CN107727533A - Become the identification of caliber water-oil emulsion fluidised form and composition detection experimental system - Google Patents

Become the identification of caliber water-oil emulsion fluidised form and composition detection experimental system Download PDF

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Publication number
CN107727533A
CN107727533A CN201711048368.5A CN201711048368A CN107727533A CN 107727533 A CN107727533 A CN 107727533A CN 201711048368 A CN201711048368 A CN 201711048368A CN 107727533 A CN107727533 A CN 107727533A
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China
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fully
pipeline
test section
oil
water mixture
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梅宁
张继
赵健
袁瀚
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Ocean University of China
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Ocean University of China
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N11/00Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00Investigating or analyzing materials by the use of thermal means
    • G01N25/20Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analyzing Materials Using Thermal Means (AREA)

Abstract

The present invention relates to the profit of oil and chemical process to transport field, especially a kind of to become the identification of caliber water-oil emulsion fluidised form and composition detection experimental system.Including oil water mixture circulation portions, hot fluid circulation portion and data collection and analysis portion, hot fluid circulation portion, data collection and analysis portion are connected with oil water mixture circulation portions respectively;The oil water mixture circulation portions include inducer, test section, oil water mixture container and circulating pump, inducer is made up of the different abundant development pipeline I of diameter and fully development pipeline II, fully one end of development pipeline I and oil water mixture reservoir, fully the other end of development pipeline I is connected with fully development pipeline II, fully development pipeline II is connected with test section, test section is long straight tube, and circulating pump is provided with the port of export of oil water mixture container.It realizes the detection to oil water mixture component, and can determine the liquid condition and rheological behavior of oil water mixture.

