cross-sectional view showing a first embodiment of the present invention.

[第二A圖]係本發明第一實施例之濾有害藍光鍍膜層的反射率光譜圖。 [Second A] is a reflectance spectrum of the filter-defective blue light-coating layer of the first embodiment of the present invention.

[第二B圖]係本發明第一實施例之抗反射鍍膜層的反射率光譜圖。 [Second B] is a reflectance spectrum of the antireflection coating layer of the first embodiment of the present invention.

[第三圖]係本發明第一實施例之抗反射鍍膜層的導納軌跡圖。 [Third image] is an admittance trace diagram of the antireflection coating layer of the first embodiment of the present invention.

[第四圖]係本發明第二實施例之反射率光譜圖。 [Fourth Diagram] is a reflectance spectrum diagram of a second embodiment of the present invention.

[第五圖]係本發明第三實施例之反射率光譜圖。 [Fifth Graph] is a reflectance spectrum diagram of a third embodiment of the present invention.

[第六圖]係本發明第四實施例之反射率光譜圖。 [Sixth Graph] is a reflectance spectrum diagram of a fourth embodiment of the present invention.

[第七圖]係本發明第五實施例之反射率光譜圖。 [Seventh Graph] is a reflectance spectrum diagram of a fifth embodiment of the present invention.

[第八圖]係本發明第六實施例之反射率光譜圖。 [Eighth Graph] is a reflectance spectrum diagram of a sixth embodiment of the present invention.

[第九圖]係本發明第七實施例之反射率光譜圖。 [9th] is a reflectance spectrum diagram of a seventh embodiment of the present invention.

[第十圖]係本發明第八實施例之反射率光譜圖。 [Tenth Graph] is a reflectance spectrum diagram of an eighth embodiment of the present invention.

[第十一A圖]係本發明第九實施例之反射率光譜圖。 [11th A] is a reflectance spectrum diagram of a ninth embodiment of the present invention.

[第十一B圖]係本發明第九實施例之導納軌跡圖。 [11th B] is an admittance trajectory diagram of a ninth embodiment of the present invention.

[第十二A圖]係本發明第十實施例之反射率光譜圖。 [Twelfth AA] is a reflectance spectrum diagram of a tenth embodiment of the present invention.

[第十二B圖]係本發明第十實施例之導納軌跡圖。 [Twelfth B] FIG. 4 is an admittance trajectory diagram of a tenth embodiment of the present invention.

[第十三圖]係本發明第十一實施例之剖視示意圖。 [Thirteenth Figure] is a schematic cross-sectional view showing an eleventh embodiment of the present invention.

[第十四圖]係本發明第十一實施例之反射率光譜圖。 [Fourteenth] is a reflectance spectrum of the eleventh embodiment of the present invention.

[第十五圖]係本發明第十二實施例之反射率光譜圖。 [Fifteenth Figure] is a reflectance spectrum diagram of the twelfth embodiment of the present invention.

[第十六圖]係本發明第十三實施例之反射率光譜圖。 [16] Fig. 16 is a reflectance spectrum diagram of the thirteenth embodiment of the present invention.

[第十七圖]係本發明第十四實施例之反射率光譜圖。 [17th] is a reflectance spectrum diagram of the fourteenth embodiment of the present invention.

綜合上述技術特徵,本發明藍光之濾光元件的主要功效將可於下述實施例清楚呈現。 In summary of the above technical features, the main effects of the blue light filtering element of the present invention will be apparent from the following examples.

請先參閱第一圖,係揭示本發明第一實施例藍光之濾光元件,包含:一基板(1)、一濾有害藍光鍍膜層(2)及一抗反射鍍膜層(3),其中:該基板(1)於本實施例中係採用玻璃,但並不以此為限,亦可以是聚甲基丙烯酸甲酯(Polymethylmethacrylate,PMMA)、聚對苯二甲酸乙二酯(polyethylene terephthalate,PET)、聚碳酸酯(Polycarbonate,PC)、甲基丙烯酸羥乙酯(Hydroxyethyl methacrylate,HEMA)等。 Please refer to the first figure, which discloses a blue light filter element according to a first embodiment of the present invention, comprising: a substrate (1), a filter harmful blue light coating layer (2) and an anti-reflection coating layer (3), wherein: The substrate (1) is made of glass in the embodiment, but is not limited thereto, and may be polymethylmethacrylate (PMMA) or polyethylene terephthalate (PET). ), polycarbonate (Polycarbonate, PC), hydroxyethyl methacrylate (HEMA), and the like.

