CN107721402A - 一种抗菌型压电材料的制备方法 - Google Patents
一种抗菌型压电材料的制备方法 Download PDFInfo
- Publication number
- CN107721402A CN107721402A CN201711164616.2A CN201711164616A CN107721402A CN 107721402 A CN107721402 A CN 107721402A CN 201711164616 A CN201711164616 A CN 201711164616A CN 107721402 A CN107721402 A CN 107721402A
- Authority
- CN
- China
- Prior art keywords
- parts
- temperature
- antimicrobial form
- preparation
- form piezoelectric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- 238000003756 stirring Methods 0.000 claims abstract description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 15
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004411 aluminium Substances 0.000 claims abstract description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 11
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 11
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 11
- 238000010992 reflux Methods 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 9
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 4
- 235000019441 ethanol Nutrition 0.000 claims description 18
- 125000005909 ethyl alcohol group Chemical group 0.000 claims description 12
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical class [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 10
- 235000015165 citric acid Nutrition 0.000 claims description 8
- 150000008064 anhydrides Chemical class 0.000 claims description 7
- 239000006227 byproduct Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 150000004760 silicates Chemical class 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000463 material Substances 0.000 description 8
- 230000010287 polarization Effects 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- 239000003519 biomedical and dental material Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000002513 implantation Methods 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
- C04B2235/3203—Lithium oxide or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
- C04B2235/3234—Titanates, not containing zirconia
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3239—Vanadium oxides, vanadates or oxide forming salts thereof, e.g. magnesium vanadate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3289—Noble metal oxides
- C04B2235/3291—Silver oxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
