CN106589582A - Reinforced and toughened antibacterial polypropylene material and preparing method thereof - Google Patents

Reinforced and toughened antibacterial polypropylene material and preparing method thereof Download PDF

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Publication number
CN106589582A
CN106589582A CN201611029882.XA CN201611029882A CN106589582A CN 106589582 A CN106589582 A CN 106589582A CN 201611029882 A CN201611029882 A CN 201611029882A CN 106589582 A CN106589582 A CN 106589582A
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temperature
area
polypropylene
antibacterial
molecular weight
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何丹农
林琳
张春明
陈超
金彩虹
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Shanghai National Engineering Research Center for Nanotechnology Co Ltd
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Shanghai National Engineering Research Center for Nanotechnology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92514Pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/9258Velocity
    • B29C2948/9259Angular velocity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/068Ultra high molecular weight polyethylene

Abstract

The invention relates to a reinforced and toughened antibacterial polypropylene material and a preparing method thereof. The polypropylene material is prepared from, be weight, 54-87.7% of polypropylene, 0.5%-5% of inorganic antibacterial agent, 10%-30% of ultra-high molecular weight polyethylene masterbatch, 1%-8% of graft polypropylene, 0.2%-1% of dispersant, 0.2%-1% of stabilizer and 0.4%-1% of antioxygen. The method comprises the steps of preparing ultra-high molecular weight polyethylene into ultra-high molecular weight polyethylene masterbatch under a certain condition, and then mixing and extruding inorganic antibacterial agent, polypropylene, ultra-high molecular weight polyethylene masterbatch, graft polypropylene and other auxiliaries at high speed to prepare the polypropylene composite material with high strengh,toughness and antibacterial property. According to the reinforcing and toughening antibacterial polypropylene material and the preparing method thereof, the inorganic antibacterial agent is ensured to be added to endow polypropylene with good antibacterial activity, and meanwhile polypropylene is reinforced and toughened by adding organic ultra-long chain macromolecules. The prepared reinforced and toughened antibacterial polypropylene material has the advantages of being good in antibacterial performance and remarkable in mechanical characteristic.

Description

Activeness and quietness antibacterial polypropylene material and preparation method thereof
Technical field
The present invention relates to activeness and quietness antibacterial polypropylene material and preparation method thereof, belongs to technical field of polymer materials.
Background technology
Data shows the various surface of plastic products contaminations touched in daily life and grows various pathogenic bacterias.Such as hotel Antibacterial on restaurant's toilet seat has escherichia coli, staphylococcus aureuses, White staphylococcus, bacillus subtilis, tetracoccuss etc., bacterium Fall to counting up to 40;The clump count of public telephone microphone is up to 50;Hospital, the clump count of the door handle at hotel even may be up to more than 200. With the raising of people's living standard, everybody is to health and healthy requirement also more and more higher.Since the nineties, with day This has carried out antibacterial at aspects such as household electrical appliance, packaging for foodstuff, toy for children, kitchen and sanitary bath equipments for the developed country of representative Research, exploitation and the production work of material, to reduce because of the bacterium infection occurred using plastic.
Polypropylene is widely used in house as a kind of non-toxic plastic because density is little, price is low and good processing characteristics Each field such as electrical appliance.But polypropylene is easily polluted by various noxious bacteria as other plastics, in the case of being adapted to, it is more easy to Bacterial growth.Generally adopt now addition antibacterial to improve polyacrylic anti-microbial property.Conventional plastic antimicrobial agent can at present It is divided into organic antibacterial agent and inorganic antiseptic, organic antibacterial agent mainly has ethers, phenol, biphenyl ethers, quaternary ammonium salt etc., its Feature is that sterilization speed is fast, but antibacterial effect duration is short, heat resistance is poor.Inorganic antiseptic be mainly silver, zinc, titanium plasma and its Compound, is characterized in heat-resist, safe, antibacterial effect duration length etc..Such as Chinese patent CN101089038A is disclosed Nanometer silver addition polypropylene obtains a kind of antibiotic rate more than 99% PP composite material;Chinese patent CN1699459A is disclosed A kind of silver-carrying nano oxide antibacterial polypropylene water-feeding pipes and preparation method thereof.Above-mentioned patent is related to nanometer silver, load silver and receives Rice application of the oxide antibacterial in polypropylene, and obtain certain achievement.But silver-series antibacterial agent there is also many shortcomings, such as easily Discoloration, poor heat resistance, manufacture are difficult, and in the plastic using complex process etc., noble metal toxic is also disputable in addition.In machinery Aspect of performance, polypropylene cause material as the impact energy for absorbing has little time transmission in time under low temperature or high strain rate Impact resistance ability, notch sensitivity are strong, impact strength is low, so as to greatly limit polypropylene as engineering material and structural wood The application of material.To optimize Properties of Polypropylene, further expand its range of application, all having carried out substantial amounts of polypropylene both at home and abroad strengthens The research and development of toughening modifying, has achieved certain achievement in terms of multiphase copolymer and blending and modifying.Such as Chinese patent CN201110308569.0 discloses a kind of using rubber sulfonation flexibilized polypropylene material;Chinese patent CN201010214965.2 Disclose a kind of using butadiene-styrene rubber toughening modifying polypropylene material and preparation method thereof;Japanese Patent Laid-Open 6-190991 is public A kind of high density polyethylene (HDPE)/polypropylene bonding composite is opened;United States Patent (USP) US20020010241A1 discloses a kind of by gathering The polyolefin composition of propylene and ultra-high molecular weight polyethylene composition.Although above-mentioned patent report is polypropylene toughness-increasing modified, It is not relate in disclosed research study of both Mechanical Properties of PP and antibacterial.
The content of the invention
To overcome the deficiencies in the prior art, the invention provides a kind of activeness and quietness antibacterial polypropylene material and its preparation side Method, while the material use addition inorganic antiseptic gives polypropylene excellent anti-microbial property, by adding overlength chain high score Son improves polyacrylic tensile strength and notch impact strength.
