CN106366985A - Water-based sealing compound adhesive emulsion and preparation method thereof - Google Patents
Water-based sealing compound adhesive emulsion and preparation method thereof Download PDFInfo
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- CN106366985A CN106366985A CN201610854838.6A CN201610854838A CN106366985A CN 106366985 A CN106366985 A CN 106366985A CN 201610854838 A CN201610854838 A CN 201610854838A CN 106366985 A CN106366985 A CN 106366985A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Graft Or Block Polymers (AREA)
Abstract
The invention relates to a water-based sealing compound adhesive emulsion which is mainly composed of butyl acrylate, methyl methacrylate, vinyl acetate, polyvinyl alcohol, an emulsifier, a tackifier, methacrylic acid, 2-hydroxypropyl acrylate, an initiator and deionized water. The preparation method mainly comprises the following steps: (1) preparing a preemulsion; (2) carrying out seed emulsion polymerization; (3) carrying out core monomer polymerization; (4) carrying out shell monomer polymerization; (5) curing by keeping the temperature; and (6) discharging. The water-based sealing compound adhesive emulsion can form a film at lower temperature; and the water resistance and adhesive property stability of the adhesive emulsion are enhanced.
Description
Technical field
The present invention relates to a kind of gluing agent emulsion, especially a kind of aqueouss sealing compound gluing agent emulsion.
Background technology
At present, the sealings such as side mouth and the base that sealing compound is widely used in the packaging such as Medicine box, food box, packing box are glued
Connect or take a mouthful molding.But mostly the sealing compound of domestic market is containing inflammable, explosive, poisonous, pollutes the organic molten of environment
Dosage form sealing compound (i.e. oily gum), not only pollutes the product of packaging, and also the workman of harm packing shop is healthy, for country
Explicitly provided superseded property sealing compound, the country such as America and Europe even more strictly forbids.
In recent years, the continuous expansion that people apply to environmental protection, safety, the attention of energy-conservation and water-base cement is so that aqueouss are sealed
Chewing gum gradually instead of solvent base compound.Promote aqueouss sealing compound towards low stain, low energy consumption, high-performance and multifunction side
To development.The features such as aqueouss sealing compound is with its environmental protection, excellent weatherability, alkali resistance, oxidative resistance, is developed rapidly.
But current aqueouss sealing compound can't replace solvent base compound completely at the aspect of combination property, especially to low temperature resistant and
The higher product of mechanical property requirements.
The method of the preparation aqueouss sealing compound gluing agent emulsion commonly used at present is semi-continuous seed emulsion polymerization method, for example public
The number of opening is that the patent document of cn101974299a discloses a kind of semi-continuous seed emulsion polymerization method.Its exemplary steps is as follows:
(1) all monomers of formula ratio, partial emulsifier, portions of de-ionized water are placed in pre-emulsification tank, stirring, will be single
Body carries out pre-emulsification and obtains pre-emulsion；
(2) in part pre-emulsion, injection initiator obtains seed emulsion；
(3) remaining pre-emulsion and initiator solution are simultaneously added dropwise in seed emulsion, insulation, complete polymerization anti-
Should；
(4) lower the temperature, adjust ph, be subsequently adding viscosifier, filtering and discharging.
Inventor finds, the aqueouss sealing compound made using the method generally can not under conditions of temperature is less than -10 DEG C
Film forming is that is to say, that too low temperature can lead to the glued membrane of aqueouss sealing compound a large amount of crackles, efflorescence, lead to degumming.Aqueouss
The shortcoming of this resistance to low temperature difference of sealing compound seriously limits application and the development of aqueouss sealing compound.
Content of the invention
For improving the film formation at low temp performance of aqueouss sealing compound, the invention provides a kind of aqueouss sealing compound gluing agent emulsion and
Its preparation method.
The technical solution adopted in the present invention is: aqueouss sealing compound gluing agent emulsion it is characterised in that: the quality of each component
Number is as follows:
As a further improvement on the present invention, described emulsifying agent is selected from anion emulsifier, nonionic emulsifier, reactivity
Two or three of emulsifying agent, described initiator is Ammonium persulfate., and described viscosifier are in terpene resin, rosin resin
One or two.
More preferably, described nonionic emulsifier is alkylol polyether-type emulsifying agent, and described reactive emulsifier is vinyl
Sodium sulfonate.
