CN107706289A - Quantum dot LED and preparation method thereof - Google Patents

Quantum dot LED and preparation method thereof Download PDF

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Publication number
CN107706289A
CN107706289A CN201711081559.1A CN201711081559A CN107706289A CN 107706289 A CN107706289 A CN 107706289A CN 201711081559 A CN201711081559 A CN 201711081559A CN 107706289 A CN107706289 A CN 107706289A
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China
Prior art keywords
quantum dot
led
led chip
wall
layer
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Granted
Application number
CN201711081559.1A
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Chinese (zh)
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CN107706289B (en
Inventor
李富琳
宋志成
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Hisense Visual Technology Co Ltd
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Qingdao Hisense Electronics Co Ltd
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Priority to CN201711081559.1A priority Critical patent/CN107706289B/en
Publication of CN107706289A publication Critical patent/CN107706289A/en
Priority to PCT/CN2018/090063 priority patent/WO2019091107A1/en
Application granted granted Critical
Publication of CN107706289B publication Critical patent/CN107706289B/en
Priority to US16/673,830 priority patent/US11508882B2/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/50Wavelength conversion elements
    • H01L33/505Wavelength conversion elements characterised by the shape, e.g. plate or foil
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/50Wavelength conversion elements
    • H01L33/507Wavelength conversion elements the elements being in intimate contact with parts other than the semiconductor body or integrated with parts other than the semiconductor body
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2933/00Details relating to devices covered by the group H01L33/00 but not provided for in its subgroups
    • H01L2933/0008Processes
    • H01L2933/0033Processes relating to semiconductor body packages
    • H01L2933/0041Processes relating to semiconductor body packages relating to wavelength conversion elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/50Wavelength conversion elements
    • H01L33/501Wavelength conversion elements characterised by the materials, e.g. binder
    • H01L33/502Wavelength conversion materials
    • H01L33/504Elements with two or more wavelength conversion materials

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Power Engineering (AREA)
  • Led Device Packages (AREA)

Abstract

The invention discloses a kind of quantum dot LED, belong to LED light source technical field.The quantum dot LED includes:Support, the frame bottom are flat board, and surrounding upwardly extends to form middle cavity;The LED chip being fixed in the frame bottom, the LED chip are centrally located on the central shaft of support;Quantum dot layer, the quantum dot layer include red quantum dot material and green quanta point material;Wall, the wall is between quantum dot layer and the LED chip, quanta point material is avoided directly to be contacted with LED chip, make the LED chip spaced apart to the quantum dot layer, the maximum blue power that quanta point material receives directly over LED chip is reduced in the limit range of its blue light luminous power that can be born, the problem of avoiding position quantum point failure directly over LED, improve quantum dot LED life-span.

