CN107655021A - A kind of method and system using absorption heat pump Mist heat recovering - Google Patents

A kind of method and system using absorption heat pump Mist heat recovering Download PDF

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Publication number
CN107655021A
CN107655021A CN201711043917.XA CN201711043917A CN107655021A CN 107655021 A CN107655021 A CN 107655021A CN 201711043917 A CN201711043917 A CN 201711043917A CN 107655021 A CN107655021 A CN 107655021A
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CN
China
Prior art keywords
heat
heat pump
water
spray column
flue gas
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Pending
Application number
CN201711043917.XA
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Chinese (zh)
Inventor
孙晓阳
李强
郭涛
江建忠
吕海生
刘冠杰
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Huaneng Clean Energy Research Institute
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Huaneng Clean Energy Research Institute
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Priority to CN201711043917.XA priority Critical patent/CN107655021A/en
Publication of CN107655021A publication Critical patent/CN107655021A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/08Arrangements of devices for treating smoke or fumes of heaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D3/00Hot-water central heating systems
    • F24D3/18Hot-water central heating systems using heat pumps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D2200/00Heat sources or energy sources
    • F24D2200/16Waste heat
    • F24D2200/18Flue gas recuperation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/52Heat recovery pumps, i.e. heat pump based systems or units able to transfer the thermal energy from one area of the premises or part of the facilities to a different one, improving the overall efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/30Technologies for a more efficient combustion or heat usage

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Treating Waste Gases (AREA)

Abstract

A kind of system using absorption heat pump Mist heat recovering,Including spray column,The bottom of spray column sets the smoke inlet after wet desulphurization,Top sets exhanst gas outlet after cooling,Top sets spray water inlet,Bottom sets spray water out,The Heating medium for spraying water out and plate type heat exchanger connects,The heating agent outlet for spraying water inlet and plate type heat exchanger connects,The refrigerant gateway of plate type heat exchanger and the cold end of heat pump form loop,The hot junction of heat pump forms loop with heat supply network backwater,The bottom of spray column is delivered to after flue gas,Run up,Exchanged heat with downward shower water,Transfer heat to shower water,Flue gas after temperature reduces is discharged by spray column top,Shower water after temperature rise transfers heat to the cold end of absorption heat pump by plate type heat exchanger,Under the driving of driving heat source,The heat supply network backwater that heat pump is used to heat hot junction from cold end recovery heat,With organic efficiency height,Energy consumption is low,The characteristics of environmentally friendly.

