CN107698855A - A kind of high tenacity uvioresistant composite plastic packaging material - Google Patents
A kind of high tenacity uvioresistant composite plastic packaging material Download PDFInfo
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- CN107698855A CN107698855A CN201711121413.5A CN201711121413A CN107698855A CN 107698855 A CN107698855 A CN 107698855A CN 201711121413 A CN201711121413 A CN 201711121413A CN 107698855 A CN107698855 A CN 107698855A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
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Abstract
The invention discloses a kind of high tenacity uvioresistant composite plastic packaging material, it is prepared by the raw material of following parts by weight：50 70 parts of polyethylene, 10 15 parts of long chain cellulose, 12 16 parts of polyacrylamide, 38 parts of Fypro, 38 parts of epoxy resin, 6 12 parts of fiber reinforcing fillers, metallocene ethene 6 12 parts of alkene copolymer, 48 parts of nano silicon, 5 10 parts of attapulgite clay, 26 parts of stearic acid, 13 parts of chromium nitride, 58 parts of natural bactericidal agent, 14 parts of ultra-violet absorber, 25 parts of toughener, 25 parts of stabilizer, 36 parts of antistatic additive, 38 parts of coconut oil, 24 parts of coupling agent.The present invention coordinates long chain cellulose, polyacrylamide, Fypro, epoxy resin using polyethylene as primary raw material, then adds appropriate additive, substantially increases intensity, toughness, anti-aging, antibacterial and the anti-ultraviolet property of packaging material；Fypro is due to possessing longer thread fibril tissue, while can strengthening intensity and toughness, moreover it is possible to enhancing elasticity and anti-wear performance.
Description
Technical field
The present invention relates to plastics package field, specifically a kind of high tenacity uvioresistant composite plastic packaging material.
Background technology
Polyethylene is current general-purpose plastics most important in the world, and yield is maximum, most widely used in synthetic resin
High polymer material.He occurs polyaddition reaction by ethene and formed.Polyethylene can use general thermoplastic into
Type method is processed, and odorless, the five poisonous creatures: scorpion, viper, centipede, house lizard, toad, feel ceraceous, has excellent resistance to low temperature, chemical stability is good, is resistant to most of alkali
Erosion, do not dissolve in common solvent under normal temperature, water imbibition is small, but to be that linear molecule can be slowly dissolved in some organic molten due to it
Agent, and be not swelled, electrical insulation capability is excellent, therefore is widely used in the fields such as industry, agricultural and daily living article, main
To be used for manufacturing packaging material, container, pipeline, monofilament, electric wire etc., wherein being most widely used on packaging material.
With the development of global economy and the progress of science and technology, the living standard of people constantly improves, and people are to packing timber
The higher and higher requirement of function admirable of material, such as the intensity of packaging material, toughness, anti-flammability, anti-ultraviolet property, antibiotic property
Deng therefore, in order to further expand application of the polythene material in packaging material field, preparing a kind of more excellent poly- of performance
Ethene packaging material is crucial.
The content of the invention
It is an object of the invention to provide a kind of high tenacity uvioresistant composite plastic packaging material, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of high tenacity uvioresistant composite plastic packaging material, is prepared by the raw material of following parts by weight：
Polyethylene 50-70 parts, long chain cellulose 10-15 parts, polyacrylamide 12-16 parts, Fypro 3-8 parts, epoxy
It is resin 3-8 parts, fiber reinforcing fillers 6-12 parts, metallocene ethylene-hexene copolymer 6-12 parts, nano silicon 4-8 parts, recessed
Convex rod clay 5-10 parts, stearic acid 2-6 parts, chromium nitride 1-3 parts, natural bactericidal agent 5-8 parts, ultra-violet absorber 1-4 parts, toughness reinforcing
Agent 2-5 parts, stabilizer 2-5 parts, antistatic additive 3-6 parts, coconut oil 3-8 parts, coupling agent 2-4 parts.
Preferably, the coupling agent is selected from lauroyl peroxide, m-methyl benzoyl formyl chloride, 4-Nitrobenzenesulfonyl chloride, sulfanilamide (SN)
One or more in vinegar acyl.
The natural antibacterial agent is common cnidium fruit P.E, folium eucalypti extract, pyrethrum extract, borax are 1- in mass ratio
3:1-3:1:1-3:1-3 mixture.
The stabilizer is phosphorous acid lipid stabilizer.
