CN106281141A - A kind of high temperature resistant aluminium foil glue - Google Patents
A kind of high temperature resistant aluminium foil glue Download PDFInfo
- Publication number
- CN106281141A CN106281141A CN201610736570.6A CN201610736570A CN106281141A CN 106281141 A CN106281141 A CN 106281141A CN 201610736570 A CN201610736570 A CN 201610736570A CN 106281141 A CN106281141 A CN 106281141A
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- parts
- aluminium foil
- high temperature
- temperature resistant
- mixture
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of high temperature resistant aluminium foil glue, described high temperature resistant aluminium foil glue is prepared as by the component of following weight portion: butyl acrylate 20 60 parts, acrylic ester compound 5 15 parts, methyl methacrylate 1 10 parts, containing carboxyl function monomer 0.5 10 parts, emulsifying agent 0.7 3 parts, initiator 0.3 3 parts, molecular weight regulator 0.1 0.8 parts, defoamer WBA 0.6 1.0 parts, wetting agent ABO 0.2 0.4 parts, deionized water 30 60 parts, oxidant 0.1 1 parts and pH adjusting agent 0.5 10 parts.It is an advantage of the current invention that: the present invention is in formula, add a small amount of wetting agent, reduce surface tension, make deionized water can be deployed in each monomer surface, increase the synergism of each monomer, and reduce emulsifying agent and the consumption of molecular weight regulator in formula, avoid the decline of the resistance to elevated temperatures that each auxiliary dosage too much causes, improve resistance to elevated temperatures, and the stability of the viscosity under temperature difference changes, thus improve the reliability of product.
Description
Technical field
The invention belongs to binding agent and manufacture field, particularly to a kind of high temperature resistant aluminium foil glue.
Background technology
Aluminium foil is compound is widely present in all kinds of packing box, and such as tobacco bale, wine box, medicine box etc., range of application widely, is adopted
With this compound product, having stronger metal-like, color is beautiful, and combination process is relatively simple, is therefore many factories
Family is as main complex method, and market capacity is bigger.
Aluminium foil glue major requirement fast drying, cohesive force are strong, ink does not produce impact, invariant color etc., particularly wants folding
Trace and higher levelability.
Traditional aluminium foil glue mostly is oily gum, the most also occurs in that some species of water-base cement.The toxicity of oily gum and
Safety in utilization problem is more and more prominent, and this is owing in oily gum, the solvent of use is toluene, dimethylbenzene, not only environmental pollution
Greatly, the health hazards to operator is big, and a large amount of volatilizations in drying course, easily cause fire.
It is reported, on market, existing water soluble aluminum foil adhesive and has bigger gap in terms of oily gum in terms of levelability,
Therefore can only be confined on part low grade products, and the most barely satisfactory in terms of resistance to folding line.
For above-mentioned phenomenon, patent CN 101676352 A discloses a kind of water soluble aluminum foil adhesive and preparation method thereof, this water
Property aluminium foil glue mainly by acrylic acid, ethyl acrylate, styrene, functional monomer, initiator, emulsifying agent, buffer agent, functional
Auxiliary agent, pH regulator and softening water are prepared from by reaction.Water soluble aluminum foil adhesive of the present invention reaches environmental protection, good for health,
Without bad smell, and there is high solids content, high tenacity, make that mounted product is wrinkle resistant, be unlikely to deform.But this water soluble aluminum foil adhesive exists
Certain shortcoming: the synergism between each monomer is relatively poor, meanwhile, in formula, the consumption of some auxiliary agents is relatively large, leads
Cause resistance to elevated temperatures declines；And temperature difference change under viscosity stability poor.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of high temperature resistant aluminium foil glue, and it is by increasing the association between each monomer
Same-action, and reduce the consumption of each auxiliary agent, and then improve the viscosity stabilization under the resistance to elevated temperatures of aluminium foil glue and temperature difference change
Property.
