CN107698853A - A kind of high-performance composite plastic packaging material - Google Patents
A kind of high-performance composite plastic packaging material Download PDFInfo
- Publication number
- CN107698853A CN107698853A CN201711111553.4A CN201711111553A CN107698853A CN 107698853 A CN107698853 A CN 107698853A CN 201711111553 A CN201711111553 A CN 201711111553A CN 107698853 A CN107698853 A CN 107698853A
- Authority
- CN
- China
- Prior art keywords
- parts
- packaging material
- resin
- plastic packaging
- composite plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of high-performance composite plastic packaging material, it is prepared by the raw material of following parts by weight：75 70 parts of polyvinyl resin, 10 15 parts of polyvinyl chloride resin, 20 25 parts of PLA, 10 15 parts of modified fluorin resin, 6 12 parts of fiber reinforcing fillers, metallocene ethene 6 12 parts of alkene copolymer, 26 parts of polyolefin elastomer, 0.5 1 parts of nitrogenated flame retardant, 58 parts of silver system antibacterial matrices, 14 parts of hardening agent, 25 parts of adhesive, 25 parts of compound stabilizer, 36 parts of antistatic additive, 38 parts of degradation of promoter, 24 parts of silane coupler.The present invention is using polyethylene as primary raw material, coordinate polyvinyl chloride resin, PLA, then add appropriate additive, not only the obdurability of guarantee packaging material, mechanical property, anti-flammability, antistatic, antibiotic property, and there is good degradation effect, reduce the influence to surrounding environment；By adding hardening agent and adhesive so that the packaging material has the use hardness far above existing packaging material, can pack the safety of products to be packaged.
Description
Technical field
The present invention relates to plastics package field, specifically a kind of high-performance composite plastic packaging material.
Background technology
Polyethylene is current general-purpose plastics most important in the world, and yield is maximum, most widely used in synthetic resin
High polymer material.He occurs polyaddition reaction by ethene and formed.Polyethylene can use general thermoplastic into
Type method is processed, and odorless, the five poisonous creatures: scorpion, viper, centipede, house lizard, toad, feel ceraceous, has excellent resistance to low temperature, chemical stability is good, is resistant to most of alkali
Erosion, do not dissolve in common solvent under normal temperature, water imbibition is small, but to be that linear molecule can be slowly dissolved in some organic molten due to it
Agent, and be not swelled, electrical insulation capability is excellent, therefore is widely used in the fields such as industry, agricultural and daily living article, main
To be used for manufacturing packaging material, container, pipeline, monofilament, electric wire etc., wherein being most widely used on packaging material.
With the development of global economy and the progress of science and technology, the living standard of people constantly improves, and people are to packing timber
The higher and higher requirement of function admirable of material, for example, the intensity of packaging material, mechanical property, anti-flammability, antistatic, antibiotic property,
Biodegradable performance etc., therefore, in order to further expand application of the polythene material in packaging material field, prepare a kind of property
Polyethylene packaging material that can be more excellent is crucial.
The content of the invention
It is an object of the invention to provide a kind of high-performance composite plastic packaging material, to solve to carry in above-mentioned background technology
The problem of going out.
To achieve the above object, the present invention provides following technical scheme：
A kind of high-performance composite plastic packaging material, is prepared by the raw material of following parts by weight：
Polyethylene 50-70 parts, polyvinyl chloride resin 10-15 parts, PLA 20-25 parts, modified fluorin resin 10-15 parts, fiber reinforcement
Filler 6-12 parts, metallocene ethylene-hexene copolymer 6-12 parts, polyolefin elastomer 2-6 parts, nitrogenated flame retardant 0.5-1 parts, silver
It is antibacterial matrices 5-8 parts, hardening agent 1-4 parts, adhesive 2-5 parts, compound stabilizer 2-5 parts, antistatic additive 3-6 parts, degraded rush
Enter agent 3-8 parts, silane coupler 2-4 parts.
The fiber reinforcing fillers are nanometer boron fibre, glass fibre, carbon fiber with 2-4:1:1-3 mass ratio mixing
Mixture.
The degradation of promoter is double (4- hydroxy phenyls) propane of 2,2-.
The compound stabilizer is one kind in barium zinc compound stabilizer, calcium-zinc composite stabilizing agent, barium cadmium compound stabilizer.
A kind of high-performance composite plastic packaging material, is prepared by the raw material of following parts by weight：
50 parts of polyvinyl resin, 10 parts of polyvinyl chloride resin, 20 parts of PLA, 10 parts of modified fluorin resin, 6 parts of fiber reinforcing fillers,
6 parts of metallocene ethylene-hexene copolymer, 2 parts of polyolefin elastomer, 0.5 part of nitrogenated flame retardant, 5 parts of silver system antibacterial matrices, reinforcing
1 part of agent, 2 parts of adhesive, 2 parts of compound stabilizer, 3 parts of antistatic additive, 3 parts of degradation of promoter, 2 parts of silane coupler.