Description

Quantum dot LED and preparation method thereof
Technical field
The present invention relates to LED light source technical field, is related to a kind of quantum dot LED and its manufacture method.
Background technology
Light emitting diode (light-emitting diode, LED) is a kind of New Solid light source, because with brightness it is high, Light efficiency is high, radiation is low, long lifespan, pollution are small, without stroboscopic, do not allow to be also easy to produce depending on receiving much concern the advantages that visual fatigue, be to shine Bright engineering, the focus of optoelectronic areas research.Wherein, white light LEDs as a new generation lighting source just progressively by people's Concern, it is mainly used in the fields such as interior and road lighting, display screen and display light source, lamps for vehicle and decoration.
Business quanta point material is influenceed that its failure, the blue light light that quantum dot can be born can be caused by high temperature and oxygen at present Power limit is typically in 5W/cm2Hereinafter, it is in 2W/cm to recommend normal use2Below.Therefore the utilization of currently commercially quantum dot All need to protect quanta point material.Quantum dot backlight technology has chip package (On-Chip), light-metering encapsulation (On-Edge), optical film Integrated (On-Surface) three kinds of main implementations.The form of the integrated corresponding quantum dot diaphragm (QD-film) of optical film, leads to PET is crossed to be encapsulated quanta point material;Corresponding quantum bar (QD-rail) form of light-metering encapsulation, is encapsulated using hollow glass tube Quanta point material;Quantum dot diaphragm needs to use more quanta point material, and the limitation of the lighting angle of quantum bar, result in , it is necessary to which substantial amounts of quantum bar, does not meet economic benefit if the backlight of display field uses quantum dot.
In chip encapsulation technology, quantum dot is directly placed above LED chip, this form most saves quantum dot material Material.The blue power limit that quanta point material can be born is in 5W/cm2Under, but the distribution of the optical cavity of LED chip is in lambertian distribution, Shooting angle is smaller, and unit area and luminous power are higher.Quanta point material directly over LED chip is more susceptible to the photograph of high intensity Penetrate, this distance can make quantum dot by peak 60W/cm2~100W/cm2Blue light luminous power irradiation.Cause LED chip The quantum point failure at surface position.
The content of the invention
The invention provides a kind of quantum dot LED and its manufacture method, by between LED chip and quantum dot wealth material Wall is set, LED chip and quanta point material are separated, solves the unit area maximum that LED chip is radiated at quantum dot layer The problem of luminous power is excessive, the crash rate of quanta point material is reduced, improve quantum dot LED service life.The technology of the present invention side Case is as follows:
Embodiments of the present invention provide quantum dot LED.Including support, surrounding upwardly extends to form middle cavity;It is fixed In the LED chip in frame bottom, the LED chip is centrally located on the central shaft of support;Quantum dot layer, the quantum dot Layer includes red quantum dot material and green quanta point material;Wall, the wall are located at quantum dot layer and the LED core Between piece, the whole frame bottom and the LED chip are covered, upper surface is parallel to frame bottom, in the wall Thickness meets h >=0.03mm at the heart.
Further, the material of the wall includes at least one of epoxy resin and silica gel.
Further, water oxygen separation layer is set in the light emission side of the quantum dot layer, for make the quantum dot layer with it is outer Boundary isolates.
Further, the main component of the water oxygen separation layer includes Al2O3And SiO2At least one.
Further, the green quantum dot material-wavelength scope is 520nm~550nm, the red quantum dot material Wave-length coverage is 610nm~650nm.
A kind of preparation method for quantum dot LED that the present invention also provides, comprises the following steps:Mould is controlled, by support bottom Flat board is made in portion, and surrounding upwardly extends to form middle cavity;LED chip is weldingly fixed on frame bottom;Utilize mode for dispensing glue Silica gel is covered in LED chip and frame bottom, forms wall;Wall is toasted to solidify;By quanta point material dispensing, It is arranged on above the wall, forms quantum dot layer;Quantum dot layer is toasted to solidify.
Further, water oxygen barrier layer is sputtered on the quantum dot layer surface in the mode using magnetron sputtering.
Further, the material of water oxygen barrier layer includes Al2O3And SiO2At least one.
