CN107673737A - Recycle the production method of strong basicity waste residue manufacture ceramic tile - Google Patents

Recycle the production method of strong basicity waste residue manufacture ceramic tile Download PDF

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Publication number
CN107673737A
CN107673737A CN201710948234.2A CN201710948234A CN107673737A CN 107673737 A CN107673737 A CN 107673737A CN 201710948234 A CN201710948234 A CN 201710948234A CN 107673737 A CN107673737 A CN 107673737A
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Prior art keywords
waste residue
mass percent
raw material
ceramic tile
production method
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CN107673737B (en
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叶德林
黄春林
朱光耀
韦守泉
韦前
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Foshan Sanshui Newpearl Building Ceramic Industry Co Ltd
Newpearl Group Co Ltd
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Guangdong Xinmingzhu Ceramic Group Co Ltd
Foshan Sanshui Newpearl Building Ceramic Industry Co Ltd
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    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C—CHEMISTRY; METALLURGY
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    • C04B33/00—Clay-wares
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
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    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/963—Surface properties, e.g. surface roughness
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Materials Engineering (AREA)
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  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

A kind of production method for recycling strong basicity waste residue manufacture ceramic tile of the present invention, the sewage squeezing waste residue that the production method of the ceramic tile is obtained using the squeezing of architectural pottery de-suphur of kiln fume denitration wastewater is primary raw material, through being granulated, punch forming, glazing, firing process is prepared, in composition of raw materials, the mass percent of the sewage squeezing waste residue is 40 60%, also containing the spodumene that mass percent is 10 20% in the blank raw material, mass percent is 4 10% Concave-convex clay rod or pyrophyllite, mass percent is the aluminium chloride of 1 3% micron grain size, mass percent is the aluminum oxide of 2 4% micron grain size, surplus is the feldspar and/or chiltern raw material needed for architectural pottery production.The present invention provides a kind of production method for recycling strong basicity waste residue manufacture ceramic tile, solves the problems, such as that equipment is easily corroded in billet surface scum and production process.