What the present invention was realized in.
A kind of activeness and quietness antibacterial polypropylene material, it is characterised in that polypropylene, inorganic antiseptic, super high molecular weight are gathered The proportioning of ethylene master batch, graft polypropylene, dispersant, stabilizer and antioxidant percentage is as follows:
Polypropylene 54~87.7%
Inorganic antiseptic 0.5~5%
Ultra-high molecular weight polyethylene master batch 10~30%
Graft polypropylene 1~8%
Dispersant 0.2~1%
Stabilizer 0.2~1%
Antioxidant 0.4~1%.
Described polypropylene is the one kind in homopolymerization and COPP or its combination, and its melt index is 1~25g/ 10min;During the graft polypropylene is maleic anhydride inoculated polypropylene or glycidyl methacrylate graft polypropylene A kind of or its combination.
Described antibacterial is nano inorganic antibacterial, the one kind in composite hybridization nano inorganic antimicrobial agent or its combination;Institute The dispersant stated is ethylene group bis-stearamides, glycerol monostearate, the one kind in glyceryl tristearate or its combination.
Described stabilizer is in dibutyl tin laurate, dibutyitin maleate, dibutyltin mercaptide in organic tin One kind or its combination;Described antioxidant is primary antioxidant and auxiliary anti-oxidant, and primary antioxidant is hindered phenol and thioesters class antioxygen One kind or its combination in agent, auxiliary anti-oxidant are the one kind in phosphorite kind antioxidant or its combination.
To increase the affinity of inorganic antiseptic and fluoropolymer resin, the inorganic antiseptic being modified using coupling agent surface, Wherein coupling agent is silane coupler, titanate coupling agent, one kind of aluminate coupling agent or its combination.
Described ultra-high molecular weight polyethylene master batch is made up of following substances in percentage by weight:
Ultra-high molecular weight polyethylene 30~50%
Linear low density polyethylene 30~40%
Inorganic particle 10~15%
Compatilizer 10~15%
The molecular weight of described ultra-high molecular weight polyethylene is 150~5,000,000;Described linear low density polyethylene density is 0.92g/cm3, melt index is 24g/10min.
Described inorganic particle be Calcium Carbonate, Pulvis Talci, carbon fiber, glass fibre, silicon dioxide, in potassium titanate crystal whisker A kind of or its combination;Described compatilizer is liquid paraffin, and molecular weight is 100~200 g/mol.
Described ultra-high molecular weight polyethylene master batch preparation process is as follows:By the ultra-high molecular weight polyethylene of certain proportioning, Linear low density polyethylene, the inorganic particle and compatilizer mix homogeneously in super mixer, then by mixture Jing twin screw Extruder extruding pelletization, expressing technique is:One 190~200 DEG C of area's temperature, two 190~200 DEG C of area's temperature, three area's temperature 200~ 210 DEG C, four 200~210 DEG C of area's temperature, five 200~210 DEG C of area's temperature, six 210~220 DEG C of area's temperature, seven area's temperature 210~ 220 DEG C, eight 215~225 DEG C of area's temperature, nine 215~225 DEG C of area's temperature, 200~220 DEG C of head temperature, screw speed 200~ 250 turns/min, 20~25MPa of melt pressure.
A kind of preparation method of activeness and quietness antibacterial polypropylene material, it is characterised in that will be poly- by double screw extruder Propylene, inorganic antiseptic, ultra-high molecular weight polyethylene master batch, graft polypropylene, dispersant, stabilizer and antioxidant melting extrusion Cooling granulation, is obtained activeness and quietness antibacterial polypropylene material afterwards, and step is as follows:
(1)First at a certain temperature, using coupling agent inorganic antiseptic is carried out surface be modified, surface modification temperature be 60~ 70 DEG C, coupling agent consumption is 0.5~2%;
(2)Polypropylene, inorganic antiseptic, ultra-high molecular weight polyethylene master batch, graft polypropylene, dispersion are weighed by weight ratio Agent, stabilizer and antioxidant mix in super mixer 15~20 minutes;
(3)Mixed raw material is added in double screw extruder, the cooling granulation Jing after melting extrusion, expressing technique is:One area 180~190 DEG C of temperature, two 180~190 DEG C of area's temperature, three 190~200 DEG C of area's temperature, four 190~200 DEG C of area's temperature, 5th area 190~200 DEG C of temperature, six 200~210 DEG C of area's temperature, seven 200~210 DEG C of area's temperature, eight 210~220 DEG C of area's temperature, 9th area 210~220 DEG C of temperature, 200~210 DEG C of head temperature, 200~250 revs/min of screw speed, 18~25MPa of pressure.
In polypropylene toughness-increasing modified research, the most frequently used toughening methods are exactly that flexible polymer is introduced in plastic substrate Thing, when system is subject to external impacts, absorbs a large amount of punching by causing the crazing and shear yielding of flexible polymer surrounding matrix Energy is hit, so as to improve the toughness of matrix.But this method has fatal weakness, although that is, the toughness of polypropylene matrix is improved , but often result in the reduction of tensile strength and hardness;On the other hand, for the Pp System of addition inorganic antiseptic, draw Enter flexible polymer to be easy to clad be formed in inorganic antiseptic particle surface, reduce the antimicrobial efficiency of inorganic antiseptic.Cause This, simply adds flexible polymer in inorganic antiseptic/Pp System, although improve polyacrylic to a certain extent Toughness, but the antimicrobial efficiency with sacrificial inorganic antibacterial is as cost to a great extent.Therefore, ensureing that inorganic antiseptic is excellent While different anti-microbial property, how to improve Mechanical Properties of PP is one of difficult point of antibacterial polypropylene material research.
Many researchers using super long chain macromolecule is introduced in polypropylene matrix, using overlength strand shape in the base Into the framing structure of physical entanglement, when material is subject to external force to act on, in matrix, the skeleton of this entanglement absorbs and transmits impact Can, to play a part of activeness and quietness.For example, using the PE modified polypropylene that molecular weight is high so as to polypropylene melt Melt blending and form linear interpenetrating networks or physical cross-linked network, when material under external force, there is large deformation in network, absorb outer Boundary's energy, plays the effect of activeness and quietness.But ultra-high molecular weight polyethylene molecular weight is very long, mutually tangle each other, even if More than melting temperature, the state of elastomer is also kept not with mobility.