Description

Become the identification of caliber water-oil emulsion fluidised form and composition detection experimental system
Technical field
The present invention relates to the profit of oil and chemical process to transport field, especially a kind of to become caliber water-oil emulsion fluidised form Identification and composition detection experimental system.
Background technology
The oil water mixing proportional of water-oil emulsion is different to cause fluid to have Newtonian fluid property and non-newtonian flow volume property, Two kinds of kenels of water-in-oil type (W/O) and oil-in-water type (O/W) be present.Profit breast in the gathering line and submerged pipeline of offshore oil The presence of shape liquid or the phase inversion of the stability change of emulsion and emulsion can all bring many problems, such as oil to production If emulsion stability is destroyed in bag aqueous emulsion, or because the pressure drop of tube runs process is anxious caused by phase inversion occurs Play rise, may cause the generation of the accidents such as oil pipe stopping transportation and cohesion.Simultaneously as water-in-oil type (W/O) and oil-in-water type (O/ W) the emulsus fluid viscosity of two kinds of phases differs greatly, thus it transmits and transports performance and have very big difference.Therefore, real-time online Oil water mixture component in signal piping is also urgent need to solve the problem in engineering with the profit liquid condition determined in pipeline. For separation process for ocean platform and ship oil-water separation device, oil water mixture before separation, separation neutralize separation Afterwards, fluid mixture has different fluid properties, i.e. Newtonian fluid property or non-newtonian flow volume property.Therefore, profit is understood The rheological behavior of mixture and the composition composition in pipeline, to oily water separating equipment efficiently separate and water-oil emulsion Transport system designs, and has certain project reference value.
The content of the invention
It is an object of the invention to solve the above-mentioned problems in the prior art, it is proposed that one kind becomes caliber profit emulsus Liquid stream state identifies and composition detection experimental system, and it realizes the detection to oil water mixture component, and can determine that profit mixes The liquid condition and rheological behavior of compound.
The technical scheme is that:One kind becomes the identification of caliber water-oil emulsion fluidised form and composition detection experimental system, its In, including oil water mixture circulation portions, hot fluid circulation portion and data collection and analysis portion, hot fluid circulation portion, data acquisition point Analysis portion is connected with oil water mixture circulation portions respectively;
The oil water mixture circulation portions include inducer, test section, oil water mixture container and circulating pump, inducer by The different abundant development pipeline I of diameter and fully development pipeline II form, and the one end and oil water mixture for fully developing pipeline I hold Device is connected, and the other end for fully developing pipeline I is connected with fully development pipeline II, is fully developed pipeline II and is connected with test section, Test section is long straight tube, and circulating pump is provided with the port of export of oil water mixture container;
Pitot tube is mounted in the fully development pipeline I and abundant development pipeline II, in fully development pipeline I and is filled The porch of distribution exhibition pipeline II is mounted on pressure testing point, fully develops pipeline I and fully development pipeline II both ends are pacified Equipped with pressure obtaning device, differential pressure transmitter is connected between the pressure obtaning device at both ends;
The outside of the test section is provided with hot fluid circulation portion, and hot fluid circulation portion includes constant water bath box, and test section is arranged on In constant water bath box, test section is connected with data acquisition portion.The oil water mixture in test section is carried out by constant water bath box Heating, by changing external environment condition, obtain the hot physical property delta data of oil water mixture when temperature field changes.
The data acquisition portion includes a diameter of thermocouple, temperature data modular converter and computer, close to test section Exit, along the several thermocouples of radially uniform setting of test section inner surface, the angle phase between the probe of neighboring thermocouple Together, the probe tip of thermocouple increases successively apart from the distance of tube hub, and thermocouple electrically connects with temperature data modular converter, temperature Degrees of data modular converter is with calculating mechatronics.
Preferably, along three thermocouples of radially uniform setting of test section inner surface, respectively thermocouple I, thermocouple II With thermocouple III, the angle between the probe of neighboring thermocouple is 120 °, and the probe tip of three thermocouples is apart from tube hub Distance increase successively.Thermocouple probe position depending on pipe diameter size, using near wall, pipe upper lower half, caliber center as Preferably.
The temperature data modular converter uses the temperature measurement module of model Yanhua ADAM 4118.Heat convection temperature fluctuation Scope is no more than 100 DEG C.
The data collection and analysis portion also includes NI data acquisition equipments, and NI data acquisition equipments are used to gather inducer The signals such as pressure, pressure difference, NI data acquisition equipments are connected with computer.
Beneficial effects of the present invention:
(1) by making profit fluid respectively flow through the different abundant development pipeline of diameter and test pipeline, in reducing process The middle rheological behavior for determining profit fluid, so that it is determined that different heat convection governing equations, so as to the different rheological equationms of state Fluid establishes suitable mathematical modeling;
(2) by hot fluid circulation system, it can be heated with convection body and gather internal fluid temperature field, so as to according to engineering Inverse Problem Method determines water-oil emulsion component.
Brief description of the drawings
Fig. 1 is the attachment structure schematic diagram of the present invention;
Fig. 2 is the structural representation of inducer;
Fig. 3 is the distribution schematic diagram of thermocouple.
In figure:1 oil water mixture container;2 circulating pumps;3 inducers;301 fully develop pipeline I;302 fully develop pipeline Ⅱ;4 constant water bath box;5 thermocouples;501 thermocouples I;502 thermocouples II;503 thermocouples III;6 temperature data converters;7 meters Calculation machine;8 Pitot tubes;9 pressure testing points;10 differential pressure transmitters;11 test sections.
Embodiment
The present invention is further illustrated with reference to the accompanying drawings and examples.
As shown in figure 1, change caliber water-oil emulsion fluidised form identification of the present invention and composition detection experimental system include Oil water mixture circulation portions, hot fluid circulation portion and data collection and analysis portion, hot fluid circulation portion, data collection and analysis portion difference It is connected with oil water mixture circulation portions, hot fluid circulation portion is mainly used in heating the oil water mixture circulatory system, data Collection analysis portion is mainly used in collecting the parameter of oil water mixture circulation portions, such as temperature, pressure, pressure difference data.
