CN102134465B - Self-crosslinking aqueous complex film adhesive and preparation method thereof - Google Patents
Self-crosslinking aqueous complex film adhesive and preparation method thereof Download PDFInfo
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- CN102134465B CN102134465B CN 201110056376 CN201110056376A CN102134465B CN 102134465 B CN102134465 B CN 102134465B CN 201110056376 CN201110056376 CN 201110056376 CN 201110056376 A CN201110056376 A CN 201110056376A CN 102134465 B CN102134465 B CN 102134465B
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- monomer
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- 238000004132 cross linking Methods 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000853 adhesive Substances 0.000 title abstract description 15
- 230000001070 adhesive effect Effects 0.000 title abstract description 15
- 239000000178 monomer Substances 0.000 claims abstract description 66
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 50
- 239000003999 initiator Substances 0.000 claims abstract description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 43
- 238000006243 chemical reaction Methods 0.000 claims abstract description 39
- -1 alkyl ether ammonium sulfate Chemical class 0.000 claims abstract description 26
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 24
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 24
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 24
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 24
- 239000007787 solid Substances 0.000 claims abstract description 22
- 239000008367 deionised water Substances 0.000 claims abstract description 18
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 238000004945 emulsification Methods 0.000 claims abstract description 14
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 11
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 8
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims abstract description 7
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 7
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 7
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000839 emulsion Substances 0.000 claims description 47
- 239000003292 glue Substances 0.000 claims description 35
- 230000001804 emulsifying effect Effects 0.000 claims description 28
- 239000012939 laminating adhesive Substances 0.000 claims description 28
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 23
- 239000002131 composite material Substances 0.000 claims description 15
- 239000000872 buffer Substances 0.000 claims description 14
- 239000003153 chemical reaction reagent Substances 0.000 claims description 14
- 238000002242 deionisation method Methods 0.000 claims description 14
- 238000009413 insulation Methods 0.000 claims description 14
- 239000003002 pH adjusting agent Substances 0.000 claims description 14
- 238000005070 sampling Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 238000012360 testing method Methods 0.000 claims description 14
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000003755 preservative agent Substances 0.000 claims description 12
- 230000002335 preservative effect Effects 0.000 claims description 12
- 239000000080 wetting agent Substances 0.000 claims description 10
- 238000007599 discharging Methods 0.000 claims description 7
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical compound O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004160 Ammonium persulphate Substances 0.000 claims description 2
- 239000004159 Potassium persulphate Substances 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 2
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
- 235000019394 potassium persulphate Nutrition 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 3
- 229940117958 vinyl acetate Drugs 0.000 abstract 2
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 abstract 1
- 239000006172 buffering agent Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
- 239000012528 membrane Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 125000003636 chemical group Chemical group 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 230000002110 toxicologic effect Effects 0.000 description 3
- 231100000027 toxicology Toxicity 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000001473 noxious effect Effects 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110056376 CN102134465B (en) | 2010-08-19 | 2011-03-09 | Self-crosslinking aqueous complex film adhesive and preparation method thereof |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201010258149.1 | 2010-08-19 | ||
CN2010102581491A CN101955742A (en) | 2010-08-19 | 2010-08-19 | Self-crosslinking aqueous laminating adhesive and preparation method thereof |
CN 201110056376 CN102134465B (en) | 2010-08-19 | 2011-03-09 | Self-crosslinking aqueous complex film adhesive and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN102134465A CN102134465A (en) | 2011-07-27 |
CN102134465B true CN102134465B (en) | 2013-02-27 |
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CN2010102581491A Pending CN101955742A (en) | 2010-08-19 | 2010-08-19 | Self-crosslinking aqueous laminating adhesive and preparation method thereof |
