CN107674613A - Medical medicine box binding agent - Google Patents
Medical medicine box binding agent Download PDFInfo
- Publication number
- CN107674613A CN107674613A CN201711227558.3A CN201711227558A CN107674613A CN 107674613 A CN107674613 A CN 107674613A CN 201711227558 A CN201711227558 A CN 201711227558A CN 107674613 A CN107674613 A CN 107674613A
- Authority
- CN
- China
- Prior art keywords
- parts
- medicine box
- binding agent
- medical medicine
- box binding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention discloses a kind of medical medicine box binding agent, belongs to medical macromolecular materials technical field.The present invention it be made using the raw materials of following parts by weight：10 parts~15 parts of 65 parts~85 parts of polyacrylate, 15 parts~20 parts of chlorinated polypropylene, 5 parts~10 parts of rosin modified phenolic resin, 5 parts~10 parts of carbon fiber, 5 parts~10 parts of ox-hide cream, 1 part~5 parts of acetic acid, 3 parts~7 parts of phosphoric acid, 4 parts~8 parts of dioctyl phthalate, 1 part~5 parts of hydroquinones and deionized water.The present invention in original medical medicine box binding agent conventional formulation on the basis of add chlorinated polypropylene, rosin modified phenolic resin, carbon fiber, ox-hide cream, by using mutual compatibility effect improve the medical medicine box binding agent of finished product bonding strength.
Description
Technical field
The invention belongs to medical macromolecular materials technical field, more particularly to a kind of medical medicine box binding agent.
Background technology
Medical medicine box be for packing medical box, wherein, medicine box can be divided into medicine box packaging with two kinds of Medicine box composed of several small boxes, its
In, common Medicine box composed of several small boxes is the medicine box most often mentioned in spoken language.Typically with plastic production more than food-grade, main material be PP or
ABS, also there is part to be made with metal material.The connection combination of its each component is mainly realized by binding agent.
At present, the species of the existing binding agent of in the market is a lot, but due to the particularity of medical drugs box material, is not to say that
It is to have binding agent to be all suitable for.For example, when most binding agent is used to be bonded medical medicine box, each component bonding is often shown not
Firmly, easily there is crack, the phenomenon of poor sealing.
The content of the invention
The present invention provides a kind of medical medicine box binding agent, so as to solve existing medical medicine box binding agent for being bonded
Have that medical medicine box each component bonding is unstable, the problem of crack, poor sealing easily occurs during medical medicine box.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
It is made using the raw material of following parts by weight：
65 parts~85 parts of polyacrylate, 15 parts~20 parts of chlorinated polypropylene, 5 parts~10 parts of rosin modified phenolic resin, carbon are fine
5 parts~10 parts of dimension, 5 parts~10 parts of ox-hide cream, 1 part~5 parts of acetic acid, 3 parts~7 parts of phosphoric acid, dioctyl phthalate 4 parts~8
10 parts~15 parts of part, 1 part~5 parts of hydroquinones and deionized water.
In above-mentioned technical proposal, more specifically technical scheme can also be：65 parts of polyacrylate, chlorinated polypropylene 15
Part, 5 parts of rosin modified phenolic resin, 5 parts of carbon fiber, 5 parts of ox-hide cream, 1 part of acetic acid, 3 parts of phosphoric acid, dioctyl phthalate 4
10 parts of part, 1 part of hydroquinones and deionized water.
Further, 75 parts of polyacrylate, 17 parts of chlorinated polypropylene, 7 parts of rosin modified phenolic resin, 7 parts of carbon fiber,
12 parts of 7 parts of ox-hide cream, 2 parts of acetic acid, 5 parts of phosphoric acid, 5 parts of dioctyl phthalate, 3 parts of hydroquinones and deionized water.
Further, 80 parts of polyacrylate, 18 parts of chlorinated polypropylene, 8 parts of rosin modified phenolic resin, 8 parts of carbon fiber,
14 parts of 8 parts of ox-hide cream, 4 parts of acetic acid, 6 parts of phosphoric acid, 7 parts of dioctyl phthalate, 4 parts of hydroquinones and deionized water.