The present invention adopts linear low density polyethylene for carrier, and the alkane and super high molecular weight for adding certain low-molecular-weight gathers Ethylene melt blending generates low viscous ultra-high molecular weight polyethylene master batch;Using nano zine oxide or titanium dioxide as inorganic Then polypropylene, ultra-high molecular weight polyethylene master batch, inorganic antiseptic, graft polypropylene and other auxiliary agents are passed through by antibacterial Double screw extruder melt blending extrusion obtains activeness and quietness antibacterial polypropylene material.For preparing activeness and quietness antibacterial polypropylene The requirement of material, the present invention have the property that:(1)Nano zine oxide or titanium dioxide are selected as inorganic antiseptic;(2)Choosing The ultra-high molecular weight polyethylene with overlength strand is selected as organic filler, and by the use of linear low density polyethylene as carrier Low viscous ultra-high molecular weight polyethylene master batch is generated with ultra-high molecular weight polyethylene melt blending extrusion;(3)Effectively improving On the premise of polypropylene antibacterial activity and mechanical strength, as far as possible using a small amount of inorganic antiseptic and ultra-high molecular weight polyethylene Master batch.
Compared with existing antibacterial polypropylene material, the present invention has the effect that:The polypropylene material that the present invention is prepared Material antibacterial more rapidly, it is more longlasting, safer;Simultaneously present invention uses super long chain macromolecule improves material as filler Mechanical property, widened the range of application of antibacterial polypropylene material.
Description of the drawings
Fig. 1 is the TEM pictures of KH550 modified nano zinc oxide powder body in embodiment 1.
Fig. 2 is 3 polypropylene impact fracture surface SEM photograph of embodiment.
Specific embodiment
Following embodiment is that the present invention is further illustrated, and the present invention is not limited to following examples and reality Applying method.
Embodiment 1
(1) surface modification of inorganic antiseptic
60 DEG C are heated to by disperse medium of ethanol, Silane coupling agent KH550 dispersion 5min are added, is subsequently adding inorganic antiseptic Zinc Oxide disperses 30min, dries, grinds, sieving obtains modified zinc oxide, and wherein KH550 consumptions are 0.5%.
(2) preparation of ultra-high molecular weight polyethylene master batch
By 30% ultra-high molecular weight polyethylene, 40% linear low density polyethylene, 15% Calcium Carbonate, 15% liquid paraffin in mixed at high speed Mix homogeneously in device.Mixture Jing double screw extruder extruding pelletizations are standby, and wherein ultra-high molecular weight polyethylene molecular weight is 150 Ten thousand, expressing technique is:One 190 DEG C of area's temperature, two 190 DEG C of area's temperature, three 200 DEG C of area's temperature, four 200 DEG C of area's temperature, five area's temperature 200 DEG C of degree, six 210 DEG C of area's temperature, seven 210 DEG C of area's temperature, eight 215 DEG C of area's temperature, nine 215 DEG C of area's temperature, head temperature 200 DEG C, 200 turns/min of screw speed, melt pressure 20MPa.
(3) preparation of activeness and quietness antibacterial polypropylene material
Will be 87.7% HOPP, 0.5% modified zinc oxide, 10% ultra-high molecular weight polyethylene master batch, the grafting of 1% maleic anhydride poly- Propylene, 0.2% glycerol monostearate, 0.2% dibutyl tin laurate, each 0.2% primary antioxidant 3114 and auxiliary anti-oxidant 168 exist Then mixture Jing double screw extruders extrusion is obtained activeness and quietness antibacterial polypropylene material by mix homogeneously in super mixer Material.Wherein polypropylene melt index is 1g/10min, and expressing technique is:One 180 DEG C of area's temperature, two 180 DEG C of area's temperature, three area's temperature 190 DEG C of degree, four 190 DEG C of area's temperature, five 190 DEG C of area's temperature, six 200 DEG C of area's temperature, seven 200 DEG C of area's temperature, eight area's temperature 210 DEG C, nine 210 DEG C of area's temperature, 200 DEG C of head temperature, 200 turns/min of screw speed, melt pressure 18MPa.
Embodiment 2
(1) surface modification of inorganic antiseptic
60 DEG C are heated to by disperse medium of ethanol, Silane coupling agent KH550 dispersion 5min are added, is subsequently adding inorganic antiseptic Zinc Oxide disperses 30min, dries, grinds, sieving obtains modified zinc oxide, and wherein KH550 consumptions are 0.5%.
(2) preparation of ultra-high molecular weight polyethylene master batch
By 50% ultra-high molecular weight polyethylene, 30% linear low density polyethylene, 10% Calcium Carbonate, 10% liquid paraffin in mixed at high speed Mix homogeneously in device.Mixture Jing double screw extruder extruding pelletizations are standby, and wherein ultra-high molecular weight polyethylene molecular weight is 150 Ten thousand, expressing technique is:One 200 DEG C of area's temperature, two 200 DEG C of area's temperature, three 210 DEG C of area's temperature, four 210 DEG C of area's temperature, five area's temperature 210 DEG C of degree, six 220 DEG C of area's temperature, seven 220 DEG C of area's temperature, eight 225 DEG C of area's temperature, nine 225 DEG C of area's temperature, head temperature 220 DEG C, 250 turns/min of screw speed, melt pressure 25MPa.