Description

Recycle the production method of strong basicity waste residue manufacture ceramic tile
Technical field
The present invention relates to ceramic tile method field of manufacturing, more particularly to a kind of life for recycling strong basicity waste residue manufacture ceramic tile Production.
Background technology
The purified processing extraction squeezing pug of sewage by the use of Production of Ceramics factory manufactures acquisition environmental protection as primary raw material Tile product, recycling for sewage and fertilizer is promoted, eliminate plant waste and discharge pollution to environment, be truly realized The zero-emission of factory's pollutant.Production method before applicant passes through to sewage squeezing mud raw material chemical analysis and ball milling, spray Expect that performance carries out batching adjusting, make environmentally friendly Imitation Rock Porcelain Tiles body recipe, sieved again after ball milling mixing and degreasing is handled, Material spray, shaping, glazing again, then through 1190~1210 DEG C of high-temperature calcinations, environmentally friendly porcelain of the manufacture water absorption rate 0.5% or so Brick, and introduce and be successfully introduced into market.When putting into production, it is found by the applicant that pH value is very after mix grinding for sewage squeezing mud raw material Height, all there is larger corrosivity to equipment such as ball milling, material sprays, cause the life-span of equipment liner not high, further, since sewage pressure Press filt raw material relatively mixes, and base substrate exhaust caused by burn till is more violent, and calcium can deposit in billet surface with this process, burn It is likely in billet surface have one layer of whiteness after knot, this has a strong impact on product quality, billet surface scum, influences brick face Decorative effect.
The content of the invention
The purpose of the present invention, that is, a kind of production method for recycling strong basicity waste residue manufacture ceramic tile is being provided, solving base The problem of equipment is easily corroded in body surface face scum and production process.
The technical scheme is that：A kind of production method for recycling strong basicity waste residue manufacture ceramic tile, the ceramic tile Production method using architectural pottery de-suphur of kiln fume denitration wastewater squeezing obtain sewage squeezing waste residue be primary raw material, pass through Granulation, punch forming, glazing, firing process are prepared, in composition of raw materials, the mass percent of the sewage squeezing waste residue For 40-60%, the spodumene for being also 10-20% containing mass percent in the blank raw material, mass percent 4-10% Concave-convex clay rod or pyrophyllite, the aluminium chloride that mass percent is 1-3% micron grain sizes, mass percent be 2-4% The aluminum oxide of micron grain size, surplus are the feldspar and/or chiltern raw material needed for architectural pottery production.
The particle diameter of the aluminum oxide is 100-1000 microns.
The aluminum oxide addition manner be in punch forming process charity on powder layer bottom and surface.
The firing temperature of the firing process is more than or equal to 1100 DEG C, less than or equal to 1200 DEG C.
A kind of raw material for recycling strong basicity waste residue manufacture ceramic tile, the squeezing of architectural pottery de-suphur of kiln fume denitration wastewater The sewage squeezing waste residue of acquisition is primary raw material, and the mass percent of the sewage squeezing waste residue is 40-60%, and the base substrate is former The Concave-convex clay rod or leaf wax that the spodumene for being also 10-20% containing mass percent in material, mass percent are 4-10% Stone, mass percent be 1-3% micron grain sizes aluminium chloride, mass percent be 2-4% micron grain size aluminum oxide, surplus For the feldspar and/or chiltern raw material needed for architectural pottery production.
Beneficial effects of the present invention are：Mainly reduce its alkalescence using the aluminium chloride of micron grain size, reduce to ball milling Corrosion in machine subsequent granulation moulding process to equipment, the aluminum oxide of micron grain size can be used for producing during closure base substrate high temperature sintering Steam vent, and then suppress calcium constituent and deposited in product surface, it is easily rotten to solve equipment in billet surface scum and production process The problem of erosion.
Embodiment
Contain substantial amounts of hydroxide, such as calcium hydroxide, caustic soda etc. in de-suphur of kiln fume denitration wastewater of the present invention, because This waste water is in strong basicity, and nertralizer can be used in sewage disposal process, but the pH value of its mud is still up to more than 8.5, this There is certain corrosivity to equipment, and in sintering process, be vented as base substrate melts, calcium can sink to billet surface with stomata Product, white sedimentary is formed in product surface, and this is in the field of business referred to as " scum ".For problem above, the present invention provides following solution Certainly scheme, 10-20% spodumene being added in blank raw material as solvent, it is used as solvent in sintering process, meanwhile, its There is higher high temperature viscosity compared to potassium, sodium class solvent, therefore make exhaust will not especially acutely, and introducing space has layer The Concave-convex clay rod and pyrophyllite of shape and fenestral fabric, can also further such that base substrate exhaust become more controllable, make Mainly reduce its alkalescence with the aluminium chloride of micron grain size, reduce to the corruption in ball mill subsequent granulation moulding process to equipment Erosion, the aluminum oxide of micron grain size can be used for steam vent caused by closure base substrate high temperature sintering, and then suppress calcium constituent in product Surface deposits.