Oil water mixture circulation portions include inducer, test section 11, oil water mixture container 1 and circulating pump 2, inducer One end is connected with the port of export of oil water mixture container 1, and the other end of inducer is connected with test section 11, test section 11 it is another End connects with the entrance of oil water mixture container 1, is provided with circulating pump 2 in the port of export of oil water mixture container 1, passes through circulation Pump 2 realizes oil water mixture circulating in system.Rheological Index calculates, fluidised form identifies and emulsion fluid temperature field Change all occurs in this part.
Due to the liquid mixture that the working fluid is different oil-water ratios, the determination of entrance length according to actual conditions come It is determined that the setting of the length of inducer has to meet that test fluid turns into full-blown laminar flow shape before test section is entered State.In order to obtain the rheological coefficient of fluid by flow velocity and pressure-drop in pipeline, inducer is by the different abundant development pipeline I of diameter 301 form with fully development pipeline II 302, and fully development pipeline I 301 and fully development pipeline II 302 being made by copper pipe.Fill The diameter and length of distribution exhibition pipeline I 301 and abundant development pipeline II 302 are mainly fully sent out depending on the project situation of reality One end of exhibition pipeline I 301 connects with oil water mixture container 1, fully develops the other end and fully development pipeline of pipeline I 301 II 302 connections, fully develop pipeline II 302 and be connected with test section 11.The determination of entrance length determines according to actual conditions, But the setting of the fully length of development pipeline II 302 has to meet that test fluid turns into full-blown before bringing-up section is entered Laminar condition, its shortest length are
L=0.05RePrd,
Wherein l represents entrance length, and Re represents fluid Reynolds number, and Pr represents tube fluid Prandtl number, and d represents that caliber is straight Footpath.
Pitot tube 8 fully is mounted in development pipeline I 301 and abundant development pipeline II 302, is surveyed by Pitot tube 8 Measure refrigerant flow rate.Pressure testing point 9 is mounted in the porch of fully development pipeline I 301 and fully development pipeline II 302, For measuring the pressure in pipeline, meanwhile, the both ends for fully developing pipeline I 301 and fully development pipeline II 302 are mounted on taking Pressure device, pressure obtaning device are connected by connecting pipe with differential pressure transmitter 10, and changing the measurement fluid of device 10 by differential pressure flows separately through Fully development pipeline I 301 and the fully pressure drop of development pipeline II 302, as shown in Figure 2.Measured according to two sections of fully development pipelines Flow velocity, pressure drop data can determine the rheological coefficient of oil water mixture.
Test section 11 is long straight length, it is therefore an objective to final profit component is tried to achieve according to the thermal physical property data of change.Test The outside of section 11 is provided with hot fluid circulation portion.Hot fluid circulation portion includes constant water bath box 4, constant temperature water tank and circulating pump, test section 11 It is arranged in constant water bath box 4.The warm water in constant temperature water tank is sent constantly into constant water bath box 4 by circulating pump, passes through perseverance Warm water bath cabinet 4 heats to the oil water mixture in test section 11, by changing external environment condition, obtains oil when temperature field changes The hot physical property delta data of aqueous mixtures.
Test section 11 is also to be made up of copper pipe, and the Temporal Temperature Fields in test section after being heated by constant water bath box 4 lead to Cross data collection and analysis portion and carry out data acquisition, data acquisition portion includes a diameter of 1mm K-type thermocouple, temperature data conversion Module 6 and computer 7.As shown in figure 3, in the exit of close test section 11, along radially uniform the setting of the inner surface of test section 11 Three thermocouples, respectively thermocouple I 501, thermocouple II 502 and thermocouple III 503 are put, between the probe of neighboring thermocouple Angle is 120 °.The probe tip of three thermocouples increases successively apart from the distance of tube hub, and purpose is more accurate in order to obtain Radial temperature field, thermocouple location is advisable depending on pipe diameter size with upper lower half, caliber center near wall, pipe.At this In embodiment, the distance of thermocouple I 501 and tube hub is 1.6mm, and the distance of thermocouple II 502 and tube hub is 2.4mm, heat The distance of galvanic couple III 503 and tube hub is 3.2mm.The burial place of thermocouple uses apart from copper pipe exit 80mm when embedded Laser scanner is corrected to positional precision, and the temperature data that thermocouple collects is changed by temperature data modular converter 6 Afterwards, synchronized upload is to computer 7, according to indirect problem technology on-line prediction profit working medium component.Thermocouple is carried out before the use Calibration, measurement error is no more than ± 0.5 DEG C in the range of 0-90 DEG C.In this implementation, temperature data modular converter 6 uses model For the temperature measurement module of Yanhua ADAM 4118.In test section 11, heat convection temperature fluctuation range is no more than 100 DEG C.
Data collection and analysis portion also includes NI data acquisition equipments, and NI data acquisition equipments are used for the pressure for gathering inducer The signals such as power, pressure difference, NI data acquisition equipments are connected with computer 7, and the signal collected is delivered to by NI data acquisition equipments After computer 11, the data measured are converted into by pressure value and pressure difference by LabVIEW softwares, and control needed for gathered data Time.
The operation principle of this experimental system is as described below:Oil water mixture is in the presence of circulating pump 2, in oil water mixture Circulation portions internal circulation flow, by the flow process of inducer, due to abundant development pipeline 301 and testing pipeline 302 Diameter is different, therefore flow velocity, pressure and pressure difference of the oil water mixture in two pipelines are all different, are becoming caliber process In, the rheology characteristic of profit fluid is determined by above-mentioned parameter, so that it is determined that different heat convection governing equations.Profit afterwards After mixture enters test section, oil solution is heated by constant water bath box 4, by data acquisition and analysis system to warp The temperature information for crossing the oil solution of test section carries out data acquisition, is made up of indirect problem technology on-line prediction profit working medium, I.e. using the above-mentioned temperature collected and its rule that changes with time, then by solving heat transfer differential equation come reverse pipe The hot material properties of profit in road, and then determine profit component.