Further, quantum dot layer includes red quantum dot material and green quanta point material, red quantum dot material ripple Long scope is 610nm~650nm, and green quantum dot material-wavelength scope is 520nm~550nm.
Compared with prior art, the advantageous effects for the technical scheme that the embodiment of the present application is proposed include:
The invention provides a kind of quantum dot LED, including support, the bottom of the support is flat board, and surrounding upwardly extends Cavity in formation;The LED chip being fixed in the frame bottom, the LED chip are centrally located on the central shaft of support; Quantum dot layer, the quantum dot layer include red quantum dot material and green quanta point material;Wall, the wall are located at Between quantum dot layer and the LED chip, the whole frame bottom and the LED chip are covered, upper surface is parallel to described Frame bottom, surrounding are agreed with cradle wall.By thickness limit scope at the center to wall, avoid quanta point material with LED chip directly contacts, and makes the maximum blue light luminous power that quanta point material receives in the limit of its blue light luminous power that can be born In the range of, the problem of avoiding position quantum point failure directly over LED, improve quantum dot LED life-span.
Brief description of the drawings
In order to illustrate more clearly of embodiment of the present invention, the required accompanying drawing used in being described below to embodiment It is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the present invention, for this area For those of ordinary skill, on the premise of not paying creative work, other accompanying drawings can also be obtained according to these accompanying drawings.
Fig. 1 is the quantum dot LED of the embodiment of the present invention one structural representation;
Fig. 2 is the quantum dot LED of the embodiment of the present invention one functional diagram;
Fig. 3 is the quantum dot LED of the embodiment of the present invention two structural representation;
Fig. 4 is the quantum dot LED of the embodiment of the present invention two functional diagram;
Fig. 5 is the flow chart of the first embodiment of quantum dot LED manufacture methods of the present invention.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with accompanying drawing to embodiment party of the present invention Formula is described in further detail.
Embodiment one:
Fig. 1 is the quantum dot LED of the embodiment of the present invention one, as shown in figure 1, a kind of quantum dot LED includes support 110, branch Frame bottom 111 is flat board, and surrounding upwardly extends to form middle cavity, and its key property has the high reflectivity of total visible light wave band, The characteristic such as resistance to blue ray radiation and high temperature resistant, can be EMC the or PC materials of specially treated.Generally, centered on support Symmetric form, central shaft are located at the geometric center of support.LED chip 120 is generally blue chip, can send 400nm~480nm's Blue light.LED chip 120 is centrally located on the central shaft of support 110.Wall 130 covers whole frame bottom 111 and LED Chip 120, upper surface are closely agreed with parallel to frame bottom 111, surrounding with support 110.Quantum dot layer is covered above interval 140, quantum dot layer 140 includes red quantum dot material and green quanta point material.The blue light sent for LED chip 120 exists Quantum dot layer excites to form mixed white light.
To delay the working life of red green quantum dot in quantum dot layer 140, water oxygen is obstructed to quanta point material from top Destruction, ensure its validity.In the top of quantum dot layer 140, water oxygen separation layer 150 is set.
Because quantum dot layer produces amount of heat in excitation process, temperature is higher, so wall should select translucency Good, resistant to elevated temperatures material.Preferably, the material of wall includes at least one of silica gel and epoxy resin.
The main component of the water oxygen separation layer includes Al2O3And SiO2At least one.
Optionally, the green quantum dot material-wavelength scope is 520nm~550nm, the red quantum dot material ripple Long scope is 610nm~650nm.
If Fig. 2 is the quantum dot LED function figure of the embodiment of the present invention one, interval is placed on quantum dot layer 140 and LED chip Between 120, the two is set to keep certain distance h.
According to the light extraction lambertian distribution of LED chip, under different distance, the maximum blue light of common blue-ray LED unit area is strong Degree and the relation of the ultimate range from LED chip, close to following relational expression:
Y=a (0.0338h4-0.5712h3+3.6895h2-11.213h+14.77)
Wherein y is the blue light energy that the LED chip that the quanta point material of unit area receives is sent, and h is quantum dot layer With LED chip distance.Wherein a=Pe/0.55, Pe are the luminous power for the LED chip selected.