該濾有害藍光鍍膜層(2)結合於該基板(1)的其中一面(11),該濾有害藍光鍍膜層(2)於波長範圍介於415奈米至455奈米之有害藍光的平均反射率為20%±5%,而其餘可見光波長範圍之光的平均反射率不高於2%。具體而言,該濾有害藍光鍍膜層(2)係複數層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,該高折射率鍍膜於本實施例係選用五氧化二鉭(Ta2O5),但並不以此為限,亦可以是五氧化二鈮(Nb2O5)、二氧化鉿(HfO2)、二氧化鋯(ZrO2)等;該低折射率鍍膜於本實施例係選用氟鋁酸鈉(Na3AlF6),但並不以此為限,亦可以是氟化鎂(MgF2)、二氧化矽(SiO2)等材質。該高折射率鍍膜及該低折射率鍍膜材料較佳的是包括可濾除紫外光區的光,因此,同時適用的高、 低折射率材料不多,較佳的是於波長範圍介於320奈米至400奈米之紫外光的平均反射率高於99%,而具有抗紫外線功能,以提供使用者更完善的保護。 The filter harmful blue light coating layer (2) is bonded to one side (11) of the substrate (1), and the filtered harmful blue light coating layer (2) has an average reflection of harmful blue light in a wavelength range of 415 nm to 455 nm. The rate is 20% ± 5%, and the average reflectance of the remaining visible light wavelength range is not higher than 2%. Specifically, the filter harmful blue light coating layer (2) is a periodic structure composed of a plurality of layers of a high-refractive-index coating and a low-refractive-index coating, and the high-refractive-index coating is pentoxide in this embodiment. Dioxane (Ta 2 O 5 ), but not limited thereto, may also be niobium pentoxide (Nb 2 O 5 ), hafnium oxide (HfO 2 ), zirconium dioxide (ZrO 2 ), etc.; In the present embodiment, sodium fluoroaluminate (Na 3 AlF 6 ) is used for the refractive index coating, but it is not limited thereto, and may be a material such as magnesium fluoride (MgF 2 ) or cerium oxide (SiO 2 ). Preferably, the high refractive index coating and the low refractive index coating material comprise light that can filter out ultraviolet light regions. Therefore, there are not many high and low refractive index materials applicable at the same time, and preferably in the wavelength range of 320. The average reflectance of ultraviolet light from nanometer to 400 nm is higher than 99%, and it has anti-ultraviolet function to provide users with better protection.

續請參閱表1-1,詳細而言,該濾有害藍光鍍膜層係13層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,而該週期性結構每一層的厚度自相鄰空氣的一端起算,其各層配置如下表1-1: Continued, please refer to Table 1-1. In detail, the filter harmful blue light coating layer is a periodic structure composed of a 13-layer alternating stack of high refractive index coating and a low refractive index coating, and the periodic structure is composed of each layer. The thickness is calculated from one end of the adjacent air, and its layers are configured as shown in Table 1-1 below:

上述第一實施例的濾有害藍光鍍膜層之反射率光譜圖如第二A圖所示,其中紫外光波段320nm至380nm平均反射率99.27%、有害藍光區415nm至455nm平均反射率21.98%、可見光區500nm至780nm平均反射率1.88%。 The reflectance spectrum of the filter-defective blue light-coating layer of the first embodiment is as shown in FIG. 2A, wherein the ultraviolet light band has an average reflectance of 99.27% from 320 nm to 380 nm, and the harmful blue light region has an average reflectance of 21.98% from 415 nm to 455 nm. The average reflectance of the region from 500 nm to 780 nm is 1.88%.

該抗反射鍍膜層(3)結合於該基板(1)的另一面(12),該抗反射鍍膜層(3)對波長範圍介於320奈米至780奈米之光的反射率低於2.5%。 The anti-reflective coating layer (3) is bonded to the other side (12) of the substrate (1), and the anti-reflective coating layer (3) has a reflectance of less than 2.5 for light having a wavelength ranging from 320 nm to 780 nm. %.