A kind of high-performance composite plastic packaging material, is prepared by the raw material of following parts by weight：
70 parts of polyvinyl resin, 15 parts of polyvinyl chloride resin, 25 parts of PLA, 15 parts of modified fluorin resin, fiber reinforcing fillers 12
It is part, 12 parts of metallocene ethylene-hexene copolymer, 6 parts of polyolefin elastomer, 1 part of nitrogenated flame retardant, 8 parts of silver system antibacterial matrices, strong
4 parts of agent, 5 parts of adhesive, 5 parts of compound stabilizer, 6 parts of antistatic additive, 8 parts of degradation of promoter, 4 parts of silane coupler.
A kind of high-performance composite plastic packaging material, is prepared by the raw material of following parts by weight：
60 parts of polyvinyl resin, 13 parts of polyvinyl chloride resin, 22 parts of PLA, 12 parts of modified fluorin resin, 9 parts of fiber reinforcing fillers,
9 parts of metallocene ethylene-hexene copolymer, 4 parts of polyolefin elastomer, 0.8 part of nitrogenated flame retardant, 6 parts of silver system antibacterial matrices, reinforcing
3 parts of agent, 3 parts of adhesive, 4 parts of compound stabilizer, 5 parts of antistatic additive, 4 parts of degradation of promoter, 3 parts of silane coupler.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention coordinates polyvinyl chloride resin, PLA using polyethylene as primary raw material, then adds appropriate additive, not only protects
The obdurability of card packaging material, mechanical property, anti-flammability, antistatic, antibiotic property, and there is good degradation effect, reduce
Influence to surrounding environment, the degradation of promoter of addition can accelerate degradation speed；By adding hardening agent and adhesive so that should
Packaging material has the use hardness far above existing packaging material, can pack the safety of products to be packaged.The bag of the present invention
Package material can strengthen the anti-uv-ray of packaging material by adding modified fluorin resin, the stretching for improving packaging material
Intensity and elongation at break play the role of larger, achieve very good effect.Addition metallocene ethylene-hexene copolymer,
Polyolefin elastomer, its high tenacity, the performance of high impact-resistant power can be lifted.
Embodiment
Embodiment 1
A kind of high-performance composite plastic packaging material, is prepared by the raw material of following parts by weight：
50 parts of polyvinyl resin, 10 parts of polyvinyl chloride resin, 20 parts of PLA, 10 parts of modified fluorin resin, 6 parts of fiber reinforcing fillers,
6 parts of metallocene ethylene-hexene copolymer, 2 parts of polyolefin elastomer, 0.5 part of nitrogenated flame retardant, 5 parts of silver system antibacterial matrices, reinforcing
1 part of agent, 2 parts of adhesive, 2 parts of compound stabilizer, 3 parts of antistatic additive, 3 parts of degradation of promoter, 2 parts of silane coupler.
The fiber reinforcing fillers are nanometer boron fibre, glass fibre, carbon fiber with 2-4:1:1-3 mass ratio mixing
Mixture.
The degradation of promoter is double (4- hydroxy phenyls) propane of 2,2-.
The compound stabilizer is one kind in barium zinc compound stabilizer, calcium-zinc composite stabilizing agent, barium cadmium compound stabilizer.
Embodiment 2
A kind of high-performance composite plastic packaging material, is prepared by the raw material of following parts by weight：
70 parts of polyvinyl resin, 15 parts of polyvinyl chloride resin, 25 parts of PLA, 15 parts of modified fluorin resin, fiber reinforcing fillers 12
It is part, 12 parts of metallocene ethylene-hexene copolymer, 6 parts of polyolefin elastomer, 1 part of nitrogenated flame retardant, 8 parts of silver system antibacterial matrices, strong
4 parts of agent, 5 parts of adhesive, 5 parts of compound stabilizer, 6 parts of antistatic additive, 8 parts of degradation of promoter, 4 parts of silane coupler.
The fiber reinforcing fillers are nanometer boron fibre, glass fibre, carbon fiber with 2-4:1:1-3 mass ratio mixing
Mixture.
The degradation of promoter is double (4- hydroxy phenyls) propane of 2,2-.
The compound stabilizer is one kind in barium zinc compound stabilizer, calcium-zinc composite stabilizing agent, barium cadmium compound stabilizer.
