CN107674619A - A kind of floating bead is modified non-bituminous base adhesive waterproof coil - Google Patents
A kind of floating bead is modified non-bituminous base adhesive waterproof coil Download PDFInfo
- Publication number
- CN107674619A CN107674619A CN201711130651.2A CN201711130651A CN107674619A CN 107674619 A CN107674619 A CN 107674619A CN 201711130651 A CN201711130651 A CN 201711130651A CN 107674619 A CN107674619 A CN 107674619A
- Authority
- CN
- China
- Prior art keywords
- floating bead
- base adhesive
- adhesive waterproof
- modified non
- waterproof coil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention provides a kind of floating bead and is modified non-bituminous base adhesive waterproof coil, it is characterised in that is formulated by mass percentage including following material：Electron rich system softening oil (a kind of mixture, because its contain big pi bond but electron rich system) 15~48%, PUR level elastomer 0.5~6%, styrene butadiene styrene block copolymer 2~10%, tackified rubber 1~5%, waste rubber elastomer 5~20%, UV resistance agent 0.1~0.5%, high-temperature resin 3~8%, tackifying resin 8~20%, interfacial agents 0.1~0.2%, floating bead 5~30%, gutter oil 5~15%.
Description
Technical field
The present invention relates to chemical industry waterproof material technical field, specifically a kind of self-adhesion for being different from traditional asphalt base is prevented
Water material.
Background technology
It is constantly soaring with the price of pitch；The technology of self-adhesive coiled material is increasingly mature, because technology is increasingly mature so that one
A little small a large amount of substandard products of station-service flood market, so the good and bad jumbled together for many pitch adhesive waterproof coils of in the market, so as to cause waterproof
Quality cannot be guaranteed；At this stage, requirement of the people to environmental protection is more and more stricter, and pitch is the thing of an extremely complex composition
Matter, the inside are contained much to the disagreeableness material of environment, and environmental protection can be influenceed due to the presence of pitch；People are prevented waterproof material
The water time limit requires more and more higher, and pitch its weatherability is very limited amount of；In addition, traditional waterproof roll is due to own wt
It is larger, no small difficulty is brought to storage, construction, simultaneously because powder, than great, mixing need to be warming up to 200 DEG C or so,
Energy consumption is increased, and environmental pollution is larger.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of floating bead to be modified non-bituminous base adhesive waterproof coil, this
Non-bituminous base adhesive waterproof coil is by floating bead as main stuffing, and floating bead is a kind of fly ash hollow ball, light, high intensity,
Grain is thin, specific surface area is big, and because floating bead is hollow ball structure, during extrusion forming is mixed, carcass consistency is high, significantly
The transmitance of hydrone has been obstructed, has improved the water resistance of waterproof roll, the filler of sphere structure hinders in whipping process in addition
Power is small, and filling is evenly abundant, can effectively reduce mixing temperature, reduces energy consumption, while the waterproof roll weight being prepared is
The half of traditional asphalt coiled material is even lower, and facility is brought to transport and construction.
A kind of floating bead provided by the invention is modified non-bituminous base adhesive waterproof coil, it is characterised in that by mass percentage
It is formulated including following material：
Electron rich system softening oil 15~48%, PUR level elastomer 0.5~6%, s-B-S
Block copolymer 2~10%, tackified rubber 1~5%, waste rubber elastomer 5~20%, UV resistance agent 0.1~0.5%, height
Warm resin 3~8%, tackifying resin 8~20%, interfacial agents 0.1~0.2%, floating bead 5~30%, gutter oil 5~15%.
Described softening oil be tapped oil (oil of the Extract of petroleum distillate solvent refining after desolvation), heavy oil and
1~3 kind in light oil.
Described SBS (SBS) is that line style s-B-S is embedding
1~2 kind in section copolymer (SBS), star benzene blending ethylene-butadiene-styrene block copolymer (SBS).
Described PUR level elastomer is ethane-acetic acid ethyenyl (vinyl acetate) ester copolymer (EVA), acrylic acid and
1~3 kind of butyl rubber.