續請參閱表1-1,詳細而言,該抗反射鍍膜層係8層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,而該週期性結構每一層的厚度自相鄰空氣的一端起算,其各層配置如下表: Continuing to refer to Table 1-1, in detail, the anti-reflective coating layer is a periodic structure composed of one layer of a high-refractive-index coating and a low-refractive-index coating, and the thickness of each layer of the periodic structure. From the end of the adjacent air, the layers are configured as follows:

上述第一實施例抗反射鍍膜層之反射率光譜圖如第二B圖所示,其中波段320nm至780nm平均反射率0.424%、全波段反射率低於0.5%。 The reflectance spectrum of the antireflection coating layer of the first embodiment described above is as shown in FIG. 2B, wherein the average reflectance of the wavelength band 320 nm to 780 nm is 0.424%, and the total band reflectance is less than 0.5%.

較佳的是,該抗反射鍍膜層包含不影響參考波長反射率之一拓寬層,以拓寬波長介於320奈米至780奈米的低反射區的範圍,該抗反射鍍膜層依導納軌跡法分析之一導納軌跡圖如第三圖所示。 Preferably, the anti-reflective coating layer comprises a widening layer that does not affect the reflectance of the reference wavelength to broaden a range of low-reflection regions having a wavelength between 320 nm and 780 nm, and the anti-reflective coating layer is guided by an admittance trajectory. One of the method analysis admittance trajectories is shown in the third figure.

以下將進一步說明本發明之第二實施例,該濾有害藍光鍍膜層係13層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其中該高折射率鍍膜為五氧化二鉭(Ta2O5),該低折射率鍍膜為氟鋁酸鈉(Na3AlF6),而該週期性結構每一層的厚度自相鄰空氣的一端起算,其各層配置如下表2-1: Hereinafter, the second embodiment of the present invention will be further described. The filter harmful blue light coating layer is a periodic structure composed of a 13-layer alternating stack of a high refractive index coating and a low refractive index coating, wherein the high refractive index coating is five. Bismuth oxide (Ta 2 O 5 ), the low refractive index coating is sodium fluoroaluminate (Na 3 AlF 6 ), and the thickness of each layer of the periodic structure is calculated from one end of the adjacent air, and the layers are arranged as shown in Table 2 below. -1:

上述第二實施例之反射率光譜圖如第四圖所示,其中紫外光波段320nm至380nm平均反射率99.5%、有害藍光區415nm至455nm平均反射率22.07%、可見光區500nm至780nm平均反射率1.66%。 The reflectance spectrum of the second embodiment is as shown in the fourth figure, wherein the ultraviolet light band has an average reflectance of 99.5% from 320 nm to 380 nm, the average reflectance of the harmful blue region from 415 nm to 455 nm is 22.07%, and the average reflectance of the visible light region is from 500 nm to 780 nm. 1.66%.

以下將進一步說明本發明之第三實施例,該濾有害藍光鍍膜層係13層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,且其基板材質為聚甲基丙烯酸甲酯(Polymethylmethacrylate,PMMA),其各層配置如下表3-1: Hereinafter, a third embodiment of the present invention will be further described. The filter harmful blue light coating layer is a periodic structure composed of a 13-layer alternating stack of a high refractive index coating and a low refractive index coating, and the substrate material is polymethyl. Polymethylmethacrylate (PMMA), the configuration of each layer is as follows Table 3-1:

上述第三實施例之反射率光譜圖如第五圖所示。 The reflectance spectrum of the third embodiment described above is as shown in the fifth figure.

以下將進一步說明本發明之第四實施例,該濾有害藍光鍍膜層係14層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: The fourth embodiment of the present invention will be further described. The filter-detrimental blue-light coating layer is a periodic structure composed of a 14-layer alternating stack of a high refractive index coating and a low refractive index coating. The layers are arranged as follows:

上述第四實施例之反射率光譜圖如第六圖所示,其中紫外光波段320nm至380nm平均反射率99.42%、有害藍光區415nm至455nm平均反射率20.93%、可見光區500nm至780nm平均反射率1.21%。 The reflectance spectrum of the fourth embodiment is as shown in the sixth figure, wherein the average reflectance of the ultraviolet light band from 320 nm to 380 nm is 99.42%, the average reflectance of the harmful blue light region from 415 nm to 455 nm is 20.93%, and the average reflectance of the visible light region is from 500 nm to 780 nm. 1.21%.