Granulation, punch forming in the present invention, glazing, firing process are prior art, and this case is improved mainly in raw material Formula.Its a whole set of preparation method step is as follows：Squeezing waste residue puts in storage → dispensing ball milling → waste residue mud detection → mist projection granulating → blank forming → drying base substrate → glaze dispensing → mill glaze → glaze slip detection → glazing → high temperature burns till → physicochemical property detection → finished product sorting → finished product sampling observation → packaging is put in storage.
Specific embodiment is seen below：
Embodiment 1
(1) blank raw material presses following mass fraction proportion ingredient, sewage squeezing waste residue 60%, spodumene 10%, pyrophillite 4%th, aluminum oxide (average grain diameter of aluminum oxide is 500 microns), 10% sodium sand and 13% length of 1% aluminium chloride, 2% micron grain size Stone, using wet ball grinding, slurry is spray-dried, the powder of base substrate bed material, old 24h is made；
(2) by bed material powder cloth in mould, punch forming obtains base substrate, dries；
(3) kiln kiln roasting is sent into, 1200 DEG C, firing time 65min of firing temperature, obtains environment protection tile.
Embodiment 2
(1) blank raw material presses following mass fraction proportion ingredient, sewage squeezing waste residue 60%, spodumene 10%, concave convex rod Stone clay 4%, 1% aluminium chloride, the aluminum oxide (average grain diameter of aluminum oxide be 500 microns) of 2% micron grain size, 11% sodium sand and 12% feldspar；
(2) by bed material powder cloth in mould, punch forming obtains base substrate, dries；
(3) kiln kiln roasting is sent into, 1100 DEG C, firing time 65min of firing temperature, obtains environment protection tile.
Embodiment 2-1
(1) blank raw material presses following mass fraction proportion ingredient, sewage squeezing mud 60%, spodumene 10%, attapulgite Clay 4%, 10% sodium sand and 16% feldspar, using wet ball grinding, slurry is spray-dried, and the powder of base substrate bed material is made Material, old 24h；
(2) by bed material powder cloth in mould, punch forming obtains base substrate, dries；
(3) kiln kiln roasting is sent into, 1200 DEG C, firing time 65min of firing temperature, obtains environment protection tile.
Embodiment 2-2
(1) blank raw material presses following mass fraction proportion ingredient, sewage squeezing mud 60%, spodumene 10%, attapulgite Clay 4%, 1% aluminium chloride, 10% sodium sand and 15% feldspar, using wet ball grinding, slurry is spray-dried, and base substrate is made The powder of bed material, old 24h；
(2) by bed material powder cloth in mould, punch forming obtains base substrate, dries；
(3) kiln kiln roasting is sent into, 1200 DEG C, firing time 65min of firing temperature, obtains environment protection tile.
Embodiment 2-3 (existing formula)
(1) blank raw material presses following mass fraction proportion ingredient, sewage squeezing mud 60%, spodumene 5%, middle mountain black mud 10%th, 10% sodium sand and 15% quartz sand, using wet ball grinding, slurry is spray-dried, and the powder of base substrate bed material is made, Old 24h；
(2) by bed material powder cloth in mould, punch forming obtains base substrate, dries；
(3) kiln kiln roasting is sent into, 1100 DEG C, firing time 65min of firing temperature, obtains environment protection tile.
The various embodiments described above are obtained with environment protection tile and carries out porcelain density measurement and breakdown strength test, test data result It see the table below 1.
Table 1
It can be obtained from embodiment 1,2,2-1,2-2 and embodiment 2-3 test data contrast, add chlorination in the feed Aluminium, the alkaline of mud pH value that ball milling obtains is reduced, alkalescent is changed into by original strong basicity, with two new ball mills Exemplified by, a material for being formulated to match for being used for the existing such as embodiment 2-3 of ball milling, another is used in ball milling such as the application The formula of embodiment 1 is come the material that matches, after continuous use one month, its liner extent of corrosion of the former ball mill it is serious, it is necessary to More changeable liner, the liner of the latter's ball mill are added by aluminium chloride still without changing, can effectively extend the use of production equipment In the life-span, reduce maintenance cost.
In addition, with the addition of the Examples 1 and 2 of the aluminum oxide of micron grain size, tile density is improved to some extent, micro- The aluminum oxide in grain of rice footpath can block caused steam vent in base substrate high temperature sintering, can suppress calcium constituent and be deposited on surface, Scum phenomenon is avoided, also further improves the rupture strength of ceramic tile in addition.
Embodiment 3
(1) blank raw material presses following mass fraction proportion ingredient, sewage squeezing waste residue 60%, spodumene 10%, concave convex rod Stone clay 7%, the aluminium chloride of 2% micron grain size, 2% micron grain size aluminum oxide (average grain diameter of aluminum oxide be 500 microns), 8% sodium sand and 11% feldspar；
(2) by bed material powder cloth in mould, punch forming obtains base substrate, dries；
