CN108413654A - A kind of processing unit of wet desulfurization flue gas - Google Patents

A kind of processing unit of wet desulfurization flue gas Download PDF

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Publication number
CN108413654A
CN108413654A CN201810378651.2A CN201810378651A CN108413654A CN 108413654 A CN108413654 A CN 108413654A CN 201810378651 A CN201810378651 A CN 201810378651A CN 108413654 A CN108413654 A CN 108413654A
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CN
China
Prior art keywords
heat
heat exchanger
flue gas
processing unit
wet desulfurization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810378651.2A
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Chinese (zh)
Inventor
薛海君
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Shuangliang Cooling System Co., Ltd
Original Assignee
Shuangliang Eco Energy Systems Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shuangliang Eco Energy Systems Co Ltd filed Critical Shuangliang Eco Energy Systems Co Ltd
Priority to CN201810378651.2A priority Critical patent/CN108413654A/en
Publication of CN108413654A publication Critical patent/CN108413654A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B30/00Heat pumps
    • F25B30/04Heat pumps of the sorption type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/08Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being otherwise bent, e.g. in a serpentine or zig-zag
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/30Technologies for a more efficient combustion or heat usage

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to a kind of processing units of wet desulfurization flue gas, it is made of desulfurizing tower, heat absorbing heat exchanger, heat release heat exchanger, chimney, flue, steam turbine, low plus heat exchanger, chilled water line and heat medium water pipeline, heat absorbing heat exchanger reduces water capacity and pollutant for flue gas cool-down condensation, heat release heat exchanger eliminates the white plume and gypsum rain that are formed after chimney discharge for flue gas, add absorption heat pump, the low-temperature receiver and heat source needed for flue gas condensing and heating are provided with absorption heat pump, while the heat source of heating steam turbine condensed water being provided to low plus heat exchanger.It is an advantage of the invention that:1)Reduce the pollutant in flue gas;2)The condenser heat discharged when being cooled down using flue gas removes heating flue gas and condensed water, takes full advantage of waste heat, improves energy use efficiency.