Description

A kind of method and system using absorption heat pump Mist heat recovering
Technical field
It is more particularly to a kind of to utilize more than absorption heat pump recovered flue gas the invention belongs to Industrial Boiler and field of energy-saving technology The method and system of heat.
Background technology
Coal fired power plant is the most important part of China's power generating industry.Although country greatly develops new energy and built in recent years If progressively control and reduce newly-built coal fired power plant, but coal fired power plant generated energy still accounts for the 70% of national gross generation.In north Side area, coal fired power plant are also responsible for the important function of heat supply in winter.Quickening and economy recently as Development of China's Urbanization is fast Speed development, more residential areas and industrial enterprise are built, while the policy of central heating is progressively being implemented, adjoint Be that many cities breach that heats in the winter time is continuously increased.Therefore, in the case of coal fired power plant total installation of generating capacity constantly reduction, Need further to excavate unit itself potentiality, waste heat and heat loss are recycled.In the various heat loss of boiler, smoke evacuation Heat loss is the problem of a worth primary study.
China's coal-fired power station boiler exhaust gas temperature design load is typically between 120~140 DEG C, the smoke evacuation of large-sized station boiler Heat loss accounts for the 3~8% of power plant's heat loss, while also contains substantial amounts of vapor in discharging fume, and entrained gasification latent heat is huge, It can be seen that heat loss due to exhaust gas is a kind of abundant cryogenic waste heat resource.In the past, because the presence of flue gas acid dew point causes boiler to arrange Cigarette temperature can not be too low, otherwise can severe corrosion equipment heating surface and pipeline.With the soaring and energy-saving and emission-reduction of energy prices The it is proposed of policy, flue gas in power station boiler UTILIZATION OF VESIDUAL HEAT IN receive increasing attention.In the last few years, it is wide with low temperature electrostatic precipitation technology General application, exhaust gas temperature have already decreased to 90~110 DEG C, in the OK range of the inlet flue gas temperature in wet desulphurization.Through Sour content is very low in flue gas after low temperature dedusting technology and wet desulfurization system processing, and flue-gas temperature is 50~70 ℃.A large amount of vapor are carried by the saturated flue gas of wet desulfurization system, latent heat of vaporization amount is still huge.
Utilized at present for large-scale coal-fired power station boiler (including most CFB boiler), used smoke pre-heating Scheme is mainly using low-level (stack-gas) economizer come the waste heat in recovered flue gas.Low-level (stack-gas) economizer is typically located at the upstream of deduster, Smoke pre-heating is reclaimed by condensate, the waste heat after recovery, or return to the therrmodynamic system of power plant or for as power plant's warm wind The thermal source of device, or as heat source, heat circulation water for heating.
Limited by heat transfer temperature difference, while in order to prevent the low-temperature corrosion of heating surface, low-level (stack-gas) economizer is designed at present Mouth cigarette temperature, general control is more than 90 DEG C.At present, low-level (stack-gas) economizer waste heat recovery profit used by most of coal-fired power station boiler With technology, the heat reclaimed only accounts for 20% of fume afterheat or so.Still there is most obvious heat of smoke and flue gas reclaimed water to steam The gasification latent heat of gas is underutilized.Therefore develop that a kind of simple system is reliable, efficiency high, obvious heat of smoke can be made full use of With the heat recovery technology of gasification latent heat, for improving fuel utilization efficiency, reach energy-saving purpose with very heavy The meaning wanted.
The content of the invention
The shortcomings that in order to overcome above-mentioned prior art, reclaimed it is an object of the invention to provide one kind using absorption heat pump The method and system of fume afterheat, has that waste heat recovery rate is high, system power consumption is small, economic benefit is strong, reliable stabilization etc. Feature, while also have and alleviate chimney " emitting white cigarette " phenomenon, reduce the content of dust and sulfur dioxide in flue gas, save wet desulphurization The advantages of with water.
To achieve these goals, the technical solution adopted by the present invention is:
A kind of method using absorption heat pump Mist heat recovering, spray column is delivered to after the flue gas after wet desulphurization Bottom, run up, exchanged heat with downward shower water, transfer heat to shower water, temperature reduce after flue gas by spraying Top of tower is discharged, and the shower water after temperature rise transfers heat to the cold end of absorption heat pump by plate type heat exchanger, is driving Under the driving of dynamic thermal source, heat supply network backwater of the heat pump from cold end recovery heat for heating hot junction.
50-100 DEG C of the flue-gas temperature scope of the bottom for delivering to spray column, when less than when, heat flue gas.
After the flue gas exchanges heat in spray column, temperature is down to 20-30 DEG C.
Present invention also offers a kind of system using absorption heat pump Mist heat recovering, including spray column, spray column Bottom set wet desulphurization after smoke inlet, top set cooling after exhanst gas outlet, top set spray water inlet, bottom The Heating medium connection of setting spray water out, spray water out and plate type heat exchanger, spray water inlet and plate type heat exchanger Heating agent outlet connection, the refrigerant gateway of plate type heat exchanger and the cold end of heat pump form loop, hot junction and the heat supply network backwater of heat pump Form loop.