下將進一步說明本發明之第五實施例,該濾有害藍光鍍膜層係15層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: The fifth embodiment of the present invention will be further described. The filter harmful blue light coating layer is a periodic structure composed of a 15-layer alternating stack of a high refractive index coating and a low refractive index coating. The layers are arranged as follows:

上述第五實施例之反射率光譜圖如第七圖所示,其中紫外光波段320nm至380nm平均反射率99.54%、有害藍光區415nm至455nm平均反射率22.39%、可見光區500nm至780nm平均反射率1.46%。 The reflectance spectrum of the fifth embodiment is as shown in the seventh figure, wherein the average reflectance of the ultraviolet light band from 320 nm to 380 nm is 99.54%, the average reflectance of the harmful blue light region from 415 nm to 455 nm is 22.39%, and the average reflectance of the visible light region is from 500 nm to 780 nm. 1.46%.

下將進一步說明本發明之第六實施例,該濾有害藍光鍍膜層係17層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: The sixth embodiment of the present invention will be further described. The filter harmful blue light coating layer is a periodic structure composed of a high-refractive-index coating and a low-refractive-index coating of 17 layers of alternating layers, and the layers are arranged as follows:

上述第六實施例之反射率光譜圖如第八圖所示,其中紫外光波段320nm至380nm平均反射率99.81%、有害藍光區415nm至455nm平均反射率21.44%、可見光區500nm至780nm平均反射率1.79%。 The reflectance spectrum of the sixth embodiment described above is as shown in the eighth figure, wherein the average reflectance of the ultraviolet light band from 320 nm to 380 nm is 99.81%, the average reflectance of the harmful blue light region from 415 nm to 455 nm is 21.44%, and the average reflectance of the visible light region is from 500 nm to 780 nm. 1.79%.

下將進一步說明本發明之第七實施例,該抗反射鍍膜層係2層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: A seventh embodiment of the present invention will be further described. The anti-reflective coating layer is a periodic structure composed of a two-layer alternating stack of a high refractive index coating and a low refractive index coating. The layers are arranged as follows:

上述第七實施例之反射率光譜圖如第九圖所示,其中波段320nm至780nm平均反射率1.32%、全波段(全波段為320~780nm)反射率低於2.1%。 The reflectance spectrum of the seventh embodiment described above is as shown in the ninth figure, wherein the average reflectance of the band 320 nm to 780 nm is 1.32%, and the reflectance of the whole band (the whole band is 320 to 780 nm) is less than 2.1%.

下將進一步說明本發明之第八實施例,該抗反射鍍膜層係4層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: The eighth embodiment of the present invention will be further described. The anti-reflective coating layer is a periodic structure composed of a 4-layer alternating stack of a high refractive index coating and a low refractive index coating. The layers are arranged as follows:

上述第八實施例之反射率光譜圖如第十圖所示,其中波段320nm至780nm平均反射率1.24%、全波段反射率低於1.5%。 The reflectance spectrum of the eighth embodiment described above is as shown in the tenth graph, wherein the average reflectance of the wavelength band 320 nm to 780 nm is 1.24%, and the total band reflectance is less than 1.5%.

下將進一步說明本發明之第九實施例,該抗反射鍍膜層係6層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: The ninth embodiment of the present invention will be further described. The anti-reflective coating layer is a periodic structure composed of a 6-layer alternating stack of a high refractive index coating and a low refractive index coating. The layers are arranged as follows:

上述第九實施例之反射率光譜圖如第十一A圖所示,其中波段320nm至780nm平均反射率0.625%、全波段反射率低於1.25%。而導納軌跡圖如第十一B圖所示,其中靠近基板第3層為全波段半波厚的虛設層。 The reflectance spectrum of the ninth embodiment described above is as shown in FIG. 11A, in which the average reflectance of the wavelength band 320 nm to 780 nm is 0.625%, and the total band reflectance is less than 1.25%. The admittance trajectory is as shown in FIG. 11B, in which the third layer near the substrate is a dummy layer with a full-band half-wave thickness.

下將進一步說明本發明之第十實施例,該抗反射鍍膜層係10層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: The tenth embodiment of the present invention will be further described. The anti-reflective coating layer is a periodic structure composed of a 10-layer alternating stack of a high refractive index coating and a low refractive index coating. The layers are arranged as follows:

上述第十實施例之反射率光譜圖如第十二A圖所示,其中波段320nm至780nm平均反射率0.374%、全波段反射率低於0.4%。而導納軌跡圖如第十二B圖所示,其中,靠近基板第7層為虛設層。 The reflectance spectrum of the above-described tenth embodiment is as shown in Fig. 12A, in which the average reflectance of the wavelength band 320 nm to 780 nm is 0.374%, and the total band reflectance is less than 0.4%. The admittance trajectory is as shown in the twelfth B-picture, wherein the seventh layer near the substrate is a dummy layer.