The fiber reinforcing fillers are polyethylene fibre, glass fibre, bamboo fibre with 1:2:1-3 mass ratio mixing mixes
Compound.
A kind of high tenacity uvioresistant composite plastic packaging material, is prepared by the raw material of following parts by weight：
50 parts of polyethylene, 10 parts of long chain cellulose, 12 parts of polyacrylamide, 3 parts of Fypro, 3 parts of epoxy resin, fiber
6 parts of reinforcer, 6 parts of metallocene ethylene-hexene copolymer, 4 parts of nano silicon, 5 parts of attapulgite clay, 2 parts of stearic acid,
1 part of chromium nitride, 5 parts of natural bactericidal agent, 1 part of ultra-violet absorber, 2 parts of toughener, 2 parts of stabilizer, 3 parts of antistatic additive, coconut
Oily 3 parts, 2 parts of coupling agent.
A kind of high tenacity uvioresistant composite plastic packaging material, is prepared by the raw material of following parts by weight：
70 parts of polyethylene, 15 parts of long chain cellulose, 16 parts of polyacrylamide, 8 parts of Fypro, 8 parts of epoxy resin, fiber
12 parts of reinforcer, 12 parts of metallocene ethylene-hexene copolymer, 8 parts of nano silicon, 10 parts of attapulgite clay, stearic acid 6
Part, 3 parts of chromium nitride, 8 parts of natural bactericidal agent, 4 parts of ultra-violet absorber, 5 parts of toughener, 5 parts of stabilizer, 6 parts of antistatic additive, coconut palm
8 parts of seed oil, 4 parts of coupling agent.
A kind of high tenacity uvioresistant composite plastic packaging material, is prepared by the raw material of following parts by weight：
60 parts of polyethylene, 13 parts of long chain cellulose, 14 parts of polyacrylamide, 5 parts of Fypro, 5 parts of epoxy resin, fiber
9 parts of reinforcer, 9 parts of metallocene ethylene-hexene copolymer, 6 parts of nano silicon, 8 parts of attapulgite clay, 4 parts of stearic acid,
2 parts of chromium nitride, 6 parts of natural bactericidal agent, 3 parts of ultra-violet absorber, 4 parts of toughener, 4 parts of stabilizer, 4 parts of antistatic additive, coconut
Oily 5 parts, 3 parts of coupling agent.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention coordinates long chain cellulose, polyacrylamide, Fypro, epoxy resin using polyethylene as primary raw material,
Appropriate additive is added again, substantially increases intensity, toughness, anti-aging, antibacterial and the uvioresistant of packaging material of the present invention
Performance, wherein, Fypro can strengthen packaging material intensity of the present invention and tough due to possessing longer thread fibril tissue
Property while, moreover it is possible to enhancing elasticity and anti-wear performance；Stearic addition, make package material surface of the present invention bright and clean, be easy to add
Work processing, can also coordinate with age resistor, improve ageing-resistant and antioxygenic property；And addition of the coconut oil as softening agent, can be
While improving plasticity, tensile strength, elasticity and the toughness of the present invention are improved；Metallocene ethylene-hexene copolymer is added, can
To lift its high tenacity, the performance of high impact-resistant power, the addition of natural bactericidal agent so that packaging material has good sterilization effect
Fruit, and it is environmentally friendly.
Embodiment
Embodiment 1
A kind of high tenacity uvioresistant composite plastic packaging material, is prepared by the raw material of following parts by weight：
50 parts of polyethylene, 10 parts of long chain cellulose, 12 parts of polyacrylamide, 3 parts of Fypro, 3 parts of epoxy resin, fiber
6 parts of reinforcer, 6 parts of metallocene ethylene-hexene copolymer, 4 parts of nano silicon, 5 parts of attapulgite clay, 2 parts of stearic acid,
1 part of chromium nitride, 5 parts of natural bactericidal agent, 1 part of ultra-violet absorber, 2 parts of toughener, 2 parts of stabilizer, 3 parts of antistatic additive, coconut
Oily 3 parts, 2 parts of coupling agent.
Preferably, the coupling agent is selected from lauroyl peroxide, m-methyl benzoyl formyl chloride, 4-Nitrobenzenesulfonyl chloride, sulfanilamide (SN)
One or more in vinegar acyl.
The natural antibacterial agent is common cnidium fruit P.E, folium eucalypti extract, pyrethrum extract, borax are 1- in mass ratio
3:1-3:1:1-3:1-3 mixture.