Warm-air drier is provided with smoke conveying duct after wet desulphurization, to be carried out when flue-gas temperature is too low to flue gas Preheating.
The spray column uses multi-stage spray, the setting of two-stage demisting, it is ensured that flue gas fully exchanges heat with shower water, and removes Vapor in flue gas.
The spray column sets overflow pipe, and the water that overflow goes out enters desulphurization system, as wet desulfurizing process water.
Water pump one, the heat pump are provided with the connecting line of the Heating medium of the spray water out and plate type heat exchanger Cold end loop be provided with water pump two.
The heat pump is absorption heat pump, and using lithium bromide as absorbent, water is refrigerant, and driving heat source is steam.
Compared with prior art, the beneficial effects of the invention are as follows:
1. the present invention can abundant Mist heat recovering, exit gas temperature can as little as 20-30 DEG C.It is now exhausted in flue gas The latent heat of vaporization of most of vapor is recovered, and waste heat recovery efficiency is very high.
2. system energy consumption is low.Lithium bromide absorption type heat pump is driven by high-temperature steam, it is only necessary to a small amount of electrical energy drive water pump, with biography System heat pump substantially reduces compared to energy consumption.
3. flue gas carries out secondary spraying in spray column, dust and sulfur dioxide in flue gas are further removed, to realize Unit " ultra-clean discharge " lays the first stone.
4. the flue-gas temperature after spray column is reduced near ambient temperature, water vapour content is relatively low, alleviates cigarette significantly The phenomenon of chimney " emitting white cigarette ", reduces the harm of gypsum rain.
5. a large amount of vapor in flue gas are absorbed by spray column, wet desulphurization water can be used as, saves great lot of water resources.
Brief description of the drawings
Fig. 1 is present system structural representation.
Embodiment
Describe embodiments of the present invention in detail with reference to the accompanying drawings and examples.
As shown in figure 1, a kind of system using absorption heat pump Mist heat recovering of the invention, including spray column 3, spray The bottom of tower 3 sets the smoke inlet after wet desulphurization, and top sets exhanst gas outlet after cooling, and top sets spray water inlet, Bottom sets spray water out, and spray water out is connected with the Heating medium of plate type heat exchanger 5, sprays water inlet and plate-type heat-exchange The cold end of the heating agent outlet connection of device 5, the refrigerant gateway of plate type heat exchanger 5 and heat pump 7 forms loop, the hot junction of heat pump 7 with Heat supply network backwater forms loop.Heat pump 7 is absorption heat pump, and using lithium bromide as absorbent, water is refrigerant, and driving heat source is steaming Vapour.
The present invention can set warm-air drier 1 on the smoke conveying duct after wet desulphurization, with when flue-gas temperature is too low pair Flue gas is preheated.
Spray column 3 of the present invention is sprayed using multistage (2-4 levels), the setting of two-stage demisting, it is ensured that flue gas is abundant with shower water Heat exchange, and remove the vapor in flue gas.Spray column 3 sets overflow pipe 2, and the water that overflow goes out enters desulphurization system, as wet method Sulfur removal technology water.
The bottom of spray column is delivered to after flue gas after wet desulphurization, is run up, is exchanged heat with downward shower water, will Heat transfer is to shower water, and the flue gas (20-30 DEG C) after temperature reduces is discharged by spray column top, the shower water after temperature rise The cold end of absorption heat pump is transferred heat to by plate type heat exchanger, under the driving of driving heat source, heat pump reclaims from cold end Heat is used for the heat supply network backwater for heating hot junction.
Detailed process and principle are as follows:
If the flue gas temperature after wet desulphurization is relatively low, has a large amount of Water vapor condensations in the duct, influence normal operation, So flue-gas temperature is improved by warm-air drier 1.Subsequent flue gas enters from the bottom of spray column 3, by multi-stage spray, demisting etc. Discharged after flow from tower top.Shower water is a circulatory system, is driven by water pump 1, between spray column 3 and plate type heat exchanger 5 Circular flow.The cold end of heat pump 7, as working medium, is run by the driving cycle of water pump 26 using water, constantly absorbs what shower water was brought Heat.The hot junction of heat pump 7 connects heat supply network backwater and heat supply network feedwater respectively, and heat supply network backwater is heated using the waste heat of recovery. The driving heat source of heat pump 7 uses steam, is derived from turbine low pressure cylinder exhaust, heat pump 7 is entered after pressure-reducing valve depressurizes.
According to the above description, specific implementation step of the invention is:
1. carrying out basic equipment inspection, whether special survey heat exchanger has the absorbent and refrigerant of stopping state, heat pump Whether whether sufficient, each pipeline has evaporating, emitting, dripping or leaking of liquid or gas phenomenon.
2. starting absorption heat pump, respective water circulation is formed in cold end and hot junction, introduces driving heat source (steam).
3. opening shower water water pump, shower water forms circulation between spray column and plate type heat exchanger.
4. a flue gas introduces spray column, waste heat recovery process starts.As flue-gas temperature is relatively low, is formed condense in the duct Water, then opening warm-air drier is needed to preheat flue gas.