續請參閱第十三圖,係本發明第十一實施例之藍光之濾光元件的剖視示意圖,包括一基板(10)及一濾有害藍光鍍膜層(20),主要差異在於僅針對濾藍光設計,因此材質選擇上可不局限於可濾除紫外光區的光。 Continuing to refer to a thirteenth embodiment, a cross-sectional view of a blue light filter element according to an eleventh embodiment of the present invention includes a substrate (10) and a filter harmful blue light coating layer (20), the main difference being that only for filtering The blue light design, so the material selection is not limited to the light that can filter out the ultraviolet region.

該濾有害藍光鍍膜層(20)於本實施例係4層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: The filter harmful blue light coating layer (20) is a periodic structure composed of a high-refractive-index coating and a low-refractive-index coating in the fourth layer of the present embodiment, and the layers are arranged as follows:

上述第十一實施例之反射率光譜圖如第十四圖所示,由圖示可知,若僅針對濾藍光設計,則鍍膜數可減少至4層。 As shown in the fourteenth embodiment, the reflectance spectrum of the eleventh embodiment shows that the number of coatings can be reduced to four layers if only designed for the blue light filtering.

以下將進一步說明本發明之第十二實施例,該濾有害藍光鍍膜層係6層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: Hereinafter, the twelfth embodiment of the present invention will be further described. The filter harmful blue light coating layer is a periodic structure composed of a 6-layer alternating stack of a high refractive index coating and a low refractive index coating, and the layers are arranged as follows:

上述第十二實施例之反射率光譜圖如第十五圖所示。 The reflectance spectrum of the above twelfth embodiment is as shown in Fig. 15.

下將進一步說明本發明之第十三實施例,該濾有害藍光鍍膜層係10層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: The thirteenth embodiment of the present invention will be further described. The filter harmful blue light coating layer is a periodic structure composed of a 10-layer alternating stack of a high refractive index coating and a low refractive index coating. The layers are arranged as follows:

上述第十三實施例之反射率光譜圖如第十六圖所示。 The reflectance spectrum of the above-described thirteenth embodiment is as shown in Fig. 16.

下將進一步說明本發明之第十四實施例,該濾有害藍光鍍膜層係12層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其各層配置如下表: The fourteenth embodiment of the present invention will be further described. The filter harmful blue light coating layer is a periodic structure composed of a 12-layer alternating stack of a high refractive index coating and a low refractive index coating. The layers are arranged as follows:

上述第十四實施例之反射率光譜圖如第十七圖所示。 The reflectance spectrum of the above-described fourteenth embodiment is as shown in Fig. 17.

綜合上述實施例之說明,當可充分瞭解本發明之操作、使用及本發明產生之功效,惟以上所述實施例僅係為本發明之較佳實施例,當不能以此限定本發明實施之範圍,即依本發明申請專利範圍及發明說明內容所作簡單的等效變化與修飾,皆屬本發明涵蓋之範圍內。 In view of the foregoing description of the embodiments, the operation and the use of the present invention and the effects of the present invention are fully understood, but the above described embodiments are merely preferred embodiments of the present invention, and the invention may not be limited thereto. Included within the scope of the present invention are the scope of the present invention.

(1)‧‧‧基板 (1) ‧‧‧Substrate

(11)‧‧‧其中一面 (11) ‧ ‧ ‧ one side

(12)‧‧‧另一面 (12) ‧ ‧ the other side

(2)‧‧‧濾有害藍光鍍膜層 (2) ‧ ‧ ‧ harmful blue coating layer

(3)‧‧‧抗反射鍍膜層 (3) ‧‧‧Anti-reflective coating

Claims (10)