(3) preparation of activeness and quietness antibacterial polypropylene material
Will be 67.7% HOPP, 0.5% modified zinc oxide, 30% ultra-high molecular weight polyethylene master batch, the grafting of 1% maleic anhydride poly- Propylene, 0.2% glycerol monostearate, 0.2% dibutyl tin laurate, each 0.2% primary antioxidant 3114 and auxiliary anti-oxidant 168 exist Then mixture Jing double screw extruders extrusion is obtained activeness and quietness antibacterial polypropylene material by mix homogeneously in super mixer Material.Wherein polypropylene melt index is 1g/10min, and expressing technique is:One 190 DEG C of area's temperature, two 190 DEG C of area's temperature, three area's temperature 200 DEG C of degree, four 200 DEG C of area's temperature, five 200 DEG C of area's temperature, six 210 DEG C of area's temperature, seven 210 DEG C of area's temperature, eight area's temperature 220 DEG C, nine 220 DEG C of area's temperature, 210 DEG C of head temperature, 230 turns/min of screw speed, melt pressure 20MPa.
Embodiment 3
(1). the surface modification of inorganic antiseptic
70 DEG C are heated to by disperse medium of isopropanol, silane coupler DL602 dispersion 5min are added, is subsequently adding inorganic antibacterial Agent Zinc Oxide disperses 30min, dries, grinds, sieving obtains modified zinc oxide, and wherein DL602 consumptions are 2%.
(2) preparation of ultra-high molecular weight polyethylene master batch
By 30% ultra-high molecular weight polyethylene, 40% linear low density polyethylene, 15% Pulvis Talci, 15% liquid paraffin in mixed at high speed Mix homogeneously in device.Mixture Jing double screw extruder extruding pelletizations are standby, and wherein ultra-high molecular weight polyethylene molecular weight is 150 Ten thousand, expressing technique is:One 190 DEG C of area's temperature, two 190 DEG C of area's temperature, three 200 DEG C of area's temperature, four 200 DEG C of area's temperature, five area's temperature 200 DEG C of degree, six 210 DEG C of area's temperature, seven 210 DEG C of area's temperature, eight 215 DEG C of area's temperature, nine 215 DEG C of area's temperature, head temperature 200 DEG C, 200 turns/min of screw speed, melt pressure 20MPa.
(3) preparation of activeness and quietness antibacterial polypropylene material
By 74% HOPP, 5% modified zinc oxide, 10% ultra-high molecular weight polyethylene master batch, 8% maleic anhydride grafting poly- third Alkene, 1% glycerol monostearate, 1% dibutyl tin laurate, each 0.5% primary antioxidant 3114 and auxiliary anti-oxidant 168 are mixed in high speed Then mixture Jing double screw extruders extrusion is obtained activeness and quietness antibacterial polypropylene material by mix homogeneously in clutch.Wherein Polypropylene melt index is 1g/10min, and expressing technique is:One 180 DEG C of area's temperature, two 180 DEG C of area's temperature, three area's temperature 190 DEG C, four 190 DEG C of area's temperature, five 190 DEG C of area's temperature, six 200 DEG C of area's temperature, seven 200 DEG C of area's temperature, eight 210 DEG C of area's temperature, 9th area 210 DEG C of temperature, 200 DEG C of head temperature, 200 turns/min of screw speed, melt pressure 20MPa.
Embodiment 4
(1) surface modification of inorganic antiseptic
70 DEG C are heated to by disperse medium of ethanol, titanate coupling agent UP-131 dispersion 5min are added, are subsequently adding inorganic anti- Microbial inoculum Zinc Oxide disperses 30min, dries, grinds, sieving obtains modified zinc oxide, and wherein UP-131 consumptions are 1%.
(2) preparation of ultra-high molecular weight polyethylene master batch
By 50% ultra-high molecular weight polyethylene, 30% linear low density polyethylene, 10% potassium titanate crystal whisker, 10% liquid paraffin at a high speed Mix homogeneously in blender.Mixture Jing double screw extruder extruding pelletizations are standby, wherein ultra-high molecular weight polyethylene molecular weight For 1,500,000, expressing technique is:One 200 DEG C of area's temperature, two 200 DEG C of area's temperature, three 210 DEG C of area's temperature, four 210 DEG C of area's temperature, five 210 DEG C of area's temperature, six 220 DEG C of area's temperature, seven 220 DEG C of area's temperature, eight 225 DEG C of area's temperature, nine 225 DEG C of area's temperature, head temperature 220 DEG C, 250 turns/min of screw speed, melt pressure 25MPa.
(3) preparation of activeness and quietness antibacterial polypropylene material
By 54% HOPP, 5% modified zinc oxide, 30% ultra-high molecular weight polyethylene master batch, 8% maleic anhydride grafting poly- third Alkene, 1% glycerol monostearate, 1% dibutyl tin laurate, each 0.5% primary antioxidant 1010 and auxiliary anti-oxidant 168 are mixed in high speed Then mixture Jing double screw extruders extrusion is obtained activeness and quietness antibacterial polypropylene material by mix homogeneously in clutch.Wherein Polypropylene melt index is 1g/10min, and expressing technique is:One 190 DEG C of area's temperature, two 190 DEG C of area's temperature, three area's temperature 200 DEG C, four 200 DEG C of area's temperature, five 200 DEG C of area's temperature, six 210 DEG C of area's temperature, seven 210 DEG C of area's temperature, eight 220 DEG C of area's temperature, 9th area 220 DEG C of temperature, 210 DEG C of head temperature, 250 turns/min of screw speed, melt pressure 25MPa.
Embodiment 5
(1) surface modification of inorganic antiseptic
60 DEG C are heated to by disperse medium of ethanol, Silane coupling agent KH550 dispersion 5min are added, is subsequently adding inorganic antiseptic Titanium dioxide disperses 30min, dries, grinds, sieving obtains modifying titanium dioxide, and wherein KH550 consumptions are 0.5%.
(2) preparation of ultra-high molecular weight polyethylene master batch
By 30% ultra-high molecular weight polyethylene, 40% linear low density polyethylene, 15% Calcium Carbonate, 15% liquid paraffin in mixed at high speed Mix homogeneously in device.Mixture Jing double screw extruder extruding pelletizations are standby, and wherein ultra-high molecular weight polyethylene molecular weight is 150 Ten thousand, expressing technique is:One 190 DEG C of area's temperature, two 190 DEG C of area's temperature, three 200 DEG C of area's temperature, four 200 DEG C of area's temperature, five area's temperature 200 DEG C of degree, six 210 DEG C of area's temperature, seven 210 DEG C of area's temperature, eight 215 DEG C of area's temperature, nine 215 DEG C of area's temperature, head temperature 200 DEG C, 200 turns/min of screw speed, melt pressure 20MPa.