本发明公开了一种抗菌型压电材料的制备方法，包括如下步骤：取硅酸铯铝、钛酸镧、五氧化二钒、氧化锌、柠檬酸和无水乙醇，常温加热搅拌至均匀状态；随后在烘箱中干燥、制成粉末，放入马弗炉中在温度500‑550℃下焙烧2‑4h，得前驱体；将纳米二氧化硅和硝酸银加入无水乙醇中，于温度100‑120℃下搅拌回流反应2‑4h；将前驱体加入，升高温度至130‑160℃，以速率500‑800r/min搅拌反应1‑2h；随后将产物过滤、干燥后于温度500‑600℃下保温5‑10min，随后在温度1100‑1200℃下常压烧结3‑5h，即可得到所述抗菌型压电材料。
Description
技术领域
本发明属于电子材料领域，特别涉及一种抗菌型压电材料的制备方法。
背景技术
压电材料是指具有压电效应的材料，其主要的特性是电致伸缩现象，也就是这种材料会因为电流的变化而产生形变。压电材料因为这一特性而成为重要的功能材料，并广泛应用于换能器、压电变压器、滤波器等领域，因此关于压电陶瓷的研究一直是个热点。生物医用压电材料广泛用作生物压电传感器和生物医用压电植入体材料，同属于生物医用材料领域的范畴，生物医用材料因其应用领域的特殊性，要求材料必须符合生物医用的应用标准。压电材料的广泛应用在于电子工业领域，其极化方式常采用溅射涂层或银浆涂覆涂层作为电极材料，可分别采用电晕极化和高温油浴极化方式进行极化。由于电晕极化难以稳定控制，操作安全性低，目前国内技术难以达到，所以，国内通常使用高温油浴极化方式进行极化。然而，这种极化方式，不仅电极涂层会对压电材料的生物医用植入带来污染，而且高温硅油渗入压电材料后，难以清洗干净，会引发生物菌性，不利于生物医用。因此，需要开发一种抗菌型的压电材料，以适应市场发展。
发明内容
针对现有技术中压电材料应用于医药生物植入领域存在的易引发细菌感染的不足，本发明的目的是提供一种抗菌型压电材料的制备方法，提高压电材料的抗菌性能，防范细菌感染。
本发明的技术方案如下：
一种抗菌型压电材料的制备方法，包括如下步骤：
S1：取8-10份硅酸铯铝、3-7份钛酸镧、2-6份五氧化二钒、3-8份氧化锌、5-8份柠檬酸和15-25份无水乙醇，常温加热搅拌至均匀状态；随后在烘箱中干燥、制成粉末，放入马弗炉中在温度500-550℃下焙烧2-4h，得前驱体；
S2：将4-9份纳米二氧化硅和5-10份硝酸银加入30-40份无水乙醇中，于温度100-120℃下搅拌回流反应2-4h；
S3：将步骤S1所得前驱体加入步骤S2中，升高温度至130-160℃，以速率500-800r/min搅拌反应1-2h；
S4：将步骤S3中产物过滤、干燥后于温度500-600℃下保温5-10min，随后在温度1100-1200℃下常压烧结3-5h，即可得到所述抗菌型压电材料。
优选的，步骤S2中还包括加入5-10份碳酸锂。
优选的，步骤S1中取9份硅酸铯铝、6份钛酸镧、4份五氧化二钒、5份氧化锌、7份柠檬酸和20份无水乙醇。
优选的，步骤S1中温度为520℃下焙烧3h。
优选的，步骤S2中将7份纳米二氧化硅、7份碳酸锂和8份硝酸银加入35份无水乙醇。
优选的，步骤S2中温度为110℃下搅拌回流反应3h。
优选的，步骤S3中温度为140℃，以速率650r/min搅拌反应1.5h。
优选的，步骤S4中温度550℃下保温8min，随后在温度1150℃下常压烧结4h。
本发明与现有技术相比，其有益效果为：
本发明所述一种抗菌型压电材料的制备方法，以硅酸铯铝、钛酸镧、五氧化二钒、氧化锌混合物为前驱体，其中掺杂硝酸银和碳酸锂，在制备压电材料过程中加入抗菌型物质，使其有效的融入压电材料中，均匀覆盖于压电材料前驱体表面，提高其抗菌性能，使其在作为生物压电材料过程中避免菌体感染。
具体实施方式
以下结合实施例对本发明作进一步的说明。
实施例1
S1：取8份硅酸铯铝、3份钛酸镧、2份五氧化二钒、3份氧化锌、5份柠檬酸和15份无水乙醇，常温加热搅拌至均匀状态；随后在烘箱中干燥、制成粉末，放入马弗炉中在温度500℃下焙烧2h，得前驱体；
S2：将4份纳米二氧化硅、5份碳酸锂和5份硝酸银加入40份无水乙醇中，于温度100℃下搅拌回流反应2h；
S3：将步骤S1所得前驱体加入步骤S2中，升高温度至130℃，以速率800r/min搅拌反应1h；
S4：将步骤S3中产物过滤、干燥后于温度500℃下保温5min，随后在温度1100℃下常压烧结3h，即可得到所述抗菌型压电材料。
实施例2
S1：取10份硅酸铯铝、7份钛酸镧、6份五氧化二钒、8份氧化锌、8份柠檬酸和25份无水乙醇，常温加热搅拌至均匀状态；随后在烘箱中干燥、制成粉末，放入马弗炉中在温度550℃下焙烧4h，得前驱体；
S2：将9份纳米二氧化硅、10份碳酸锂和10份硝酸银加入30份无水乙醇中，于温度120℃下搅拌回流反应4h；
S3：将步骤S1所得前驱体加入步骤S2中，升高温度至160℃，以速率500r/min搅拌反应2h；
S4：将步骤S3中产物过滤、干燥后于温度600℃下保温10min，随后在温度1200℃下常压烧结5h，即可得到所述抗菌型压电材料。
实施例3
S1：取8份硅酸铯铝、5份钛酸镧、4份五氧化二钒、5份氧化锌、6份柠檬酸和18份无水乙醇，常温加热搅拌至均匀状态；随后在烘箱中干燥、制成粉末，放入马弗炉中在温度520℃下焙烧2.5h，得前驱体；
S2：将5份纳米二氧化硅、9份碳酸锂和8份硝酸银加入32份无水乙醇中，于温度110℃下搅拌回流反应2h；
