CN105572770A - Antireflection film used in blue-light-proof spectacle lens - Google Patents

Antireflection film used in blue-light-proof spectacle lens Download PDF

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Publication number
CN105572770A
CN105572770A CN201610105323.6A CN201610105323A CN105572770A CN 105572770 A CN105572770 A CN 105572770A CN 201610105323 A CN201610105323 A CN 201610105323A CN 105572770 A CN105572770 A CN 105572770A
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layer
silicon dioxide
blue light
light
present
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CN201610105323.6A
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CN105572770B (en
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侯绪华
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Jiangxi Lanjing Photoelectric Technology Co ltd
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/113Anti-reflection coatings using inorganic layer materials only
    • G02B1/115Multilayers
    • G02B1/116Multilayers including electrically conducting layers
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/113Anti-reflection coatings using inorganic layer materials only
    • G02B1/115Multilayers

Abstract

The antireflection film used in the blue-light-proof spectacle lens has natural appearance, simple manufacturing process and low production cost, sequentially comprises a first silicon dioxide layer, a first zirconium oxide layer, a second silicon dioxide layer, a first titanium oxide layer, a first aluminum oxide layer, a second zirconium dioxide layer, a first silicon carbonate layer, a second titanium dioxide layer, a second silicon carbonate layer, a second aluminum oxide layer and a third silicon dioxide layer according to the sequence of being far away from the lens substrate, and further comprises a conducting layer formed by indium tin oxide.