Claims (8)

  1. A kind of 1. method using absorption heat pump Mist heat recovering, it is characterised in that after the flue gas after wet desulphurization The bottom of spray column is delivered to, is run up, is exchanged heat with downward shower water, shower water is transferred heat to, after temperature reduces For flue gas by being discharged at the top of spray column, the shower water after temperature rise transfers heat to absorption heat pump by plate type heat exchanger Cold end, under the driving of driving heat source, heat supply network backwater of the heat pump from cold end recovery heat for heating hot junction.
  2. 2. the method for absorption heat pump Mist heat recovering is utilized according to claim 1, it is characterised in that the flue gas exists After being exchanged heat in spray column, temperature is down to 20-30 DEG C.
  3. 3. a kind of system using absorption heat pump Mist heat recovering, it is characterised in that including spray column (3), spray column (3) Bottom set wet desulphurization after smoke inlet, top set cooling after exhanst gas outlet, top set spray water inlet, bottom Spray water out is set, and spray water out is connected with the Heating medium of plate type heat exchanger (5), sprays water inlet and plate type heat exchanger (5) heating agent outlet connection, the refrigerant gateway of plate type heat exchanger (5) form loop with the cold end of heat pump (7), heat pump (7) Hot junction forms loop with heat supply network backwater.
  4. 4. the system of absorption heat pump Mist heat recovering is utilized according to claim 4, it is characterised in that in wet desulphurization Warm-air drier (1) is provided with smoke conveying duct afterwards, to be preheated when flue-gas temperature is too low to flue gas.
  5. 5. the system of absorption heat pump Mist heat recovering is utilized according to claim 4, it is characterised in that the spray column (3) multi-stage spray, the setting of two-stage demisting are used, it is ensured that flue gas fully exchanges heat with shower water, and removes the vapor in flue gas.
  6. 6. the system of absorption heat pump Mist heat recovering is utilized according to claim 4, it is characterised in that the spray column (3) overflow pipe (2) is set, and the water that overflow goes out enters desulphurization system, as wet desulfurizing process water.
  7. 7. the system of absorption heat pump Mist heat recovering is utilized according to claim 4, it is characterised in that the shower water Outlet is returned with being provided with water pump one (4), the cold end of the heat pump (7) on the connecting line of the Heating medium of plate type heat exchanger (5) Road is provided with water pump two (6).
  8. 8. the system of absorption heat pump Mist heat recovering is utilized according to claim 4, it is characterised in that the heat pump (7) it is absorption heat pump, using lithium bromide as absorbent, water is refrigerant, and driving heat source is steam.
CN201711043917.XA 2017-10-31 2017-10-31 A kind of method and system using absorption heat pump Mist heat recovering Pending CN107655021A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108413654A (en) * 2018-04-25 2018-08-17 双良节能系统股份有限公司 A kind of processing unit of wet desulfurization flue gas
CN109045976A (en) * 2018-08-29 2018-12-21 航天环境工程有限公司 A kind of ammonia process of desulfurization flue gas disappears white waste heat depth recovery system and application
CN109945278A (en) * 2019-03-25 2019-06-28 大连理工大学 A kind of energy conserving system being used for central heating using absorption heat pump depth Mist heat recovering
CN109945277A (en) * 2019-03-25 2019-06-28 大连理工大学 A kind of energy conserving system being used for central heating using electric heat pump depth recycling remaining heat of flue gas from steam power plant
CN109974062A (en) * 2019-03-25 2019-07-05 大连理工大学 A kind of fume afterheat depth recovery system using absorption heat pump and two-stage heat exchanger
CN110645587A (en) * 2019-11-01 2020-01-03 浙江城建煤气热电设计院有限公司 Flue gas takes off white device condensate waste heat recovery and utilizes system
CN112629281A (en) * 2020-11-30 2021-04-09 哈尔滨工业大学 Coal-fired flue gas complementary energy recovery packed tower and system with load adaptability
US11821637B2 (en) 2019-03-25 2023-11-21 Dalian University Of Technology Energy-saving system using electric heat pump to deeply recover flue gas waste heat from heat power plant for district heating