For solving above-mentioned technical problem, the technical scheme is that a kind of high temperature resistant aluminium foil glue, its innovative point is:
Described high temperature resistant aluminium foil glue is prepared as by the component of following weight portion: butyl acrylate 20-60 part, acrylic ester compound 5-
15 parts, methyl methacrylate 1-10 part, containing carboxyl function monomer 0.5-10 part, emulsifying agent 0.7-3 part, initiator 0.3-3 part,
Molecular weight regulator 0.1-0.8 part, defoamer WBA 0.6-1.0 part, wetting agent ABO 0.2-0.4 part, deionized water 30-60
Part, oxidant 0.1-1 part and pH adjusting agent 0.5-10 part；
Wherein, described acrylic ester compound is 2-(Acryloyloxy)ethanol or Hydroxypropyl acrylate or both mixture；Described
It is acrylic or methacrylic acid or both mixture containing carboxyl function monomer；Described emulsifying agent is DBSA
Sodium, described initiator is Ammonium persulfate. or potassium peroxydisulfate or both mixture, and described molecular weight regulator is n-dodecyl mereaptan
Or tert-dodecyl mercaptan or both mixture, described oxidant is tert-butyl hydroperoxide, and described pH adjusting agent is ammonia.
It is an advantage of the current invention that: the present invention is high temperature resistant aluminium foil glue, in formula, by adding a small amount of wetting agent, fall
Low surface tension, makes deionized water can be deployed in each monomer surface, increases the synergism of each monomer, and reduces emulsifying in formula
Agent and the consumption of molecular weight regulator, it is to avoid the decline of the resistance to elevated temperatures that each auxiliary dosage too much causes, improve resistance to height
Warm nature energy, and the stability of the viscosity under temperature difference changes, thus improve the reliability of product.
Detailed description of the invention
The following examples can make professional and technical personnel that the present invention is more fully understood, but the most therefore by this
Bright it is limited among described scope of embodiments.
Embodiment 1
The present embodiment is high temperature resistant aluminium foil glue, this is high temperature resistant, and aluminium foil glue is prepared as by the component of following weight portion: butyl acrylate 20
Part, 2-(Acryloyloxy)ethanol or Hydroxypropyl acrylate or 15 parts of both mixture, methyl methacrylate 10 parts, acrylic acid or first
Base acrylic acid or 10 parts of both mixture, dodecylbenzene sodium sulfonate 3 parts, Ammonium persulfate. or potassium peroxydisulfate or both mixing
Thing 3 parts, n-dodecyl mereaptan or tert-dodecyl mercaptan or 0.8 part of both mixture, defoamer WBA1.0 part, wetting agent ABO 0.4
Part, deionized water 60 parts, tert-butyl hydroperoxide 1 part and ammonia 10 parts.
Embodiment 2
The present embodiment is high temperature resistant aluminium foil glue, this is high temperature resistant, and aluminium foil glue is prepared as by the component of following weight portion: butyl acrylate 60
Part, 2-(Acryloyloxy)ethanol or Hydroxypropyl acrylate or 5 parts of both mixture, methyl methacrylate 1 part, acrylic acid or methyl
Acrylic acid or 0.5 part of both mixture, dodecylbenzene sodium sulfonate 0.7 part, Ammonium persulfate. or potassium peroxydisulfate or both is mixed
Compound 0.3 part, n-dodecyl mereaptan or tert-dodecyl mercaptan or 0.1 part of both mixture, defoamer WBA 0.6 part, wetting agent ABO
0.2 part, deionized water 30 parts, tert-butyl hydroperoxide 0.1 part and ammonia 0.5 part.
Embodiment 3
The present embodiment is high temperature resistant aluminium foil glue, this is high temperature resistant, and aluminium foil glue is prepared as by the component of following weight portion: butyl acrylate 30
Part, 2-(Acryloyloxy)ethanol or Hydroxypropyl acrylate or 12 parts of both mixture, methyl methacrylate 6 parts, acrylic acid or first
Base acrylic acid or 5.5 parts of both mixture, dodecylbenzene sodium sulfonate 1.9 parts, Ammonium persulfate. or potassium peroxydisulfate or both
1.7 parts of mixture, n-dodecyl mereaptan or tert-dodecyl mercaptan or 0.5 part of both mixture, defoamer WBA 0.9 part, wetting agent
ABO 0.35 part, deionized water 50 parts, tert-butyl hydroperoxide 0.6 part and ammonia 4.8 parts.