Described tackified rubber is butadiene-styrene rubber, SIS (SIS), butylbenzene rubber
1~3 kind in rubber powder (SBR).
Described waste rubber elastomer is 1~2 kind in devulcanized rubber powder and sole rubber.
Described UV resistance agent is 1~5 kind in UV531, UV327, UV328, UV320, UV1164.
The high-temperature resin is high softening point resin, in high softening-point Petropols and high softening-point coumarone indene resin
1~2 kind.Described tackifying resin is C9 Petropols, terpene resin, modified terpene resin, rosin resin and modified rosin tree
1~5 kind in fat.
Described interfacial agents are mainly used for improving the infiltration with base material to meet water dissolvable epoxy modification acrylate
Power.
The present invention has advantages below：
1st, persistently splendid adhesive property, it can form fine and close and high intensity the fourth of the twelve Earthly Branches with cast-in-place concrete and connect face；
2nd, superpower stripping performance, stripping performance are 2~3 times of traditional asphalt base volume material, are closely combined with concrete,
Form the waterproof barrier of skin formula；
3rd, material is non-bituminous base, less smell, is greatly reduced in production and work progress to the bad shadow of personnel
Ring, safety and environmental protection；
4th, excellent weather resistance, solve traditional asphalt base volume material and lose the disadvantage of waterproof effect with time and season passage
Disease；
5th, good heat endurance and low-temperature bending performance are adapted to even low temperature high thermal etc. extreme climate area in all parts of the country
With used under environment；
6th, the waterproof roll weight being prepared is that the half of traditional coiled material is even lower, to storage, transport and construction band
Facility is carried out；
7th, turn waste into wealth, industry or life waste material are subjected to product modification as inserts, ensureing the feelings of properties of product
Production cost is not only reduced under condition, while effectively solves gutter oil, the problem of environmental pollution that flyash is brought.
Embodiment
Embodiment 1
Tapped oil 30%, gutter oil (edible oil of recovery) 10%, PUR level elastomer (EVA) the 4%, (LG of SBS 411
Company star benzene blending ethylene-butadiene-styrene block copolymer, the trade mark be 411) 6.8%, SIS 2%, high softening-point it is ancient
The grand resin 5% of horse, C9 Petropols 15%, devulcanized rubber powder 12%, floating bead 15%, ultraviolet agent (UV531) 0.1%, interface
Agent (meeting water dissolvable epoxy modification acrylate) 0.1%.
The non-bituminous base waterproof roll being prepared according to the above-mentioned technological process of production, properties of product are as follows：Peel strength
3.7N/mm, and Concrete Bond Strength are 5.0N/mm, and -30 DEG C of low-temperature tenderness is not broken, and 70 DEG C of high temperature resistant is not trickled, resistance to ultraviolet
Peel strength 2.0N/mm after line aging, -25 DEG C of low-temperature tenderness is not broken, and 70 DEG C of high temperature resistant is not trickled, and is peeled off after heat-proof aging strong
2.5N/mm is spent, -25 DEG C of low-temperature tenderness is not broken, and 70 DEG C of high temperature resistant is not trickled.Fully meet the II types of national standard GB/T 23441 and
The wet-laying P class II types of GB/T 23457.
Embodiment 2
Heavy oil 32%, gutter oil (edible oil of recovery) 7%, PUR level elastomer (EVA) 6%, styrene-fourth two
(Yueyang petrochemical industry line style SBS (SBS) trade mark is alkene-styrene block copolymer
1301) 8.8%, SIS 1%, high softening-point coumarone indene resin 7%, C9 Petropols 15%, devulcanized rubber powder 13%, floating bead
10%th, UV resistant agent (UV327) 0.1%, interfacial agents (meeting water dissolvable epoxy modification acrylate) 0.1%.