Using the blue power that quantum dot can be born as 5W/cm2, the blue light light work(of quantum dot LED chip outgoing of the invention Rate Pe and the distance h of LED chip to quantum dot layer need to meet that relation is:Then
Pe in general use ranges are:20mW~1800mW.In general, LED thickness is thinner, and light extraction efficiency is higher. The minimum range for meeting reliability thus is taken, corresponding h span is generally:h≥0.03mm.
Optionally, it is 0.03mm to choose thickness at wall center, brings above-mentioned formula into, and now, quanta point material receives Maximum blue light luminous power be 0.2W, the limiting value for the blue light luminous power that can be born less than quanta point material, it is ensured that quantum dot LED reliability.
The interval of the embodiment of the present invention one is placed between quantum dot layer 140 and LED chip 120, avoids quanta point material Directly contacted with LED chip, make the LED chip to being separated with certain distance between the quantum dot layer, and reduce LED chip just The maximum blue power that top quanta point material receives avoids LED in the limit range of its blue light luminous power that can be born The problem of surface position quantum point failure, improve quantum dot LED life-span.
Embodiment two:
Fig. 3 is the quantum dot LED of the embodiment of the present invention two, as shown in figure 1, a kind of quantum dot LED includes support 210, branch Frame bottom 211 is flat board, and surrounding upwardly extends to form middle cavity, and its key property has the high reflectivity of total visible light wave band, The characteristic such as resistance to blue ray radiation and high temperature resistant, can be EMC the or PC materials of specially treated.Generally, centered on support Symmetric form, central shaft are located at the geometric center of support.LED chip 220 is generally blue chip, can send 400nm~480nm's Blue light.LED chip 220 is centrally located on the central shaft of support 210.Wall 230 covers whole frame bottom 211 and LED Chip 220, upper surface are closely agreed with parallel to frame bottom 211, surrounding with support 210.Quantum dot layer is covered above interval 240, quantum dot layer 240 includes red quantum dot material and green quanta point material.The blue light sent for LED chip 220 exists Quantum dot layer excites to form mixed white light.
In order that Integral luminous is uniform, reduce light extraction luminous power directly over LED chip, in wall 230 and quantum dot layer Scattering layer 260 is set between 240, and the material of the scattering layer is SiO2、CaCO3、TiO2、BaSO4At least one it is micro- with glass The mixture of pearl material.
To avoid quanta point material from directly being contacted with LED chip, between LED chip and quantum dot layer fill wall and Scattering layer, the LED chip is set to be received to certain distance h, LED chip surface quanta point material is separated between the quantum dot layer Maximum blue power be reduced in the limit range of its blue light luminous power that can be born, corresponding h span is generally: h≥0.03mm。
Optionally, because quantum dot layer produces amount of heat in excitation process, temperature is higher, so wall should be selected Translucency is good, resistant to elevated temperatures material.Preferably, the material of wall includes at least one of epoxy resin or silica gel.
Optionally, the main component of the water oxygen separation layer includes Al2O3And SiO2At least one.
Optionally, the green quantum dot material-wavelength scope is 520nm~550nm, the red quantum dot material ripple Long scope is 610nm~650nm.
Embodiment three:
Fig. 5 is the flow chart of the first embodiment of quantum dot LED manufacture methods of the present invention, for quantum dot LED of the present invention The first embodiment of manufacture method, step S101, using resistance to blue ray radiation, high temperature resistant, full visible waveband high reflectivity EMC or PC is material, frame bottom is made into flat board, surrounding upwardly extends to form middle cavity;Frame bottom is integrally formed with surrounding.Step Rapid S102, LED chip is weldingly fixed on frame bottom, LED chip is centrally located on the central shaft of support;Step S103, Silica gel or epoxy resin are covered in LED chip and frame bottom using mode for dispensing glue, form wall;Step S104, Wall is toasted to solidify;Step S105, quanta point material dispensing is arranged on above the wall, forms quantum dot layer; Step S106, quantum dot layer is toasted to solidify;Step S107, by way of sputtering or being deposited, water oxygen separation layer is set Above quantum dot layer, the destruction from top barrier moisture and oxygen to quanta point material.Optionally, water oxygen separation layer is main Composition includes Al2O3And SiO2At least one.
The better embodiment of the present invention is the foregoing is only, is not intended to limit the invention, all spirit in the present invention Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.