Embodiment 4
The present embodiment is high temperature resistant aluminium foil glue, this is high temperature resistant, and aluminium foil glue is prepared as by the component of following weight portion: butyl acrylate 50
Part, 2-(Acryloyloxy)ethanol or Hydroxypropyl acrylate or 8 parts of both mixture, methyl methacrylate 5 parts, acrylic acid or methyl
Acrylic acid or 5 parts of both mixture, dodecylbenzene sodium sulfonate 1.8 parts, Ammonium persulfate. or potassium peroxydisulfate or both mixing
Thing 1.6 parts, n-dodecyl mereaptan or tert-dodecyl mercaptan or 0.4 part of both mixture, defoamer WBA 0.7 part, wetting agent ABO
0.25 part, deionized water 40 parts, tert-butyl hydroperoxide 0.5 part and ammonia 4.7 parts.
Embodiment 5
The present embodiment is high temperature resistant aluminium foil glue, this is high temperature resistant, and aluminium foil glue is prepared as by the component of following weight portion: butyl acrylate 40
Part, 2-(Acryloyloxy)ethanol or Hydroxypropyl acrylate or 10 parts of both mixture, methyl methacrylate 5.5 parts, acrylic acid or
Methacrylic acid or 5.25 parts of both mixture, dodecylbenzene sodium sulfonate 1.85 parts, Ammonium persulfate. or potassium peroxydisulfate or two
1.65 parts of the mixture of person, n-dodecyl mereaptan or tert-dodecyl mercaptan or 0.45 part of both mixture, defoamer WBA 0.8 part,
Wetting agent ABO 0.3 part, deionized water 45 parts, tert-butyl hydroperoxide 0.55 part and ammonia 4.75 parts.
In order to compare the performance of the present invention high temperature resistant aluminium foil glue and tradition water soluble aluminum foil adhesive, by GB/T 2793-1995 glue
The algoscopy of glutinous agent non-volatile content measures the solid content preparing glue, uses the pH value of GB/T 14518-1993 adhesive
Algoscopy measures the pH value preparing glue, uses GB/T 4852-2002 pressure sensitive adhesive adhesive tape tack experimental test procedures to survey
Customize to obtain glue first viscous；It is viscous that employing GB/T 4851-1998 pressure sensitive adhesive holds holding of the prepared glue of Adhesion Test Method test, adopts
The peeling force preparing glue is measured with 180 ° of peel strength experimental test procedures of GB/T 2792-1998 pressure sensitive adhesive tape.
Following table is the test result of the high temperature resistant aluminium foil glue of embodiment 1～5 and the performance of tradition water soluble aluminum foil adhesive.
As can be seen from the above table, the present invention is high temperature resistant aluminium foil glue, in formula, by adding a small amount of wetting agent, reduces
Surface tension, makes deionized water can be deployed in each monomer surface, increases the synergism of each monomer, and reduces emulsifying agent in formula
Consumption with molecular weight regulator, it is to avoid the decline of the resistance to elevated temperatures that each auxiliary dosage too much causes, improves high temperature resistant
Performance, and at 160 DEG C, adhesive property is still greater than 3 Pa.s and the stability of the viscosity under temperature difference changes, thus carries
The high reliability of product.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The skill of the industry
The art personnel simply explanation it should be appreciated that the present invention is not restricted to the described embodiments, described in above-described embodiment and description
The principle of the present invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these
Changes and improvements both fall within scope of the claimed invention.Claimed scope by appending claims and
Its equivalent defines.