Further, 85 parts of polyacrylate, 20 parts of chlorinated polypropylene, 10 parts of rosin modified phenolic resin, carbon fiber 10
Part, 10 parts of ox-hide cream, 5 parts of acetic acid, 7 parts of phosphoric acid, 8 parts of dioctyl phthalate, 5 parts of hydroquinones and deionized water 15
Part.
Due to being had the advantages that using above-mentioned technical proposal, the present invention：
The present invention in original medical medicine box binding agent conventional formulation on the basis of add chlorinated polypropylene, rosin modified phenolic tree
Fat, carbon fiber, ox-hide cream, the bonding strength of the medical medicine box binding agent of finished product is improved by using mutual compatibility effect.
Embodiment
Below in conjunction with instantiation, the invention will be further described：
Embodiment 1 --- medical medicine box binding agent
It uses following raw material：
Polyacrylate 65kg, chlorinated polypropylene 15kg, rosin modified phenolic resin 5kg, carbon fiber 5kg, ox-hide cream 5kg, vinegar
Sour 1kg, phosphoric acid 3kg, dioctyl phthalate 4kg, hydroquinones 1kg and deionized water 10kg；
Its preparation method comprises the following steps：
According to the above ratio, first by polyacrylate, chlorinated polypropylene, rosin modified phenolic resin, ox-hide cream, acetic acid, phosphoric acid with
Deionization is put into reactor, under conditions of the vacuum in the stirred tank is 0.1MPa, is heated to 50 DEG C, is stirred 10 points
Clock；Carbon fiber, dioctyl phthalate, hydroquinones are added followed by, and the vacuum in the stirred tank is 1MPa's
Under the conditions of, 80 DEG C are heated to, is stirred 10 minutes.
The adhesive strength of medical medicine box binding agent made from the present embodiment is 17N.
Embodiment 2 --- medical medicine box binding agent
Using following raw material：
Polyacrylate 75kg, chlorinated polypropylene 17kg, rosin modified phenolic resin 7kg, carbon fiber 7kg, ox-hide cream 7kg, vinegar
Sour 2kg, phosphoric acid 5kg, dioctyl phthalate 5kg, hydroquinones 3kg and deionized water 12kg；
Its preparation method comprises the following steps：
According to the above ratio, first by polyacrylate, chlorinated polypropylene, rosin modified phenolic resin, ox-hide cream, acetic acid, phosphoric acid with
Deionization is put into reactor, under conditions of the vacuum in the stirred tank is 0.2MPa, is heated to 52 DEG C, is stirred 7 minutes；
Carbon fiber, dioctyl phthalate, hydroquinones are added followed by, and the vacuum in the stirred tank is 2MPa condition
Under, 82 DEG C are heated to, is stirred 6 minutes.
The adhesive strength of medical medicine box binding agent made from the present embodiment is 17.3N.
Embodiment 3 --- medical medicine box binding agent
Using following raw material：
Polyacrylate 80kg, chlorinated polypropylene 18kg, rosin modified phenolic resin 8kg, carbon fiber 8kg, ox-hide cream 8kg, vinegar
Sour 4kg, phosphoric acid 6kg, dioctyl phthalate 7kg, hydroquinones 4kg and deionized water 14kg；
Its preparation method comprises the following steps：
According to the above ratio, first by polyacrylate, chlorinated polypropylene, rosin modified phenolic resin, ox-hide cream, acetic acid, phosphoric acid with
Deionization is put into reactor, under conditions of the vacuum in the stirred tank is 0.8MPa, is heated to 58 DEG C, is stirred 8 minutes；
Carbon fiber, dioctyl phthalate, hydroquinones are added followed by, and the vacuum in the stirred tank is 8MPa condition
Under, 85 DEG C are heated to, is stirred 8 minutes.
The adhesive strength of medical medicine box binding agent made from the present embodiment is 17.1N.
Embodiment 4 --- medical medicine box binding agent
Using following raw material：
Polyacrylate 85kg, chlorinated polypropylene 20kg, rosin modified phenolic resin 10kg, carbon fiber 10kg, ox-hide cream 10kg,
Acetic acid 5kg, phosphoric acid 7kg, dioctyl phthalate 8kg, hydroquinones 5kg and deionized water 15kg；
Its preparation method comprises the following steps：
According to the above ratio, first by polyacrylate, chlorinated polypropylene, rosin modified phenolic resin, ox-hide cream, acetic acid, phosphoric acid with
Deionization is put into reactor, under conditions of the vacuum in the stirred tank is 1MPa, is heated to 60 DEG C, is stirred 5 minutes；Connect
And add carbon fiber, dioctyl phthalate, hydroquinones, and the vacuum in the stirred tank is 10MPa condition
Under, 90 DEG C are heated to, is stirred 5 minutes.