S3：将步骤S1所得前驱体加入步骤S2中，升高温度至135℃，以速率6000r/min搅拌反应1h；
S4：将步骤S3中产物过滤、干燥后于温度520℃下保温7min，随后在温度1150℃下常压烧结3h，即可得到所述抗菌型压电材料。
实施例4
S1：取9份硅酸铯铝、4份钛酸镧、3份五氧化二钒、7份氧化锌、8份柠檬酸和22份无水乙醇，常温加热搅拌至均匀状态；随后在烘箱中干燥、制成粉末，放入马弗炉中在温度550℃下焙烧3.5h，得前驱体；
S2：将8份纳米二氧化硅、7份碳酸锂和6份硝酸银加入36份无水乙醇中，于温度115℃下搅拌回流反应4h；
S3：将步骤S1所得前驱体加入步骤S2中，升高温度至140℃，以速率700r/min搅拌反应2h；
S4：将步骤S3中产物过滤、干燥后于温度580℃下保温9min，随后在温度1180℃下常压烧结4h，即可得到所述抗菌型压电材料。
实施例5
S1：取9份硅酸铯铝、6份钛酸镧、4份五氧化二钒、5份氧化锌、7份柠檬酸和20份无水乙醇，常温加热搅拌至均匀状态；随后在烘箱中干燥、制成粉末，放入马弗炉中在温度520℃下焙烧3h，得前驱体；
S2：将7份纳米二氧化硅、7份碳酸锂和8份硝酸银加入35份无水乙醇中，于温度110℃下搅拌回流反应3h；
S3：将步骤S1所得前驱体加入步骤S2中，升高温度至140℃，以速率650r/min搅拌反应1.5h；
S4：将步骤S3中产物过滤、干燥后于温度550℃下保温8min，随后在温度1150℃下常压烧结4h，即可得到所述抗菌型压电材料。
本发明不限于这里的实施例，本领域技术人员根据本发明的揭示，不脱离本发明范畴所做出的改进和修改都应该在本发明的保护范围之内。
Claims (8)
1.一种抗菌型压电材料的制备方法，其特征在于，包括如下步骤：
S1：取8-10份硅酸铯铝、3-7份钛酸镧、2-6份五氧化二钒、3-8份氧化锌、5-8份柠檬酸和15-25份无水乙醇，常温加热搅拌至均匀状态；随后在烘箱中干燥、制成粉末，放入马弗炉中在温度500-550℃下焙烧2-4h，得前驱体；
S2：将4-9份纳米二氧化硅和5-10份硝酸银加入30-40份无水乙醇中，于温度100-120℃下搅拌回流反应2-4h；
S3：将步骤S1所得前驱体加入步骤S2中，升高温度至130-160℃，以速率500-800r/min搅拌反应1-2h；
S4：将步骤S3中产物过滤、干燥后于温度500-600℃下保温5-10min，随后在温度1100-1200℃下常压烧结3-5h，即可得到所述抗菌型压电材料。
2.根据权利要求1所述的一种抗菌型压电材料的制备方法，其特征在于，步骤S2中还包括加入5-10份碳酸锂。
3.根据权利要求1所述的一种抗菌型压电材料的制备方法，其特征在于，步骤S1中取9份硅酸铯铝、6份钛酸镧、4份五氧化二钒、5份氧化锌、7份柠檬酸和20份无水乙醇。
4.根据权利要求1所述的一种抗菌型压电材料的制备方法，其特征在于，步骤S1中温度为520℃下焙烧3h。
5.根据权利要求2所述的一种抗菌型压电材料的制备方法，其特征在于，步骤S2中将7份纳米二氧化硅、7份碳酸锂和8份硝酸银加入35份无水乙醇。
6.根据权利要求1所述的一种抗菌型压电材料的制备方法，其特征在于，步骤S2中温度为110℃下搅拌回流反应3h。
7.根据权利要求1所述的一种抗菌型压电材料的制备方法，其特征在于，步骤S3中温度为140℃，以速率650r/min搅拌反应1.5h。
8.根据权利要求1所述的一种抗菌型压电材料的制备方法，其特征在于，步骤S4中温度550℃下保温8min，随后在温度1150℃下常压烧结4h。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711164616.2A CN107721402A (zh) | 2017-11-21 | 2017-11-21 | 一种抗菌型压电材料的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711164616.2A CN107721402A (zh) | 2017-11-21 | 2017-11-21 | 一种抗菌型压电材料的制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107721402A true CN107721402A (zh) | 2018-02-23 |
Family
ID=61217751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711164616.2A Withdrawn CN107721402A (zh) | 2017-11-21 | 2017-11-21 | 一种抗菌型压电材料的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107721402A (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112624737A (zh) * | 2021-01-07 | 2021-04-09 | 林萍华 | 一种具有优良抗菌性的陶瓷材料的制备方法及陶瓷材料 |
| CN115143998A (zh) * | 2022-07-05 | 2022-10-04 | 新余学院 | 一种抗菌型单电极柔性压电传感器及其制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104557023A (zh) * | 2013-10-14 | 2015-04-29 | 王佳栋 | 一种压电材料 |