Description

The antireflecting film used in a kind of anti-blue light lens
Technical field
The present invention relates to a kind of antireflecting film, particularly relate to the antireflecting film used in a kind of anti-blue light lens.
Background technology
In prior art, the research of anti-blue light lens is like a raging fire, and especially along with the development of Internet technology, the anti-radiation glasses comprising anti-blue light ultraviolet radiation preventing is used widely.Generally, visible light wave range is approximately the spectral range from the wavelength of 380 nanometers (nm) to the wavelength of 780nm.The part of about 380nm to about 500nm corresponds essentially to high energy blue light.Blue light is very large to the especially amphiblestroid infringement of human eye, if the long-time exposure of human eye may cause serious ophthalmology disease, such as age-related maculopathy under blue light, seriously even causes human eye blind.But, health is but conducive to for 465nm to the 495nm part in above-mentioned blue wave band, because relevant to human biological's cycle, can stimulates circulation.What existing safety goggles against radiation filtered generally includes ultraviolet light and most of short-wave band visible ray.And rarely have in prior art and retain higher than the anti-blue light glasses of 465nm, its reason is at this wave band narrower, filter 450nm and more short wavelength time, can't help the blue light just having filtered more than 465nm.The high-reflecting film used in existing anti-blue light glasses or optical filter are all wide area type diaphragm usually, because Narrowband Spectral High-Reflectivity Filter Multilayers or the optical filter process when vacuum evaporation deposits is very long and complicated, manufacturing cost is high.On the other hand, even if use narrow band pass filter, the harmful blue light of coming from lens front surface reflection is filtered, but the indirect light being derived from wearer rear then can reflex in the eye of eyeglass wearer in an identical manner, these arrive wearers amphiblestroid harmful blue light luminous flux can and front incidence suitable, cause blue light to injure to wearer's eyes.
As everyone knows, in anti-harmful blue light eyeglass, front and rear surfaces can apply UV coating, in order to absorb UV light, also has the coating of some other functions, such as impact-resistant coating, wear-resistant coating, anti-reflection coating, antistatic coating, polarizing coating and anti-pollution layer and/or antifogging coating etc., and this transparent substrate be made up of organic resin or glass as one of eyeglass, the materials such as such as thermoplastic polymer are made.
The described thermoplastic for using in the substrate, such as (methyl) acrylate copolymer, tygon (methyl methacrylate) (PMMA), sulfo-(methyl) acrylic acid, polyvinyl butyral (PVB), polycarbonate (PC), polyurethane (PU), tygon (thioxanthamide), polyvalent alcohol allyl carbonate, Ethylene/vinyl acetate, also such as polyethylene terephthalate (PET) or polybutylene terephthalate (PBT), many episulfide compounds, polyepoxide, the multipolymer of polycarbonate and polyester, the multipolymer of cyclenes copolymer such as ethene and norborene or the multipolymer of ethene and cyclopentadiene, and their combination etc.
In prior art, in order to strengthen the penetrability of anti-blue light lens, usually at the plated surface antireflection film layer of eyeglass.Antireflecting film is also known as anti-reflection film, and its major function is the reflected light reducing or eliminating lens surface, thus increases light transmission capacity, reduces or eliminates the parasitic light of system.The requirement reducing blue light injury and increase transmittance often can not get both, and attends to one thing and lose sight of another, shifting, wants to reduce blue light injury, must to sacrifice transmittance as cost.Existing motion proposes at such as acrylic acid series substrate front and rear surfaces plated film, comprises antireflecting film or anti-reflection film etc., to reach anti-reflection effect while anti-blue light injury.Namely adopt the structure that this front and rear surfaces film system is different, front surface rete efficiently prevents blue light to the injury of human eye, and rear surface rete increases the transmitance of eyeglass, reaches anti-reflection effect.
For anti-reflection film, prior art generally uses green antireflective coating, this is because green anti-reflection rete is more prone to control, even if antireflection film layer layer thickness error is larger, but little for Film color impact, this be also at present on the market with the eyeglass of antireflection rete under daylight lamp irradiates, seem mostly in green or blue reason, if add antireflective coating in anti-blue light lens, this impacts outward appearance.Not yet there is the natural anti-blue light lens of outward appearance with antireflective coating on the market at present.
The problem that the present invention studies just is to provide the antireflecting film used in the natural anti-blue light lens of a kind of outward appearance.
Summary of the invention
In view of above-mentioned technical matters, the object of the present invention is to provide a kind of outward appearance nature, manufacturing process is simple, the antireflecting film used in the anti-blue light lens that production cost is low.
Lens antireflecting film provided by the invention is by the order away from eyeglass substrate, comprise the first silicon dioxide layer 1, first zirconia layer 2, second silicon dioxide layer 3, first titanium oxide layer 4, first alumina layer 5, second zirconia layer 6, first carbonic acid silicon layer 7, second titanium oxide layer 8, second carbonic acid silicon layer 9, second alumina layer 10, the 3rd silicon dioxide layer 11 successively, in addition, the conductive layer that tin indium oxide is formed also is comprised.
As above-mentioned lens antireflecting film, it is characterized in that, this antireflecting film is used for anti-blue light glasses.