CN 201110056376 Expired - Fee Related CN102134465B (en) | 2010-08-19 | 2011-03-09 | Self-crosslinking aqueous complex film adhesive and preparation method thereof |
Family Applications Before (1)
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CN2010102581491A Pending CN101955742A (en) | 2010-08-19 | 2010-08-19 | Self-crosslinking aqueous laminating adhesive and preparation method thereof |
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CN (2) | CN101955742A (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102140320B (en) * | 2010-08-19 | 2012-12-12 | 北京高盟新材料股份有限公司 | Water-based polyacrylic emulsion laminating adhesive and preparation method thereof |
CN102206476B (en) * | 2011-05-11 | 2013-03-20 | 宝利时(深圳)胶粘制品有限公司 | PE (polyurethane) protective film glue and preparation method thereof |
CN102994018B (en) * | 2011-09-16 | 2015-06-17 | 吴祖顺 | Formula and process for preparing water-based PVC (polyvinyl chloride) corrosion-resisting adhesive |
CN102443094B (en) * | 2011-10-26 | 2013-03-27 | 烟台前进化工有限公司 | Method for producing special glue of tufted fabric |
CN103059784B (en) * | 2013-02-01 | 2014-10-08 | 东莞市星宇高分子材料有限公司 | Water-based plastic-plastic compound adhesive for food and drug flexible package and preparation method thereof |
CN103131359B (en) * | 2013-03-21 | 2014-03-26 | 辽宁吕氏化工(集团)有限公司 | Environment-friendly quick-drying type adhesive |
CN105368351A (en) * | 2015-11-19 | 2016-03-02 | 佛山市新榜包装材料有限公司 | Improved-type self-crosslinking acrylate adhesive formula and preparation method thereof |
CN109401688B (en) * | 2018-10-31 | 2021-07-30 | 江苏国胶新材料有限公司 | Processing production device for water-based laminating adhesive |
CN110218536B (en) * | 2019-05-17 | 2021-04-20 | 福建蓝海黑石新材料科技有限公司 | Water-based paper-plastic laminating adhesive and preparation method thereof |
CN110655885A (en) * | 2019-11-11 | 2020-01-07 | 怀化学院 | Laminating adhesive and preparation method thereof |
CN111944460A (en) * | 2020-08-17 | 2020-11-17 | 浙江科力森化学有限公司 | Adhesive sticker for glass fiber mesh cloth, preparation method and application |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1285382A (en) * | 1999-08-23 | 2001-02-28 | 杭州富阳华源电热有限公司 | Composition of composite crosslinking type aqueous compound film adhesive and preparation process thereof |
CN1352223A (en) * | 2000-11-02 | 2002-06-05 | 福州大学 | New aqueous emulsion type paper-plastic composite adhesive and its preparing method |
CN1807536A (en) * | 2006-01-13 | 2006-07-26 | 济南大学 | Hydroxy acrylate copolymer adhesive and its preparation method and uses |
CN101168650A (en) * | 2006-10-23 | 2008-04-30 | 吴达文 | Single-component self-crosslink emulsion adhesive for dry type composite film and preparation method thereof |
CN101698783A (en) * | 2009-04-30 | 2010-04-28 | 北京高盟化工有限公司 | Dry-type compound aqueous paper/plastic laminating emulsion adhesive and preparation method thereof |
-
2010
- 2010-08-19 CN CN2010102581491A patent/CN101955742A/en active Pending
-
2011
- 2011-03-09 CN CN 201110056376 patent/CN102134465B/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1285382A (en) * | 1999-08-23 | 2001-02-28 | 杭州富阳华源电热有限公司 | Composition of composite crosslinking type aqueous compound film adhesive and preparation process thereof |
CN1352223A (en) * | 2000-11-02 | 2002-06-05 | 福州大学 | New aqueous emulsion type paper-plastic composite adhesive and its preparing method |
CN1807536A (en) * | 2006-01-13 | 2006-07-26 | 济南大学 | Hydroxy acrylate copolymer adhesive and its preparation method and uses |
CN101168650A (en) * | 2006-10-23 | 2008-04-30 | 吴达文 | Single-component self-crosslink emulsion adhesive for dry type composite film and preparation method thereof |
CN101698783A (en) * | 2009-04-30 | 2010-04-28 | 北京高盟化工有限公司 | Dry-type compound aqueous paper/plastic laminating emulsion adhesive and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN101955742A (en) | 2011-01-26 |
CN102134465A (en) | 2011-07-27 |
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Owner name: BEIJING COMENS YANSHAN TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: BEIJING COMENS NEW MATERIALS CO., LTD. Effective date: 20141103 |
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Effective date of registration: 20141103 Address after: 102502 No. 14, Yan Shandong water industrial zone, Beijing, Fangshan District Patentee after: BEIJING COMENS YANSHAN TECH. CO., LTD. Address before: 102502 Yanshan Industrial Zone, Beijing, No. 8, No. Patentee before: Beijing Comens New Materials Co., Ltd. |
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Effective date of registration: 20190404 Address after: 226407 Yangkou Chemical Industrial Park, Rudong Coastal Economic Development Zone, Nantong City, Jiangsu Province Patentee after: Nantong Gaomeng New Material Co., Ltd. Address before: 102502 No. 14 Yanshan Running Water Industrial Zone, Fangshan District, Beijing Patentee before: BEIJING COMENS YANSHAN TECH. CO., LTD. |
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Granted publication date: 20130227 Termination date: 20200309 |
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