| CN106348787A (zh) * | 2016-11-10 | 2017-01-25 | 佛山蓝途科技有限公司 | 一种添加稀土抗菌陶瓷釉及其制备方法 |
-
2017
- 2017-11-21 CN CN201711164616.2A patent/CN107721402A/zh not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104557023A (zh) * | 2013-10-14 | 2015-04-29 | 王佳栋 | 一种压电材料 |
| CN106348787A (zh) * | 2016-11-10 | 2017-01-25 | 佛山蓝途科技有限公司 | 一种添加稀土抗菌陶瓷釉及其制备方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112624737A (zh) * | 2021-01-07 | 2021-04-09 | 林萍华 | 一种具有优良抗菌性的陶瓷材料的制备方法及陶瓷材料 |
| CN115143998A (zh) * | 2022-07-05 | 2022-10-04 | 新余学院 | 一种抗菌型单电极柔性压电传感器及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105272244B (zh) | 一种铌酸钾钠基无铅压电陶瓷及其制备方法 | |
| CN111302797B (zh) | 一种铌酸钾钠基无铅压电陶瓷及其制备方法 | |
| Guo et al. | Electromechanical and electrical properties of Bi0. 5Na0. 5Ti1− xMnxO3− δ ceramics with high remnant polarization | |
| CN104291817B (zh) | 高居里温度的pzt压电陶瓷材料及其制备方法 | |
| CN113666744B (zh) | 一种成分梯度铌酸钾钠基无铅压电陶瓷及其制备方法 | |
| CN110590352A (zh) | 低极化场强产生高压电铁酸铋-钛酸钡基压电陶瓷及制备 | |
| CN102390997B (zh) | 高耐压铌酸钾钠基无铅压电陶瓷及其制备方法和用途 | |
| Zhao et al. | Enhanced piezoelectric properties and excellent thermal stabilities of cobalt-modified Aurivillius-type calcium bismuth titanate (CaBi4Ti4O15) | |
| CN107721402A (zh) | 一种抗菌型压电材料的制备方法 | |
| CN102924082A (zh) | 锰掺杂铌镍-锆钛酸铅压电陶瓷及其制备方法 | |
| CN111269009A (zh) | 一种锆锰酸铋-钪酸铋-钛酸铅系压电陶瓷材料及其制备方法 | |
| CN102976747A (zh) | 掺杂铌酸锂的钛酸钡基正温度系数电阻材料及其制备方法 | |
| CN102167585A (zh) | 一种多元素掺杂钛酸铋基无铅压电陶瓷材料及其制备方法 | |
| CN115385689A (zh) | 一种铌镁酸铅-锆钛酸铅基压电陶瓷材料及其制备方法 | |
| CN101215168A (zh) | 镁钽酸锆钛酸铅陶瓷的掺杂改性方法 | |
| JP2010150060A (ja) | 非鉛系圧電セラミックス、積層型圧電デバイスおよび非鉛系圧電セラミックスの製造方法 | |
| CN108409321B (zh) | 一种掺杂LaMnO3的钛酸铋铁高温压电陶瓷及其制备方法 | |
| JP2015113279A (ja) | 温度補償用誘電体材料及びその製造方法 | |
| CN106977196B (zh) | 一种非化学计量比钛酸铋钠基陶瓷及其制备方法和应用 | |
| Fang et al. | Structural and dielectric relaxor behavior of Ba1− xNdxBi4Ti4O15 ceramics | |
| CN117088684A (zh) | 一种具有高压电性能的无铅铁酸铋基压电陶瓷材料及其制备方法 | |
| CN107162585A (zh) | 一种钛酸铋钠基电致伸缩陶瓷及其制备方法和应用 | |
| CN115403375B (zh) | 一种锆钛酸铅压电陶瓷材料及其制备方法 | |
| Prasatkhetragarn et al. | Phase formation, electrical properties and morphotropic phase boundary of 0.95 Pb (ZrxTi1− x) O3–0.05 Pb (Mn1/3Nb2/3) O3 ceramics | |
| JP5462759B2 (ja) | 圧電セラミックスおよび圧電素子 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180223 |