CN107722710A - A kind of baking vanish paint removing composition and its preparation method and application - Google Patents

A kind of baking vanish paint removing composition and its preparation method and application Download PDF

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Publication number
CN107722710A
CN107722710A CN201710843016.2A CN201710843016A CN107722710A CN 107722710 A CN107722710 A CN 107722710A CN 201710843016 A CN201710843016 A CN 201710843016A CN 107722710 A CN107722710 A CN 107722710A
Authority
CN
China
Prior art keywords
baking vanish
paint removing
removing composition
paint
phenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710843016.2A
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Chinese (zh)
Inventor
刘卫兵
谭华
陈翠
周鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong University of Petrochemical Technology
Original Assignee
Guangdong University of Petrochemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong University of Petrochemical Technology filed Critical Guangdong University of Petrochemical Technology
Priority to CN201710843016.2A priority Critical patent/CN107722710A/en
Publication of CN107722710A publication Critical patent/CN107722710A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention discloses a kind of baking vanish paint removing composition.The baking vanish paint removing composition includes following component by mass percentage:Urea 2.5 ~ 5%;Metasilicate pentahydrate sodium 1 ~ 3%;Butyl acetate 10 ~ 17%;Phenol 2 ~ 5%;Benzotriazole 0 ~ 1%;Surplus is water.Baking vanish paint removing composition cost provided by the present invention is cheap, pollution is few, the depainting time is short, penetration is strong, can be kept completely separate completely coating and matrix in the short time is, and corrosion-free to matrix, paint removing effect is strong, without dead angle and residual, baking vanish paint removing composition provided by the invention is applicable to the depainting of a variety of different types of baking vanish, can provide technical support for the development of industrial cleaning agent.