According to the present invention, this antireflecting film comprises at least one high refractive index layer and at least one low-index layer.Be formed as 7 layers ~ 11 Rotating fields, high refractive index layer and low-index layer can alternative stacked, also can not alternative expression lamination.In the present invention, described high index of refraction refers to refractive index higher than 1.70, and low-refraction refers to refractive index lower than 1.47, and they all refer to the refractive index for 550nm wavelength under normal temperature.
According to the present invention, material such as zirconia (ZrO2), titanium dioxide (TiO2), aluminium oxide (Al2O3), tantalum pentoxide (Ta2O5) etc. that described high refractive index layer adopts, material such as silicon dioxide (SiO2) or silicon dioxide and alumina mixture etc. that low-index layer adopts.The skin normally low-index layer of antireflecting film of the present invention, preferably adopts silicon dioxide (SiO2) as outer.
According to the present invention, have employed carbonic acid silicon as low-refraction layer material, not yet find pertinent literature to report at present.Adopt carbonic acid silica-based in following consideration, first, carbonic acid silicon is a kind of material preferably diseases such as angiocardiopathy, skin disease, obesity to certain curative effect, and be present in the collagen of human body, if can effective integration carbonic acid silicon be wholesome in antireflective film, secondly, carbonic acid silicon has the characteristic of class pottery, so be widely used as in abrasive substance, if attempt the low-index layer material being applied to antireflective film, reflectivity not only can be made greatly to reduce, also there is stronger compressive strength.But carbonic acid silicon is the mineral compound that a kind of chemical property is not bery stable, so should try not to destroy its chemical form when depositing.Through the careful thinking of applicant and diligent test, really find that its antireflective effect is very outstanding, this may be relevant with its reticulate texture.Especially combinationally use with alumina layer, play antireflective effect remarkable, and no longer present green and blueness under light irradiates, but close to colourless.
According to the present invention, also combine at least one deck conductive layer, for release electrostatic at this antireflective film skin.This conductive adopts tin indium oxide (ITO) to make.
According to the present invention, not only can effectively anti-harmful blue light, protection wearer eyes, and can also visual contrast be improved, transmission is increased to the light of the vision protections such as green.
Accompanying drawing explanation
Fig. 1 is for illustrating antireflecting film structural representation of the present invention.
Embodiment
As shown in Figure 1, lens antireflecting film provided by the invention is by the order away from eyeglass substrate 100, comprise the first silicon dioxide layer 1, first zirconia layer 2, second silicon dioxide layer 3, first titanium oxide layer 4, first alumina layer 5, second zirconia layer 6, first carbonic acid silicon layer 7, second titanium oxide layer 8, second carbonic acid silicon layer 9, second alumina layer 10, the 3rd silicon dioxide layer 11 successively, in addition, the conductive layer 12 that tin indium oxide is formed also is comprised.
In the present invention, this antireflecting film is used for anti-blue light glasses.
According to the present invention, this antireflecting film comprises at least one high refractive index layer and at least one low-index layer.Be formed as 7 layers ~ 11 Rotating fields, high refractive index layer and low-index layer can alternative stacked, also can not alternative expression lamination.In the present invention, described high index of refraction refers to refractive index higher than 1.70, and low-refraction refers to refractive index lower than 1.47, and they all refer to the refractive index for 550nm wavelength under normal temperature.
According to the present invention, material such as zirconia (ZrO2), titanium dioxide (TiO2), aluminium oxide (Al2O3), tantalum pentoxide (Ta2O5) etc. that described high refractive index layer adopts, material such as silicon dioxide (SiO2) or silicon dioxide and alumina mixture etc. that low-index layer adopts.The skin normally low-index layer of antireflecting film of the present invention, preferably adopts silicon dioxide (SiO2) as outer.
According to the present invention, have employed carbonic acid silicon as low-refraction layer material, especially combinationally use with alumina layer, the antireflective effect played is remarkable, and no longer presents green and blueness under light irradiates, but close to colourless.
According to the present invention, also combine at least one deck conductive layer, for release electrostatic at this antireflective film skin.This conductive adopts tin indium oxide (ITO) to make.
In the present invention, each rete of described antireflecting film is all completed by evaporation in vacuum coating equipment, for conductive layer, adopts ion beam or electron beam-induced deposition.Vacuum vapour deposition and ion beam or electron beam process depositing operation are the processing technologys of comparative maturity in prior art, and the present invention can adopt technique in these prior aries to realize, and reflectance spectrum also can be designed by professional software of the prior art.
According to the present invention, not only can effectively anti-harmful blue light, protection wearer eyes, and can also visual contrast be improved, transmission is increased to the light of the vision protections such as green.
Be described in detail the present invention by embodiment above, but it should be noted that, the present invention is not limited to this specific embodiment, and the present invention can carry out various modification and change on this basis.Allly do not depart from the equivalents such as any amendment that the spirit and principles in the present invention do, all should be included within protection scope of the present invention.