Embodiment 3
A kind of high-performance composite plastic packaging material, is prepared by the raw material of following parts by weight：
60 parts of polyvinyl resin, 13 parts of polyvinyl chloride resin, 22 parts of PLA, 12 parts of modified fluorin resin, 9 parts of fiber reinforcing fillers,
9 parts of metallocene ethylene-hexene copolymer, 4 parts of polyolefin elastomer, 0.8 part of nitrogenated flame retardant, 6 parts of silver system antibacterial matrices, reinforcing
3 parts of agent, 3 parts of adhesive, 4 parts of compound stabilizer, 5 parts of antistatic additive, 4 parts of degradation of promoter, 3 parts of silane coupler.
The fiber reinforcing fillers are nanometer boron fibre, glass fibre, carbon fiber with 2-4:1:1-3 mass ratio mixing
Mixture.
The degradation of promoter is double (4- hydroxy phenyls) propane of 2,2-.
The compound stabilizer is one kind in barium zinc compound stabilizer, calcium-zinc composite stabilizing agent, barium cadmium compound stabilizer.
Claims (7)
1. a kind of high-performance composite plastic packaging material, it is characterised in that be prepared by the raw material of following parts by weight：
Polyvinyl resin 75-70 parts, polyvinyl chloride resin 10-15 parts, PLA 20-25 parts, modified fluorin resin 10-15 parts, fiber reinforcement
Filler 6-12 parts, metallocene ethylene-hexene copolymer 6-12 parts, polyolefin elastomer 2-6 parts, nitrogenated flame retardant 0.5-1 parts, silver
It is antibacterial matrices 5-8 parts, hardening agent 1-4 parts, adhesive 2-5 parts, compound stabilizer 2-5 parts, antistatic additive 3-6 parts, degraded rush
Enter agent 3-8 parts, silane coupler 2-4 parts.
2. high-performance composite plastic packaging material according to claim 1, it is characterised in that the fiber reinforcing fillers are
Nanometer boron fibre, glass fibre, carbon fiber are with 2-4:1:The mixture of 1-3 mass ratio mixing.
3. high-performance composite plastic packaging material according to claim 1, it is characterised in that the degradation of promoter is 2,
Double (4- hydroxy phenyls) propane of 2-.
4. high-performance composite plastic packaging material according to claim 1, it is characterised in that the compound stabilizer is barium
One kind in zinc composite stabilizer, calcium-zinc composite stabilizing agent, barium cadmium compound stabilizer.
5. high-performance composite plastic packaging material according to claim 1, it is characterised in that by the raw material of following parts by weight
It is prepared：
50 parts of polyvinyl resin, 10 parts of polyvinyl chloride resin, 20 parts of PLA, 10 parts of modified fluorin resin, 6 parts of fiber reinforcing fillers, cyclopentadienyl gold
Belong to 6 parts of ethylene-hexene copolymer, 2 parts of polyolefin elastomer, 0.5 part of nitrogenated flame retardant, 5 parts of silver system antibacterial matrices, hardening agent 1
Part, 2 parts of adhesive, 2 parts of compound stabilizer, 3 parts of antistatic additive, 3 parts of degradation of promoter, 2 parts of silane coupler.
6. high-performance composite plastic packaging material according to claim 1, it is characterised in that by the raw material of following parts by weight
It is prepared：
70 parts of polyvinyl resin, 15 parts of polyvinyl chloride resin, 25 parts of PLA, 15 parts of modified fluorin resin, 12 parts of fiber reinforcing fillers, cyclopentadienyl
12 parts of metal ethylene-hexene copolymer, 6 parts of polyolefin elastomer, 1 part of nitrogenated flame retardant, 8 parts of silver system antibacterial matrices, hardening agent 4
Part, 5 parts of adhesive, 5 parts of compound stabilizer, 6 parts of antistatic additive, 8 parts of degradation of promoter, 4 parts of silane coupler.