Present invention also offers a kind of preparation method of aqueouss sealing compound gluing agent emulsion, particularly as follows:
(1) prepare primer solution；
(2) mixed nucleus raw material monomer is obtained nuclear monomer；
(3) part taking nuclear monomer carries out pre-emulsification, obtains pre-emulsion；
(4) Deca initiator Priming Seeds emulsion polymerization, obtains seed emulsion；
(5) Deca residue nuclear monomer and initiator carry out nuclear monomer polyreaction；
(6) butyl acrylate, vinyl acetate, methacrylic acid, Hydroxypropyl acrylate, methyl methacrylate mixing are taken
Prepared shell monomer；
(7) shell monomer is injected in the deionized water containing emulsifying agent, pre-emulsification shell monomer is obtained through pre-emulsification；
(8) pre-emulsification shell monomer and initiator are simultaneously added dropwise in reactor, Deca process temperature controls 83～87
DEG C, after pre-emulsification shell monomer completion of dropping, system temperature is controlled at 86～90 DEG C, be incubated 1～2 hour；
(9), after insulation terminates, add viscosifier to stir, system temperature is down to 50～60 DEG C, regulation system ph value
To 6～7, it is cooled to 50 DEG C with bottom discharge, obtains adhesive product emulsion.
In production technology, the present invention is used core-shell emulsion polymerization method and is tied with semi-continuous seed emulsion polymerization method phase
Close it may be assumed that first completing the polymerization of nuclear monomer, then add pre-emulsification shell monomer in reactor and be simultaneously introduced initiator solution, make
Pre-emulsification shell monomer forms complete shell structure around nuclear monomer.The purpose of the method is to form tool on the surface of emulsion particle
There is the shell compared with lower glass transition temperatures, and glass transition temperature and minimum film formation temperature are closely bound up, direct shadow
Ring gluing agent emulsion and can have good filming performance at a lower temperature, the experiment proved that, through the method preparation
The gluing agent emulsion going out has more excellent film formation at low temp performance than ordinary emulsion.
As a further improvement on the present invention, in step (8), pre-emulsification shell monomer and the Deca mode of initiator are:
Drip pre-emulsification shell monomer in 1.5～2h, and the completion of dropwise addition of initiator is after pre-emulsification shell monomer completion of dropwise addition.Pass through
Control the instillation speed of pre-emulsification shell monomer and initiator, pre-emulsification shell monomer in reactor can be kept to be in trace inequality all the time,
Ensure that pre-emulsification shell monomer forms uniform shell structure on nuclear monomer surface, new without producing because of Polymer adsorption emulsifying agent
Emulsion particle.
As a further improvement on the present invention, the preparation method of the described primer solution of step (1) is: adds in reactor
Polyvinyl alcohol and deionized water, make polyvinyl alcohol be dissolved in the water, and solution temperature is more than 95 DEG C；Temperature of reactor is reduced to
50 DEG C～60 DEG C, then add sodium bicarbonate and mixed by anion emulsifier and nonionic emulsifier in reactor
Emulsifying agent so as to be uniformly dispersed, prepared primer solution.More preferably, described emulsifying agent is by nonionic emulsifier and anionic emulsifying
The agent ratio of 2:3 in mass ratio mixes.Through adding polyvinyl alcohol as protecting colloid, further increase the steady of emulsion
Qualitative, also function to certain emulsification, be simultaneously introduced the viscosity that suitable consumption can adjust whole emulsion, to avoid adding
The auxiliary agent of thickening agent etc.
In terms of emulsifying agent, this experiment employ anion, nonionic, in reactive emulsifier two or more
Emulsifying agent, and the emulsifying agent selected not only emulsifying capacity strong it is important that having done one in terms of environmental conservation using emulsifying agent
Fixed contribution, employs the nonionic emulsifier without apeo (all having certain harmful effect to environment, human body), or using anti-
Answering property emulsifying agent, final emulsifying agent participates in copolyreaction, and prevent emulsifying agent moves to the adhesive property to product for the film surface
Impact, it also avoid the harmful effect that emulsifying agent produces to environment, also improve the water-resistant capacity of gluing agent emulsion simultaneously,
Improve adhesive emulsion intercalation method.
As a further improvement on the present invention, described pre-emulsification shell monomer is by butyl acrylate, vinyl acetate, methyl-prop
Olefin(e) acid, Hydroxypropyl acrylate, methyl methacrylate, emulsifying agent, deionized water 57～63:11 in mass ratio～13:11～13:
The ratio of 7～9:9～11:0.5～1.5:45～55 compounds and forms.
As a further improvement on the present invention, described nuclear monomer raw material is by butyl acrylate, vinyl acetate, metering system
The ratio of acid, Hydroxypropyl acrylate, methyl methacrylate 155～165:75 in mass ratio～85:7～8:7～8:14～16
Mix.
