CN107902916A - A kind of preparation method of self-cleaning glass - Google Patents
A kind of preparation method of self-cleaning glass Download PDFInfo
- Publication number
- CN107902916A CN107902916A CN201711109111.6A CN201711109111A CN107902916A CN 107902916 A CN107902916 A CN 107902916A CN 201711109111 A CN201711109111 A CN 201711109111A CN 107902916 A CN107902916 A CN 107902916A
- Authority
- CN
- China
- Prior art keywords
- glass
- self
- parts
- preparation
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/29—Mixtures
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/76—Hydrophobic and oleophobic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
Abstract
The present invention provides a kind of preparation method of self-cleaning glass, including following operating procedure:(1)After glass surface is cleaned up using ethanol solution, drying and processing;(2)The spray paint immediately of glass surface after the drying, room temperature dry processing 23 it is small when;(3)Step will be passed through(2)The glass of processing is put into baking oven, and drying, is made self-cleaning glass.A kind of preparation method of self-cleaning glass provided by the invention, easy to operate, environmentally protective, obtained self-cleaning glass, anti-pollution characteristic is excellent, can effectively reduce the number of glass cleaning, meanwhile, there is excellent light transmission, do not interfere with the normal use of glass.
Description
Technical field
The invention belongs to glass making techniques field, and in particular to a kind of preparation method of self-cleaning glass.
Background technology
Easy clean glass, is usually commercially also visually known as glass with clean.It is to refer to smear on the glass surface
After one layer of special coating so that dust or dirty liquid(Including aqueous, or even the liquid of oil-containing)All it is difficult to be attached to glass
The surface of glass, or relatively easily by water(Or rainwater)Rinse out, such glass surface is very easy to keep cleaning, reduces
The trouble of cleaning glass surface, can also save increasingly deficient water resource.But some are commercially available with self-cleaning function
Coating, after glass surface drying so that the transparency of glass reduces, and have impact on the use of glass.
The content of the invention
In order to solve the above technical problem, the present invention provides a kind of preparation method of self-cleaning glass.
The present invention is achieved by the following technical solutions.
A kind of preparation method of self-cleaning glass, including following operating procedure:
(1)After glass surface is cleaned up using ethanol solution, drying and processing;
(2)The spray paint immediately of glass surface after the drying, room temperature dry processing 2-3 it is small when, wherein coating is by following weight
The component of part is made:18-22 parts of water-based fluorocarbon resin emulsion, 34-38 parts of water-based acrylic resin lotion, the fluoro- 4- methylbenzenes of 2-
5-8 parts of formaldehyde, 3-6 parts of two molybdic acid hydrate sodium, 1-2 parts of 1- sodium heptanesulfonates, 3-5 parts of three silicic acid, two magnesium, 1,2- cyclohexanediamine four
2-5 parts of acetic acid;
(3)Step will be passed through(2)The glass of processing is put into baking oven, and drying, is made self-cleaning glass.
Specifically, above-mentioned steps(1)In, the volume fraction of ethanol solution is 75-85%.
Specifically, above-mentioned steps(2)In, the dosage of coating is 300-400g/m2。
Specifically, the purity of above-mentioned three silicic acid, two magnesium is 99%, and the purity of above-mentioned 1,2-cyclohexanediaminetetraacetic acid is 97%.
Specifically, above-mentioned steps(3)In, temperature during oven for drying is 75-80 DEG C.
From the above technical scheme, it can be seen that the beneficial effects of the invention are as follows:
A kind of preparation method of self-cleaning glass provided by the invention, easy to operate, environmentally protective, obtained self-cleaning glass,
Anti-pollution characteristic is excellent, can effectively reduce the number of glass cleaning, meanwhile, there is excellent light transmission, do not interfere with glass
Normal use.Coating provided by the invention, water-based fluorocarbon resin emulsion and the fluoro- 4- tolyl aldehydes of 2-, 1- sodium heptanesulfonates
After synergistic effect, super-hydrophobic surface can be formed in glass surface, water can not be attached completely by glass, allows the table of water droplet in itself
Face tension force produces the phenomenon of drops, and water droplet meeting nature, which slides, takes away dust, glass is possessed easy clean effect, dust also will be unable to
Accumulation, and then the effective automatically cleaning effect for improving glass;And water-based fluorocarbon resin emulsion the translucency of glass is influenced compared with
Greatly, therefore water-based acrylic resin lotion is added, the dosage of water-based fluorocarbon resin emulsion can be effectively reduced, and then ensure that glass
The translucency of glass;Meanwhile three silicic acid, two magnesium and 1,2-cyclohexanediaminetetraacetic acid can effectively lift the uniformity of coating distribution, prevent
Only there is local accumulation and then influences the phenomenon of translucency, and can prevent smearing from forming crackle and showing during brushing in coating
As effectively improving the quality of self-cleaning glass.