一種藍光之濾光元件,包含:一基板;以及一濾有害藍光鍍膜層,結合於該基板的其中一面,該濾有害藍光鍍膜層係13層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其中該高折射率鍍膜為五氧化二鉭(Ta2O5),該低折射率鍍膜為氟鋁酸鈉(Na3AlF6),而該週期性結構每一層的厚度自相鄰空氣的一端起算,依序為22.40奈米、72.49奈米、48.07奈米、61.14奈米、38.01奈米、63.91奈米、39.75奈米、60.06奈米、34.56nm、65.66奈米、40.81奈米、50.83奈米、34.97奈米,使該濾光元件於波長範圍介於320至380奈米之紫外光的平均反射率高於99.27%,於波長範圍介於415奈米至455奈米之有害藍光的平均反射率為21.98%,於波長範圍介於500奈米至780奈米之光的平均反射率1.88%。 A blue light filter component comprising: a substrate; and a filter harmful blue light coating layer bonded to one side of the substrate, the filter harmful blue light coating layer is 13 layers of alternating high refractive index coating and a low refractive index a periodic structure formed by the coating, wherein the high refractive index coating is tantalum pentoxide (Ta 2 O 5 ), and the low refractive index coating is sodium fluoroaluminate (Na 3 AlF 6 ), and the periodic structure is each layer The thickness is from the end of the adjacent air, in order of 22.40 nm, 72.49 nm, 48.07 nm, 61.14 nm, 38.01 nm, 63.91 nm, 39.75 nm, 60.06 nm, 34.56 nm, 65.66 Meter, 40.81 nm, 50.83 nm, 34.97 nm, the average reflectance of the filter element in the wavelength range of 320 to 380 nm is higher than 99.27%, and the wavelength range is 415 nm to The average reflectance of the harmful blue light of 455 nm is 21.98%, and the average reflectance of light of the wavelength range of 500 nm to 780 nm is 1.88%. 如申請專利範圍第1項所述之藍光之濾光元件,其中,該基板選自下列組群中之一:玻璃、聚甲基丙烯酸甲酯(Polymethylmethacrylate,PMMA)、聚對苯二甲酸乙二酯(polyethylene terephthalate,PET)、聚碳酸酯(Polycarbonate,PC)、甲基丙烯酸羥乙酯(Hydroxyethyl methacrylate,HEMA)。 The blue light filter element of claim 1, wherein the substrate is selected from one of the group consisting of glass, polymethylmethacrylate (PMMA), and polyethylene terephthalate. Polyethylene terephthalate (PET), polycarbonate (Polycarbonate, PC), hydroxyethyl methacrylate (HEMA). 如申請專利範圍第1項所述之藍光之濾光元件,更包括一抗反射鍍膜層,結合於該基板的另一面,該抗反射鍍膜層對波長範圍介於320奈米至780奈米之光的反射率低於2.5%。 The blue light filter component of claim 1, further comprising an anti-reflective coating layer bonded to the other side of the substrate, the anti-reflective coating layer having a wavelength range of from 320 nm to 780 nm. The reflectance of light is less than 2.5%. 如申請專利範圍第1項所述之藍光之濾光元件,更包括一抗反射鍍膜層,結合於該基板的另一面,該抗反射鍍膜層包含不影響參考波長反射率之一拓寬層,以拓寬波長介於320奈米至780奈米的低反射區的範圍。 The blue light filter component of claim 1, further comprising an anti-reflective coating layer bonded to the other side of the substrate, the anti-reflective coating layer comprising a widening layer that does not affect the reflectance of the reference wavelength, Broaden the range of low reflection areas with wavelengths from 320 nm to 780 nm. 如申請專利範圍第1項所述之藍光之濾光元件,更包括一抗反射鍍膜層,結合於該基板的另一面,該抗反射鍍膜層係8層交互堆疊之一高折射率鍍膜 及一低折射率鍍膜所構成之週期性結構,其中該高折射率鍍膜為五氧化二鉭(Ta2O5),該低折射率鍍膜為氟鋁酸鈉(Na3AlF6),而該週期性結構每一層的厚度自相鄰空氣的一端起算,依序為86.81奈米、18.59奈米、17.52奈米、114.07奈米、16.06奈米、25.20奈米、30.99奈米、10.31奈米,使該抗反射鍍膜層對波長範圍介於320奈米至780奈米之光的反射率低於0.5%。 