Claims (9)

1. a kind of quantum dot LED, including it is characterised in that it includes
Support, cavity in formation;
The LED chip being fixed in the frame bottom, the LED chip are centrally located on the central shaft of support;
Quantum dot layer, the quantum dot layer include red quantum dot material and green quanta point material;
Wall, the wall between the quantum dot layer and the LED chip, cover the whole frame bottom and The LED chip, surrounding are agreed with the cradle wall, and thickness meets at the center of the wallh≥0.03mm。
2. the quantum dot LED according to claim 1, it is characterised in that the material of the wall include epoxy resin and At least one of silica gel.
3. quantum dot LED according to claim 2, it is characterised in that water oxygen is set in the light emission side of the quantum dot layer Separation layer, for making the quantum dot layer be isolated from the outside.
4. quantum dot LED according to claim 3, it is characterised in that the main component of the water oxygen separation layer includes Al2O3And SiO2At least one.
5. quantum dot LED according to claim 4, it is characterised in that the green quantum dot material-wavelength scope is 520 The nm of nm ~ 550, the red quantum dot material wave-length coverage are the nm of 610 nm ~ 650.
6. a kind of quantum dot LED preparation method, it is characterised in that comprise the following steps:
Mould is controlled, flat board is made in frame bottom, surrounding upwardly extends to form middle cavity;
LED chip is weldingly fixed on frame bottom;
Silica gel is covered in LED chip and frame bottom using mode for dispensing glue, forms wall;
Wall is toasted to solidify;
Quanta point material dispensing is arranged on above the wall, forms quantum dot layer;
Quantum dot layer is toasted to solidify.
7. preparation method according to claim 6, it is characterised in that further comprising the steps of:Utilize the side of magnetron sputtering Formula sputters water oxygen barrier layer on the quantum dot layer surface.
8. preparation method according to claim 7, it is characterised in that the material of the water oxygen barrier layer includes Al2O3With SiO2At least one.
9. preparation method according to claim 8, it is characterised in that the quantum dot layer include red quantum dot material and Green quanta point material, red quantum dot material wave-length coverage are the nm of 610 nm ~ 650, green quantum dot material-wavelength scope For the nm of 520 nm ~ 550.
CN201711081559.1A 2017-11-07 2017-11-07 Quantum dot LED and preparation method thereof Active CN107706289B (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201711081559.1A CN107706289B (en) 2017-11-07 2017-11-07 Quantum dot LED and preparation method thereof
PCT/CN2018/090063 WO2019091107A1 (en) 2017-11-07 2018-06-06 Quantum dot led, manufacturing method therefor and display device
US16/673,830 US11508882B2 (en) 2017-11-07 2019-11-04 Quantum dot LED, manufacturing method thereof and display device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711081559.1A CN107706289B (en) 2017-11-07 2017-11-07 Quantum dot LED and preparation method thereof

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CN107706289A true CN107706289A (en) 2018-02-16
CN107706289B CN107706289B (en) 2019-08-20

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108548105A (en) * 2018-04-27 2018-09-18 南昌大学 A kind of yellow light LED encapsulating structure and packaging method
WO2019091107A1 (en) * 2017-11-07 2019-05-16 青岛海信电器股份有限公司 Quantum dot led, manufacturing method therefor and display device
CN109830475A (en) * 2019-02-18 2019-05-31 南通创亿达新材料股份有限公司 High colour gamut quantum dot lamp bar, preparation method and its backlight module

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103456865A (en) * 2013-09-03 2013-12-18 易美芯光(北京)科技有限公司 LED package
CN205452347U (en) * 2015-09-29 2016-08-10 易美芯光(北京)科技有限公司 Support type quantum dot LED packaging structure
CN106098906A (en) * 2016-06-13 2016-11-09 青岛海信电器股份有限公司 Quantum dot light emitting device packaging part, backlight module and liquid crystal indicator
CN106299075A (en) * 2015-05-18 2017-01-04 青岛海信电器股份有限公司 A kind of quantum dot light emitting element, backlight module and display device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103456865A (en) * 2013-09-03 2013-12-18 易美芯光(北京)科技有限公司 LED package
CN106299075A (en) * 2015-05-18 2017-01-04 青岛海信电器股份有限公司 A kind of quantum dot light emitting element, backlight module and display device
CN205452347U (en) * 2015-09-29 2016-08-10 易美芯光(北京)科技有限公司 Support type quantum dot LED packaging structure
CN106098906A (en) * 2016-06-13 2016-11-09 青岛海信电器股份有限公司 Quantum dot light emitting device packaging part, backlight module and liquid crystal indicator

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019091107A1 (en) * 2017-11-07 2019-05-16 青岛海信电器股份有限公司 Quantum dot led, manufacturing method therefor and display device
US11508882B2 (en) 2017-11-07 2022-11-22 Hisense Visual Technology Co., Ltd. Quantum dot LED, manufacturing method thereof and display device
CN108548105A (en) * 2018-04-27 2018-09-18 南昌大学 A kind of yellow light LED encapsulating structure and packaging method
CN109830475A (en) * 2019-02-18 2019-05-31 南通创亿达新材料股份有限公司 High colour gamut quantum dot lamp bar, preparation method and its backlight module

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Address after: 266100 Zhuzhou Road, Laoshan District, Shandong, No. 151, No.

Patentee after: Hisense Visual Technology Co., Ltd.

Address before: 266100 Zhuzhou Road, Laoshan District, Shandong, No. 151, No.

Patentee before: QINGDAO HISENSE ELECTRONICS Co.,Ltd.