Claims (6)

1. one kind becomes the identification of caliber water-oil emulsion fluidised form and composition detection experimental system, it is characterised in that:Including oil mixing with water Thing circulation portions, hot fluid circulation portion and data collection and analysis portion, hot fluid circulation portion, data collection and analysis portion are mixed with profit respectively Compound circulation portions connect;
The oil water mixture circulation portions include inducer, test section (11), oil water mixture container (1) and circulating pump (2), enter By the different abundant development pipeline I (301) of diameter and fully, development pipeline II (302) forms mouth section, fully develops pipeline I (301) one end connects with oil water mixture container (1), fully develops the other end and fully development pipeline II of pipeline I (301) (302) connect, fully develop pipeline II (302) and be connected with test section (11), test section (11) is long straight tube, in oil water mixture The port of export of container (1) is provided with circulating pump (2);
Pitot tube (8) is mounted in the fully development pipeline I (301) and abundant development pipeline II (302), is fully being developed The porch of pipeline I (301) and fully development pipeline II (302) is mounted on pressure testing point (9), fully develops pipeline I (301) both ends for and fully developing pipeline II (302) are mounted on pressure obtaning device, and differential pressure is connected between the pressure obtaning device at both ends Transmitter (10);
The outside of the test section (11) is provided with hot fluid circulation portion, and hot fluid circulation portion includes constant water bath box (4), test section (11) It is arranged in constant water bath box (4), test section (11) is connected with data acquisition portion.
2. change caliber water-oil emulsion fluidised form identification according to claim 1 and composition detection experimental system, its feature exist In:The data acquisition portion includes a diameter of thermocouple, temperature data modular converter (6) and computer (7), close to test section (11) exit, along the several thermocouples of radially uniform setting of test section (11) inner surface, between the probe of neighboring thermocouple Angle it is identical, the probe tip of thermocouple increases successively apart from the distance of tube hub, thermocouple and temperature data modular converter (6) electrically connect, temperature data modular converter (6) electrically connects with computer (7).
3. change caliber water-oil emulsion fluidised form identification according to claim 2 and composition detection experimental system, its feature exist In:Along three thermocouples of radially uniform setting of test section (11) inner surface, respectively thermocouple I (501), thermocouple II (502) and thermocouple III (503), the angle between the probe of neighboring thermocouple is 120 °, the probe tip of three thermocouples Distance apart from tube hub increases successively.
4. change caliber water-oil emulsion fluidised form identification according to claim 1 and composition detection experimental system, its feature exist In:It is described fully development pipeline II (302) shortest length be
L=0.05RePrd
Wherein l represents fully development pipeline II (302) length, and Re represents fluid Reynolds number, and Pr represents tube fluid Prandtl number, d tables Show caliber diameter.
5. change caliber water-oil emulsion fluidised form identification according to claim 1 and composition detection experimental system, its feature exist In:The temperature data modular converter (6) uses the temperature measurement module of model Yanhua ADAM 4118.
6. change caliber water-oil emulsion fluidised form identification according to claim 1 and composition detection experimental system, its feature exist In:The data collection and analysis portion also includes NI data acquisition equipments, and NI data acquisition equipments are connected with computer (7).
CN201711048368.5A 2017-10-31 2017-10-31 Become the identification of caliber water-oil emulsion fluidised form and composition detection experimental system Pending CN107727533A (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH288778A (en) * 1949-11-25 1953-02-15 Henry Preston Joseph Device for measuring the flow of a fluid in a pipe.
JPS62194441A (en) * 1986-02-21 1987-08-26 Nippon Kokan Kk <Nkk> Apparatus for measuring non-newtonian property in pipeline
CN2114159U (en) * 1991-10-18 1992-08-26 中国矿业大学北京研生部 Multi-capillary viscometer
JPH0674887A (en) * 1992-08-26 1994-03-18 Mitsubishi Heavy Ind Ltd Process viscosity measuring device
US5306734A (en) * 1993-09-08 1994-04-26 Shell Oil Company Use of viscosity as an in-line diagnostic for high internal phase emulsion generation
JP2006258782A (en) * 2005-03-17 2006-09-28 Hikari Sangyo Kk Differential pressure gauge pipe type inline viscosity sensor
CN102374960A (en) * 2010-08-10 2012-03-14 中国石油化工集团公司 Variable-diameter-tube drilling fluid rheology measuring method
CN103115849A (en) * 2013-01-21 2013-05-22 江苏大学 Device for testing all-flow resistance reduction characteristic of high-molecular polymer solution
CN207457002U (en) * 2017-10-31 2018-06-05 中国海洋大学 Become the identification of caliber water-oil emulsion fluidised form and composition detection experimental system