As a further improvement on the present invention, described viscosifier by terpene resin and rosin resin 40:20 in mass ratio～
25 ratio mixes.In terms of viscosifier, we employ two kinds of viscosifier and gluing agent emulsion are modified simultaneously, and
And be incorporated in system with an optimal ratio, the tack not only increasing product also makes the viscosity of holding of product refer to relatively
Big lifting.The gluing agent emulsion with different bonding performance can also be prepared by adjusting the consumption of viscosifier.
The invention has the beneficial effects as follows: 1) enable (- 13 DEG C at lower temperatures of aqueouss sealing compound gluing agent emulsion
～-16 DEG C) film forming；2) improve the water-resistant capacity of gluing agent emulsion and the stability of adhesive property.
Specific embodiment
With reference to embodiment, the present invention is further described.
Embodiment one
Weigh each reagent by following mass fraction:
1) first 20 parts of deionized waters are added in reactor, add 1 part of polyvinyl alcohol to be uniformly dispersed, so under agitation
After be gradually heating to 95 DEG C, so that polyvinyl alcohol is completely dissolved.
2) cool the temperature to 60 DEG C, add 0.04 part of sodium bicarbonate buffer agent, 0.5 part of emulsifying agent (alkylol polyether-type breast
Agent and anion emulsifier in: the ratio of 2:3 compounds), dispersed with stirring is uniform.
3) 7 parts of butyl acrylate, 3.5 parts of vinyl acetate, 0.35 part of methacrylic acid, Hydroxypropyl acrylate 0.35 are taken
Part, 0.7 part of methyl methacrylate are mixed to get nuclear monomer,
4) take 3 parts of nuclear monomers to add in the reactor filling primer solution and carry out pre-emulsification, obtain pre-emulsion
5) heat up, in reactor, 0.05 part of initiator Priming Seeds emulsion polymerization of Deca, obtains seed emulsion；
6) remaining nuclear monomer and 0.05 part of initiator solution are simultaneously added dropwise in seed emulsion, insulation, complete vouching
Body polyreaction；
7) 10 parts of butyl acrylate, 2.5 parts of vinyl acetate, methacrylic acid 2.5,2 parts of Hydroxypropyl acrylate, first are separately taken
2 parts of base acrylic acid methyl ester. is mixed to prepare shell monomer；
8) shell monomer is injected in 30 parts of deionized waters containing 0.5 part of emulsifying agent, pre-emulsification shell list is obtained through pre-emulsification
Body
9) pre-emulsification shell monomer and 0.06 part of initiator are simultaneously added dropwise in reactor, Deca process temperature controls 83
DEG C, drip pre-emulsification shell monomer in 1.5h, and the completion of dropwise addition of initiator is after pre-emulsification shell monomer completion of dropwise addition, in advance
After emulsifying shell monomer completion of dropping, system temperature is controlled at 86 DEG C, be incubated 1 hour.
10), after insulation terminates, system temperature is down to 60 DEG C, regulation system ph value to 6, add viscosifier (by terpenes tree
Fat and the rosin resin ratio of 40:23 in mass ratio mix) 2.5 parts, it is cooled to 50 DEG C of dischargings.
Obtained product vitrification point is low, reaches -16 DEG C, has excellent film formation at low temp performance, has excellent simultaneously
Resistance to water, UV resistant performance.
Embodiment two:
Weigh each reagent by following mass fraction:
1) first 30 parts of deionized waters are added in reactor, add 3 parts of polyvinyl alcohol to be uniformly dispersed, so under agitation
After be gradually heating to 95 DEG C, so that polyvinyl alcohol is completely dissolved.
2) cool the temperature to 60 DEG C, add 0.06 part of sodium bicarbonate buffer agent, 1 part of emulsifying agent (alkylol polyether-type emulsifying
Agent and anion emulsifier in: the ratio of 2:3 compounds), dispersed with stirring is uniform.
3) 10 parts of butyl acrylate, 6 parts of vinyl acetate, 0.3 part of methacrylic acid, 0.3 part of Hydroxypropyl acrylate, first are taken
0.6 part of base acrylic acid methyl ester. is mixed to get nuclear monomer,
4) take 5 parts of nuclear monomers to add in the reactor filling primer solution and carry out pre-emulsification, obtain pre-emulsion
5) heat up, in reactor, 0.04 part of initiator Priming Seeds emulsion polymerization of Deca, obtains seed emulsion；
6) remaining nuclear monomer and 0.04 part of initiator solution are simultaneously added dropwise in seed emulsion, insulation, complete vouching
Body polyreaction；
7) 15 parts of butyl acrylate, 4 parts of vinyl acetate, methacrylic acid 2,1.8 parts of Hydroxypropyl acrylate, methyl are separately taken
0 part of acrylic acid methyl ester. is mixed to prepare shell monomer；
8) shell monomer is injected in 32 parts of deionized waters containing 1 part of emulsifying agent, pre-emulsification shell monomer is obtained through pre-emulsification
9) pre-emulsification shell monomer and 0.06 part of initiator are simultaneously added dropwise in reactor, Deca process temperature controls 87
DEG C, drip pre-emulsification shell monomer in 1.5h, and the completion of dropwise addition of initiator is after pre-emulsification shell monomer completion of dropwise addition, in advance
After emulsifying shell monomer completion of dropping, system temperature is controlled at 90 DEG C, be incubated 2 hours.