Claims (2)

1. a lens antireflecting film, by the order away from eyeglass substrate, comprise the first silicon dioxide layer, the first zirconia layer, the second silicon dioxide layer, the first titanium oxide layer, the first alumina layer, the second zirconia layer, the first carbonic acid silicon layer, the second titanium oxide layer, the second carbonic acid silicon layer, the second alumina layer, the 3rd silicon dioxide layer successively, in addition, the conductive layer that tin indium oxide is formed also is comprised.
2. lens antireflecting film as claimed in claim 1, is characterized in that, this antireflecting film is used for anti-blue light glasses.
CN201610105323.6A 2016-02-25 2016-02-25 Antireflection film used in blue-light-proof spectacle lens Active CN105572770B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107422402A (en) * 2016-05-24 2017-12-01 蓝思科技股份有限公司 A kind of damage resistant hyaline membrane and preparation method thereof
CN107728239A (en) * 2017-11-24 2018-02-23 江苏康耐特光学有限公司 A kind of anti-blue light anti-dazzle plated film resin lens and preparation method thereof
CN107957600A (en) * 2018-01-17 2018-04-24 江苏康耐特光学有限公司 A kind of anti-reflection anti-infrared plated film resin lens and preparation method thereof
CN108318944A (en) * 2018-02-07 2018-07-24 无锡奥芬光电科技有限公司 A kind of resin anti-reflection film and preparation method thereof
CN109588061A (en) * 2016-08-11 2019-04-05 Lg伊诺特有限公司 Camera module
CN110187425A (en) * 2019-05-06 2019-08-30 厦门大学 Material with anti-blue light function and the protective film using the material

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CN101529311A (en) * 2006-08-23 2009-09-09 高效光学技术有限公司 System and method for selective light inhibition
CN202771111U (en) * 2012-04-26 2013-03-06 曾勇 Radiation resistant spectacles
CN203519943U (en) * 2013-10-25 2014-04-02 上海伟星光学有限公司 Film-coated blue-ray-preventing resin lens
CN203688926U (en) * 2013-12-31 2014-07-02 上海希尔康光学眼镜有限公司 Blue-ray film resin eyeglasses
WO2015079087A1 (en) * 2013-11-27 2015-06-04 Indo Optical S.L. Ophthalmic lens comprising a base of polymeric material with a coating having an interferential, anti-reflective, anti-iridescent and ir filter multiple layer structure.
CN104704420A (en) * 2012-10-11 2015-06-10 埃西勒国际通用光学公司 Photochromic ophthalmic lens

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CN1564052A (en) * 2004-04-12 2005-01-12 温州众生科技有限公司 Health lens for preventing blue light harm and its mfg. method
CN101529311A (en) * 2006-08-23 2009-09-09 高效光学技术有限公司 System and method for selective light inhibition
CN202771111U (en) * 2012-04-26 2013-03-06 曾勇 Radiation resistant spectacles
CN104704420A (en) * 2012-10-11 2015-06-10 埃西勒国际通用光学公司 Photochromic ophthalmic lens
CN203519943U (en) * 2013-10-25 2014-04-02 上海伟星光学有限公司 Film-coated blue-ray-preventing resin lens
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107422402A (en) * 2016-05-24 2017-12-01 蓝思科技股份有限公司 A kind of damage resistant hyaline membrane and preparation method thereof
CN109588061A (en) * 2016-08-11 2019-04-05 Lg伊诺特有限公司 Camera module
CN109588061B (en) * 2016-08-11 2021-03-26 Lg伊诺特有限公司 Camera device module
US10996462B2 (en) 2016-08-11 2021-05-04 Lg Innotek Co., Ltd. Camera module
US11435574B2 (en) 2016-08-11 2022-09-06 Lg Innotek Co., Ltd. Camera module
CN107728239A (en) * 2017-11-24 2018-02-23 江苏康耐特光学有限公司 A kind of anti-blue light anti-dazzle plated film resin lens and preparation method thereof
CN107957600A (en) * 2018-01-17 2018-04-24 江苏康耐特光学有限公司 A kind of anti-reflection anti-infrared plated film resin lens and preparation method thereof
CN107957600B (en) * 2018-01-17 2020-08-21 江苏康耐特光学有限公司 Anti-reflection anti-infrared coated resin lens and preparation method thereof
CN108318944A (en) * 2018-02-07 2018-07-24 无锡奥芬光电科技有限公司 A kind of resin anti-reflection film and preparation method thereof
CN110187425A (en) * 2019-05-06 2019-08-30 厦门大学 Material with anti-blue light function and the protective film using the material

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