Description

A kind of processing unit of wet desulfurization flue gas
Technical field
The present invention relates to a kind of processing units of wet desulfurization flue gas, are mainly used for thermal power plant to coal-fired after wet desulphurization The processing procedure of flue gas.
Background technology
In power industry, the coal-fired flue-gas of boiler emission largely passes through the processing procedure of wet desulfurizing process.Through wet method Flue gas after desulfurization process, not only temperature is relatively low(About 50 DEG C), and water capacity is high(Vapor is in saturation state), also carry A large amount of fine particle(PM2.5 and smaller particle), it is discharged into after air and easily forms high humidity environment in some areas, makes these thin Grain object is converted to " haze ".So wet-method desulfurized fume administer by government be classified as improve atmospheric environment, administer haze it is primary Task.
The main technological route handled at present flue gas after desulfurization is the fume treatment side using " condensation+reheating " Method." condensation " is cooled flue gas, and vapor therein is made to be condensed, and reduces water capacity in flue gas and also reduces pollutant simultaneously (Fine particle)Concentration;" reheating " is to reheat flue gas after " condensation " processing, and flue gas is made to become insatiable hunger by steam-laden state And state, white plume and gypsum rain phenomenon can be eliminated after being discharged into air into chimney, be also beneficial to the expansion of pollutant in flue gas It dissipates.There are mainly two types of the condensation methods of flue gas, and one is indirect coolings, i.e., flue gas cooling device is arranged in flue(Heat absorption is changed Hot device);Another kind is direct cooling, arranges slurries cooling device outside the desulfurizing tower on spray piping(Heat absorbing heat exchanger), first Slurries are cooled down, the process cooling flue gas by desulfurizing tower again is sprayed in tower using slurries, flue-gas temperature is made to reduce and containing wet Amount reduces.Cooling and condensation process needs low-temperature receiver, usually provides low-temperature receiver by the cooling equipment such as cooling tower.The reheating process of flue gas Heat source is needed, is provided by equipment such as low-level (stack-gas) economizers, even it is also required to provide steam as auxiliary thermal source sometimes.
The low-temperature receiver and heat source of the prior art have the following disadvantages:1)Condensation heat in flue gas is not fully used, and 2) Flue gas reheat needs the thermal energy that low-level (stack-gas) economizer provides, even additional auxiliary thermal energy, for example use heating steam heating etc., Energy consumption is big, and 3)There is provided low-temperature receiver cooling tower there may be(Water mist and waste water etc.)Secondary pollution discharges.
Invention content
It is an object of the invention to avoid, fume afterheat in above-mentioned technical proposal cannot make full use of, to reheat energy consumption big Deficiency provides and can make full use of waste heat, more energy-efficient flue gas after desulfurization processing unit.
The object of the present invention is achieved like this:A kind of processing unit of wet desulfurization flue gas is exchanged heat by desulfurizing tower, heat absorption Device, heat release heat exchanger, chimney, flue, steam turbine, low plus heat exchanger, chilled water line, heat medium water pipeline composition, add absorption Formula heat pump makes absorption heat pump evaporator be connect with heat absorbing heat exchanger through chilled water line, makes absorption heat pump condenser through heat Matchmaker's waterpipe is connect with heat release heat exchanger and low plus heat exchanger.
A kind of processing unit of wet desulfurization flue gas, the heat release heat exchanger and low plus heat exchanger are set as in parallel, i.e.,: The outlet of condenser is connect through heating agent waterpipe with heat release heat exchanger and low plus heat exchanger import, and the import of condenser is through heat medium water Pipeline and heat release heat exchanger and low plus heat exchanger exit are connected or the heat release heat exchanger and low heat exchanger are added to be set as going here and there Connection, i.e.,:Condensator outlet is connected with heat release heat exchanger import, and heat release heat exchanger outlet is connect with low plus heat exchanger import, low to add Heat exchanger exit is connect with condenser inlet.
A kind of processing unit of wet desulfurization flue gas, the heat absorbing heat exchanger are arranged in flue, in desulfurizing tower and heat absorption Between heat exchanger;Or it is arranged outside desulfurizing tower on spray piping, after slurries pump.
Compared with prior art, a kind of processing unit of wet desulfurization flue gas of the present invention has below after implementing beneficial to effect Fruit:
1)By adding absorption heat pump, the waste heat of flue gas cooling and condensation process is absorbed, for again after low temperature exhaust heat is heated up Flue gas and steam turbine condensed water are heated, so that thermal energy is fully used, good energy-conserving effect.
2)Low-temperature receiver is provided using evaporator with heat pump, does not use cooling tower, avoids the emission problem for generating secondary pollution, more Add environmental protection.
Description of the drawings
Fig. 1 is a kind of 1 schematic diagram of processing unit embodiment of wet desulfurization flue gas of the present invention.
Fig. 2 is a kind of 2 schematic diagram of processing unit embodiment of wet desulfurization flue gas of the present invention.
Fig. 3 is a kind of 3 schematic diagram of processing unit embodiment of wet desulfurization flue gas of the present invention
Wherein:
Desulfurizing tower 1, spray piping 1-1, slurries pump 1-2, tower body 1-3, heat absorbing heat exchanger 2, flue 3, heat release heat exchanger 4, chimney 5, steam turbine 6, heating agent waterpipe 7, condensing water conduit 8, absorption heat pump 9, evaporator 9-1, condenser 9-2, chilled water line 10, low plus heat exchanger 11.
Specific implementation mode
Embodiment 1:
Referring to Fig. 1, a kind of processing unit of wet desulfurization flue gas, by desulfurizing tower 1, heat absorbing heat exchanger 2, heat release heat exchanger 4, chimney 5, flue 3, steam turbine 6, low plus heat exchanger 11 and chilled water line 10 and heating agent waterpipe 7 composition, add absorption heat pump 9, so that the evaporator 9-1 of absorption heat pump 9 is connect with heat absorbing heat exchanger 2 through chilled water line 10, makes the condensation of absorption heat pump 9 Device 9-2 is connect through heating agent waterpipe 7 with heat release heat exchanger 4 and low plus heat exchanger 11.