Embodiment
Following embodiments are used to illustrate the present invention, but cannot be used for limiting the scope of the invention.The reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of preparation method of self-cleaning glass, including following operating procedure:
(1)After glass surface is cleaned up using ethanol solution, drying and processing;
(2)The spray paint immediately of glass surface after the drying, room temperature dry processing 2 it is small when, wherein coating is by following parts by weight
Component be made:18 parts of water-based fluorocarbon resin emulsion, 34 parts of water-based acrylic resin lotion, 5 parts of the fluoro- 4- tolyl aldehydes of 2-,
Two 3 parts of molybdic acid hydrate sodium, 1 part of 1- sodium heptanesulfonates, 3 parts of three silicic acid, two magnesium, 2 parts of 1,2- 1,2-diaminocyclohexane tetraacetic acids;
(3)Step will be passed through(2)The glass of processing is put into baking oven, and drying, is made self-cleaning glass.
Specifically, above-mentioned steps(1)In, the volume fraction of ethanol solution is 75%.
Specifically, above-mentioned steps(2)In, the dosage of coating is 300g/m2。
Specifically, the purity of above-mentioned three silicic acid, two magnesium is 99%, and the purity of above-mentioned 1,2-cyclohexanediaminetetraacetic acid is 97%.
Specifically, above-mentioned steps(3)In, temperature during oven for drying is 75 DEG C.
Embodiment 2
A kind of preparation method of self-cleaning glass, including following operating procedure:
(1)After glass surface is cleaned up using ethanol solution, drying and processing;
(2)The spray paint immediately of glass surface after the drying, room temperature dry processing 2.5 it is small when, wherein coating is by following weight
The component of part is made:20 parts of water-based fluorocarbon resin emulsion, 36 parts of water-based acrylic resin lotion, the fluoro- 4- tolyl aldehydes 7 of 2-
Part, 5 parts of two molybdic acid hydrate sodium, 1 part of 1- sodium heptanesulfonates, 4 parts of three silicic acid, two magnesium, 3 parts of 1,2- 1,2-diaminocyclohexane tetraacetic acids;
(3)Step will be passed through(2)The glass of processing is put into baking oven, and drying, is made self-cleaning glass.
Specifically, above-mentioned steps(1)In, the volume fraction of ethanol solution is 80%.
Specifically, above-mentioned steps(2)In, the dosage of coating is 350g/m2。
Specifically, the purity of above-mentioned three silicic acid, two magnesium is 99%, and the purity of above-mentioned 1,2-cyclohexanediaminetetraacetic acid is 97%.
Specifically, above-mentioned steps(3)In, temperature during oven for drying is 78 DEG C.
Embodiment 3
A kind of preparation method of self-cleaning glass, including following operating procedure:
(1)After glass surface is cleaned up using ethanol solution, drying and processing;
(2)The spray paint immediately of glass surface after the drying, room temperature dry processing 3 it is small when, wherein coating is by following parts by weight
Component be made:22 parts of water-based fluorocarbon resin emulsion, 38 parts of water-based acrylic resin lotion, 8 parts of the fluoro- 4- tolyl aldehydes of 2-,
Two 6 parts of molybdic acid hydrate sodium, 2 parts of 1- sodium heptanesulfonates, 5 parts of three silicic acid, two magnesium, 5 parts of 1,2- 1,2-diaminocyclohexane tetraacetic acids;
(3)Step will be passed through(2)The glass of processing is put into baking oven, and drying, is made self-cleaning glass.
Specifically, above-mentioned steps(1)In, the volume fraction of ethanol solution is 85%.
Specifically, above-mentioned steps(2)In, the dosage of coating is 400g/m2。
Specifically, the purity of above-mentioned three silicic acid, two magnesium is 99%, and the purity of above-mentioned 1,2-cyclohexanediaminetetraacetic acid is 97%.
Specifically, above-mentioned steps(3)In, temperature during oven for drying is 80 DEG C.