The blue light filter component of claim 1, further comprising an anti-reflective coating layer bonded to the other side of the substrate, the anti-reflective coating layer is an 8-layer alternating stack of high refractive index coating and a a periodic structure composed of a low refractive index coating, wherein the high refractive index coating is tantalum pentoxide (Ta 2 O 5 ), and the low refractive index coating is sodium fluoroaluminate (Na 3 AlF 6 ), and the periodicity The thickness of each layer of the structure is calculated from the end of the adjacent air, which is 86.81 nm, 18.59 nm, 17.52 nm, 114.07 nm, 16.06 nm, 25.20 nm, 30.99 nm, 10.31 nm. The antireflective coating layer has a reflectance of less than 0.5% for light having a wavelength ranging from 320 nm to 780 nm. 一種藍光之濾光元件,包含:一基板;以及一濾有害藍光鍍膜層,結合於該基板的其中一面,其中,該濾有害藍光鍍膜層係14層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其中該高折射率鍍膜為五氧化二鉭(Ta2O5),該低折射率鍍膜為氟化鎂(MgF2),而該週期性結構每一層的厚度自相鄰空氣的一端起算,依序為122.10奈米、37.23奈米、54.66奈米、40.88奈米、69.16奈米、34.97奈米、58.13奈米、39.23奈米、62.69奈米、37.51奈米、69.66奈米、43.63奈米、59.15奈米、35.30奈米,使該濾光元件於波長範圍介於320至380奈米之紫外光的平均反射率為99.42%,於波長範圍介於415奈米至455奈米之有害藍光的平均反射率為20.93%,於波長範圍介於500奈米至780奈米之光的平均反射率1.21%。 A blue light filter component comprising: a substrate; and a filter harmful blue light coating layer bonded to one side of the substrate, wherein the filter harmful blue light coating layer is a layer of 14 layers of alternating high refractive index coating and a low a periodic structure formed by a refractive index coating, wherein the high refractive index coating is tantalum pentoxide (Ta 2 O 5 ), and the low refractive index coating is magnesium fluoride (MgF 2 ), and the periodic structure is each layer The thickness is from the end of the adjacent air, in order of 122.10 nm, 37.23 nm, 54.66 nm, 40.88 nm, 69.16 nm, 34.97 nm, 58.13 nm, 39.23 nm, 62.69 nm, 37.51 Nai Meter, 69.66 nm, 43.63 nm, 59.15 nm, 35.30 nm, the average reflectance of the filter element in the wavelength range of 320 to 380 nm is 99.42%, in the wavelength range of 415 The average reflectance of harmful blue light from nanometer to 455 nm is 20.93%, and the average reflectance of light in the wavelength range of 500 nm to 780 nm is 1.21%. 一種藍光之濾光元件,包含:一基板;以及一濾有害藍光鍍膜層,結合於該基板的其中一面,其中,該濾有害藍光鍍膜層係15層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其中該高折射率鍍膜為五氧化二鉭(Ta2O5),該低折射率鍍膜為氟化鎂(MgF2),而該週期性結構每一層的厚度自相鄰空氣的一端起算,依序為14.56奈米、80.15奈米、45.53奈米、59.44奈米、38.71奈米、77.29奈米、37.29奈米、60.29奈米、37.46奈米、61.19奈米、37.16奈米、56.67奈米、47.45奈米、51.35奈米、31.07奈米, 使該濾光元件於波長範圍介於320至380奈米之紫外光的平均反射率為99.54%,於波長範圍介於415奈米至455奈米之有害藍光的平均反射率為22.39%,於波長範圍介於500奈米至780奈米之光的平均反射率1.46%。 A blue light filter component comprising: a substrate; and a filter harmful blue light coating layer bonded to one side of the substrate, wherein the filter harmful blue light coating layer is a layer of 15 layers of alternating high refractive index coating and a low a periodic structure formed by a refractive index coating, wherein the high refractive index coating is tantalum pentoxide (Ta 2 O 5 ), and the low refractive index coating is magnesium fluoride (MgF 2 ), and the periodic structure is each layer The thickness is from the end of the adjacent air, in order of 14.56 nm, 80.15 nm, 45.53 nm, 59.44 nm, 38.71 nm, 77.29 nm, 37.29 nm, 60.29 nm, 37.46 nm, 61.19 Nai Meter, 37.16 nm, 56.67 nm, 47.45 nm, 51.35 nm, 31.07 nm, the average reflectance of the filter element in the wavelength range of 320 to 380 nm is 99.54%, at the wavelength The average reflectance of harmful blue light ranging from 415 nm to 455 nm is 22.39%, and the average reflectance of light having a wavelength range of 500 nm to 780 nm is 1.46%. 