Flue 3 connects desulfurizing tower 1, heat release heat exchanger 4 and chimney 5, forms smoke flow channels, 4 cloth of heat absorbing heat exchanger It sets on flue 3, after desulfurizing tower 1, before heat release heat exchanger 4.
In terms of heating agent Water flow-path, heat release heat exchanger 4 and low plus heat exchanger 11 are arranged in parallel, i.e.,:Condenser 9-2's goes out Mouth is connect through heating agent waterpipe 7 with heat release heat exchanger 4 and low plus heat exchanger 11 import, and condenser 9-2 imports are through heating agent water pipe Road 7 is connected with heat release heat exchanger 4 and low plus heat exchanger 11 outlet;The heat medium water sent out and returned from condenser 9-2 simultaneously into Go out heat release heat exchanger 4 and low plus heat exchanger 11.
After the processing of desulfurizing tower 1, flue gas institute containing water vapor is in saturation state, is introduced into the shell side of heat absorbing heat exchanger 2, with Temperature reduces after chilled water in tube side carries out heat exchange, while condensed water is precipitated in the Water vapor condensation in flue gas, discharges smoke Gas latent heat and sensible heat, water content and pollutant concentration in flue gas are reduced with condensation process;Then, flue gas enters back into heat release Heat exchanger 4 exchanges heat with the heat medium water in tube side, and since heating agent coolant-temperature gage is high, flue-gas temperature increases, and becomes undersaturated condition It is admitted to chimney 5, final discharge system enters air.Flue-gas temperature increase after in it is unsaturated when, can avoid white plume and The generation of gypsum rain phenomenon.
Flue gas heat of the absorption heat pump 9 in evaporator 9-1 interior suctions fetch 2 chilled water of self-priming heat exchanger(Latent heat and Sensible heat), the thermal energy for this low temperature heat energy being become higher temperature is transported to condenser 9-2, and heating heat medium water makes its temperature increase; The high heat medium water of temperature enters heat release heat exchanger 4 through 7 part of heating agent waterpipe and heats flue gas, partly enters low plus heat exchanger 11 and adds Condensed water of the heat from steam turbine, heat medium water sends absorption back to again after temperature reduces in heat release heat exchanger 4 and low plus heat exchanger 11 Formula heat pump 9.
The purpose of the present invention is the function using absorption heat pump 9, absorbs thermal energy in flue gas cooling and condensation process and go to add Hot wet desulfurization flue gas and steam turbine condensed water, heat do not have discharge system, and all energy, which do not lose, all have been obtained effectively It utilizes.
Embodiment 2:
Fig. 2 is the schematic diagram of the embodiment of the present invention 2.Referring to Fig. 2, a kind of processing unit of wet desulfurization flue gas, by desulfurizing tower 1, Heat absorbing heat exchanger 2, heat release heat exchanger 4, chimney 5, steam turbine 6, low plus heat exchanger 11, chilled water line 10 and heating agent waterpipe 7 Composition, desulfurizing tower 1, heat absorbing heat exchanger 2, heat release heat exchanger 4 and chimney 5 are connected by flue 3, add absorption heat pump 9, make successively The evaporator 9-1 of absorption heat pump 9 is connect through chilled water line 10 with heat absorbing heat exchanger 2, the condenser 9-2 of absorption heat pump 9 It is connect with heat release heat exchanger 4 and low plus heat exchanger 11 through heating agent waterpipe 7.
As different from Example 1, heat release heat exchanger 4 and low plus heat exchanger 11 are arranged to connect embodiment 2, i.e.,:Through Heating agent waterpipe makes 9 outlet condenser 9-2 of absorption heat pump be connected with 4 import of heat release heat exchanger, heat release heat exchanger 4 export and Low plus 11 import of heat exchanger connection, the outlet of low plus heat exchanger 11 are connect with condenser 9-2 imports.
The heat medium water of high temperature is introduced into heat release heat exchanger 4 after going out condenser 9-2, then enters back into low plus heat exchanger 11, most Return to condenser 9-2 again afterwards.
Above-mentioned heat medium water is introduced into heat release heat exchanger 4 and enters back into low plus heat exchanger 11 series system, is suitable for desulfurization Flue-gas temperature afterwards is higher than the case where condensing water temperature from steam turbine 6;If flue-gas temperature is relatively low, can also be arranged to another Outer series system makes heat medium water be introduced into low plus heat exchanger 11, then into exothermic heat heat exchanger 4.
Other technical characteristics of embodiment 2 are same as Example 1.
Embodiment 3:
Fig. 3 is the schematic diagram of the embodiment of the present invention 3.Referring to Fig. 3, a kind of processing unit of wet desulfurization flue gas, by desulfurizing tower 1, Heat absorbing heat exchanger 2, heat release heat exchanger 4, chimney 5, steam turbine 6, low plus heat exchanger 11, chilled water line 10 and heating agent waterpipe 7 Composition, flue 3 link together desulfurizing tower 1, heat release heat exchanger 4 and chimney 5, add absorption heat pump 9, make absorption heat pump 9 evaporator 9-1 is connect through chilled water line 10 with heat absorbing heat exchanger 2, makes the condenser 9-2 of absorption heat pump 9 through heat medium water Pipeline 7 is connect with heat release heat exchanger 4 and low plus heat exchanger 11.
Desulfurizing tower 1 includes slurries pump 1-2, spray piping 1-1 and tower body 1-3;Heat absorbing heat exchanger 2 be arranged in tower body 1-3 it is outer, On spray piping 1-1 after slurries pump 1-2, it is used for cooling desulfurization slurry.
Heat release heat exchanger 4 and low plus heat exchanger 11 are set as in parallel.
As different from Example 1, the position that heat absorbing heat exchanger 2 is arranged is different with cooled material.In embodiment 3 In, heat absorbing heat exchanger 2 is arranged in outside tower body 1-3, on the spray piping 1-1 behind the outlets slurries pump 1-2, for cooling down desulfurizing tower 1 slurries.Enter in tower body 1-3 under slurries pump 1-2 drivings through 2 low temperature slurries after cooling of heat absorbing heat exchanger and spray, with tower The flue gas flowed in body 1-3 directly carries out heat exchange, so that flue-gas temperature is reduced, water capacity reduces.Spray the slurry in tower body 1-3 Liquid is increased with temperature after flue gas heat exchange, is sent out by slurries pump 1-2 to falling to behind the bottoms tower body 1-3, is exchanged heat into heat absorption again It cools in device 2.
Other technical characteristics are same as Example 1.