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CN102242946A (en) * 2011-04-29 2011-11-16 清华大学 Concentrated heat supply system for reclaiming smoke afterheat by absorption heat pump
CN202092207U (en) * 2011-04-29 2011-12-28 清华大学 Central heating system recovering waste heat of smoke through absorbing type heat pump
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CN204254934U (en) * 2014-11-25 2015-04-08 燕山大学 A kind of heating system utilizing compression heat pump to realize the recovery of the residual heat from boiler fume degree of depth
CN105605647A (en) * 2016-02-03 2016-05-25 清华大学 Synergic-purification all-heat-recovery combined heat and power generation system
CN207539920U (en) * 2017-10-31 2018-06-26 中国华能集团清洁能源技术研究院有限公司 A kind of system using absorption heat pump Mist heat recovering

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CN102242946A (en) * 2011-04-29 2011-11-16 清华大学 Concentrated heat supply system for reclaiming smoke afterheat by absorption heat pump
CN202092207U (en) * 2011-04-29 2011-12-28 清华大学 Central heating system recovering waste heat of smoke through absorbing type heat pump
JP2014070750A (en) * 2012-09-28 2014-04-21 Miura Co Ltd Steam generation system
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CN207539920U (en) * 2017-10-31 2018-06-26 中国华能集团清洁能源技术研究院有限公司 A kind of system using absorption heat pump Mist heat recovering

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108413654A (en) * 2018-04-25 2018-08-17 双良节能系统股份有限公司 A kind of processing unit of wet desulfurization flue gas
CN109045976A (en) * 2018-08-29 2018-12-21 航天环境工程有限公司 A kind of ammonia process of desulfurization flue gas disappears white waste heat depth recovery system and application
CN109945278A (en) * 2019-03-25 2019-06-28 大连理工大学 A kind of energy conserving system being used for central heating using absorption heat pump depth Mist heat recovering
CN109945277A (en) * 2019-03-25 2019-06-28 大连理工大学 A kind of energy conserving system being used for central heating using electric heat pump depth recycling remaining heat of flue gas from steam power plant
CN109974062A (en) * 2019-03-25 2019-07-05 大连理工大学 A kind of fume afterheat depth recovery system using absorption heat pump and two-stage heat exchanger
US11821637B2 (en) 2019-03-25 2023-11-21 Dalian University Of Technology Energy-saving system using electric heat pump to deeply recover flue gas waste heat from heat power plant for district heating
CN110645587A (en) * 2019-11-01 2020-01-03 浙江城建煤气热电设计院有限公司 Flue gas takes off white device condensate waste heat recovery and utilizes system
CN110645587B (en) * 2019-11-01 2023-11-17 浙江城建煤气热电设计院有限公司 Condensate water waste heat recycling system of flue gas whitening device
CN112629281A (en) * 2020-11-30 2021-04-09 哈尔滨工业大学 Coal-fired flue gas complementary energy recovery packed tower and system with load adaptability

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Application publication date: 20180202