7. high-performance composite plastic packaging material according to claim 1, it is characterised in that by the raw material of following parts by weight
It is prepared：
60 parts of polyvinyl resin, 13 parts of polyvinyl chloride resin, 22 parts of PLA, 12 parts of modified fluorin resin, 9 parts of fiber reinforcing fillers, cyclopentadienyl gold
Belong to 9 parts of ethylene-hexene copolymer, 4 parts of polyolefin elastomer, 0.8 part of nitrogenated flame retardant, 6 parts of silver system antibacterial matrices, hardening agent 3
Part, 3 parts of adhesive, 4 parts of compound stabilizer, 5 parts of antistatic additive, 4 parts of degradation of promoter, 3 parts of silane coupler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711111553.4A CN107698853A (en) | 2017-11-13 | 2017-11-13 | A kind of high-performance composite plastic packaging material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711111553.4A CN107698853A (en) | 2017-11-13 | 2017-11-13 | A kind of high-performance composite plastic packaging material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107698853A true CN107698853A (en) | 2018-02-16 |
Family
ID=61179211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711111553.4A Pending CN107698853A (en) | 2017-11-13 | 2017-11-13 | A kind of high-performance composite plastic packaging material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107698853A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110467802A (en) * | 2019-07-25 | 2019-11-19 | 安徽新翔包装材料有限公司 | A kind of degradable environment-friendly type packaging material and its manufacture craft |
| CN114276631A (en) * | 2022-01-18 | 2022-04-05 | 苏州润鑫包装科技有限公司 | PVC packaging film and production process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250295A (en) * | 2008-04-15 | 2008-08-27 | 开原市升达塑料彩印厂 | Degradable plastic film |
| CN102174222A (en) * | 2011-01-31 | 2011-09-07 | 开原市升达塑料彩印厂 | Degradable plastic film and production method thereof |
| CN102321287A (en) * | 2011-07-22 | 2012-01-18 | 蚌埠蓝天塑料包装有限公司 | Biodegradable polyethylene thin film and preparation method thereof |
| CN103819792A (en) * | 2012-11-16 | 2014-05-28 | 无锡市黄盛包装制品有限公司 | Fruit and vegetable antibacterial fresh-keeping packaging material |
| CN105754194A (en) * | 2016-04-28 | 2016-07-13 | 太仓市金毅电子有限公司 | Nano-plastic fresh-keeping packaging material |
-
2017
- 2017-11-13 CN CN201711111553.4A patent/CN107698853A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250295A (en) * | 2008-04-15 | 2008-08-27 | 开原市升达塑料彩印厂 | Degradable plastic film |
| CN102174222A (en) * | 2011-01-31 | 2011-09-07 | 开原市升达塑料彩印厂 | Degradable plastic film and production method thereof |
| CN102321287A (en) * | 2011-07-22 | 2012-01-18 | 蚌埠蓝天塑料包装有限公司 | Biodegradable polyethylene thin film and preparation method thereof |
| CN103819792A (en) * | 2012-11-16 | 2014-05-28 | 无锡市黄盛包装制品有限公司 | Fruit and vegetable antibacterial fresh-keeping packaging material |
| CN105754194A (en) * | 2016-04-28 | 2016-07-13 | 太仓市金毅电子有限公司 | Nano-plastic fresh-keeping packaging material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110467802A (en) * | 2019-07-25 | 2019-11-19 | 安徽新翔包装材料有限公司 | A kind of degradable environment-friendly type packaging material and its manufacture craft |
| CN114276631A (en) * | 2022-01-18 | 2022-04-05 | 苏州润鑫包装科技有限公司 | PVC packaging film and production process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Pfaendner | How will additives shape the future of plastics? | |
| CN104119598A (en) | Composite material for case | |
| CN104086895B (en) | A kind of super low-temperature resistant PP composite material and preparation method thereof | |
| CN105440505A (en) | PVC (polyvinyl chloride) foam material for sole and preparation method of PVC foam material | |
| CN102585338A (en) | Anti-wear halogen-free flame-retardant cable material | |
| CN107698853A (en) | A kind of high-performance composite plastic packaging material | |
| CN105419167A (en) | Carpet environmental protection PVC modified material and preparation method therefor | |
| CN106336574A (en) | BOPP film | |
| CN102250427A (en) | High-strength high-flexibility flame-retardant cable sheath rubber and preparation method thereof | |
| CN102424712B (en) | Halogen-free flame-retardant thermoplastics elastomer (TPE) material and preparation method thereof | |
| CN111117113A (en) | High-cold-resistance wear-resistant polyvinyl chloride modified material for automobile wire and preparation method thereof | |
| CN104530554A (en) | Calcium-carbonate-filling-modified linear low density polyethylene film and preparation method thereof | |
| CN106916394A (en) | A kind of anti-slip carpet is material modified and preparation method thereof with PVC | |
| CN107641243A (en) | A kind of high-strength degradable polyethylene packaging material | |
| CN101851368A (en) | Anti-125 DEG C-level low smoke halogen free-flame retardant single-core cable insulation rubber for railway locomotive | |
| CN105061911A (en) | Conveyor belt contactable with food | |
| CN107325408A (en) | A kind of flame retardant plastics packaging material | |
| CN104292613A (en) | Corrosion-resistant plastic manhole | |
| CN107828109A (en) | A kind of anti-aging polyethylene packaging material of antibacterial | |
| CN112812472B (en) | Environment-friendly low-precipitation soft PVC material and preparation method thereof | |
| CN105061949A (en) | Insulating PVC (polyvinyl chloride) plastic particle | |
| CN108794865A (en) | A kind of high tenacity composite plastic packing film | |
| CN110819010A (en) | Halogen-free flame-retardant polypropylene material with ultrahigh specific gravity and preparation method thereof | |
| CN105038037A (en) | Flame-retardant PVC plastic particles | |
| KR101978717B1 (en) | A safety boots |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180216 |