The non-bituminous base waterproof roll being prepared according to the above-mentioned technological process of production, properties of product are as follows：Peel strength
4.3N/mm, and Concrete Bond Strength are 4.5N/mm, and -30 DEG C of low-temperature tenderness is not broken, and 70 DEG C of high temperature resistant is not trickled, resistance to ultraviolet
Peel strength 2.2N/mm after line aging, -25 DEG C of low-temperature tenderness is not broken, and 70 DEG C of high temperature resistant is not trickled, and is peeled off after heat-proof aging strong
2.3N/mm is spent, -25 DEG C of low-temperature tenderness is not broken, and 70 DEG C of high temperature resistant is not trickled.Fully meet the II types of national standard GB/T 23441 and
The wet-laying P class II types of GB/T 23457.
Embodiment 3
Light oil 30%, gutter oil (edible oil of recovery), PUR level elastomer (EVA) 2%, styrene-butadiene-benzene
Ethylene block copolymer (SBS 411) 2%, SBR 1%, high softening-point coumarone indene resin 7%, C9 Petropols 10%, sole
Glue 16%, floating bead 19.8%, ultraviolet agent (UV1164) 0.1%, interfacial agents (meeting water dissolvable epoxy modification acrylate)
0.1%.
The non-bituminous base waterproof roll being prepared according to the above-mentioned technological process of production, properties of product are as follows：Peel strength
3.3N/mm, and Concrete Bond Strength are 4.0N/mm, and -30 DEG C of low-temperature tenderness is not broken, and 70 DEG C of high temperature resistant is not trickled, resistance to ultraviolet
Peel strength 1.8N/mm after line aging, -25 DEG C of low-temperature tenderness is not broken, and 70 DEG C of high temperature resistant is not trickled, and is peeled off after heat-proof aging strong
2.0N/mm is spent, -25 DEG C of low-temperature tenderness is not broken, and 70 DEG C of high temperature resistant is not trickled.Fully meet the II types of national standard GB/T 23441 and
The wet-laying P class II types of GB/T 23457.
Claims (10)
1. a kind of floating bead is modified non-bituminous base adhesive waterproof coil, it is characterised in that matches somebody with somebody by mass percentage including following material
System forms：
Electron rich system softening oil 15~48%, PUR level elastomer 0.5~6%, s-B-S block
Copolymer 2~10%, tackified rubber 1~5%, waste rubber elastomer 5~20%, UV resistance agent 0.1~0.5%, high temperature tree
Fat 3~8%, tackifying resin 8~20%, interfacial agents 0.1~0.2%, floating bead 5~30%, gutter oil 5~15%.
2. a kind of floating bead according to claim 1 is modified non-bituminous base adhesive waterproof coil, it is characterised in that：Described is soft
Carburetion is 1~3 kind in tapped oil, heavy oil and light oil.
3. a kind of floating bead according to claim 1 is modified non-bituminous base adhesive waterproof coil, it is characterised in that：Described benzene
Ethylene-butadiene-styrene block copolymer is line style SBS, star benzene blending second
1~2 kind in alkene-butadiene-styrene block copolymer.
4. a kind of floating bead according to claim 1 is modified non-bituminous base adhesive waterproof coil, it is characterised in that：Described heat
Melten gel level elastomer is 1~3 kind in ethane-acetic acid ethyenyl (vinyl acetate) ester copolymer, acrylic acid and butyl rubber.
5. a kind of floating bead according to claim 1 is modified non-bituminous base adhesive waterproof coil, it is characterised in that：Described increasing
Viscous rubber is butadiene-styrene rubber, 1~3 kind in SIS, styrene butadiene rubber powder.
6. a kind of floating bead according to claim 1 is modified non-bituminous base adhesive waterproof coil, it is characterised in that：Described is useless
Rubber elastomer is abandoned as 1~2 kind in devulcanized rubber powder and sole rubber.
7. a kind of floating bead according to claim 1 is modified non-bituminous base adhesive waterproof coil, it is characterised in that described is anti-
Ultraviolet dose is 1~5 kind in UV531, UV327, UV328, UV320 and UV1164.
8. a kind of floating bead according to claim 1 is modified non-bituminous base adhesive waterproof coil, it is characterised in that：The high temperature
Resin is high softening point resin.