(3) preparation of activeness and quietness antibacterial polypropylene material
By 87.7% HOPP, 0.5% modifying titanium dioxide, 10% ultra-high molecular weight polyethylene master batch, the grafting of 1% maleic anhydride Polypropylene, 0.2% glycerol monostearate, 0.2% dibutyl tin laurate, each 0.2% primary antioxidant 3114 and auxiliary anti-oxidant 168 Then mixture Jing double screw extruders extrusion is obtained activeness and quietness antibacterial polypropylene material by the mix homogeneously in super mixer Material.Wherein polypropylene melt index is 1g/10min, and expressing technique is:One 180 DEG C of area's temperature, two 180 DEG C of area's temperature, three area's temperature 190 DEG C of degree, four 190 DEG C of area's temperature, five 190 DEG C of area's temperature, six 200 DEG C of area's temperature, seven 200 DEG C of area's temperature, eight area's temperature 210 DEG C, nine 210 DEG C of area's temperature, 200 DEG C of head temperature, 200 turns/min of screw speed, melt pressure 18MPa.
Embodiment 6
(1) surface modification of inorganic antiseptic
65 DEG C are heated to by disperse medium of isopropanol, titanate coupling agent UP-131 dispersion 5min are added, is subsequently adding inorganic Antibacterial titanium dioxide disperses 30min, dries, grinds, sieving obtains modifying titanium dioxide, and wherein UP-131 consumptions are 2%.
(2) preparation of ultra-high molecular weight polyethylene master batch
By 50% ultra-high molecular weight polyethylene, 30% linear low density polyethylene, 10% Pulvis Talci, 10% liquid paraffin in mixed at high speed Mix homogeneously in device.Mixture Jing double screw extruder extruding pelletizations are standby, and wherein ultra-high molecular weight polyethylene molecular weight is 500 Ten thousand, expressing technique is:One 200 DEG C of area's temperature, two 200 DEG C of area's temperature, three 210 DEG C of area's temperature, four 210 DEG C of area's temperature, five area's temperature 210 DEG C of degree, six 220 DEG C of area's temperature, seven 220 DEG C of area's temperature, eight 225 DEG C of area's temperature, nine 225 DEG C of area's temperature, head temperature 220 DEG C, 250 turns/min of screw speed, melt pressure 25MPa.
(3) preparation of activeness and quietness antibacterial polypropylene material
Will be 54% COPP, 5% modifying titanium dioxide, 30% ultra-high molecular weight polyethylene master batch, 8% Glycidyl methacrylate sweet Grease graft polypropylene, 1% glyceryl tristearate, 1% dibutyitin maleate, each 0.5% primary antioxidant 1010 and auxiliary anti-oxidant 618 in super mixer mix homogeneously, then by mixture Jing double screw extruders extrusion obtain activeness and quietness antibacterial poly- third Alkene material.Wherein polypropylene melt index is 25g/10min, and expressing technique is:One 190 DEG C of area's temperature, two 190 DEG C of area's temperature, Three 200 DEG C of area's temperature, four 200 DEG C of area's temperature, five 200 DEG C of area's temperature, six 210 DEG C of area's temperature, seven 210 DEG C of area's temperature, eight area's temperature 220 DEG C of degree, nine 220 DEG C of area's temperature, 210 DEG C of head temperature, 250 turns/min of screw speed, melt pressure 25MPa.
Embodiment 7
(1) surface modification of inorganic antiseptic
60 DEG C are heated to by disperse medium of ethanol, Silane coupling agent KH550 dispersion 5min are added, is subsequently adding inorganic antiseptic Zinc Oxide disperses 30min, dries, grinds, sieving obtains modified zinc oxide, and wherein KH550 consumptions are 0.5%.Same method, obtains To titanate coupling agent UP-131 modifying titanium dioxides.
(2) preparation of ultra-high molecular weight polyethylene master batch
By 30% ultra-high molecular weight polyethylene, 40% linear low density polyethylene, 15% Calcium Carbonate, 15% liquid paraffin in mixed at high speed Mix homogeneously in device.Mixture Jing double screw extruder extruding pelletizations are standby, and wherein ultra-high molecular weight polyethylene molecular weight is 250 Ten thousand, expressing technique is:One 190 DEG C of area's temperature, two 190 DEG C of area's temperature, three 200 DEG C of area's temperature, four 200 DEG C of area's temperature, five area's temperature 200 DEG C of degree, six 210 DEG C of area's temperature, seven 210 DEG C of area's temperature, eight 215 DEG C of area's temperature, nine 215 DEG C of area's temperature, head temperature 200 DEG C, 200 turns/min of screw speed, melt pressure 20MPa.
(3) preparation of activeness and quietness antibacterial polypropylene material
By 85% COPP, each 0.5% modified zinc oxide and titanium dioxide, 10% ultra-high molecular weight polyethylene master batch, 2% Malaysia Anhydride-grafted polypropylene, 0.5% glycerol monostearate, 0.5% dibutyl tin laurate, each 0.5% primary antioxidant 3114 and auxiliary anti- Then mixture Jing double screw extruders extrusion is obtained activeness and quietness antibacterial by the mix homogeneously in super mixer of oxygen agent 168 Polypropylene material.Wherein polypropylene melt index is 25g/10min, and expressing technique is:One 180 DEG C of area's temperature, two area's temperature 180 DEG C, three 190 DEG C of area's temperature, four 190 DEG C of area's temperature, five 190 DEG C of area's temperature, six 200 DEG C of area's temperature, seven 200 DEG C of area's temperature, 8th area 210 DEG C of temperature, nine 210 DEG C of area's temperature, 200 DEG C of head temperature, 200 turns/min of screw speed, melt pressure 18MPa.