(3) kiln kiln roasting is sent into, 1100 DEG C, firing time 65min of firing temperature, obtains environment protection tile, tile density For 2.0g/cm3, ceramic tile intensity is 676N.
Embodiment 4
(1) blank raw material presses following mass fraction proportion ingredient, sewage squeezing waste residue 60%, spodumene 10%, concave convex rod Stone clay 10%, the aluminium chloride of 2% micron grain size, (average grain diameter of aluminum oxide is 500 micro- to the aluminum oxide of 2% micron grain size Rice), 8% sodium sand and 8% feldspar；
(2) by bed material powder cloth in mould, punch forming obtains base substrate, dries；
(3) kiln kiln roasting is sent into, 1100 DEG C, firing time 65min of firing temperature, obtains environment protection tile, tile density For 2.0g/cm3, ceramic tile intensity is 686N.
It can be drawn from above-described embodiment 2,3 and embodiment 4, Concave-convex clay rod or pyrophillite are introduced in formula, into The rupture strength of product ceramic tile greatly improves, and the Concave-convex clay rod or pyrophyllite that the application introduces have layer mineral structure, especially It is Concave-convex clay rod, and with more tufted space structure, under such configuration, it can suppress carborundum and high-temperature resin in high temperature It is expanded foamed in sintering process, and then cause the base substrate after burning that there is preferable flatness.Moreover, because suppress expansion hair Bubble, the density of base substrate lifted, and relatively before the product for preparing of technique, also have a distinct increment, make on rupture strength Its density of the tile product obtained reaches 2.0-2.1g/cm3, solves the ceramic tile ceramic density of existing sewage squeezing waste residue manufacture The problem of low, the intensity of the effective ceramic tile for improving the manufacture of sewage squeezing waste residue.
It can be obtained from the test data contrast of embodiment 1,2,3,4, addition and the finished product porcelain of Concave-convex clay rod or pyrophillite The rupture strength correlation of brick, but in actual production, if Concave-convex clay rod or pyrophillite add more, mud Viscosity greatly improves, and the yield of powder is relatively low during spray drying, it may appear that more serious wall sticking phenomenon, therefore Concave-convex clay rod Or the addition of pyrophillite is preferably in 4%-10%.
Further description, the firing temperature of the firing process are less than 1200 DEG C.Because temperature is higher than this critical value Liquid phase viscosity can be greatly reduced, it is difficult to it is expanded foamed to suppress base substrate.
Embodiment 5
(1) blank raw material presses following mass fraction proportion ingredient, sewage squeezing waste residue 40%, spodumene 20%, concave convex rod Stone clay 10%, the aluminium chloride of 3% micron grain size, (average grain diameter of aluminum oxide is 100 micro- to the aluminum oxide of 3% micron grain size Rice), 10% sodium sand and 4% feldspar, using wet ball grinding, slurry pH value 7.4, slurry is spray-dried, base substrate is made The powder of bed material, old 24h；
(2) by bed material powder cloth in mould, punch forming obtains base substrate, dries；
(3) kiln kiln roasting is sent into, 1200 DEG C, firing time 65min of firing temperature, obtains environment protection tile, tile density For 2.0g/cm3, ceramic tile intensity is 685N.
Embodiment 6
(1) blank raw material presses following mass fraction proportion ingredient, sewage squeezing waste residue 40%, spodumene 20%, concave convex rod Stone clay 10%, 3% aluminium chloride, aluminum oxide (average grain diameter of aluminum oxide is 100 microns), 10% sodium sand of 4% micron grain size With 3% feldspar, using wet ball grinding, slurry pH value 7.5, slurry is spray-dried, the powder of base substrate bed material is made, it is old Rotten 24h；
(2) by bed material powder cloth in mould, punch forming obtains base substrate, dries；
(3) kiln kiln roasting is sent into, 1100 DEG C, firing time 65min of firing temperature, obtains environment protection tile, tile density For 2.1g/cm3, ceramic tile intensity is 689N.
Embodiment 7
(1) blank raw material presses following mass fraction proportion ingredient, sewage squeezing waste residue 40%, spodumene 20%, concave convex rod Stone clay 10%, 2% aluminium chloride, aluminum oxide (average grain diameter of aluminum oxide is 1000 microns), 10% sodium sand of 3% micron grain size With 5% feldspar, using wet ball grinding, slurry pH value 7.5, slurry is spray-dried, the powder of base substrate bed material is made, it is old Rotten 24h；
(2) by bed material powder cloth in mould, punch forming obtains base substrate, dries；
(3) kiln kiln roasting is sent into, 1150 DEG C, firing time 65min of firing temperature, obtains environment protection tile, tile density For 2.0g/cm3, ceramic tile intensity is 663N.
Further description, the ceramic tile of above-mentioned preparation, it can carry out spraying pattern glaze layer or ink jet printing in billet surface Make to burn till rear billet surface there is diversified pattern etc. process, enrich the brick face effect of environment protection tile.
The technical principle of the present invention is described above in association with specific embodiment.These descriptions are intended merely to explain the present invention's Principle, and limiting the scope of the invention can not be construed in any way.Based on explanation herein, the technology of this area Personnel would not require any inventive effort the other embodiments that can associate the present invention, and these modes are fallen within Within protection scope of the present invention.