The stabilizer is phosphorous acid lipid stabilizer.
The fiber reinforcing fillers are polyethylene fibre, glass fibre, bamboo fibre with 1:2:1-3 mass ratio mixing mixes
Compound.
Embodiment 2
A kind of high tenacity uvioresistant composite plastic packaging material, is prepared by the raw material of following parts by weight：
70 parts of polyethylene, 15 parts of long chain cellulose, 16 parts of polyacrylamide, 8 parts of Fypro, 8 parts of epoxy resin, fiber
12 parts of reinforcer, 12 parts of metallocene ethylene-hexene copolymer, 8 parts of nano silicon, 10 parts of attapulgite clay, stearic acid 6
Part, 3 parts of chromium nitride, 8 parts of natural bactericidal agent, 4 parts of ultra-violet absorber, 5 parts of toughener, 5 parts of stabilizer, 6 parts of antistatic additive, coconut palm
8 parts of seed oil, 4 parts of coupling agent.
Preferably, the coupling agent is selected from lauroyl peroxide, m-methyl benzoyl formyl chloride, 4-Nitrobenzenesulfonyl chloride, sulfanilamide (SN)
One or more in vinegar acyl.
The natural antibacterial agent is common cnidium fruit P.E, folium eucalypti extract, pyrethrum extract, borax are 1- in mass ratio
3:1-3:1:1-3:1-3 mixture.
The stabilizer is phosphorous acid lipid stabilizer.
The fiber reinforcing fillers are polyethylene fibre, glass fibre, bamboo fibre with 1:2:1-3 mass ratio mixing mixes
Compound.
Embodiment 3
A kind of high tenacity uvioresistant composite plastic packaging material, is prepared by the raw material of following parts by weight：
60 parts of polyethylene, 13 parts of long chain cellulose, 14 parts of polyacrylamide, 5 parts of Fypro, 5 parts of epoxy resin, fiber
9 parts of reinforcer, 9 parts of metallocene ethylene-hexene copolymer, 6 parts of nano silicon, 8 parts of attapulgite clay, 4 parts of stearic acid,
2 parts of chromium nitride, 6 parts of natural bactericidal agent, 3 parts of ultra-violet absorber, 4 parts of toughener, 4 parts of stabilizer, 4 parts of antistatic additive, coconut
Oily 5 parts, 3 parts of coupling agent.
Preferably, the coupling agent is selected from lauroyl peroxide, m-methyl benzoyl formyl chloride, 4-Nitrobenzenesulfonyl chloride, sulfanilamide (SN)
One or more in vinegar acyl.
The natural antibacterial agent is common cnidium fruit P.E, folium eucalypti extract, pyrethrum extract, borax are 1- in mass ratio
3:1-3:1:1-3:1-3 mixture.
The stabilizer is phosphorous acid lipid stabilizer.
The fiber reinforcing fillers are polyethylene fibre, glass fibre, bamboo fibre with 1:2:1-3 mass ratio mixing mixes
Compound.
Claims (8)
1. a kind of high tenacity uvioresistant composite plastic packaging material, it is characterised in that by the raw material preparation of following parts by weight
Into：
Polyethylene 50-70 parts, long chain cellulose 10-15 parts, polyacrylamide 12-16 parts, Fypro 3-8 parts, epoxy resin
3-8 parts, fiber reinforcing fillers 6-12 parts, metallocene ethylene-hexene copolymer 6-12 parts, nano silicon 4-8 parts, concave convex rod
Clay 5-10 parts, stearic acid 2-6 parts, chromium nitride 1-3 parts, natural bactericidal agent 5-8 parts, ultra-violet absorber 1-4 parts, toughener 2-
5 parts, stabilizer 2-5 parts, antistatic additive 3-6 parts, coconut oil 3-8 parts, coupling agent 2-4 parts.
2. high tenacity uvioresistant composite plastic packaging material according to claim 1, it is characterised in that the coupling agent
One or more in lauroyl peroxide, m-methyl benzoyl formyl chloride, 4-Nitrobenzenesulfonyl chloride, sulfacetamide.
3. high tenacity uvioresistant composite plastic packaging material according to claim 1, it is characterised in that described natural anti-
Microbial inoculum is common cnidium fruit P.E, folium eucalypti extract, pyrethrum extract, borax are 1-3 in mass ratio:1-3:1:1-3:1-3's
Mixture.