Embodiment 8
(1) surface modification of inorganic antiseptic
70 DEG C are heated to by disperse medium of isopropanol, silane coupler DL602 dispersion 5min are added, is subsequently adding inorganic antibacterial Agent Zinc Oxide disperses 30min, dries, grinds, sieving obtains modified zinc oxide, and wherein DL602 consumptions are 2%.Same method, obtains To titanate coupling agent JW-105 modifying titanium dioxides.
(2) preparation of ultra-high molecular weight polyethylene master batch
By 50% ultra-high molecular weight polyethylene, 30% linear low density polyethylene, 10% potassium titanate crystal whisker, 10% liquid paraffin at a high speed Mix homogeneously in blender.Mixture Jing double screw extruder extruding pelletizations are standby, wherein ultra-high molecular weight polyethylene molecular weight For 2,500,000, expressing technique is:One 190 DEG C of area's temperature, two 190 DEG C of area's temperature, three 200 DEG C of area's temperature, four 200 DEG C of area's temperature, five 200 DEG C of area's temperature, six 210 DEG C of area's temperature, seven 210 DEG C of area's temperature, eight 220 DEG C of area's temperature, nine 220 DEG C of area's temperature, head temperature 210 DEG C, 250 turns/min of screw speed, melt pressure 25MPa.
(3) preparation of activeness and quietness antibacterial polypropylene material
By 57% COPP, each 2% modified zinc oxide and titanium dioxide, 30% ultra-high molecular weight polyethylene master batch, 6% methyl-prop Olefin(e) acid ethylene oxidic ester graft polypropylene, 1% glyceryl tristearate, 1% dibutyitin maleate, each 0.5% primary antioxidant 1010 With auxiliary anti-oxidant 618 in super mixer mix homogeneously, then by mixture Jing double screw extruders extrusion obtain strengthen increase Tough antibacterial polypropylene material.Wherein polypropylene melt index is 25g/10min, and expressing technique is:One 180 DEG C of area's temperature, 2nd area 180 DEG C of temperature, three 190 DEG C of area's temperature, four 190 DEG C of area's temperature, five 190 DEG C of area's temperature, six 200 DEG C of area's temperature, seven area's temperature 200 DEG C, eight 210 DEG C of area's temperature, nine 210 DEG C of area's temperature, 200 DEG C of head temperature, 250 turns/min of screw speed, melt pressure 25MPa.
Comparative example 1
60 DEG C are heated to by disperse medium of ethanol, Silane coupling agent KH550 dispersion 5min are added, is subsequently adding inorganic antiseptic Zinc Oxide disperses 30min, dries, grinds, sieving obtains modified zinc oxide, and wherein KH550 consumptions are 0.5%.Then by 95.6% COPP, 1% modified zinc oxide, 2% maleic anhydride inoculated polypropylene, 0.5% glyceryl tristearate, 0.5% maleic acid two Butyl tin, each 0.2% primary antioxidant 1010 and auxiliary anti-oxidant 618 mix homogeneously in super mixer, it is then that mixture Jing is double Screw extruder extrusion obtains modified zinc oxide polypropylene material.Wherein polypropylene melt index be 25g/10min, expressing technique For:One 180 DEG C of area's temperature, two 180 DEG C of area's temperature, three 190 DEG C of area's temperature, four 190 DEG C of area's temperature, five 190 DEG C of area's temperature, 6th area 200 DEG C of temperature, seven 200 DEG C of area's temperature, eight 210 DEG C of area's temperature, nine 210 DEG C of area's temperature, 200 DEG C of head temperature, screw speed 250 Turn/min, melt pressure 25MPa.
Comparative example 2
70 DEG C are heated to by disperse medium of isopropanol, titanate coupling agent UP-131 dispersion 5min are added, is subsequently adding inorganic Antibacterial titanium dioxide disperses 30min, dries, grinds, sieving obtains modifying titanium dioxide, and wherein UP-131 consumptions are 2%.With Afterwards by 84% COPP, 5% modifying titanium dioxide, 8% glycidyl methacrylate graft polypropylene, 1% 3 stearic acid Glyceride, 1% dibutyitin maleate, each 0.5% primary antioxidant 1010 and auxiliary anti-oxidant 618 mix in super mixer It is even, mixture Jing double screw extruders extrusion is obtained into titania modified polypropylene material then.Wherein polypropylene fusion refers to It is 25g/10min to count, and expressing technique is:One 180 DEG C of area's temperature, two 180 DEG C of area's temperature, three 190 DEG C of area's temperature, four area's temperature 190 DEG C, five 190 DEG C of area's temperature, six 200 DEG C of area's temperature, seven 200 DEG C of area's temperature, eight 210 DEG C of area's temperature, nine 210 DEG C of area's temperature, 200 DEG C of head temperature, 250 turns/min of screw speed, melt pressure 25MPa.
Comparative example 3
By 40% ultra-high molecular weight polyethylene, 30% linear low density polyethylene, 15% Calcium Carbonate, 15% liquid paraffin in mixed at high speed Mix homogeneously in device.Mixture Jing double screw extruder extruding pelletizations are standby, and wherein ultra-high molecular weight polyethylene molecular weight is 150 Ten thousand, expressing technique is:One 190 DEG C of area's temperature, two 190 DEG C of area's temperature, three 200 DEG C of area's temperature, four 200 DEG C of area's temperature, five area's temperature 200 DEG C of degree, six 210 DEG C of area's temperature, seven 210 DEG C of area's temperature, eight 220 DEG C of area's temperature, nine 220 DEG C of area's temperature, head temperature 210 DEG C, 240 turns/min of screw speed, melt pressure 23MPa.Subsequently by 76% COPP, 20% ultra-high molecular weight polyethylene is female Grain, 2% maleic anhydride inoculated polypropylene, 0.5% glyceryl tristearate, 0.5% dibutyitin maleate, each 0.5% primary antioxidant 1010 and the mix homogeneously in super mixer of auxiliary anti-oxidant 618, then mixture Jing double screw extruders extrusion is increased Strong toughness reinforcing antibacterial polypropylene material.Wherein polypropylene melt index is 25g/10min, and expressing technique is:One 180 DEG C of area's temperature, Two 180 DEG C of area's temperature, three 190 DEG C of area's temperature, four 190 DEG C of area's temperature, five 190 DEG C of area's temperature, six 200 DEG C of area's temperature, seven area's temperature 200 DEG C of degree, eight 210 DEG C of area's temperature, nine 210 DEG C of area's temperature, 200 DEG C of head temperature, 250 turns/min of screw speed, melt pressure 25MPa。
Performance evaluation mode and implementation standard:
By the particle for preparing as stated above, 5~6h is dried in 80~90 DEG C of convection oven, then again by dried grain Son carries out injection moulding sample preparation in injector.