Claims (7)

1. a kind of processing unit of wet desulfurization flue gas, by desulfurizing tower(1), heat absorbing heat exchanger(2), heat release heat exchanger(4), chimney (5), flue(3), steam turbine(6), low plus heat exchanger(11), chilled water line(10)With heating agent waterpipe(7)Composition, feature It is:Add absorption heat pump(9), make absorption heat pump(9)Evaporator(9-1)Through chilled water line(10)It exchanges heat with heat absorption Device(2)Connection, makes absorption heat pump(9)Condenser(9-2)Through heating agent waterpipe(7)With heat release heat exchanger(4)With it is low plus change Hot device(11)Connection.
2. a kind of processing unit of wet desulfurization flue gas according to claim 1, it is characterised in that:The heat absorption heat exchange Device(2)It is disposed in desulfurizing tower(1)With heat release heat exchanger(4)Between flue(3)On.
3. a kind of processing unit of wet desulfurization flue gas according to claim 1, it is characterised in that:The desulfurizing tower (1)Including spray piping(1-1), slurries pump(1-2)And tower body(1-3), the heat absorbing heat exchanger(2)It is disposed in tower body (1-3)External, slurries pump(1-2)Spray piping afterwards(1-1)On.
4. a kind of processing unit of wet desulfurization flue gas according to one of claim 1-3, it is characterised in that:Described puts Heat exchanger(4)With low plus heat exchanger(11)It is set as in parallel.
5. a kind of processing unit of wet desulfurization flue gas according to claim 4, it is characterised in that:The condenser(9- 2)Outlet through heating agent waterpipe(7)With heat release heat exchanger(4)With low plus heat exchanger(11)Import connects, condenser(9-2)'s Import is through heating agent waterpipe(7)With heat release heat exchanger(4)With low plus heat exchanger(11)Outlet is connected.
6. a kind of processing unit of wet desulfurization flue gas according to one of claim 1-3, it is characterised in that:Described puts Heat exchanger(4)With low plus heat exchanger(11)It is set as connecting.
7. a kind of processing unit of wet desulfurization flue gas according to claim 6, it is characterised in that:The condenser(9- 2)Outlet and heat release heat exchanger(4)Import is connected, heat release heat exchanger(4)Outlet and low plus heat exchanger(11)Import connects, low to add Heat exchanger(11)Outlet and condenser(9-2)Import connects.
CN201810378651.2A 2018-04-25 2018-04-25 A kind of processing unit of wet desulfurization flue gas Pending CN108413654A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110173710A (en) * 2019-05-07 2019-08-27 西安交通大学 A kind of energy-saving climatic dynamics dynamic regulation device and method for eliminating plume