The adhesive strength of medical medicine box binding agent made from the present embodiment is 17.6N.
Comparative example 1 --- medical medicine box binding agent
It uses following raw material：
Polyacrylate 65kg, rosin modified phenolic resin 5kg, carbon fiber 5kg, ox-hide cream 5kg, acetic acid 1kg, phosphoric acid 3kg, neighbour
Dioctyl phthalate 4kg, hydroquinones 1kg and deionized water 10kg；
Its preparation method comprises the following steps：
According to the above ratio, first polyacrylate, rosin modified phenolic resin, ox-hide cream, acetic acid, phosphoric acid and deionization are put into instead
Answer in kettle, under conditions of the vacuum in the stirred tank is 0.1MPa, be heated to 50 DEG C, stir 10 minutes；It is added followed by
Carbon fiber, dioctyl phthalate, hydroquinones, and the vacuum in the stirred tank be 1MPa under conditions of, be heated to
80 DEG C, stir 10 minutes.
The adhesive strength of medical medicine box binding agent made from this comparative example is 6.9N.
Comparative example 2 --- medical medicine box binding agent
Using following raw material：
Polyacrylate 75kg, chlorinated polypropylene 17kg, carbon fiber 7kg, ox-hide cream 7kg, acetic acid 2kg, phosphoric acid 5kg, adjacent benzene two
Formic acid dioctyl ester 5kg, hydroquinones 3kg and deionized water 12kg；
Its preparation method comprises the following steps：
According to the above ratio, polyacrylate, chlorinated polypropylene, ox-hide cream, acetic acid, phosphoric acid and deionization are first put into reactor
In, under conditions of the vacuum in the stirred tank is 0.2MPa, 52 DEG C are heated to, is stirred 7 minutes；It is added followed by carbon fibre
Dimension, dioctyl phthalate, hydroquinones, and the vacuum in the stirred tank be 2MPa under conditions of, be heated to 82 DEG C,
Stirring 6 minutes.
The adhesive strength of medical medicine box binding agent made from this comparative example is 6.6N.
Comparative example 3 --- medical medicine box binding agent
Using following raw material：
Polyacrylate 80kg, chlorinated polypropylene 18kg, rosin modified phenolic resin 8kg, acetic acid 4kg, phosphoric acid 6kg, adjacent benzene two
Formic acid dioctyl ester 7kg, hydroquinones 4kg and deionized water 14kg；
Its preparation method comprises the following steps：
According to the above ratio, first polyacrylate, chlorinated polypropylene, rosin modified phenolic resin, acetic acid, phosphoric acid and deionization are put
Enter in reactor, under conditions of the vacuum in the stirred tank is 0.8MPa, be heated to 58 DEG C, stir 8 minutes；Then add again
Enter dioctyl phthalate, hydroquinones, and under conditions of the vacuum in the stirred tank is 8MPa, be heated to 85 DEG C,
Stirring 8 minutes.
The adhesive strength of medical medicine box binding agent made from this comparative example is 6N.
Comparative example 4 --- medical medicine box binding agent
Using following raw material：
Polyacrylate 85kg, chlorinated polypropylene 20kg, rosin modified phenolic resin 10kg, carbon fiber 10kg, ox-hide cream 10kg,
Dioctyl phthalate 8kg, hydroquinones 5kg and deionized water 15kg；
Its preparation method comprises the following steps：
According to the above ratio, first polyacrylate, chlorinated polypropylene, rosin modified phenolic resin, ox-hide cream and deionization are put into
In reactor, under conditions of the vacuum in the stirred tank is 1MPa, 60 DEG C are heated to, is stirred 5 minutes；It is added followed by carbon
Fiber, dioctyl phthalate, hydroquinones, and the vacuum in the stirred tank be 10MPa under conditions of, be heated to 90
DEG C, stir 5 minutes.
The adhesive strength of medical medicine box binding agent made from this comparative example is 6.5N.