9. a kind of floating bead according to claim 1 is modified non-bituminous base adhesive waterproof coil, it is characterised in that：Described increasing
Viscosity resin is 1~5 kind in C9 Petropols, terpene resin, modified terpene resin, rosin resin and modified rosin resin.
10. a kind of floating bead according to claim 1 is modified non-bituminous base adhesive waterproof coil, it is characterised in that：The boundary
Face agent is chance water dissolvable epoxy modified acrylic resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711130651.2A CN107674619A (en) | 2017-11-15 | 2017-11-15 | A kind of floating bead is modified non-bituminous base adhesive waterproof coil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711130651.2A CN107674619A (en) | 2017-11-15 | 2017-11-15 | A kind of floating bead is modified non-bituminous base adhesive waterproof coil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107674619A true CN107674619A (en) | 2018-02-09 |
Family
ID=61149286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711130651.2A Pending CN107674619A (en) | 2017-11-15 | 2017-11-15 | A kind of floating bead is modified non-bituminous base adhesive waterproof coil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107674619A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110564030A (en) * | 2019-09-09 | 2019-12-13 | 安徽法莱科技有限公司 | Para-aramid high-strength self-adhesive waterproof material and preparation method thereof |
| CN111518475A (en) * | 2020-06-02 | 2020-08-11 | 岳阳市科兴防水材料有限公司 | Smokeless non-cured rubber waterproof coating and preparation method thereof |
| CN114381212A (en) * | 2021-12-27 | 2022-04-22 | 合肥中科凯辰新材料有限公司 | Polyurethane self-adhesive film waterproof coiled material, preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104099039A (en) * | 2014-06-26 | 2014-10-15 | 青岛博洋生物技术有限公司 | Sticky water-proof material and preparation method thereof |
| CN105112012A (en) * | 2015-08-26 | 2015-12-02 | 湖北蓝盾之星科技股份有限公司 | Physicochemical-crosslinking-reaction high-polymer self-adhesive water-resistant coiled material |
| CN106398642A (en) * | 2016-08-26 | 2017-02-15 | 广西青龙化学建材有限公司 | High viscosity non-asphalt base self-adhesive glue for waterproof coiled materials and preparation method thereof |
| CN106810954A (en) * | 2015-12-02 | 2017-06-09 | 天长市地震办公室 | A kind of heat insulating coating material for wall |
-
2017
- 2017-11-15 CN CN201711130651.2A patent/CN107674619A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104099039A (en) * | 2014-06-26 | 2014-10-15 | 青岛博洋生物技术有限公司 | Sticky water-proof material and preparation method thereof |
| CN105112012A (en) * | 2015-08-26 | 2015-12-02 | 湖北蓝盾之星科技股份有限公司 | Physicochemical-crosslinking-reaction high-polymer self-adhesive water-resistant coiled material |
| CN106810954A (en) * | 2015-12-02 | 2017-06-09 | 天长市地震办公室 | A kind of heat insulating coating material for wall |
| CN106398642A (en) * | 2016-08-26 | 2017-02-15 | 广西青龙化学建材有限公司 | High viscosity non-asphalt base self-adhesive glue for waterproof coiled materials and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 竹涛: "《矿山固体废物处理与处置工程》", 30 June 2016, 冶金工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110564030A (en) * | 2019-09-09 | 2019-12-13 | 安徽法莱科技有限公司 | Para-aramid high-strength self-adhesive waterproof material and preparation method thereof |
| CN111518475A (en) * | 2020-06-02 | 2020-08-11 | 岳阳市科兴防水材料有限公司 | Smokeless non-cured rubber waterproof coating and preparation method thereof |
| CN111518475B (en) * | 2020-06-02 | 2021-11-23 | 岳阳市科兴防水材料有限公司 | Smokeless non-cured rubber waterproof coating and preparation method thereof |
| CN114381212A (en) * | 2021-12-27 | 2022-04-22 | 合肥中科凯辰新材料有限公司 | Polyurethane self-adhesive film waterproof coiled material, preparation method and application thereof |
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Application publication date: 20180209 |