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4543110A (en) * 1983-07-06 1985-09-24 Kraftwerk Union Aktiengesellschaft Method and plant for reheating flue gases behind a wet flue-gas desulfurization plant
CN103706221A (en) * 2013-12-11 2014-04-09 北京中能诺泰节能环保技术有限责任公司 Method for recycling water from wet desulphurization flue gas and device thereof
CN104235928A (en) * 2013-06-13 2014-12-24 烟台龙源电力技术股份有限公司 Boiler flue gas waste heat heating system
CN106440465A (en) * 2016-08-31 2017-02-22 浙江浙能节能科技有限公司 Energy-saving type thermal power plant flue gas moisture recovering system
CN107401856A (en) * 2016-05-19 2017-11-28 华电电力科学研究院 A kind of energy conserving system and its application method using heat pump heat smoke again
CN107655021A (en) * 2017-10-31 2018-02-02 中国华能集团清洁能源技术研究院有限公司 A kind of method and system using absorption heat pump Mist heat recovering
CN107860153A (en) * 2017-11-15 2018-03-30 中国大唐集团科学技术研究院有限公司西北分公司 A kind of energy-saving and water-saving type coal-burning boiler wet flue gas depth total system and method
CN208124676U (en) * 2018-04-25 2018-11-20 双良节能系统股份有限公司 A kind of processing unit of wet desulfurization flue gas

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4543110A (en) * 1983-07-06 1985-09-24 Kraftwerk Union Aktiengesellschaft Method and plant for reheating flue gases behind a wet flue-gas desulfurization plant
CN104235928A (en) * 2013-06-13 2014-12-24 烟台龙源电力技术股份有限公司 Boiler flue gas waste heat heating system
CN103706221A (en) * 2013-12-11 2014-04-09 北京中能诺泰节能环保技术有限责任公司 Method for recycling water from wet desulphurization flue gas and device thereof
CN107401856A (en) * 2016-05-19 2017-11-28 华电电力科学研究院 A kind of energy conserving system and its application method using heat pump heat smoke again
CN106440465A (en) * 2016-08-31 2017-02-22 浙江浙能节能科技有限公司 Energy-saving type thermal power plant flue gas moisture recovering system
CN107655021A (en) * 2017-10-31 2018-02-02 中国华能集团清洁能源技术研究院有限公司 A kind of method and system using absorption heat pump Mist heat recovering
CN107860153A (en) * 2017-11-15 2018-03-30 中国大唐集团科学技术研究院有限公司西北分公司 A kind of energy-saving and water-saving type coal-burning boiler wet flue gas depth total system and method
CN208124676U (en) * 2018-04-25 2018-11-20 双良节能系统股份有限公司 A kind of processing unit of wet desulfurization flue gas

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110173710A (en) * 2019-05-07 2019-08-27 西安交通大学 A kind of energy-saving climatic dynamics dynamic regulation device and method for eliminating plume
CN110173710B (en) * 2019-05-07 2020-03-31 西安交通大学 Energy-saving type climate feedback dynamic regulation and control device and method for eliminating smoke plume

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