Description

A kind of baking vanish paint removing composition and its preparation method and application
Technical field
The invention belongs to industry cleaning link field, more particularly, to a kind of baking vanish paint removing composition and preparation method thereof and Using.
Background technology
Due to baking vanish have it is bright in luster, without stagnant light, not fugitive color, it is personalized strong, can appoint with floor tile wall brick furniture fabrics Anticipate fine and smooth collocation, scrubbing resistance, surface, non-sticky dirt, easily (resistance to) scouring the features such as.Therefore, present baking vanish has been applied to each Field.But the error occurred in the aging or spraying process due to paint film is not up to standard so that this workpiece need reclaim and again Spraying, it is therefore desirable to remove old paint film.The method of past generally use machinery, such as knife is scraped, Manual shovel is except this method is not Only waste time and energy, and easily cause machinery to be, damage on collective surface, in this year, it is different that many kinds also occurs in the market The paint stripper of type, although they are more time saving and energy saving than mechanical depainting, there are many limitations in them, as depainting species has Limit, paint stripping rate are slow.Up to the present, the research of baking vanish paint stripper is related to also in the starting stage, and this is mainly due to roasting The adhesive force of paint is especially strong, and common paint stripper is difficult removing.
Therefore, develop efficiently, and take into account safe, economic, processing conveniently, be provided simultaneously with preferably low to base material corrosion take off It is one of current urgent need to solve the problem to paint agent, is had important practical significance.
The content of the invention
It is an object of the invention to according to deficiency of the prior art, there is provided a kind of baking vanish paint removing composition.It is described roasting Paint paint removing composition has the advantages that, depainting power excellent performance low to base material corrosivity, post processing is easy, and paint stripping rate is fast.
Another object of the present invention is to provide the preparation method of above-mentioned baking vanish paint removing composition.
It is still another object of the present invention to provide above-mentioned baking vanish paint removing composition answering in baking vanish depainting cleaning agent is prepared With.
The purpose of the present invention is achieved through the following technical solutions:
A kind of baking vanish paint removing composition, is made up of component as follows by mass percentage:
Urea 2.5 ~ 5%
Metasilicate pentahydrate sodium 1 ~ 3%
Butyl acetate 10 ~ 17%
Phenol 2 ~ 5%.
BTA 0 ~ 1%
Surplus is water.
In the baking vanish paint removing composition of the invention formed by urea, sodium metasilicate, butyl acetate, phenol, it can be penetrated into Enter the interface that base material is connected with paint film, and the connection destroyed between base material and paint film, so that paint film is completely from matrix Separation, and paint film is completely insoluble in this paint stripper, so as to obtain good paint removing effect.Simultaneously as paint film does not pass through The mode of dissolving, but so that paint film completely disengages with matrix in a manner of monoblock comes off.So, can be easily by paint film It is kept completely separate out from the paint-removing liquid of baking vanish paint removing composition composition, depainting combination liquid is recycled, and can be more More preferable paint removing effect is obtained in the short time.
Composition is corrosion-free to matrix material integrally in neutrality, therefore so that paint stripper of the present invention is good in paint removing effect Protect base material simultaneously.
Preferably, the baking vanish paint removing composition is made up of component as follows by mass percentage:
Urea 2.5 ~ 5%
Metasilicate pentahydrate sodium 1 ~ 3%
Butyl acetate 10 ~ 17%
Phenol 2 ~ 5%
BTA 0.5 ~ 1%
Surplus is water.
The addition of BTA can further lift paint removing effect.
More electedly, the baking vanish paint removing composition is made up of component as follows by mass percentage:
Urea 3.5 ~ 5%
Metasilicate pentahydrate sodium 1%
Butyl acetate 16%
Phenol 2 ~ 3.5%
BTA 0.5 ~ 1%
Surplus is water.
The preparation method of the baking vanish paint removing composition, comprises the following steps:Each component is well mixed and produces described bake Paint paint removing composition.
Application of the described baking vanish paint removing composition in baking vanish depainting cleaning agent is prepared.
Preferably, the baking vanish is epoxy resin, polyurethane or acrylate, and polyflon is as Main Ingredients and Appearance Baking vanish.
It is highly preferred that the baking vanish is the baking vanish of polyurethane or acrylate as Main Ingredients and Appearance.It is of the present invention Baking vanish paint removing composition handles polyurethane or during acrylate, can it is at 5 minutes in can make coating and matrix complete completely Separation;Being directed to the coating that epoxy resin, polyflon etc. are difficult to elute also has good elution effect.
Compared with prior art, the present invention has advantages below and beneficial effect:
Baking vanish paint removing composition cost provided by the present invention is cheap, definitely green, and pollution is few, and the depainting time is short, infiltration Power is strong, can be kept completely separate completely coating and matrix in the short time is, and corrosion-free to matrix, and paint removing effect is strong, no dead angle And residual, baking vanish paint removing composition provided by the invention are a kind of universal baking vanish paint removing compositions, be applicable to it is a variety of not The depainting of congener baking vanish, technical support can be provided for the development of industrial cleaning agent.
Embodiment
Further illustrate the present invention below in conjunction with specific embodiment, but embodiment the present invention is not done it is any type of Limit.Unless stated otherwise, the reagent of the invention used, method and apparatus is the art conventional reagent, methods and apparatus.
Unless stated otherwise, agents useful for same and material of the present invention are purchased in market.
The compound method of paint removing composition:Raw material is fed intake according to regulation ratio at room temperature, then stirred with mixer Uniformly, without curing, i.e., with i.e. use.
Embodiment 1:
Base material is zine plate, and zine plate is coated for polyurethane coating.Film thickness is 3mm.
Baking vanish paint removing composition formula is as follows:
Raw material Quality proportioning(%)
Urea 3.5
Metasilicate pentahydrate sodium 1
Butyl acetate 16
Phenol 3.5
Benzotriazole 0.5
Water Surplus
Embodiment 2:
Base material is aluminium sheet, and aluminium sheet is coated for epoxy coating.Film thickness is 3mm.
Baking vanish paint removing composition formula is as follows:
Raw material Quality proportioning(%)
Urea 2.5
Metasilicate pentahydrate sodium 1
Butyl acetate 17
Phenol 2.5
Benzotriazole 1
Water Surplus
Embodiment 3:
Base material is aluminium sheet, and aluminium sheet is coated for acrylate paint.Film thickness is 3mm.
Baking vanish paint removing composition formula is as follows:
Raw material Quality proportioning(%)
Urea 5
Metasilicate pentahydrate sodium 1
Butyl acetate 16
Phenol 2
Benzotriazole 1
Water Surplus
Embodiment 4:
Base material is aluminium sheet, and aluminium sheet is coated for polyflon.Film thickness is 3mm.
Baking vanish paint removing composition formula is as follows:
Raw material Quality proportioning(%)
Urea 5
Metasilicate pentahydrate sodium 3
Butyl acetate 10
Phenol 5
Benzotriazole 0.5
Water Surplus
Comparative example 1:
Base material is zine plate, and zine plate is coated for polyurethane coating.Film thickness is 3mm.
Powdery paints paint removing composition formula is as follows:
Raw material Quality proportioning(%)
Urea 7
Metasilicate pentahydrate sodium 0.5
Butyl acetate 14.5
Phenol 2
Benzotriazole 0.5
Water Surplus
Comparative example 2:
Base material is aluminium sheet, and aluminium sheet is coated for epoxy coating.Film thickness is 3mm.
Powdery paints paint removing composition formula is as follows:
Raw material Quality proportioning(%)
Urea 3.5
Metasilicate pentahydrate sodium 1
Phenol 3.5
Benzotriazole 0.5
Water Surplus
Comparative example 3:
Base material is aluminium sheet, and aluminium sheet is coated for epoxy coating.Film thickness is 3mm.
Powdery paints paint removing composition formula is as follows:
Raw material Quality proportioning(%)
Metasilicate pentahydrate sodium 1
Butyl acetate 16
Phenol 3.5
Benzotriazole 0.5
Water Surplus
Corresponding coating paint film will be prepared on the metal base of embodiment, paint film is prepared with reference to GB/T 1727-1992.It will implement The paint stripper provided in example and comparative example carries out soaking and washing, paint removal efficiency method of testing to paint film:With reference to GB/T 1745-89 《Paint stripper paint removal efficiency determines》Tested.Corrosion situation observes by the naked eye, unchanged to be corrosion-free, appearance Black splotch is slight erosion, and it is heavy corrosion line shape striped occur.
Table 1 is paint removing effect in embodiment and comparative example:
Table 1
Embodiment is numbered t(Depainting)/min Depainting situation Corrosion condition
Embodiment 1 5 Coating paint film completely disengages metal surface Metal surface is corrosion-free
Embodiment 2 25 Coating paint film completely disengages metal surface Metal surface is corrosion-free
Embodiment 3 5 Coating paint film completely disengages metal surface Metal surface is corrosion-free
Embodiment 4 30 Coating paint film completely disengages metal surface Metal surface is corrosion-free
Comparative example 1 8 Coating paint film completely disengages metal surface Metal surface is corrosion-free
Comparative example 2 -- Coating paint film does not occur being swelled and dissolution phenomena, can not depart from metal surface completely Metal surface is corrosion-free
Comparative example 3 -- Coating paint film does not occur being swelled and dissolution phenomena, can not depart from metal surface completely Metal surface is corrosion-free
The cleaning agent cleaning performance provided in the embodiment of the present invention 1 and 3 is very good, and the interior energy of 5 minutes makes polyurethane coating completely Or acrylate paint departs from metallic substrate surface, does not have any corrosion to metal, and dead angle is not stayed, offer of the present invention is provided The paint film cleaning efficiency of paint stripper, degree of cleaning and to having reached good effect in the protection of metal base.
Obviously, above-described embodiment is only to illustrate done citing to be clear, and is not the restriction to embodiment.It is right For those of ordinary skill in the art, various forms of changes or change can also be made on the basis of the above description It is dynamic.There is no necessity and possibility to exhaust all the enbodiments.And that is thus amplified shows and the change of opinion or variation Among the protection domain of the invention.