Claims (5)
1. a kind of medical medicine box binding agent, it is characterised in that be made by the raw material of following parts by weight：
65 parts~85 parts of polyacrylate, 15 parts~20 parts of chlorinated polypropylene, 5 parts~10 parts of rosin modified phenolic resin, carbon are fine
5 parts~10 parts of dimension, 5 parts~10 parts of ox-hide cream, 1 part~5 parts of acetic acid, 3 parts~7 parts of phosphoric acid, dioctyl phthalate 4 parts~8
10 parts~15 parts of part, 1 part~5 parts of hydroquinones and deionized water.
2. medical medicine box binding agent according to claim 1, it is characterised in that：
65 parts of polyacrylate, 15 parts of chlorinated polypropylene, 5 parts of rosin modified phenolic resin, 5 parts of carbon fiber, 5 parts of ox-hide cream, vinegar
10 parts of 1 part of acid, 3 parts of phosphoric acid, 4 parts of dioctyl phthalate, 1 part of hydroquinones and deionized water.
3. medical medicine box binding agent according to claim 1, it is characterised in that：
75 parts of polyacrylate, 17 parts of chlorinated polypropylene, 7 parts of rosin modified phenolic resin, 7 parts of carbon fiber, 7 parts of ox-hide cream, vinegar
12 parts of 2 parts of acid, 5 parts of phosphoric acid, 5 parts of dioctyl phthalate, 3 parts of hydroquinones and deionized water.
4. medical medicine box binding agent according to claim 1, it is characterised in that：
80 parts of polyacrylate, 18 parts of chlorinated polypropylene, 8 parts of rosin modified phenolic resin, 8 parts of carbon fiber, 8 parts of ox-hide cream, vinegar
14 parts of 4 parts of acid, 6 parts of phosphoric acid, 7 parts of dioctyl phthalate, 4 parts of hydroquinones and deionized water.
5. medical medicine box binding agent according to claim 1, it is characterised in that：
85 parts of polyacrylate, 20 parts of chlorinated polypropylene, 10 parts of rosin modified phenolic resin, 10 parts of carbon fiber, 10 parts of ox-hide cream,
15 parts of 5 parts of acetic acid, 7 parts of phosphoric acid, 8 parts of dioctyl phthalate, 5 parts of hydroquinones and deionized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711227558.3A CN107674613A (en) | 2017-11-29 | 2017-11-29 | Medical medicine box binding agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711227558.3A CN107674613A (en) | 2017-11-29 | 2017-11-29 | Medical medicine box binding agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107674613A true CN107674613A (en) | 2018-02-09 |
Family
ID=61150673
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711227558.3A Withdrawn CN107674613A (en) | 2017-11-29 | 2017-11-29 | Medical medicine box binding agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107674613A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101676352A (en) * | 2008-09-19 | 2010-03-24 | 上海奇想青晨化工科技股份有限公司 | Water soluble aluminum foil adhesive and preparation method thereof |
| CN101974300A (en) * | 2010-10-28 | 2011-02-16 | 苏州凯康化工科技有限公司 | Water-based complex membrane sealing rubber and preparation method thereof |
| CN106281141A (en) * | 2016-08-26 | 2017-01-04 | 江苏国胶化学科技有限公司 | A kind of high temperature resistant aluminium foil glue |
| CN106366985A (en) * | 2016-09-27 | 2017-02-01 | 威远翰林科技有限公司 | Water-based sealing compound adhesive emulsion and preparation method thereof |
-
2017
- 2017-11-29 CN CN201711227558.3A patent/CN107674613A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101676352A (en) * | 2008-09-19 | 2010-03-24 | 上海奇想青晨化工科技股份有限公司 | Water soluble aluminum foil adhesive and preparation method thereof |
| CN101974300A (en) * | 2010-10-28 | 2011-02-16 | 苏州凯康化工科技有限公司 | Water-based complex membrane sealing rubber and preparation method thereof |
| CN106281141A (en) * | 2016-08-26 | 2017-01-04 | 江苏国胶化学科技有限公司 | A kind of high temperature resistant aluminium foil glue |
| CN106366985A (en) * | 2016-09-27 | 2017-02-01 | 威远翰林科技有限公司 | Water-based sealing compound adhesive emulsion and preparation method thereof |
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Application publication date: 20180209 |