4. high tenacity uvioresistant composite plastic packaging material according to claim 1, it is characterised in that the stabilizer
For phosphorous acid lipid stabilizer.
5. high tenacity uvioresistant composite plastic packaging material according to claim 1, it is characterised in that the fiber increases
Strong filler is polyethylene fibre, glass fibre, bamboo fibre with 1:2:The mixture of 1-3 mass ratio mixing.
6. high tenacity uvioresistant composite plastic packaging material according to claim 1, it is characterised in that by following weight
The raw material of part is prepared：
50 parts of polyethylene, 10 parts of long chain cellulose, 12 parts of polyacrylamide, 3 parts of Fypro, 3 parts of epoxy resin, fiber reinforcement
6 parts of filler, 6 parts of metallocene ethylene-hexene copolymer, 4 parts of nano silicon, 5 parts of attapulgite clay, 2 parts of stearic acid, nitridation
1 part of chromium, 5 parts of natural bactericidal agent, 1 part of ultra-violet absorber, 2 parts of toughener, 2 parts of stabilizer, 3 parts of antistatic additive, coconut oil 3
Part, 2 parts of coupling agent.
7. high tenacity uvioresistant composite plastic packaging material according to claim 1, it is characterised in that by following weight
The raw material of part is prepared：
70 parts of polyethylene, 15 parts of long chain cellulose, 16 parts of polyacrylamide, 8 parts of Fypro, 8 parts of epoxy resin, fiber reinforcement
12 parts of filler, 12 parts of metallocene ethylene-hexene copolymer, 8 parts of nano silicon, 10 parts of attapulgite clay, 6 parts of stearic acid,
3 parts of chromium nitride, 8 parts of natural bactericidal agent, 4 parts of ultra-violet absorber, 5 parts of toughener, 5 parts of stabilizer, 6 parts of antistatic additive, coconut
Oily 8 parts, 4 parts of coupling agent.
8. high tenacity uvioresistant composite plastic packaging material according to claim 1, it is characterised in that by following weight
The raw material of part is prepared：
60 parts of polyethylene, 13 parts of long chain cellulose, 14 parts of polyacrylamide, 5 parts of Fypro, 5 parts of epoxy resin, fiber reinforcement
9 parts of filler, 9 parts of metallocene ethylene-hexene copolymer, 6 parts of nano silicon, 8 parts of attapulgite clay, 4 parts of stearic acid, nitridation
2 parts of chromium, 6 parts of natural bactericidal agent, 3 parts of ultra-violet absorber, 4 parts of toughener, 4 parts of stabilizer, 4 parts of antistatic additive, coconut oil 5
Part, 3 parts of coupling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711121413.5A CN107698855A (en) | 2017-11-14 | 2017-11-14 | A kind of high tenacity uvioresistant composite plastic packaging material |
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| CN201711121413.5A CN107698855A (en) | 2017-11-14 | 2017-11-14 | A kind of high tenacity uvioresistant composite plastic packaging material |
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| CN107698855A true CN107698855A (en) | 2018-02-16 |
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| CN201711121413.5A Pending CN107698855A (en) | 2017-11-14 | 2017-11-14 | A kind of high tenacity uvioresistant composite plastic packaging material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108976772A (en) * | 2018-07-25 | 2018-12-11 | 苏州清之绿新材料有限公司 | A kind of wear-resisting antistatic composite sheet and preparation method thereof |
| CN109502127A (en) * | 2018-12-26 | 2019-03-22 | 广州紫江包装有限公司 | A kind of aseptic plastic bottle embryo |
| CN109679191A (en) * | 2018-12-29 | 2019-04-26 | 海盐帝豪包装材料有限公司 | A kind of high temperature resistant color printing packaging bag and its production technology |
-
2017
- 2017-11-14 CN CN201711121413.5A patent/CN107698855A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108976772A (en) * | 2018-07-25 | 2018-12-11 | 苏州清之绿新材料有限公司 | A kind of wear-resisting antistatic composite sheet and preparation method thereof |
| CN109502127A (en) * | 2018-12-26 | 2019-03-22 | 广州紫江包装有限公司 | A kind of aseptic plastic bottle embryo |
| CN109679191A (en) * | 2018-12-29 | 2019-04-26 | 海盐帝豪包装材料有限公司 | A kind of high temperature resistant color printing packaging bag and its production technology |
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Application publication date: 20180216 |
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