Claims (1)
1. a high temperature resistant aluminium foil glue, it is characterised in that: described high temperature resistant aluminium foil glue is prepared as by the component of following weight portion: third
Olefin(e) acid butyl ester 20-60 part, acrylic ester compound 5-15 part, methyl methacrylate 1-10 part, containing carboxyl function monomer
0.5-10 part, emulsifying agent 0.7-3 part, initiator 0.3-3 part, molecular weight regulator 0.1-0.8 part, defoamer WBA 0.6-1.0
Part, wetting agent ABO 0.2-0.4 part, deionized water 30-60 part, oxidant 0.1-1 part and pH adjusting agent 0.5-10 part；
Wherein, described acrylic ester compound is 2-(Acryloyloxy)ethanol or Hydroxypropyl acrylate or both mixture；Described
It is acrylic or methacrylic acid or both mixture containing carboxyl function monomer；Described emulsifying agent is DBSA
Sodium, described initiator is Ammonium persulfate. or potassium peroxydisulfate or both mixture, and described molecular weight regulator is n-dodecyl mereaptan
Or tert-dodecyl mercaptan or both mixture, described oxidant is tert-butyl hydroperoxide, and described pH adjusting agent is ammonia.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610736570.6A CN106281141A (en) | 2016-08-26 | 2016-08-26 | A kind of high temperature resistant aluminium foil glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610736570.6A CN106281141A (en) | 2016-08-26 | 2016-08-26 | A kind of high temperature resistant aluminium foil glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106281141A true CN106281141A (en) | 2017-01-04 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610736570.6A Pending CN106281141A (en) | 2016-08-26 | 2016-08-26 | A kind of high temperature resistant aluminium foil glue |
Country Status (1)
| Country | Link |
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| CN (1) | CN106281141A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674613A (en) * | 2017-11-29 | 2018-02-09 | 广西众昌树脂有限公司 | Medical medicine box binding agent |
| CN112795340A (en) * | 2021-01-29 | 2021-05-14 | 江苏中金玛泰医药包装有限公司 | Water-based acrylate adhesive for medicine packaging and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717468A (en) * | 2009-11-18 | 2010-06-02 | 北京高盟化工有限公司 | Aqueous acrylic emulsion, aqueous adhesive for plastic-plastic composite materials and preparation method thereof |
| CN102140318A (en) * | 2011-01-25 | 2011-08-03 | 北京高盟新材料股份有限公司 | Water-based aluminized transfer glue and preparation method thereof |
| CN103102849A (en) * | 2012-12-19 | 2013-05-15 | 上海奇想青晨新材料科技股份有限公司 | Aluminum foil paper composite glue for candy wrapping and preparation method thereof |
| CN105884964A (en) * | 2016-05-12 | 2016-08-24 | 上海保立佳新材料有限公司 | Emulsion pressure sensitive adhesive for anti-yellowing surface protective film and preparation method thereof |
-
2016
- 2016-08-26 CN CN201610736570.6A patent/CN106281141A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717468A (en) * | 2009-11-18 | 2010-06-02 | 北京高盟化工有限公司 | Aqueous acrylic emulsion, aqueous adhesive for plastic-plastic composite materials and preparation method thereof |
| CN102140318A (en) * | 2011-01-25 | 2011-08-03 | 北京高盟新材料股份有限公司 | Water-based aluminized transfer glue and preparation method thereof |
| CN103102849A (en) * | 2012-12-19 | 2013-05-15 | 上海奇想青晨新材料科技股份有限公司 | Aluminum foil paper composite glue for candy wrapping and preparation method thereof |
| CN105884964A (en) * | 2016-05-12 | 2016-08-24 | 上海保立佳新材料有限公司 | Emulsion pressure sensitive adhesive for anti-yellowing surface protective film and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674613A (en) * | 2017-11-29 | 2018-02-09 | 广西众昌树脂有限公司 | Medical medicine box binding agent |
| CN112795340A (en) * | 2021-01-29 | 2021-05-14 | 江苏中金玛泰医药包装有限公司 | Water-based acrylate adhesive for medicine packaging and preparation method thereof |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20170104 |