Self-cleaning glass is made with the method for each embodiment respectively, then obtained self-cleaning glass comes into operation, looks into
See its resistant effect and light transmission, be commercially available common self-cleaning glass in control group, result of the test is as shown in table 1:
1 self-cleaning glass performance of table
Project | Light transmission | After 3 months, surface contamination situation |
Embodiment 1 | Translucency is good | Surface cleaning is bright |
Embodiment 2 | Translucency is good | Surface cleaning is bright |
Embodiment 3 | Translucency is good | Surface cleaning is bright |
Control group | Translucency is poor | Surface cleaning, luminance range |
As shown in Table 1, self-cleaning glass produced by the present invention, has excellent self-cleaning performance and excellent light transmission, pole
The earth improves the quality of self-cleaning glass.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved or converted according to the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention
Protect scope.
Claims (5)
1. a kind of preparation method of self-cleaning glass, it is characterised in that including following operating procedure:
(1)After glass surface is cleaned up using ethanol solution, drying and processing;
(2)The spray paint immediately of glass surface after the drying, room temperature dry processing 2-3 it is small when, wherein coating is by following weight
The component of part is made:18-22 parts of water-based fluorocarbon resin emulsion, 34-38 parts of water-based acrylic resin lotion, the fluoro- 4- methylbenzenes of 2-
5-8 parts of formaldehyde, 3-6 parts of two molybdic acid hydrate sodium, 1-2 parts of 1- sodium heptanesulfonates, 3-5 parts of three silicic acid, two magnesium, 1,2- cyclohexanediamine four
2-5 parts of acetic acid;
(3)Step will be passed through(2)The glass of processing is put into baking oven, and drying, is made self-cleaning glass.
A kind of 2. preparation method of self-cleaning glass according to claim 1, it is characterised in that above-mentioned steps(1)In, second
The volume fraction of alcoholic solution is 75-85%.
A kind of 3. preparation method of self-cleaning glass according to claim 1, it is characterised in that above-mentioned steps(2)In, apply
The dosage of material is 300-400g/m2。
4. the preparation method of a kind of self-cleaning glass according to claim 1, it is characterised in that above-mentioned three silicic acid, two magnesium
Purity is 99%, and the purity of above-mentioned 1,2-cyclohexanediaminetetraacetic acid is 97%.
A kind of 5. preparation method of self-cleaning glass according to claim 1, it is characterised in that above-mentioned steps(3)In, dry
Temperature when case is dried is 75-80 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201711109111.6A CN107902916A (en) | 2017-11-11 | 2017-11-11 | A kind of preparation method of self-cleaning glass |
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CN201711109111.6A CN107902916A (en) | 2017-11-11 | 2017-11-11 | A kind of preparation method of self-cleaning glass |
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CN107902916A true CN107902916A (en) | 2018-04-13 |
Family
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CN201711109111.6A Pending CN107902916A (en) | 2017-11-11 | 2017-11-11 | A kind of preparation method of self-cleaning glass |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110132668A (en) * | 2019-04-28 | 2019-08-16 | 西安培华学院 | A kind of super-hydrophobic processing method of conventional slide |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0826722A2 (en) * | 1996-09-02 | 1998-03-04 | Mitsubishi Plastics Inc. | Fluorocarbon resin sheet and glass laminate |
JPH11269432A (en) * | 1998-03-23 | 1999-10-05 | Central Glass Co Ltd | Microparticle-dispersed coating fluid |
CN101845124A (en) * | 2010-03-23 | 2010-09-29 | 武汉力诺化学集团有限公司 | Water-based hydrophobic nano-resin, glass thermal insulating coating and preparation method |
-
2017
- 2017-11-11 CN CN201711109111.6A patent/CN107902916A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0826722A2 (en) * | 1996-09-02 | 1998-03-04 | Mitsubishi Plastics Inc. | Fluorocarbon resin sheet and glass laminate |
JPH11269432A (en) * | 1998-03-23 | 1999-10-05 | Central Glass Co Ltd | Microparticle-dispersed coating fluid |
CN101845124A (en) * | 2010-03-23 | 2010-09-29 | 武汉力诺化学集团有限公司 | Water-based hydrophobic nano-resin, glass thermal insulating coating and preparation method |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110132668A (en) * | 2019-04-28 | 2019-08-16 | 西安培华学院 | A kind of super-hydrophobic processing method of conventional slide |
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Application publication date: 20180413 |
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