10), after insulation terminates, system temperature is down to 55 DEG C, regulation system ph value to 7, add viscosifier (by terpenes tree
Fat and the rosin resin ratio of 40:17 in mass ratio mix) 5.5 parts, it is cooled to 40 DEG C of dischargings.
Obtained product vitrification point is low, reaches -13 DEG C, has excellent film formation at low temp performance, resistance to water and resistance to purple
Outside line ability is excellent, and tensile strength is larger.
Claims (10)
1. aqueouss sealing compound gluing agent emulsion it is characterised in that: the mass fraction of each component is as follows:
.
2. aqueouss sealing compound gluing agent emulsion according to claim 1 it is characterised in that: described emulsifying agent be selected from anion
Two or three of emulsifying agent, nonionic emulsifier, reactive emulsifier, described initiator is Ammonium persulfate., described thickening
Agent is selected from one of terpene resin, rosin resin or two kinds.
3. aqueouss sealing compound gluing agent emulsion according to claim 2 it is characterised in that: described nonionic emulsifier be alkane
Base alcohol polyether-type emulsifying agent, described reactive emulsifier is sodium vinyl sulfonate.
4. the preparation method of aqueouss sealing compound gluing agent emulsion, comprises the following steps:
(1) prepare primer solution；
(2) mixed nucleus raw material monomer is obtained nuclear monomer；
(3) part taking nuclear monomer carries out pre-emulsification, obtains pre-emulsion；
(4) Deca initiator Priming Seeds emulsion polymerization, obtains seed emulsion；
(5) Deca residue nuclear monomer and initiator carry out nuclear monomer polyreaction；
It is characterized in that: it is additionally included in the step that nuclear monomer surface carries out shell monomer polymerization, specific as follows:
(6) butyl acrylate, vinyl acetate, methacrylic acid, Hydroxypropyl acrylate, methyl methacrylate is taken to be mixed to prepare
Shell monomer；
(7) shell monomer is injected in the deionized water containing emulsifying agent, pre-emulsification shell monomer is obtained through pre-emulsification；
(8) pre-emulsification shell monomer and initiator are simultaneously added dropwise in reactor, Deca process temperature controls at 83～87 DEG C, in advance
After emulsifying shell monomer completion of dropping, system temperature is controlled at 86～90 DEG C, be incubated 1～2 hour；
(9), after insulation terminates, add viscosifier to stir, system temperature is down to 50～60 DEG C, regulation system ph value to 6～
7, it is cooled to 50 DEG C with bottom discharge, obtain adhesive product emulsion.
5. aqueouss sealing compound gluing agent emulsion according to claim 4 preparation method it is characterised in that: in step (8)
Pre-emulsification shell monomer with the Deca mode of initiator is: drips pre-emulsification shell monomer, and the Deca of initiator in 1.5～2h
After terminating in pre-emulsification shell monomer completion of dropwise addition.
6. the aqueouss sealing compound gluing agent emulsion according to claim 4 or 5 preparation method it is characterised in that: step (1)
The preparation method of described primer solution is: adds polyvinyl alcohol and deionized water in reactor, makes polyvinyl alcohol be dissolved in water
In, solution temperature is more than 95 DEG C；Temperature of reactor is reduced to 50 DEG C～60 DEG C, in reactor, then adds sodium bicarbonate
With emulsifying agent so as to be uniformly dispersed, prepared primer solution.
7. aqueouss sealing compound gluing agent emulsion according to claim 6 preparation method it is characterised in that: described emulsifying agent
Compounded by nonionic emulsifier and the anion emulsifier ratio of 2:3 in mass ratio and form.
8. the aqueouss sealing compound gluing agent emulsion according to claim 4 or 5 preparation method it is characterised in that: described pre-
Emulsifying shell monomer is by butyl acrylate, vinyl acetate, methacrylic acid, Hydroxypropyl acrylate, methyl methacrylate, emulsifying
The ratio of agent, deionized water 57～63:11 in mass ratio～13:11～13:7～9:9～11:0.5～1.5:45～55 compounds
Form.