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH288778A (en) * 1949-11-25 1953-02-15 Henry Preston Joseph Device for measuring the flow of a fluid in a pipe.
JPS62194441A (en) * 1986-02-21 1987-08-26 Nippon Kokan Kk <Nkk> Apparatus for measuring non-newtonian property in pipeline
CN2114159U (en) * 1991-10-18 1992-08-26 中国矿业大学北京研生部 Multi-capillary viscometer
JPH0674887A (en) * 1992-08-26 1994-03-18 Mitsubishi Heavy Ind Ltd Process viscosity measuring device
US5306734A (en) * 1993-09-08 1994-04-26 Shell Oil Company Use of viscosity as an in-line diagnostic for high internal phase emulsion generation
JP2006258782A (en) * 2005-03-17 2006-09-28 Hikari Sangyo Kk Differential pressure gauge pipe type inline viscosity sensor
CN102374960A (en) * 2010-08-10 2012-03-14 中国石油化工集团公司 Variable-diameter-tube drilling fluid rheology measuring method
CN103115849A (en) * 2013-01-21 2013-05-22 江苏大学 Device for testing all-flow resistance reduction characteristic of high-molecular polymer solution
CN207457002U (en) * 2017-10-31 2018-06-05 中国海洋大学 Become the identification of caliber water-oil emulsion fluidised form and composition detection experimental system

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Title
JI ZHANG等: "Viscosity estimation and component identification for an oil-water emulsion with the inversion method", 《APPLIED THERMAL ENGINEERING》, vol. 111, 25 January 2017 (2017-01-25), pages 2 *

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