Claims (7)

1. a kind of baking vanish paint removing composition, it is characterised in that be made up of component as follows by mass percentage:
Urea 2.5 ~ 5%
Metasilicate pentahydrate sodium 1 ~ 3%
Butyl acetate 10 ~ 17%
Phenol 2 ~ 5%
BTA 0 ~ 1%
Surplus is water.
2. baking vanish paint removing composition according to claim 1, it is characterised in that by component group as follows by mass percentage Into:
Urea 2.5 ~ 5%
Metasilicate pentahydrate sodium 1 ~ 3%
Butyl acetate 10 ~ 17%
Phenol 2 ~ 5%
BTA 0.5 ~ 1%
Surplus is water.
3. baking vanish paint removing composition according to claim 1, it is characterised in that by component group as follows by mass percentage Into:
Urea 3.5 ~ 5%
Metasilicate pentahydrate sodium 1%
Butyl acetate 16%
Phenol 2 ~ 3.5%
BTA 0.5 ~ 1%
Surplus is water.
4. the preparation method of any one of the claim 1 ~ 3 baking vanish paint removing composition, it is characterised in that comprise the following steps: Each component is well mixed and produces the baking vanish paint removing composition.
5. application of the baking vanish paint removing composition in baking vanish depainting cleaning agent is prepared described in any one of claim 1 ~ 3.
6. application according to claim 5, it is characterised in that the baking vanish is epoxy resin, polyurethane or acrylate, Baking vanish of the polyflon as Main Ingredients and Appearance.
7. application according to claim 6, it is characterised in that the baking vanish is polyurethane or acrylate as master Want the baking vanish of composition.
CN201710843016.2A 2017-09-18 2017-09-18 A kind of baking vanish paint removing composition and its preparation method and application Pending CN107722710A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710843016.2A CN107722710A (en) 2017-09-18 2017-09-18 A kind of baking vanish paint removing composition and its preparation method and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710843016.2A CN107722710A (en) 2017-09-18 2017-09-18 A kind of baking vanish paint removing composition and its preparation method and application

Publications (1)

Publication Number Publication Date
CN107722710A true CN107722710A (en) 2018-02-23

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CN201710843016.2A Pending CN107722710A (en) 2017-09-18 2017-09-18 A kind of baking vanish paint removing composition and its preparation method and application

Country Status (1)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060258555A1 (en) * 2005-05-12 2006-11-16 The Lubrizol Corporation Oil-in-water emulsified remover
CN104059424A (en) * 2014-06-06 2014-09-24 全椒县友诚塑料利用有限公司 Surface paint cleaning agent for waste plastic and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060258555A1 (en) * 2005-05-12 2006-11-16 The Lubrizol Corporation Oil-in-water emulsified remover
CN104059424A (en) * 2014-06-06 2014-09-24 全椒县友诚塑料利用有限公司 Surface paint cleaning agent for waste plastic and preparation method thereof

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
化工科学技术研究院等: "《全国化工新技术 新产品项目汇编》", 30 April 2000, 化工技术推广交流中心 *
吴俊杰: "《汽车维修油漆喷涂工艺手册》", 31 July 1996, 上海交通大学出版社 *
张仁溥: "苯酚脱漆剂的改进", 《表面技术》 *
李群英: "《涂装工常用技术手册》", 31 July 2008, 上海科学技术出版社 *
毛志伟等: "《氮氧化物减排》", 31 August 2014, 中国建材工业出版社 *
禹茂章等: "《世界精细化工手册 续编》", 31 May 1986, 化学工业部科学技术情报研究所 *
葛娣: "食品罐用镀锡钢板的环保型脱漆剂研究", 《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》 *

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Application publication date: 20180223

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