一種藍光之濾光元件,包含:一基板;以及一濾有害藍光鍍膜層,結合於該基板的其中一面,其中,該濾有害藍光鍍膜層係17層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其中該高折射率鍍膜為五氧化二鉭(Ta2O5),該低折射率鍍膜為氟化鎂(MgF2),而該週期性結構每一層的厚度自相鄰空氣的一端起算,依序為13.43奈米、75.74奈米、42.62奈米、52.74奈米、41.00奈米、67.59奈米、40.92奈米、56.80奈米、38.89奈米、63.00奈米、36.68奈米、62.97奈米、43.46奈米、59.25奈米、46.04奈米、57.63奈米、34.52奈米,使該濾光元件於波長範圍介於320至380奈米之紫外光的平均反射率為99.81%,於波長範圍介於415奈米至455奈米之有害藍光的平均反射率為21.44%,於波長範圍介於500奈米至780奈米之光的平均反射率1.79%。 A blue light filter component comprising: a substrate; and a filter harmful blue light coating layer bonded to one side of the substrate, wherein the filter harmful blue light coating layer is a layer of 17 layers of alternating high refractive index coating and a low a periodic structure formed by a refractive index coating, wherein the high refractive index coating is tantalum pentoxide (Ta 2 O 5 ), and the low refractive index coating is magnesium fluoride (MgF 2 ), and the periodic structure is each layer The thickness is from the end of the adjacent air, in order of 13.43 nm, 75.74 nm, 42.62 nm, 52.74 nm, 41.00 nm, 67.59 nm, 40.92 nm, 56.80 nm, 38.89 nm, 63.00 Nai Meter, 36.68 nm, 62.97 nm, 43.46 nm, 59.25 nm, 46.04 nm, 57.63 nm, 34.52 nm, the average of the filter elements in the ultraviolet range of wavelengths between 320 and 380 nm The reflectance is 99.81%, the average reflectance of harmful blue light in the wavelength range from 415 nm to 455 nm is 21.44%, and the average reflectance of light in the wavelength range from 500 nm to 780 nm is 1.79%. 一種藍光之濾光元件,包含:一基板;以及一濾有害藍光鍍膜層,結合於該基板的其中一面,其中,該濾有害藍光鍍膜層係4層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其中該高折射率鍍膜為二氧化鈦(TiO2),該低折射率鍍膜為氟化鎂(MgF2),而該週期性結構每一層的厚度自相鄰空氣的一端起算,依序為110.74奈米、102.02奈米、16.60奈米、27.44奈米。 A blue light filter element comprising: a substrate; and a filter harmful blue light coating layer bonded to one side of the substrate, wherein the filter harmful blue light coating layer is a layer of 4 layers of alternating high refractive index coating and a low a periodic structure formed by a refractive index coating, wherein the high refractive index coating is titanium dioxide (TiO 2 ), the low refractive index coating is magnesium fluoride (MgF 2 ), and the thickness of each layer of the periodic structure is from adjacent air. The end of the calculation is 110.74 nm, 102.02 nm, 16.60 nm, and 27.44 nm. 一種藍光之濾光元件,包含:一基板;以及 一濾有害藍光鍍膜層,結合於該基板的其中一面,其中,該濾有害藍光鍍膜層係6層交互堆疊之一高折射率鍍膜及一低折射率鍍膜所構成之週期性結構,其中該高折射率鍍膜為二氧化鈦(TiO2),該低折射率鍍膜為氟化鎂(MgF2),而該週期性結構每一層的厚度自相鄰空氣的一端起算,依序為73.21奈米、6.64奈米、37.35奈米、101.15奈米、19.74奈米、26.57奈米。 A blue light filter component comprising: a substrate; and a filter harmful blue light coating layer bonded to one side of the substrate, wherein the filter harmful blue light coating layer is a high-refractive-index coating of 6 layers of alternating layers and a low a periodic structure formed by a refractive index coating, wherein the high refractive index coating is titanium dioxide (TiO 2 ), the low refractive index coating is magnesium fluoride (MgF 2 ), and the thickness of each layer of the periodic structure is from adjacent air. At the end of the calculation, the order is 73.21 nm, 6.64 nm, 37.35 nm, 101.15 nm, 19.74 nm, 26.57 nm.
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