Claims (6)

1. a kind of production method for recycling strong basicity waste residue manufacture ceramic tile, the production method of the ceramic tile use architectural pottery The sewage squeezing waste residue that the squeezing of de-suphur of kiln fume denitration wastewater obtains is primary raw material, through granulation, punch forming, glazing, burning It is prepared into process, it is characterised in that in composition of raw materials, the mass percent of the sewage squeezing waste residue is 40-60%, The attapulgite that the spodumene for being also 10-20% containing mass percent in the blank raw material, mass percent are 4-10% Clay or pyrophyllite, the aluminium chloride that mass percent is 1-3% micron grain sizes, mass percent are 2-4% micron grain size Aluminum oxide, surplus are the feldspar and/or chiltern raw material needed for architectural pottery production.
2. the production method of strong basicity waste residue manufacture ceramic tile is recycled as claimed in claim 1, it is characterised in that the oxygen The particle diameter for changing aluminium is 100-1000 microns.
3. the production method of strong basicity waste residue manufacture ceramic tile is recycled as claimed in claim 1, it is characterised in that the oxygen Change aluminium addition manner be in punch forming process charity on powder layer bottom and surface.
4. the production method of strong basicity waste residue manufacture ceramic tile is recycled as claimed in claim 1, it is characterised in that the burning Firing temperature into process is more than or equal to 1100 DEG C, less than or equal to 1200 DEG C.
5. a kind of raw material for recycling strong basicity waste residue manufacture ceramic tile, it is characterised in that architectural pottery de-suphur of kiln fume takes off The sewage squeezing waste residue that the squeezing of nitre waste water obtains is primary raw material, and the mass percent of the sewage squeezing waste residue is 40-60%, The attapulgite that the spodumene for being also 10-20% containing mass percent in the blank raw material, mass percent are 4-10% Clay or pyrophyllite, the aluminium chloride that mass percent is 1-3% micron grain sizes, mass percent are 2-4% micron grain size Aluminum oxide, surplus are the feldspar and/or chiltern raw material needed for architectural pottery production.
6. the raw material of strong basicity waste residue manufacture ceramic tile is recycled as claimed in claim 5, it is characterised in that the aluminum oxide Particle diameter be 100-1000 microns.
CN201710948234.2A 2017-10-12 2017-10-12 Production method for manufacturing ceramic tiles by recycling strong alkaline waste residues Active CN107673737B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796188A (en) * 2019-02-26 2019-05-24 佛山市东鹏陶瓷有限公司 A kind of is the Ceramic Tiles and its production method of raw material using desulfurization slag and glaze slag
CN111574239A (en) * 2019-12-31 2020-08-25 佛山金意绿能新材科技有限公司 Method for manufacturing high-strength foamed ceramic

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KR0153376B1 (en) * 1995-12-18 1998-11-16 구형우 Process for the preparation of a brick
CN102351512A (en) * 2011-06-28 2012-02-15 广东新明珠陶瓷集团有限公司 Environment-friendly porcelain tile made from sewage squeezing mud
CN104725029A (en) * 2015-03-22 2015-06-24 周光惠 Composite ceramic toughened ceramic brick with humidity adjusting function and production method thereof

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KR0153376B1 (en) * 1995-12-18 1998-11-16 구형우 Process for the preparation of a brick
CN102351512A (en) * 2011-06-28 2012-02-15 广东新明珠陶瓷集团有限公司 Environment-friendly porcelain tile made from sewage squeezing mud
CN104725029A (en) * 2015-03-22 2015-06-24 周光惠 Composite ceramic toughened ceramic brick with humidity adjusting function and production method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796188A (en) * 2019-02-26 2019-05-24 佛山市东鹏陶瓷有限公司 A kind of is the Ceramic Tiles and its production method of raw material using desulfurization slag and glaze slag
CN111574239A (en) * 2019-12-31 2020-08-25 佛山金意绿能新材科技有限公司 Method for manufacturing high-strength foamed ceramic
CN111574239B (en) * 2019-12-31 2022-08-23 佛山金意绿能新材科技有限公司 Method for manufacturing high-strength foamed ceramic

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