9. the aqueouss sealing compound gluing agent emulsion according to claim 4 or 5 preparation method it is characterised in that: described core
Raw material monomer presses quality by butyl acrylate, vinyl acetate, methacrylic acid, Hydroxypropyl acrylate, methyl methacrylate
Mix than the ratio of 155～165:75～85:7～8:7～8:14～16.
10. the aqueouss sealing compound gluing agent emulsion according to claim 4 or 5 preparation method it is characterised in that: described increasing
Stick is mixed by the ratio of terpene resin and rosin resin 40:15～25 in mass ratio.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674613A (en) * | 2017-11-29 | 2018-02-09 | 广西众昌树脂有限公司 | Medical medicine box binding agent |
| CN108034018A (en) * | 2018-01-18 | 2018-05-15 | 保定光普化工研究所 | A kind of water-based sealing latex solution and preparation method thereof |
| CN108250991A (en) * | 2018-01-31 | 2018-07-06 | 哥俩好（辽宁）新材料有限公司 | One kind can be used for decoration environment-friendly type amylan and preparation method thereof |
| CN108995343A (en) * | 2018-07-11 | 2018-12-14 | 桐城市万方纸塑包装有限公司 | A kind of manufacturing method of the composite evacuated bag of eight banding of aluminium foil |
| CN109897478A (en) * | 2019-04-10 | 2019-06-18 | 广东绿洲化工有限公司 | A kind of PVC edge band adhesive and preparation method thereof |
| CN110305591A (en) * | 2019-05-14 | 2019-10-08 | 广东福美新材料科技有限公司 | A kind of moisture-proof impregnated paper of high adhesion and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1342735A (en) * | 2001-09-30 | 2002-04-03 | 中山大学 | Aqueous emulsion type nm adhesive for paper or plastics and its preparing process |
| CN101362929A (en) * | 2008-09-08 | 2009-02-11 | 宁波高新区绿和科技有限公司 | Emulsion type adhesive for paper and plastics and preparation method thereof |
| CN101864258A (en) * | 2010-05-26 | 2010-10-20 | 北京高盟新材料股份有限公司 | Low temperature resistant seal adhesive and preparation method thereof |
| CN103849331A (en) * | 2013-02-01 | 2014-06-11 | 常州化学研究所 | Water-based aluminium foil glue composition with high peel strength and controllable viscosity and preparation method |
-
2016
- 2016-09-27 CN CN201610854838.6A patent/CN106366985A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1342735A (en) * | 2001-09-30 | 2002-04-03 | 中山大学 | Aqueous emulsion type nm adhesive for paper or plastics and its preparing process |
| CN101362929A (en) * | 2008-09-08 | 2009-02-11 | 宁波高新区绿和科技有限公司 | Emulsion type adhesive for paper and plastics and preparation method thereof |
| CN101864258A (en) * | 2010-05-26 | 2010-10-20 | 北京高盟新材料股份有限公司 | Low temperature resistant seal adhesive and preparation method thereof |
| CN103849331A (en) * | 2013-02-01 | 2014-06-11 | 常州化学研究所 | Water-based aluminium foil glue composition with high peel strength and controllable viscosity and preparation method |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674613A (en) * | 2017-11-29 | 2018-02-09 | 广西众昌树脂有限公司 | Medical medicine box binding agent |
| CN108034018A (en) * | 2018-01-18 | 2018-05-15 | 保定光普化工研究所 | A kind of water-based sealing latex solution and preparation method thereof |
| CN108250991A (en) * | 2018-01-31 | 2018-07-06 | 哥俩好（辽宁）新材料有限公司 | One kind can be used for decoration environment-friendly type amylan and preparation method thereof |
| CN108250991B (en) * | 2018-01-31 | 2021-03-23 | 哥俩好新材料股份有限公司 | Environment-friendly starch glue for decoration and preparation method thereof |
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| CN109897478A (en) * | 2019-04-10 | 2019-06-18 | 广东绿洲化工有限公司 | A kind of PVC edge band adhesive and preparation method thereof |
| CN110305591A (en) * | 2019-05-14 | 2019-10-08 | 广东福美新材料科技有限公司 | A kind of moisture-proof impregnated paper of high adhesion and preparation method thereof |
| CN110834438A (en) * | 2019-11-13 | 2020-02-25 | 新兴印刷有限公司 | Manufacturing process of paper film bag for packaging |
| CN110834438B (en) * | 2019-11-13 | 2024-02-13 | 新兴印刷有限公司 | Manufacturing process of paper film bag for packaging |
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