Tensile property is tested:Carry out by GB/T 1040-2006 standards, specimen size is 170mm*10mm*4mm, stretching speed Rate is 50mm/min.
Bending property is tested:Carry out by GB/T 9341-2000 standards, specimen size is 80mm*10mm*4mm, bending speed Spend for 2mm/min.
Simply supported beam notch impact strength is tested:GB/T 1043.1-2008 standards are carried out, and pattern size is 60mm*10mm* 4mm。
Anti-microbial property detection is investigated with reference to People's Republic of China's light industry standard QB/T2591-2003 film applicator coating The bacteriostasis rate of sample 24h, the measure of total plate count are counted with reference to QB/T4789.2-2003.By the antibacterial model system of injection formed Into 50mm*50mm.The calculating formula of antibiotic rate is as follows:
Wherein, B represents the average bacterial count recovered of control sample, cfu/ pieces;C represents antibiotic plastic sample average bacterial count recovered, cfu/ Piece.
1 embodiment of table, 1~8 mechanics and anti-microbial property
TEM photos of the Fig. 1 for Silane coupling agent KH550 modified nano zinc oxide powder body in embodiment 1, modified nano zine oxide Reunion degree reduces.
SEM photographs of the Fig. 2 for 3 polypropylene impact fracture surface of embodiment, nano zine oxide are uniformly dispersed in polypropylene.

Claims (10)

1. a kind of activeness and quietness antibacterial polypropylene material, it is characterised in that polypropylene, inorganic antiseptic, superhigh molecular weight polyethylene The proportioning of alkene master batch, graft polypropylene, dispersant, stabilizer and antioxidant percentage is as follows:
Polypropylene 54~87.7%
Inorganic antiseptic 0.5~5%
Ultra-high molecular weight polyethylene master batch 10~30%
Graft polypropylene 1~8%
Dispersant 0.2~1%
Stabilizer 0.2~1%
Antioxidant 0.4~1%.
2. activeness and quietness antibacterial polypropylene material as claimed in claim 1, it is characterised in that described polypropylene be homopolymerization and One kind or its combination in COPP, its melt index is 1~25g/10min;The graft polypropylene is maleic anhydride One kind or its combination in graft polypropylene or glycidyl methacrylate graft polypropylene.
3. activeness and quietness antibacterial polypropylene material as claimed in claim 1, it is characterised in that described antibacterial is nanometer nothing One kind or its combination in machine antibacterial, composite hybridization nano inorganic antimicrobial agent;Described dispersant be ethylene group bis-stearamides, One kind or its combination in glycerol monostearate, glyceryl tristearate.
4. activeness and quietness antibacterial polypropylene material as claimed in claim 1, it is characterised in that described stabilizer is organotin One kind or its combination in apoplexy due to endogenous wind dibutyl tin laurate, dibutyitin maleate, dibutyltin mercaptide;Described antioxidant is Primary antioxidant and auxiliary anti-oxidant, primary antioxidant are the one kind in hindered phenol and sulphur ester antioxidant or its combination, and auxiliary anti-oxidant is One kind or its combination in phosphorite kind antioxidant.
5. the activeness and quietness antibacterial polypropylene material as described in claim 1-4 is arbitrary, it is characterised in that to increase inorganic antibacterial The affinity of agent and fluoropolymer resin, the inorganic antiseptic being modified using coupling agent surface, wherein coupling agent be silane coupler, Titanate coupling agent, one kind of aluminate coupling agent or its combination.
6. activeness and quietness antibacterial polypropylene material as claimed in claim 1, it is characterised in that described superhigh molecular weight polyethylene Alkene master batch is made up of following substances in percentage by weight:
Ultra-high molecular weight polyethylene 30~50%
Linear low density polyethylene 30~40%
Inorganic particle 10~15%
Compatilizer 10~15%.
7. activeness and quietness antibacterial polypropylene material as claimed in claim 6, it is characterised in that described superhigh molecular weight polyethylene The molecular weight of alkene is 150~5,000,000;Described linear low density polyethylene density is 0.92g/cm3, melt index is 24g/ 10min。
8. activeness and quietness antibacterial polypropylene material as claimed in claim 6, it is characterised in that described inorganic particle is carbonic acid One kind or its combination in calcium, Pulvis Talci, carbon fiber, glass fibre, silicon dioxide, potassium titanate crystal whisker;Described compatilizer is Liquid paraffin, molecular weight are 100~200 g/mol.
9. the activeness and quietness antibacterial polypropylene material as described in claim 6-8 is arbitrary, it is characterised in that described supra polymer Weight northylen master batch preparation process is as follows:By the ultra-high molecular weight polyethylene of certain proportioning, linear low density polyethylene, inorganic powder The body and compatilizer mix homogeneously in super mixer, then by mixture Jing double screw extruder extruding pelletizations, expressing technique For:One 190~200 DEG C of area's temperature, two 190~200 DEG C of area's temperature, three 200~210 DEG C of area's temperature, four area's temperature 200~210 DEG C, five 200~210 DEG C of area's temperature, six 210~220 DEG C of area's temperature, seven 210~220 DEG C of area's temperature, eight area's temperature 215~225 DEG C, nine 215~225 DEG C of area's temperature, 200~220 DEG C of head temperature, 200~250 turns/min of screw speed, melt pressure 20~ 25MPa。
10., according to a kind of arbitrary preparation method of activeness and quietness antibacterial polypropylene material of claim 1-5, its feature exists In by double screw extruder by polypropylene, inorganic antiseptic, ultra-high molecular weight polyethylene master batch, graft polypropylene, dispersion Cooling granulation after agent, stabilizer and antioxidant melting extrusion, is obtained activeness and quietness antibacterial polypropylene material, and step is as follows:
(1)First at a certain temperature, using coupling agent inorganic antiseptic is carried out surface be modified, surface modification temperature be 60~ 70 DEG C, coupling agent consumption is 0.5~2%;
(2)Polypropylene, inorganic antiseptic, ultra-high molecular weight polyethylene master batch, graft polypropylene, dispersion are weighed by weight ratio Agent, stabilizer and antioxidant mix in super mixer 15~20 minutes;
(3)Mixed raw material is added in double screw extruder, the cooling granulation Jing after melting extrusion, expressing technique is:One area 180~190 DEG C of temperature, two 180~190 DEG C of area's temperature, three 190~200 DEG C of area's temperature, four 190~200 DEG C of area's temperature, 5th area 190~200 DEG C of temperature, six 200~210 DEG C of area's temperature, seven 200~210 DEG C of area's temperature, eight 210~220 DEG C of area's temperature, 9th area 210~220 DEG C of temperature, 200~210 DEG C of head temperature, 200~250 revs/min of screw speed, 18~25MPa of pressure.
CN201611029882.XA 2016-11-22 2016-11-22 Reinforced and toughened antibacterial polypropylene material and preparing method thereof Pending CN106589582A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107793640A (en) * 2017-11-01 2018-03-13 上海纳米技术及应用国家工程研究中心有限公司 Activeness and quietness antibacterial polypropylene material and its preparation method and application
CN108034148A (en) * 2017-12-28 2018-05-15 东北林业大学 A kind of antibacterial type cellulose/PP composite material and preparation method
CN108329587A (en) * 2018-01-31 2018-07-27 天津科技大学 A kind of novel PP elastomers TPO
CN109306115A (en) * 2018-08-24 2019-02-05 苏州润佳工程塑料股份有限公司 A kind of PP composite material and preparation method thereof with rubber sense of touch
CN109456563A (en) * 2018-09-06 2019-03-12 福建师范大学 A kind of UHMWPE alloy compatibilization and toughening modified polypropene ripple pipe as special material and preparation method thereof
CN109851920A (en) * 2019-01-31 2019-06-07 温州市疾病预防控制中心 A kind of antimicrobial form food pack
CN112574488A (en) * 2019-09-30 2021-03-30 四川大学 Modified master batch for polyolefin reinforcement and toughening and preparation method thereof
CN112724579A (en) * 2020-10-29 2021-04-30 天津金发新材料有限公司 Antibacterial low-odor polypropylene composite material for automotive interior and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101089038A (en) * 2007-06-08 2007-12-19 深圳市科聚新材料有限公司 Antibacterial polypropylene material and its prepn process
CN102070831A (en) * 2010-12-21 2011-05-25 东华大学 Polypropylene-toughening compound material and preparation method thereof
CN102850651A (en) * 2012-09-04 2013-01-02 江苏兆鋆新材料科技有限公司 Antioxidation and antibacterial polypropylene material and preparation method thereof
CN103627088A (en) * 2013-12-02 2014-03-12 上海纳米技术及应用国家工程研究中心有限公司 Reinforced and toughened anti-bacterial polypropylene composition and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101089038A (en) * 2007-06-08 2007-12-19 深圳市科聚新材料有限公司 Antibacterial polypropylene material and its prepn process
CN102070831A (en) * 2010-12-21 2011-05-25 东华大学 Polypropylene-toughening compound material and preparation method thereof
CN102850651A (en) * 2012-09-04 2013-01-02 江苏兆鋆新材料科技有限公司 Antioxidation and antibacterial polypropylene material and preparation method thereof
CN103627088A (en) * 2013-12-02 2014-03-12 上海纳米技术及应用国家工程研究中心有限公司 Reinforced and toughened anti-bacterial polypropylene composition and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107793640A (en) * 2017-11-01 2018-03-13 上海纳米技术及应用国家工程研究中心有限公司 Activeness and quietness antibacterial polypropylene material and its preparation method and application
CN108034148A (en) * 2017-12-28 2018-05-15 东北林业大学 A kind of antibacterial type cellulose/PP composite material and preparation method
CN108034148B (en) * 2017-12-28 2020-06-05 东北林业大学 Antibacterial cellulose/polypropylene composite material and preparation method thereof
CN108329587A (en) * 2018-01-31 2018-07-27 天津科技大学 A kind of novel PP elastomers TPO
CN109306115A (en) * 2018-08-24 2019-02-05 苏州润佳工程塑料股份有限公司 A kind of PP composite material and preparation method thereof with rubber sense of touch
CN109456563A (en) * 2018-09-06 2019-03-12 福建师范大学 A kind of UHMWPE alloy compatibilization and toughening modified polypropene ripple pipe as special material and preparation method thereof
CN109456563B (en) * 2018-09-06 2021-05-04 福建师范大学 Special material for UHMWPE alloy compatibilization toughening modified polypropylene corrugated pipe and preparation method thereof
CN109851920A (en) * 2019-01-31 2019-06-07 温州市疾病预防控制中心 A kind of antimicrobial form food pack
CN112574488A (en) * 2019-09-30 2021-03-30 四川大学 Modified master batch for polyolefin reinforcement and toughening and preparation method thereof
CN112724579A (en) * 2020-10-29 2021-04-30 天津金发新材料有限公司 Antibacterial low-odor polypropylene composite material for automotive interior and preparation method thereof

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Application publication date: 20170426